• Title/Summary/Keyword: Separation technology

Search Result 3,005, Processing Time 0.032 seconds

Separation of Electronic Grade Highly Pure Carbon Dioxide Using Combined Process of Membrane, LNG Cold Heat Assisted Cryogenic Distillation (분리막 공정과 LNG 냉열 및 심냉 증류를 이용한 전자급 고순도 이산화탄소의 분리)

  • YOUNGSOO KO;KYUNGRYONG JANG;JUNGHOON KIM;YOUNGJOO JO;JUNGHO CHO
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.35 no.1
    • /
    • pp.90-96
    • /
    • 2024
  • In this paper, a new technology to obtain electronic grade, highly pure carbon dioxide by using membrane and liquefied natural gas (LNG) cold heat assisted cryogenic distillation has been proposed. PRO/II with PROVISION release 2023.1 from AVEVA company was used, and Peng-Robinson equation of the state model with Twu's alpha function to predict pure component vapor pressure versus temperature more accurately was selected for the modeling of the membrane and cryogenic distillation process. Advantage of using membrane separation instead of selecting absorber-stripper configuration for the concentration of carbon dioxide was the reduction of carbon dioxide capture cost.

Separation of Zirconium and Hafnium from Zirconium Oxychloride (ZOC) Synthesis of Kalimantan Zircon Sand Concentrate Using Extraction Method with tributyl phosphate (TBP)-Dodecane in Nitric Acid Medium

  • Kharistya Rozana;Ariyani Kusuma Dewi;Herry Poernomo;Won-Chun Oh;Karna Wijaya
    • Korean Journal of Materials Research
    • /
    • v.34 no.5
    • /
    • pp.247-253
    • /
    • 2024
  • The separation of zirconium and hafnium using tributyl phosphate (TBP)-Dodecane extractants in nitric acid medium was performed. Zirconium oxychloride, used as extraction feed, was obtained from the synthesis of Kalimantan zircon sand concentrate smelted using NaOH. The extraction process was carried out by dissolving chloride-based metals in nitric acid media in the presence of sodium nitrate using TBP-Dodecane as an extractant. Some of the extraction parameters carried out in this study include variations in organic phase and aqueous phase (O/A), variations in contact time, and variations in nitric acid concentration. Extraction was carried out using a mechanical shaker according to the parameter conditions. X-ray fluorescence (XRF) was used for elemental (Zr and Hf) composition analysis of the aqueous solution. The results showed that zirconium was separated from hafnium at optimum conditions with an organic/aqueous ratio of 1:5, contact time of 75 min, and an HNO3 concentration of 7 M. The resulting separation factor of zirconium and hafnium using TBP-Dodecane was 14.4887.

Separation and Purification of Lysozyme from Chicken Eggwhite Through Ultrafiltration (한외여과를 통한 난백 중 라이소자임의 분리정제)

  • Koo Ja-Kyung;Son Dongho;Jun Hoejin;Lee Yunhee;Cho Namjun;Jang Dong Il
    • Membrane Journal
    • /
    • v.15 no.2
    • /
    • pp.121-131
    • /
    • 2005
  • Separation and purification of lysozyme from chicken egg white was studied using ultrafiltration. We have obtained experimental data through the cellulose membranes with the molecular weight cut off (MWCO) of 10 kDa, 30 kDa and 100 kDa in a stirred ultrafiltration device. Certain amounts of egg white were dissolved into 20 mM phosphate buffers of pH 6, 7 and 8 to make protein solutions of $1\%,\;2\%,\;3\%\;and\;10\%$ concentration. Permeation flux increased with increasing MWCO of the membrane. Permeation flux increased with increasing transmembrane pressure (TMP) and decreasing the protein concentration. As the MWCO of membrane decreased, the selectivity increased. The selectivity increased with increasing TMP and protein concentration of the solution.

Effects of Vegetable Extracts by Solvent Separation on Alcohol Dehydrogenase Activity from Saccharomyces cerevisiae (채소의 용매분획 추출물들이 Saccharomyces cerevisiae의 alcohol dehydrogenase 활성에 미치는 영향)

  • Kang, Bae-Kwang;Jung, Soon-Teck;Kim, Seon-Jae
    • Korean Journal of Food Science and Technology
    • /
    • v.34 no.2
    • /
    • pp.244-248
    • /
    • 2002
  • The effects of extracts from bean sprout (Glycine max), dropwort (Oenathe javanica) and radish (Raphanus sativus Var. hortensis for. acanthiformis) by solvent separation on alcohol dehydrogenase (ADH) activity in vitro were investigated. The extracts were obtained from alcohol extracts of bean sprout, dropwort and radish, followed by solvent separation. Aqueous fractions facilitated much higher ADH activity than organic fractions. The facilitating rates of bean sprout, dropwort and radish in aqueous fractions were 125.75%, 104.94% and 87.63%, respectively. Basic fractions showed the highest facilitating rate with about 40%. Also other fractions showed below 20% facilitating rate and didn't show great difference from organic fractions. Phenolic fractions didn't show great effect on ADH activity.

Study on Pressurized Diesel Reforming System for Polymer Electrolyte Membrane Fuel Cell in Underwater Environment (수중 환경에서 고분자 전해질 연료전지(PEMFC) 공급용 수소 생산을 위한 가압 디젤 개질시스템에 관한 연구)

  • Lee, Kwangho;Han, Gwangwoo;Bae, Joongmyeon
    • Journal of the Korea Institute of Military Science and Technology
    • /
    • v.20 no.4
    • /
    • pp.528-535
    • /
    • 2017
  • Fuel cells have been spotlighted in the world for being highly efficient and environmentally friendly. A hydrogen which is the fuel of fuel cell can be obtained from a number of sources. Hydrogen source for operating the polymer electrolyte membrane fuel cell(PEMFC) in the current underwater environment, such as a submarine and unmanned underwater vehicles are currently from the metal hydride cylinder. However, metal hydride has many limitations for using hydrogen carrier, such as large volume, long charging time, limited storage capacity. To solve these problems, we suggest diesel reformer for hydrogen supply source. Diesel fuel has many advantages, such as high hydrogen storage density, easy to transport and also well-infra structure. However, conventional diesel reforming system for PEMFC requires a large volume and complex CO removal system for lowering the CO level to less than 10 ppm. In addition, because the preferential oxidation(PROX) reaction is the strong exothermic reaction, cooling load is required. By changing this PROX reactor to hydrogen separation membrane, the problem from PROX reactor can be solved. This is because hydrogen separation membranes are small and permeable to pure hydrogen. In this study, we conducted the pressurized diesel reforming and water-gas shift reaction experiment for the hydrogen separation membrane application. Then, the hydrogen permeation experiments were performed using a Pd alloy membrane for the reformate gas.

Research Studies of Impingement Characteristics for Hypergolic Propellant (접촉 점화성 추진제의 충돌형 혼합 특성 연구 사례)

  • Kim, Kyu-Seop;Kim, Yehyun;Jung, Sangwoo;Jeong, Junyeong;Kwon, Sejin
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.23 no.5
    • /
    • pp.90-100
    • /
    • 2019
  • Hypergolic thrusters have been extensively researched and applied to spacecraft propulsion based on their simplicity and high reliability of ignition. Research on the impingement characteristics of $N_2O_4$/amine has been profoundly carried out since the 1960s in advanced countries, especially the United States. Recently, enhancements to advanced hypergolic thrusters using MON/MMH have been planned by NASA to improve compactness and high performance. In this work, technical studies were investigated on the mixing of hypergolic propellant and its combustion instabilities such as reactive separation flow and popping.

Preparation of Biodegradable Polylactic Acid Membranes via Phase Separation: A Review (상분리법을 활용한 생분해성 폴리젖산 분리막 제조기술 개발 동향)

  • Tunmise Ayode Otitoju;Young Hoon Cho
    • Membrane Journal
    • /
    • v.34 no.1
    • /
    • pp.20-29
    • /
    • 2024
  • Membranes are increasingly used in a variety of applications including desalination, gas separation, disposable filters, and healthcare products. Recently, sustainable and green membrane fabrication technology is recognized as one of the decisive initiatives to reach the target of pollution control. Especially, the fabrication of bio-based membranes using such as poly lactic acid (PLA), polybutylene adipate terephthalate (PBAT), and polybutylene succinate (PBS) has attracted considerable attention. The phase inversion method is one of the versatile approaches for preparing PLA membranes. This article reviews the recent advances in PLA membrane preparation via the phase inversion method. Furthermore, it provides a perspective on the potential outlook for future advances. Overall, this review has demonstrated has been conducted in the area of bio-based PLA membranes.

An Analysis of Hot-Rolling in the Twin-Roll Strip Casting Process by using the Slab Method (슬랩법을 이용한 쌍롤식 박판주조 공정의 열간 압연 해석)

  • Shim, Hyun-Bo
    • Transactions of Materials Processing
    • /
    • v.3 no.1
    • /
    • pp.63-83
    • /
    • 1994
  • In this paper, the slab method have been applied to investigate the strip casting process in which hot coil is produced from molten steel directly. In the twin roll strip casting process, molten steel supplied by the nozzle cools and solidifies due to the heat extraction effect of the rolls and hot rolling of the solidified shell takes place simultaneously. The analysis of hot rolling has been carried out by using the existing results of solidification analysis for the twin roll strip casting process. The current slab method provides basic design data such as roll separation force, rolling torque, rolling power as well as end dam separation force which are required to design strip caster. The effect of friction on the basic process parameters are investigated also. It is shown that the use of appropriate friction coefficient is important and that the characteristics of hot rolling in the twin-roll strip casting process is quite different from the conventional hot rolling processes.

  • PDF

The Flow Field Characteristics of a Rotating Circular Cylinder near a Plane Wall (벽면에 근접해서 회전하는 원주의 유동장 특성)

  • Kang, Myung-Hun;Kim, Kwang-Seok;Ro, Ki-Deok
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.31 no.2
    • /
    • pp.166-172
    • /
    • 2007
  • The flow around a rotating circular cylinder near a plane wall is investigated by the measurement of the lift acting on the cylinder and by the flow visualization using the hydrogen bubble technique in the circulating water tank. The experimental parameters are the rotating direction of the cylinder. the space ratios $H/D(H/D=0.05{\sim}0.5)$ between cylinder and plane wall and the velocity ratios ${\alpha}({\alpha}=0{\sim}{\pm}2.0)$. In the case of clockwise, the lift on the rotating circular cylinder was increased with the reduction of the space ratios and with the velocity ratios, the upper separation point was more shifted in the rotating direction with them. In the case of anticlockwise, the absolute value of the lift on the rotating circular cylinder was increased with increasing the space ratios and the velocity ratios. the lower separation point was more shifted in the rotating direction with them.

Freezing Characteristics in a Horizontal Rectangular Channel with the Two-Dimensional Protuberances (2차원 직사각형 덕트 내부에 돌기부를 갖는 흐름의 동결특성에 관한 연구)

  • Oh, Cheol
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.27 no.6
    • /
    • pp.721-727
    • /
    • 2003
  • Freezing of turbulent water flow between two horizontal cooled parallel plates with the separated region has been investigated experimentally. The flow separation was induced by vertical plates (two-dimensional plates) situated at the inlet of the rectangular channel. The degree of flow separation was varied by employing vertical thin plates with various heights. Three kinds of the vertical plates with 8.0, 9.8 and 12.5 mm in height were utilized. The Reynolds number and cooling temperature ratio were ranged from $3.45\times10^3 to 1.73\times10^4$ and 7.0 to 20.0 respectively, The measurements show that the flow separation influenced remarkably on the local ice formation characteristics. The location of the first ice layer and the average heat transfer at the ice surface were found be correlated as a function of the Reynolds number, the cooling temperature ratio, and the orifice height ratio.