• Macromolecular Research
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• 제15권6호
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• pp.565-574
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• 2007

In this study, five representative, commercially available polymers, Ultem 1000 polyetherimide, Kapton polyimide, phenolic resin, polyacrylonitrile and cellulose acetate, were used to prepare pyrolyzed polymer membranes coated on a porous {\alpha}-alumina$ tube via inert pyrolysis for gas separation. Pyrolysis conditions (i.e., final temperature and thermal dwell time) of each polymer were determined using a thermogravimetric method coupled with real-time mass spectroscopy. The surface area and pore size distribution of the pyrolyzed materials derived from the polymers were estimated from the nitrogen adsorption/desorption isotherms. Pyrolyzed membranes from polymer precursors exhibited type I sorption behavior except cellulose acetate (type IV). The gas permeation of the carbon/{\alpha}-alumina$ tubular membranes was characterized using four gases: helium, carbon dioxide, oxygen and nitrogen. The polyetherimide, polyimide, and phenolic resin pyrolyzed polymer membranes showed typical molecular sieving gas permeation behavior, while membranes from polyacrylonitrile and cellulose acetate exhibited intermediate behavior between Knudsen diffusion and molecular sieving. Pyrolyzed membranes with molecular sieving behavior (e.g., polyetherimide, polyimide, and phenolic resin) had a $CO_2/N_2$ selectivity of greater than 15; however, the membranes from polyacrylonitrile and cellulose acetate with intermediate gas transport behavior had a selectivity slightly greater than unity due to their large pore size.

• Plant Resources
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• 제6권1호
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• pp.81-88
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• 2003

Higenamine [1-(4-hydroxy-6, 7-dihydroxy-l, 2, 3, 4-tetrahydroisoquinoline) is a cardiotonic constituent of Aconiti tuber, one of the most widely prescribed oriental medicines. S-(-)higenamine was reported to have a stronger cardiotonic activity than R-(+)-higenamine and known as a central intermediate in the biosynthesis of various benzyl isoquionoline alkaloids in plants. The separation of higenamine enantiomers has been accomplished with capillary electrophoresis using cyclodextrins (CDs) as chiral selectors. Good resolution of this enantiomers was obtained using a 50 mM sodium phosphate buffer containing hydroxypropyl $\beta$-CDs using 27 cm fused silica capillary (50${\mu}{\textrm}{m}$ i.d., 20 cm to detector) at 25 $^{\circ}C$. With the electric field of 340 V/cm, the separation time of higenamine enantiomers was less than 6 min. Under this optimum conditions, the relative standard deviations of migration time and peak area were less than 1.6% and 3.2%. A 512-channel diode array detector was confirmed for the higenamine. The detection limits (S/N = 3) of these enantiomers are $1.5mutextrm{m}$/mL. We confirmed the chiral form of higenamine in medicinal plants.

• Wind and Structures
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• 제20권2호
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• pp.169-189
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• 2015

To investigate the effects of "sudden change" of wind fluctuations on vehicle running performance, which is caused by the artificial discrete simulation of wind field, a three-dimensional vehicle model is set up with multi-body dynamics theory and the vehicle dynamic responses in crosswind conditions are obtained in time domain. Based on Hilbert Huang Transform, the effects of simulation separations on time-frequency characteristics of wind field are discussed. In addition, the probability density distribution of "sudden change" of wind fluctuations is displayed, addressing the effects of simulation separation, mean wind speed and vehicle speed on the "sudden change" of wind fluctuations. The "sudden change" of vehicle dynamic responses, which is due to the discontinuity of wind fluctuations on moving vehicle, is also analyzed. With Principal Component Analysis, the comprehensive evaluation of vehicle running performance in crosswind conditions at different simulation separations of wind field is investigated. The results demonstrate that the artificial discrete simulation of wind field often causes "sudden change" in the wind fluctuations and the corresponding vehicle dynamic responses are noticeably affected. It provides a theoretical foundation for the choice of a suitable simulation separation of wind field in engineering application.

• 대한기계학회논문집
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• 제18권4호
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• pp.933-945
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• 1994

A shock-wave in a supersonic flow can be theoretically determined by a given pressure ratio at upstream and downstream flowfields, and then the obtained shock-wave is stable in its position. Under the practical situation in which the shock-wave interacts with the boundary layer along a solid wall, it cannot, however, be stable even for the given pressure ratio being independent of time and oscillates around a time-mean position. In the present study, oscillations of a weak normal shock-wave in a supersonic diffuser were measured by a Line Image Sensor(LIS), and they were compared with the data of the wall pressure fluctuations at the foot of the shock-wave interacting with the wall boundary layer. LIS was incorporated into a conventional schlieren optical system and its signal, instantaneous displacement of the interacting shock-wave, was analyzed by a statistical method. The results show that the displacement of an oscillating shock-wave increase with the upstream Mach number and the dominant frequency components of the oscillating shock-wave are below 200 Hz. Measurements indicated that shock-wave oscillations may not entirely be caused by the boundary layer separation. The statistical properties of oscillations appeared, however, to be significantly affected by shock-induced separation of turbulent boundary layer.

• Korean Chemical Engineering Research
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• 제55권4호
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• pp.503-509
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• 2017

The present experimental study proposed two ionic liquids (ILs) namely [Aliquat 336] [$HSO_4$] (prepared and characterized at our laboratory) and Cyphos 101 IL (supplied by Cytec Company) dissolved in two different diluents such as DCM (di-chloro-methane) and toluene applied for PMs extraction. The first IL [Aliquat 336] [$HSO_4$] prepared and confirmed the formation of final product by using FT-IR and TGA studies. The primary experiment in solvent extraction processing is kinetic effect; 0 to 30 time varied for PMs by using two ILs and confirmed the optimized extraction equilibrium time. This study was conducted for PMs (Pt, Rh and Cu) extraction and separation from each other by using proposed ILs. This is the primary study of the utilizing green solvents such as ILs as an extractant system for Pt, Rh and Cu extraction and possible separation.

• Korean Membrane Journal
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• 제1권1호
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• pp.65-72
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• 1999

The surface of polypropylene membrane was modified by plasma treatment using Ar,$N_{2}$, $NH_{2}$ and $O_{2}$ Permeabilities for $CO_{2}$, $N_{2}$ and separation factor for $CO_{2}$ relative to $N_{2}$ were measured. The permeation experiments were performed by a variable volume method at $25^{\circ}C$ and 0.303MPa. The effects of the plasma conditions such as treatement time power input gas flow rate and pressure in the reactor on the transport properties of modified membrane were investigated. The surface of the plasma treated membrane was analyzed by means of FTIR-ATR XPS and AFM. The surface structure of the plasma treated membrane was fairly different from that of the untreated membrane. Although the permeation rates for both $CO_{2}$ and $N_{2}$ decreased with increasing plasma treatement time the separation factor was found to be improved by the plasma treatement. The operating conditions of plasma treatement imposed on membranes had notable effect on the permeability and separation factor.

• Bulletin of the Korean Chemical Society
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• 제24권7호
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• pp.943-947
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• 2003

We have studied the migration behavior of single-stranded DNA using capillary gel electrophoresis under various conditions. It was found that optimum electric fields should be less than 150 V/cm for the good tradeoff between the separation time and the resolution. It seems that the gel matrix with the combination of different polymer average molecular weights is important to extend the maximum readable DNA bases. The total gel concentration less than 3.1% in the mixed gel system showed good separation efficiency up to 600 bases. The best result was obtained with the poy(ethylene)oxide (PEO) gel concentration of 1.2% of Mr 8,000,000 and 1.8% of Mr 600,000. We observed that the capillary length between 50 cm to 100 cm (effective length) should be employed for the optimization between the total DNA migration time and the maximum readable length. A trizma base-boric acid-ethlyenediaminetetraacetic acid (EDTA) (TBE) buffer was commonly used for DNA sequencing, but we found that 3-[tris(hydroxymethyl)methyl amino]-1-propane sulfonic acid (TAPS) buffer worked as well for the single-stranded DNA separation. Especially, TAPS buffer showed a good resolution for very short DNA bases (1 to 30 bases).

• 한국재료학회지
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• 제34권5호
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• pp.247-253
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• 2024

The separation of zirconium and hafnium using tributyl phosphate (TBP)-Dodecane extractants in nitric acid medium was performed. Zirconium oxychloride, used as extraction feed, was obtained from the synthesis of Kalimantan zircon sand concentrate smelted using NaOH. The extraction process was carried out by dissolving chloride-based metals in nitric acid media in the presence of sodium nitrate using TBP-Dodecane as an extractant. Some of the extraction parameters carried out in this study include variations in organic phase and aqueous phase (O/A), variations in contact time, and variations in nitric acid concentration. Extraction was carried out using a mechanical shaker according to the parameter conditions. X-ray fluorescence (XRF) was used for elemental (Zr and Hf) composition analysis of the aqueous solution. The results showed that zirconium was separated from hafnium at optimum conditions with an organic/aqueous ratio of 1:5, contact time of 75 min, and an HNO₃ concentration of 7 M. The resulting separation factor of zirconium and hafnium using TBP-Dodecane was 14.4887.

• 방송공학회논문지
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• 제21권2호
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• pp.169-179
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• 2016

오늘날 UHDTV (Ultra-High-Definition TV) 시대에 사용될 멀티미디어 부호화기로 MPEG-H에 대한 표준화가 진행되고 있다. 향후 방송용 오디오 콘텐츠는 채널 기반 오디오 콘텐츠에서 진화하여 객체 기반 오디오 콘텐츠까지도 포함하게 될 예정이다. 이에 따라, 채널 기반 오디오 콘텐츠의 객체 기반 오디오 콘텐츠로의 유기적인 변환이 필요한 실정이다. 본 논문에서는 이러한 유기적인 변환을 실현 가능하게 할 수 있는 비균등 선형 마이크로폰 어레이 기반의 음원분리 기법을 제안한다. 제안된 기법은 주어진 어레이 배치에 따라 채널간의 시간차를 분석하고, 분석된 시간차에 따라 주파수별로 특정 방위각에 위치한 입력 오디오 신호의 spectral magnitude를 예측한다. 이후, azimuth와 width 파라메타를 조정함으로써 객체 오디오 생성을 위한 음원을 분리한다. 제안된 음원분리 기법의 성능을 평가하기 위하여 객관적 음원분리 지표 및 분리정확도를 측정하였고, 최소 분산 무손실 응답 빔형성기와 독립 성분 분석 기법 등 기존 음원분리 기법과의 그 성능을 비교하였다. 비교 결과, 제안된 기법이 기존 음원분리 기법들에 비하여 우수한 음원분리 성능을 보이는 것을 알 수 있었다.

• Child Health Nursing Research
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• 제6권2호
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• pp.158-166
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• 2000

The purpose of this study was to confirm the efficient umbilical cord care of healthy newborns in nursery. In order to determine the efficient care, the time of umbilical cord separation and the skin condition of periumbilical area were evaluated. The data were collected in sample of 529 normal, healthy newborns of C hospital in Seoul, from September 1st, 1999 to January 16th, 2000. The babies were randomly selected and allocated into four groups-alcohol swab/tub bath, alcohol swab/partial bath, natural dry/tub bath, natural dry/partial bath- by the methods of care. The mothers of babies were also surveyed by questionnaire about general characteristics. The data were analyzed by SAS program. The results of this study were as follows : 1. The average gestation period of newborns was 39+3 weeks. The average birth weight was 3.27Kg. In gender of babies, boys were 51.7% and girls were 48.3%. The 65% of newborns were born normal vaginal delivery, 35% were C-section. The feeding methods were 55.3% of the babies fed by mixed type, 22.9% by breast, and 21.8% by bottle. There was no significance among four groups by general characteristics. 2. The average time of umbilical cord separation was 8.27 days(SD=2.3). The time was no difference significantly among four groups(F=1.68, P=0.17). 3. The prevalence of the umbilical care complication did not show differences among four groups( 2=3.93, P=0.27). In conclusion, Nurses have preferred the traditional alcohol swab/partial bath method in care of newborns. But there was no difference among the ways to take care of umbilicus according to this study. The way to naturally is more efficient due to reduce the time and expense in umbilical care for normal babies of nursery. This also matched the change in approach to healthy population from intervention to nonintervention way. This could be suggested in education for normal and healthy babies care at home and nursery as a useful way. Endly, the further study about bacterial colony nda infection rate at umbilicus by ways of care is needed.