• Title/Summary/Keyword: Separation time

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Study on the Pervaporation Characteristic of Water-alcohol Mixtures through Aromatic Polyetherimide Membranes : II. the Pervaporation of Water-isopropanol Mixtures by the Density Change of Skin Layer (방향계 폴리에테르이미드막의 물-알콜 혼합액의 투과증발 특성에 관한 연구 : II.skin layer의 density변화에 의한 물-이소프로판올 혼합액의 투과증발)

  • Kim, S.G.;Jegal, J.G.;Lee, K.H.
    • Applied Chemistry for Engineering
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    • v.8 no.5
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    • pp.853-859
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    • 1997
  • For asymmetric polyetherimide membranes having a dense layer gradient structure on the skin layer, the morphology change and pervaporation behaviors of water/isopropanol mixture through chemical modification of dense skin layer were investigated. The extent of the density was controlled by the evaporation, time, and when the evaporation time was increased from 0 min to 4 min, the permeation flux was decreased, the separation factor was increased. Also, the pervaporation behaviors of the polyetherimide membranes modified with sodium hydroxide solution, as the modification time of dense skin layer increased, the selectivity increased, and the permeation flux decreased. The morphology change identified by SEM shows that the density of dense skin layer tends to increase with increasing modification time, this result is consistent with above observations.

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Microporous Polystyrene Membranes Produced via Thermally Induced Phase Separation (열적으로 유도된 상 분리에 의해 제조된 폴리스티렌 미세 다공성 막)

  • Song, Seung-Won;Torkelson, John M.
    • Membrane Journal
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    • v.5 no.3
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    • pp.119-128
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    • 1995
  • The effects of coarsening on microstructure formation in polystyrene-cyclohexane solutions and membranes made from them were studied by scanning electron miccoscopy(SEM). Thermal analysis of the polymer solutions was carried out with a differential scanning calorimeter and the binodal curve was determined from the onset temperature of the heat of demixing peak. Using thermally induced phase separation(TIPS) and a freeze drying technique, it was demonstrated that polymer membrane microstructure can be changed significantly by controlling coarsening time and quench route. For systems undergoing phase separation by spinodal decomposition, resulting in a well interconnecmd, microporous structure with nearly uniform pore sizes, it was found that extending the phase separation time prior m freezing and solvent removal can result in a significant increase in pore or cell size which is highly dependent on both quench depth and coarsening time. Also this study has revealed the important role of polymer concentration in dictating the material continuity of the membranes.

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Pervaporation Separation of Water-isopropanol Mixtures through Modified Asymmetric Polyetherimide Membrane: the Effect of NaOH Concentration and Modification Reaction Times on the Morphology of the Morphology of the Modified Membranes (개질 비대칭 폴리에테르이미드막을 통한 물-이소프로판올 혼합물 투과증발 분리: NaOH용액의 농도와 개질반응 시간에 따른 몰폴로지 변화)

  • Kim, Sang-Gyun;Jegal, Jonggeon;Lee, Kew-Ho
    • Applied Chemistry for Engineering
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    • v.10 no.4
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    • pp.515-522
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    • 1999
  • Asymmetric polyetherimide membrane were prepared by phase inversion method, and the effects of NaOH concentration and reaction time on the morphology change of the polyetherimide membranes were studied. The morphology of skin layers varied from dense structure to sphere structure with increasing concentration of modification solution. The thickness of dense layer increased with increasing reaction time. However, when either the concentration of modifying solution was very high or the reaction time was very long, the dense layers of the asymmetric membrane were disappeared. From these results, it was found that the surface morphology of the asymmetric polyetherimide membranes depended strongly on the modification conditions such as concentration of modification solution and reaction time. These results might be explained by the hydrolysis reaction of polyetherimide into polyamic acid by the NaOH solution.

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Blind Source Separation of Instantaneous Mixture of Delayed Sources Using High-Order Taylor Approximation

  • Zhao, Wei;Yuan, Zhigang;Shen, Yuehong;Cao, Yufan;Wei, Yimin;Xu, Pengcheng;Jian, Wei
    • ETRI Journal
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    • v.37 no.4
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    • pp.727-735
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    • 2015
  • This paper deals with the problem of blind source separation (BSS), where observed signals are a mixture of delayed sources. In reference to a previous work, when the delay time is small such that the first-order Taylor approximation holds, delayed observations are transformed into an instantaneous mixture of original sources and their derivatives, for which an extended second-order blind identification (SOBI) approach is used to recover sources. Inspired by the results of this previous work, we propose to generalize its first-order Taylor approximation to suit higher-order approximations in the case of a large delay time based on a similar version of its extended SOBI. Compared to SOBI and its extended version for a first-order Taylor approximation, our method is more efficient in terms of separation quality when the delay time is large. Simulation results verify the performance of our approach under different time delays and signal-to-noise ratio conditions, respectively.

Fabrication and Simulation of Fluid Wing Structure for Microfluidic Blood Plasma Separation

  • Choe, Jeongun;Park, Jiyun;Lee, Jihye;Yeo, Jong-Souk
    • Applied Science and Convergence Technology
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    • v.24 no.5
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    • pp.196-202
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    • 2015
  • Human blood consists of 55% of plasma and 45% of blood cells such as white blood cell (WBC) and red blood cell (RBC). In plasma, there are many kinds of promising biomarkers, which can be used for the diagnosis of various diseases and biological analysis. For diagnostic tools such as a lab-on-a-chip (LOC), blood plasma separation is a fundamental step for accomplishing a high performance in the detection of a disease. Highly efficient separators can increase the sensitivity and selectivity of biosensors and reduce diagnostic time. In order to achieve a higher yield in blood plasma separation, we propose a novel fluid wing structure that is optimized by COMSOL simulations by varying the fluidic channel width and the angle of the bifurcation. The fluid wing structure is inspired by the inertial particle separator system in helicopters where sand particles are prevented from following the air flow to an engine. The structure is ameliorated in order to satisfy biological and fluidic requirements at the micro scale to achieve high plasma yield and separation efficiency. In this study, we fabricated the fluid wing structure for the efficient microfluidic blood plasma separation. The high plasma yield of 67% is achieved with a channel width of $20{\mu}m$ in the fabricated fluidic chip and the result was not affected by the angle of the bifurcation.

Separation of Burnup Monitors in Spent Nuclear Fuel Samples by Liquid Chromatography

  • Joe, Kih-Soo;Jeon, Young-Shin;Kim, Jung-Suck;Han, Sun-Ho;Kim, Jong-Gu;Kim, Won-Ho
    • Bulletin of the Korean Chemical Society
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    • v.26 no.4
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    • pp.569-574
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    • 2005
  • A coupled column liquid chromatography system was applied for the separation of the burnup monitors in spent nuclear fuel sample solutions. A reversed phase column was studied for the adsorption behavior of uranyl ions using alpha-hydroxyisobutyric acid as an eluent and used for the separation of plutonium and uranium. A cation exchange column prepared by coating 1-eicosylsulfate onto the reversed phase column was used for the separation of the lanthanides. In addition, retention of Np was checked with the reversed phase column and cation exchange column, respectively, according to the oxidation states to observe the interference effect for the separation of burnup monitors. This chromatography system showed a great reduction in separation time compared to a conventional anion exchange method. A good agreement from the burnup data was obtained between for this method and a conventional anion exchange method to within 1% of a difference for the spent nuclear fuel samples of about 40 GWD/MTU.

Separation of Kernel Space and User Space in Zephyr Kernel (Zephyr 커널에서 커널 공간과 사용자 공간의 분리 구현)

  • Kim, Eunyoung;Shin, Dongha
    • IEMEK Journal of Embedded Systems and Applications
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    • v.13 no.4
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    • pp.187-194
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    • 2018
  • The operating system for IoT should have a small memory footprint and provide low power state, real-time, multitasking, various network protocols, and security. Although the Zephyr kernel, an operating system for IoT, released by the Linux Foundation in February 2016, has these features but errors generated by the user code can generate fatal problems in the system because the Zephyr kernel adopts a single-space method that both the user code and kernel code execute in the same space. In this research, we propose a space separation method, which separates kernel space and user space, to solve this problem. The space separation that we propose consists of three modifications in Zephyr kernel. The first is the code separation that kernel code and user code execute in each space while using different stacks. The second is the kernel space protection that generates an exception by using the MPU (Memory Protection Unit) when the user code accesses the kernel space. The third is the SVC based system call that executes the system call using the SVC instruction that generates the exception. In this research, we implemented the space separation in Zephyr v1.8.0 and evaluated safety through abnormal execution of the user code. As the result, the kernel was not crashed by the errors generated by the user code and was normally executed.

Reducing Separation Force for Projection Stereolithography based on Constrained Surface Technique (규제액면기법의 전사방식 광조형 시스템을 위한 이형력 감소)

  • Kim, Hye Jung;Ha, Young Myoung;Park, In Baek;Kim, Min Sub;Jo, Kwang Ho;Lee, Seok Hee
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.9
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    • pp.1001-1006
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    • 2013
  • Projection-based stereolithography is divided into constrained-surface and free-surface type according to controlling liquid layer. The constrained-surface type has a uniform layer thickness due to the use of a projection window, which covers the pattern generator such as liquid crystal display. However, the adhered resin on the projection window causes trouble and requires great separation force when the cured layer is separated from the window. To minimize the separation force, we developed a system to measure the separation force. The influence of material covering the pattern generator and the resin temperature is investigated in the system. Several structures according to the resin temperature and the velocity of z-axis elevation are compared. As a result, the fabrication condition to minimize the separation force reduces the process time.

Numerical Analysis on Separation Dynamics of Strap-On Boosters in the Dense Atmosphere

  • Choi, Seongjin;Ko, Soon-Heum;Kim, Chongam;Rho, Oh-Hyun;Park, Jeong-joo
    • International Journal of Aeronautical and Space Sciences
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    • v.2 no.2
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    • pp.1-18
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    • 2001
  • A numerical technique for simulating the separation dynamics of strap-on boosters jettisoned in the dense atmosphere is presented. Six degree of freedom rigid body equations of motion are integrated into the three-dimensional unsteady Navier-Stokes solution procedure to determine the dynamic motions of strap-ons. An automated Chimera overlaid grid technique is introduced to achieve maximum efficiency for multi-body dynamic motion and a domain division technique is implemented in order to reduce the computational cost required to find interpolation points in the Chimera grids. The flow solver is validated by comparing the computed results around the Titan IV launch vehicle with experimental data. The complete analysis process is then applied to the. H-II launch vehicle, the central rocket in japans space program, the CZ-3C launch vehicle developed in China and the KSR-III, a three-stage sounding rocket being developed in Korea. From the analyses, separation trajectories of strap-on boosters are predicted and aerodynamic characteristics around the vehicles at every time interval are examined. In addition, separation-impulse devices generally introduced for safe separation of strap-ons are properly modeled in the present paper and the jettisoning force requirements are examined quantitatively.

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Outline and Performance Evaluation of High Quality Recycled Fine Aggregate Manufacturing System Using Drying Gravity Separation Method (건식비중분리법에 의한 고품질순환잔골재생산시스템의 개요 및 성능평가)

  • Kim Moo-Han;Kim Gyu-Yong;Choi Kyongl-Yeul;Lee Do-Heun;Song Ha-Young;Roh Kyung-Min
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.111-114
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    • 2006
  • Recently, it is increased on the concern for the reuse of waste concrete because of the shortage of natural aggregate and the increase of waste concrete. And recycled coarse aggregate is used variously, but the existing wet method producted recycled fine aggregate has problem like the high price facilities, the long time progress of the work and the poor of recycled fine aggregate. The aim of this study is to investigate outline and performance evaluation of the drying specific gravity separation method to product high duality recycled fine aggregate. Finally, this study is shown investigate process flowing of drying separation type with gravity manufacture, producte system and function of detail devices. The performance of the method of drying specific gravity separation is certificated as the qualities of recycled fine aggregate satisfied the KS

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