• Title/Summary/Keyword: Separator efficiency

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Durability of Cation Exchange Membrane Containing Psf (polysulfone) in the All-vanadium Redox Flow Battery (Psf (polysulfone) 함유 양이온교환막의 바나듐 레독스-흐름 전지에서의 내구성)

  • Kim, Joeng-Geun;Kim, Jae-Chul;Ryu, Cheol-Hwi;Hwang, Gab-Jin
    • Membrane Journal
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    • v.21 no.2
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    • pp.141-147
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    • 2011
  • The cation exchange membrane using TPA (tungstophosphoric acid) and the block co-polymer of polysulfone and polyphenylenesulfidesulfone was prepared for a separator of all-vanadium redox flow battery. The membrane resistance of the prepared cation exchange membrane in 1mol/L $H_2SO_4$ aqueous solution was measured. The membrane resistance of the prepared Psf-PPSS and Psf-TPA-PPSS cation exchange membrane was about $0.94{\Omega}{\cdot}cm^2$. Electrochemical property of all-vanadium redox flow battery using the prepared cation exchange membrane was measured. The measured charge-discharge cell resistance of V-RFB at 4 A decreased in the order; Nafion117 < Psf-TPA-PPSS < Psf-PPSS. The durability of membrane was earried out by soaking it in $VO_2{^+}$ solution and evaluated by measuring the charge-discharge cell resistance of V-RFB with an increase of soaking time. The prepared Psf-PPSS cation exchange membrane had high durability and Psf-TPA-PPSS cation exchange membrane had almost same durability compared with Nafion117.

Development of Semicontinuous Measurement System of Ionic Species in PM2.5

  • Hong, Sang-Bum;Chang, Won-il;Kang, Chang-Hee;Lee, Jai H.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1505-1515
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    • 2009
  • A new method to semicontinuously determine $PM_{2.5}$ ionic species with a short time resolution is described in detail. In this system, a particle collection section (mixing part, particle collection chamber, and air/liquid separator) was developed. A Y-type connector was used to mix steam and an air sample. The particle collection chamber was constructed in the form of a helix coil and was cooled by a water circulation system. Particle size growth occurred due to the high relative humidity and water absorbed particles were efficiently collected in it. Liquid samples were drained out with a short residence time (0.08-0.1 s). The air/liquid separator was also newly designed to operate efficiently when the flow rate of the air sample was 16.7 L $min^{-1}$. For better performance, the system was optimized for particle collection efficiency with various types of test aerosols such as ($NH_4)_2SO_4,\;NaCl,\;NH_4HSO_4,\;and\;NH_4NO_3$. The particle collection efficiencies were almost 100% at different concentration levels in the range over 500 nm in diameter but 50-90% in the range of 50-500 nm under the following experimental conditions: 15 coil turns, a water flow rate for steam generation of 0.65 mL $min^{-1}$, and an air sample flow rate of 16.7 L $min^{-1}$. Finally, for atmospheric applications, chemical compositions of $PM_{2.5}$ were determined with a time resolution of 20 min on January 11-24, 2006 in Seoul, Korea, and the chemical characteristics of $PM_{2.5}$ ions were investigated.

Design simulation of magnetic separator for purification of silica sand (자력선별방식을 이용한 고순도 실리카 정제 최적화를 위한 전산모사)

  • Choi, Hyun-Jin;Jo, Young Min;Lee, Jun Yub;Kim, Sang Bum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.1
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    • pp.181-187
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    • 2016
  • Silica is an essential material in the electronics industries of LCDs and OLEDs, which particularly require high purity. This study attempted to find the optimal design of a magnetic separator for silica sand containing iron compounds using CFD simulation. Three designs of magnetic separation were prepared and their efficiency was examined. As a result of the evaluation, the sufficient contact of particulate silica with the surface of magnetic emitters improved the magnetic separation effects. In addition, the loss of $SiO_2$ and the removal rate of $Fe_2O_3$ depended strongly on the particle size, flow rate and magnetic flux density. In addition, magnetic separation is quite effective for a particle size of $10{\mu}m$ with a 0.2 m/s flow rate.

Temperature Effect of the UASB Process for Treatment of Organic Waste (상향류식 혐기성 입상슬러지 공법의 유기폐수 처리 효율에 미치는 온도의 영향)

  • Park, Chul Hwi;Chung, Tai Hak
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.4
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    • pp.45-54
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    • 1996
  • Effects of temperature on the efficiency of the Upflow Anaerobic Sludge Blanket(UASB) process for treatment of wastewater from a starch and related products manufacturing industry were investigated using laboratory scale reactors equipped with two types of Gas-Solid Separator(GSS). Both fresh digested sludge and granular sludge stored nearly for one year at room temperature were good as a seeding material. The reactors seeded with aged granular sludge showed slow start-up, however, lowered activity at the initial period was recovered gradually. The GSS with an inner cylinder was proved to be effective in liquid-solid separation compared to the conventional type. Although the rate of organic removal and gas production per unit volatile suspended solids in the reactor reduced significantly as the temperature varied from 35 to $20^{\circ}C$, possibility of operation at low temperatures was shown as a result of gradual buildup of volatile suspended solids in the bed. Stable operation with a reduced efficiency was possible at a COD loading of $5-8kg/m^3/day$ at a temperature as low as $20^{\circ}C$.

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Optimum Design of Animal Wastewater Treatment System (畜産廢水處理시스템의 最適說計要因 導出)

  • Oh, In-Hwan;Park, Joeng-Hyun;Kim, Beom-Seok;Lee, Sang-Rak;Maeng, Won-Jae
    • Journal of Animal Environmental Science
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    • v.1 no.1
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    • pp.47-53
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    • 1995
  • An efficient Treatment of animal wastewater is one of the hot issues for preventing the environmental pollution. It should be established the design parameter in order to purify the animal wastewater. A test is carried on in the pilot plant as a simplified activated sludge process. A vibration sieve separator is deviced to keep the pollution load constant by means of separation of solid matter. The BOD removal efficiency of the vibration sieve showed over 50%. As the test results, the BOD contents of the influent was in average of 3,000 mg/I and that of the effluent 85 mg/I. So, the BOD removal rate showed 97% in average. The SS-contents in the primary chamber was about 3,300 mg/I and that of effluent 92 mg/I. The SS removal efficiency showed 97%. The removal rate of total nitrogen and phosphore were in average of 82% respectively. Carrying out in winter season, it showed relatively good results; The design parameter approved in this test can be applied to the full-time farmers.

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Study on the Development and Verification of Dry Manufacturing Technology for improving Quality of Recycled Fine Aggregate (순환잔골재 품질개선을 위한 건식생산기술의 개발 및 검증에 관한 연구)

  • Na, Chul-Sung;Choi, Hyeong-Gil;Kim, Young-Duck;Kwon, Soo-Kil;Kim, Gyu-Yong;Kim, Moo-Han
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.469-472
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    • 2008
  • As recycled fine aggregate manufacturing technology with exceeding in economical efficiency, reduction efficiency of environmental load and quality improvement effect of recycled fine aggregate, it is to develop dry manufacturing system composed specific gravity separator of high-speed rotation impact type and centrifugal Force Powder Collector, etc. in this study. And it is to verify performance with evaluating quality of recycled fine aggregate. In consequence, it is identify that performance improvement effect of recycled fine aggregate by crushing recycled fine aggregate according to high-speed rotation impact, separating and collecting powder and minuteness dust according to centrifugal Force and mass defect, separating and reclaiming minuteness sand to mass defect.

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Simulation of a geothermal power generation system using the Kalina cycle (칼리나 사이클을 이용한 지열발전 시스템의 시뮬레이션)

  • Chang, Ki-Chang;Baik, Young-Jin;Kim, Min-Sung;Lee, Young-Soo;Park, Seong-Ryong;Ra, Ho-Sang
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.626-629
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    • 2008
  • In this study, a geothermal power generation system using the Kalina cycle was investigated by the simulation method. The Kalina cycle system can be used for the utilization of a low-temperature heat sources such as geothermal and industrial waste heat that are not hot enough to produce steam. The sea/river water can be considered as a cooling media. A steady-state simulation model was developed to analyze and optimize its performance. The model contains a turbine, a pump, an expansion valve and heat exchangers. The turbine and pump were modelled by an isentropic efficiency, while a condenser, an evaporator and a regenerative heat exchanger were modeled by UA-LMTD method with a counter-flow assumption. The effect of the ammonia fraction at the separator inlet on the cycle performance is investigated in detail.

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A Hydraulic and Feasibility Study of New Tower Internal in Gas Processing Plants

  • Choo Chang-upp
    • International Journal of Safety
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    • v.3 no.1
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    • pp.15-19
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    • 2004
  • A new tower internal, which is called CSE, is presented. The CSE is composed of a nozzle perforated in its bottom along the entire periphery and equipped with a multi vane axial swirler at the inlet and hollow cylindrical separator at the outlet of the nozzle. According to the experimental work for obtaining the necessary hydraulic information of the CSE, which is used for preliminary design of a separation column, the CSE showed a stable operation over the wide rage of gas/liquid ratio. However, it caused large pressure drop due to the high gas velocity which should carry liquid droplets through the element. The high pressure drop may cause problems in energy recovery and the application of the CSE can be limited to the high pressure columns. Assuming that the tray efficiency of the CSE is the same with the existing separation columns, the results of the column design showed the size reduction of the column diameters by 30 to $40\%$ and investment cost saving, depending on operating conditions. The application of the CSE to separation column may also contribute to the de-bottlenecking the existing column.

Improved Copper Ion Recovery Efficiency through Surface Modification of Membranes in the Electrodialysis/Solvent Extraction Process (전기투석/용매추출 공정에서 멤브레인 표면 개질을 통한 구리 이온의 회수 효율 향상)

  • Joongwon, Park;Rina, Kim;Hyunju, Lee;Min-seuk, Kim;Hiesang, Sohn
    • Membrane Journal
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    • v.32 no.6
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    • pp.486-495
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    • 2022
  • This study presents the improved recovery efficiency of rare metal ions through the modified separation membrane wettability and hydrogen ion permeation in the anion exchange membrane (AEM) under the recovery process of combined electrodialysis and solvent extraction. Specifically, the wettability of the separator was enhanced by hydrophilic modification on one separator surface through polydopamine (PDA) and lipophilic modification on the other surface through SiO2 or graphene oxide (GO). In addition, the modified surface of AEM with polyethyleneimine (PEI), PDA, poly(vinylidene fluoride) (PVDF), etc. reduces the water uptake and modify the pore structure for proton ions generation. The suppressed transport resulted in the reduced hydrogen ion permeation. In the characterization, the surface morphology, chemical properties and composition of membrane or AEM were analyzed with Scanning Electron Microscopy (SEM) and Fourier Transform-Infrared Spectroscopy (FT-IR). Based on the analyses, improved extraction and stripping and hydrogen ion transport inhibition were demonstrated for the copper ion recovery system.