• Title/Summary/Keyword: Separation time

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Structure of a single polymer chain confined in a dense array of nanoposts

  • Joo, Heesun;Kim, Jun soo
    • Proceeding of EDISON Challenge
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    • 2015.03a
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    • pp.48-52
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    • 2015
  • Control of polymer conformations in heterogeneous confinement plays an important role in natural and engineering processes. We present a simulation study on the conformational structure and dynamics of a single, flexible polymer in a dense array of nanoposts with different sizes and separations, especially, when the volume of the interstitial space formed between four nanoposts is less than the size of the polymer chain. When a polymer is placed in the array of nanoposts, the size of polymer increases compared with that in the absence of nanoposts due to the confinement effect. It is shown that when a polymer is confined in the array of nanoposts the chain is elongated in the direction parallel to the nanoposts. As the interstitial volume between four nanoposts decreases either by increasing the nanopost diameter or by decreasing the separation between nanoposts, the chain elongation becomes more pronounced. On the contrary, the polymer size varies in a non-monotonic fashion, with an initial elongation followed by a chain contraction, as the interstitial volume is reduced both by increasing the nanopost diameter and decreasing the separation at the same time while keeping constant the width of the passageway between two nanoposts. The simulation analysis shows that the non-monotonic dependence of polymer size is determined by interplay between the chain alignment along the nanoposts in each interstitial volume and the chain spreading through passageways over several interstitial volume.

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"Buildings Without Walls:" A Tectonic Case for Two "First" Skyscrapers

  • Leslie, Thomas
    • International Journal of High-Rise Buildings
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    • v.9 no.1
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    • pp.53-60
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    • 2020
  • "A practical architect might not unnaturally conceive the idea of erecting a vast edifice whose frame should be entirely of iron, and clothing the frame--preserving it--by means of a casing of stone…that shell must be regarded only as an envelope, having no function other than supporting itself..." --Viollet-le-Duc, 1868. Viollet-le-Duc's recipe for an encased iron frame foresaw the separation of structural and enclosing functions into discrete systems. This separation is an essential characteristic of skyscrapers today, but at the time of his writing cast iron's brittle nature meant that iron frames could not, on their own, resist lateral forces in tall structures. Instead, tall buildings had to be braced with masonry shear walls, which often also served as environmental enclosure. The commercial availability of steel after the 1880s allowed for self-braced metal frames while parallel advances in glass and terra cotta allowed exterior walls to achieve vanishingly thin proportions. Two Chicago buildings by D.H. Burnham & Co. were the first to match a frame "entirely of iron" with an "envelope" supporting only itself. The Reliance Building (1895) was the first of these, but the Fisher Building (1896) more fully exploited this new constructive typology, eschewing brick entirely, to become the first "building without walls," a break with millennia of tall construction reliant upon masonry

Effects of ballasting Agent (Microsand) on Physical Floc Characteristics (세사 투입에 따라 형성된 플럭의 물리적 특성)

  • Ryu, Jae-Na;Lim, Yoon-Dae;Oh, Je-Ill
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.5
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    • pp.485-493
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    • 2010
  • Chemical coagulation destabilizes colloidal particles so that particles grow to larger flocs. Solid particles are then removed by solid-liquid separation after typical precipitation. Rapid precipitation enhances the separation by reducing the precipitation time with larger and denser particles. Conventionally, polyelectolyte compounds (polymers) function as a flocculant aid by introducing a interparticle binding, which increases the particle size and density. And more recent ballasted flocculation adds a ballasting agent (microsand) to form denser particles with its high-density(sp gr=2.65). The current research was to evaluate the manner in which ballasted flocs are formed under different injection timings of microsand and to recognize the effects on floc formation. $FeCl_3$ as a coagulant, anionic polymer for a flocculation aid and microsand were used for the floc formation. Floc size (diameter) was widely ranged with the highest mean value when microsand was injected between $FeCl_3$ and polymer. Mean floc density was larger when the floc formed smaller. Settling velocity increased with larger floc size, whilst not significantly affected by the timing of microsand injection. The additional slow mixing on floc formation increased floc size to some extent.

A Rapid Method of Ginsenoside Analysis in HPLC by Pretreatment through the reverse-phase minicolumn (역상소형컬럼 전처리를 이용한 Ginsenoside의 신속정량법)

  • Lee, Mee-Kyoung;Lim, Sun-Uk;Park, Hoon
    • Journal of Ginseng Research
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    • v.12 no.2
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    • pp.164-172
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    • 1988
  • The solvent separation step in the conventional method for quantitative analysis of ginsenosides was substituted by purification through a small reverse-phase $C_18$-column resulting in the decrease of analysis time by one fourth. New method showed high recovery of total ginsenosides but low recovery in protopanaxatriol-ginsenosides. Sugars did not affect the recovery by the amount in usual root sample. Coefficient of variation in recovery of ginsenosides was lower in the rapid minicolumn method. Optimum load of ginsenosides to minicolumn was 10 to 15 mg. The rapid minicolumn method showed highly significant correlation with the solvent separation method for dried root and red ginseng. For the rapid minicolumn method a small acryl device was used for the simultaneous extraction of 8 samples. This method appeared to be beneficial in cost and for the health of analyst.

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Functional Properties of $\alpha$-Lactalbumin Separated from Bovine Whey (우우 유청으로부터 분리한 $\alpha$-락트알부민의 기능적 특성)

  • 홍윤호
    • Food Science of Animal Resources
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    • v.18 no.1
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    • pp.9-18
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    • 1998
  • This study was performed to obtain a large quantity of $\alpha$-lactalbumin ($\alpha$-LA) from milk by an improved separation and purification method. Functional properties-solubility viscosity, emulsifying activity, foamability surface hydrophobicity and gelation-of the purified $\alpha$-LA were investigated, $\alpha$-LA was purified in a large quantity by DEAE-Sephacel chromatography using 0.15M NaCl in 20mM Tris-HCl buffer(pH 7.2), as an eluent. The yield and purity of the purified $\alpha$-LA were 23.6%, 92.5%, respect-ively. The solubility viscosity and emulsifying activity of the purified $\alpha$-LA were 92.2$\pm$2% 3.46$\pm$0.19 cP and 345$\pm$5.0m^2$-/g respecively. The foamability of $\alpha$ -LA was 762 after 5min whipping which was lower than that of WPC and showed decreasing tendency with whipping time. The relative surface hydrophobicity of the $\alpha$-LA was formed when a 10% $\alpha$-LA solution containing 100mM NaCl and 20 mM $CaCl_2$ was heated at 92$^{\circ}C$for 40min. The $\alpha$-LA gel showed 31.5 as hardness and showed low springiness and cohesiveness.

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A Study about the Separation of the materials Used in Refractory Cast Dies For Making All Ceramic Crowns (전부 주조관 제작을 위한 내화모형재 분리에 관한 연구)

  • Shin, Moo-Hak;Kim, Yeoun-Soo;Choi, Un-Jea
    • Journal of Technologic Dentistry
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    • v.21 no.1
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    • pp.123-130
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    • 1999
  • I attempted to suggest a better method to separate a refractory cast in order to solve the problems caused by bonding between refractory casts and ceramics in the firing-processing of all ceramic crowns as a part of dental prosthodontics. I emphasize the advantages and effectiveness of easy separation after firing by using the separating materials about the refractory cast dies. 1. We must not usse HF(55%) that is used as the chemical separating methods. 2. We decrease such methods as grinding, blasting, bur, and point 3. We can save time, costs and manual labors by using this methods. 4. This method regulates the expansion and constriction of heat because of the chemical reaction of the separating materials. 5. This method contribute to the breaking down without modification by minimizing the chemical and mechanical damages of the marginal and interior parts.

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A Study on Flow and Creation and Dissipation of Vorticity around Rectangular Floating Breakwater (부방파제의 유동과 와의 생성 및 소멸에 관한 연구)

  • Yoon, Jung-Sung;Kim, Myoung-Kyu;Jung, Kwang-Hyo;Kim, Ga-Ya
    • Journal of Ocean Engineering and Technology
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    • v.22 no.3
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    • pp.24-33
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    • 2008
  • In this study, flow and creation and dissipation of vorticity around rectangular floating breakwater is investigated both experimentally and numerically. The PIV system(Particle image velocimetry) is employed to obtain the velocity field in the vorticity of rectangular structure. The numerical model, combined with ${\kappa}-{\varepsilon}$ turbulence model and the VOF method based on RANS equation, is used to analyze the turbulence structure. In the results of this study, the vorticity is found around conner of rectangular structure at all time domain, and creation and dissipation of vorticity are closely related to wave period. Separation points of phase of vortex due to flow separation for longer period waves are faster then for shorter period waves.

Assessment of Earth Remote Sensing Microsatellite Power Subsystem Capability during Detumbling and Nominal Modes

  • Zahran M.;Okasha M.;Ivanova Galina A.
    • Journal of Power Electronics
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    • v.6 no.1
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    • pp.18-28
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    • 2006
  • The Electric Power Subsystem (EPS) is one of the most critical systems on any satellite because nearly every subsystem requires power. This makes the choice of power systems the most important task facing satellite designers. The main purpose of the Satellite EPS is to provide continuous, regulated and conditioned power to all the satellite subsystems. It has to withstand radiation, thermal cycling and vacuums in hostile space environments, as well as subsystem degradation over time. The EPS power characteristics are determined by both the parameters of the system itself and by the satellite orbit. After satellite separation from the launch vehicle (LV) to its orbit, in almost all situations, the satellite subsystems (attitude determination and control, communication and onboard computer and data handling (OBC&DH)), take their needed power from a storage battery (SB) and solar arrays (SA) besides the consumed power in the EPS management device. At this point (separation point, detumbling mode), the satellite's angular motion is high and the orientation of the solar arrays, with respect to the Sun, will change in a non-uniform way, so the amount of power generated by the solar arrays will be affected. The objective of this research is to select satellite EPS component types, to estimate solar array illumination parameters and to determine the efficiency of solar arrays during both detumbling and normal operation modes.

A Parametric Study on Rupture Disc with Radial Slit of Pulse Separation Device (원주방향 슬릿을 가진 파열판의 매개변수 연구)

  • Han, Houk-Seop;Cho, Won-Man;Lee, Won-Bok;Koo, Song-Hoe;Lee, Bang-Eop
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.261-264
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    • 2010
  • Dual Pulse Rocket Motor is a solid rocket motor with two grains separated by a bulkhead and rupture disc. The elasto-plastic explicit dynamic analysis of rupture disc was conducted by the finite element method. The effect of the slit geometry of rupture disc with radial slit was parametrically analyzed in terms of rupture time and shape. The results can be used to control the rupture pressure by changing the slit geometry of rupture disc.

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Capillary Electrochromatography with Liquid Crystal Crown Ether Modified Hybrid Silica Monolith for Analysis of Imidacloprid and Carbendazim in Tomatoes

  • Wang, Mingming;Feng, Rui;Shen, Jing;Chen, Hao;Zeng, Zhaorui
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2224-2228
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    • 2012
  • This study describes the ability of capillary electrochromatography (CEC) for the determination of imidacloprid and carbendazim in tomato samples. A novel liquid crystal crown ether modified hybrid silica monolithic column was synthesized, characterized and developed as separation column for the first time. Baseline separation of imidacloprid and carbendazim could be achieved using a mobile phase containing 90% (v/v) 20 mmol/L phosphate buffer (pH 7.0) and 10% (v/v) acetonitrile. The matrix matched calibration curves were linear with correlation coefficient $r^2$ > 0.9998 in the range of 0.20-10.00 mg/L. The limits of detection for imidacloprid and carbendazim were 0.061 and 0.15 mg/kg, respectively, which were below the maximum residue limits established by the European Union as well as Codex Alimentarius. Average recoveries for imidacloprid and carbendazim varied from 101.6-108.0% with relative standard deviations lower than 6.3%. This method was applied to the analysis of tomatoes collected from local markets.