• Title/Summary/Keyword: Separation technology

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The Structural Transitions of $\pi$-Complexes of Poly(styrene-b-butadiene-b-styrene) Block Copolymers with Silver Salts and Their Relation to Facilitated Olefin Transport

  • Lee, Dong-Hoon;Kim, Jong-Hak;Jongok Won;Kang, Yong-Soo
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.211-215
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    • 2004
  • Olefins are the most important feedstock in the petrochemical industry and thus the separation of olefin/paraffin mixtures is crucial to that industry. At present, this separation is mostly carried out using cryogenic distillation processes that require enormous capital investment and have high operational costs.(omitted)

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Separation and purification of elements from alkaline and carbonate nuclear waste solutions

  • Alexander V. Boyarintsev ;Sergei I. Stepanov ;Galina V. Kostikova ;Valeriy I. Zhilov;Alfiya M. Safiulina ;Aslan Yu Tsivadze
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.391-407
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    • 2023
  • This article provides a survey of wet (aqueous) methods for recovery, separation, and purification of uranium from fission products in carbonate solutions during the reprocessing of spent nuclear fuel and methods for removal of radionuclides from alkaline radioactive waste. The main methods such as selective direct precipitation, ion exchange, and solvent extraction are considered. These methods were compared and evaluated for reprocessing of spent nuclear fuel in carbonate media according to novel alternative non-acidic methods and for treatment processes of alkaline radioactive waste.

Separation and analysis of Cr(III) and Cr(VI) using 8-hydroxyquinoline complexation of Cr(III) (8-Hydroxyquinoline을 이용한 크롬 3가 및 6가의 분리 및 분석)

  • Lim, Heon-Sung;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.20 no.3
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    • pp.246-250
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    • 2007
  • The quantitative determination of chromium(VI) by separation from chromium(III) complex of 8-hydroxyquinoline using solvent extraction has been studied. The reaction conditions for chromium(III) complex of 8-hydroxyquinoline and the solvent extraction of complex were investigated in detail. The chromium(III) complex was extracted with organic solvent (n-hexane) and residual chromium(VI) was determined by ICP-AES in aqueous layer. This technique is quantitative in the pH range of 8-9 and the limitations such as interfering ions were discussed.

Treatment of Rolled Steel Coolant Wastewater by Superconducting High Gradient Magnetic Separation

  • Kim, Tea-Hyung;Ha, Dong-Woo;Oh, Sang-Soo;Kim, Ho-Sup;Ko, Rock-Kil;Lee, Nam-Jin;Kwon, Jun-Mo;Kim, Young-Hun;Kung, Chae-Hun;Ha, Tae-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.354-354
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    • 2009
  • We have developed the prototypes of superconducting magnetic separation system with high temperature superconductor wire. This separation filter system consist of magnetized matrix SUS430 wire and acrylic frame. This study introduced rolled steel process coolant wastewater applied superconductor HGMS(High Gradient Magnetic Separation). HGMS treatment have acted high efficient method for various wastewater. We have surveyed superconducting magnetic separation technology and reviewed the status of related industries using applied superconductivity. In our basic preliminary experiment using HGMS, it was made clear that the fine para-magnetic particles in the wastewater obtained from rolling process of steel can be separated with high efficiency. We investigated the ability of magnetic flock formation, which used inorganic materials and polymer coagulants. We had a purpose to remove SS of coolant at steel factory. Maximum coagulation remove rate of SS 98%. Removing ratio of $Fe_3O_4$ fine particles in wastewater showed over than 99% in the wastewater containing magnetic fines after four times of repetition of separation.

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Separation of Plutonium Oxidation States by Ion Chromatography (이온크로마토그래피를 이용한 산화수별 플루토늄의 분리)

  • Kim, Seung Soo;Jun, Kwan Sik;Kang, Chul Hyung
    • Analytical Science and Technology
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    • v.14 no.1
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    • pp.28-33
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    • 2001
  • The ion chromatography for the separation of plutonium species which are suggested to be $Pu^{3+}$, $Pu^{4+}$, $PuO_2{^+}$ and $PuO_2{^{2+}}$ in natural water was studied. Two separation methods were performed; 1) two-column method containing each of $SiO^-$ and SiO-$SO_3{^-}$ cation exchanger, 2) IC with AG11 column and the eluent of oxalate/nitric acid. Separation conditions for $Eu^{3+}$, $Th^{4+}$, $NpO_2{^+}$, $UO_2{^{2+}}$ in place of plutonium species were acquired from preliminary tests. When these conditions were applied to separate the plutonium species, two-column method was separated them successfully. However, the IC method with oxalate eluent was difficult in the separation of plutonium species due to the change of $Pu^{3+}$ and $PuO_2{^{2+}}$ to $Pu^{4+}$ and $PuO_2{^+}$ respectively.

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Effect of internal pressure variation on the ceramic particle separation characteristics : computer simulation (분리기 내부 압력 변화에 따른 세라믹 입자 분리 거동 전산모사)

  • 우효상;심광보;정용재
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.6
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    • pp.304-308
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    • 2003
  • By controlling the internal pressure in the cyclone separator, we investigated the separation charateristics of $Al_2O_3$, $Fe_2O_3$ particles with the internal pressure variation. 3-dimensional Langrangian approach was applied for the analysis of the particles separation, and then the minimum cut diameter of the separated particles and the separation rate were calculated through tracking the particle trajectories. The density of the argon gas for transporting particles was decreased corresponding the pressure decrease, consequently, caused the internal pressure drop in the cyclone separator. For that reason the finer particles were separated as the pressure was changed from an atmospheric pressure to an low pressure. Specifically, at 50 torr pressure, $Al_2O_3$ particles of the size of about 4 $\mu\textrm{m}$ and $Fe_2O_3$particles of about 3 $\mu\textrm{m}$ could be separated.

An Analysis for the Characteristics of Headward Erosion and Separation Zone due to Bed Discordance at Confluence (합류부 하상고 불일치에 의한 두부침식 및 분리구역 특성분석)

  • Choi, Heung Sik;Mo, Sun Jea;Lee, Sam Hee
    • Journal of Korea Water Resources Association
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    • v.48 no.11
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    • pp.879-889
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    • 2015
  • The pattern of headward erosion at tributary and the separation zone formation in a loosed bed at confluence according to the confluence angle, discharge ratio, and dredging depth ratio have been analyzed. The separation zone is defined the inside of zero velocity boundary at downstream of confluence. The limit of separation zone occurrence is presented with dredging depth ratio. The propagation length of knickpoint increases as the confluence angle, discharge ratio, and dredging depth ratio increase in general and its regression equation has been suggested. The length and width ratios of separation zone in a loosed bed increase as discharge ratio and confluence angle increase as well as in a fixed bed. The length ratio decreases and the width ratio increases as dredging depth ratio increases results in great increase of shape factor and backwater rise by the conveyance reduction at confluence. The regression equation of shape factor with confluence angle, discharge ratio, and dredging depth ratio has been suggested.

Development of Solid/Liquid Separation Technique for Krill (Eupausia superba) (남극 크릴새우의 고액분리 기술개발)

  • Oh, I.H.;Jang, C.H.;Kim, W.G.;Yang, S.Y.
    • Journal of Animal Environmental Science
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    • v.17 no.1
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    • pp.33-38
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    • 2011
  • Economic development involves increase in life expectancy as well as human health care. Consequently, demand for fish meal and fish oil is rapidly growing. In particular, Krill (Eupausia superba) oil product is in high demand due to its rich unsaturated-fatty acid, and thus stable supplies are necessary in the krill oil market. It is required for captured krills to be immediately frozen and stored during ship transport, since proteins of the krill are quickly denatured in natural temperature condition. However, the transportation cost has been sharply increased, which encourages researchers to involve in studies for development of efficient oil extraction process. In this study, a solid/liquid separation technique on boat for the krill oil was developed through triple separation tests using only a separator or using either brush or crusher prior to the separator. The separation tests revealed that the efficiency were 46.2, 60.2 and 60.4 % by the separator, combination with brush, and combination with crusher, respectively. In addition, it was found that byproduct, extracted cake, derived from the separation process could be used as a feed stuff. These results suggest that smashing using the brush or crusher prior to the separator is more efficient than using only the separator.

Separation of Hg(II) by using the poly-NTOE(1, 12-diaza-3, 4:9, 10-dibenzo-5, 8-dioxacyclopentadeca-1, 12-ylene-2, 7-dihydroxyoctamethylene) in Liquid Chromatography (액체 크로마토그래피에서 Poly-NTOE(1, 12-diaza-3, 4:9, 10-dibenzo-5, 8-dioxacyclopentadeca-1, 12-ylene-2, 7-dihydroxyoctamethylene)를 이용한 Hg(II)의 분리)

  • Kim, Hae-Joong;Shin, Young-Kook;Kim, Si-Joong
    • Analytical Science and Technology
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    • v.8 no.3
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    • pp.259-264
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    • 1995
  • The separation efficiency of metal ions by using the poly-NTOE(1, 12-diaza-3, 4:9, 10-dibenzo-5, 8-dioxacyclopentadeca-1, 12-ylene-2, 7-dihydroxyoctamethylene) has been determined by column chromatography in aqueous solution. Binding constants and separation factors for several poly-NTOE interactions were measured in aqueous solution. The order of these binding constants and separation factors with metal ions were Co(II)Zn(II) for the transition metal ions and Cd(II)

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Bioseparations in Lab-On-A-Chip (랩온어칩에서의 생물분리기술)

  • Chang Woo-Jin;Koo Yoon-Mo
    • KSBB Journal
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    • v.20 no.3
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    • pp.197-204
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    • 2005
  • Lab-on-a-chip is a miniaturized analytical device in which all of the procedures for the analysis of molecules are carried out, such as pretreatment, reaction, separation, detection, etc. Lab-on-a-chip has increasing concern as a device not only for rapid detection of molecules but also for high throughput screening and point of care, because conventional laborious and time consuming analytical procedures can be substituted. Thus, a lot of microfabrication and analytical techniques for lab-on-a-chip have been developed with microstructures smaller than a few hundreds of micrometers. Separation of the molecules is one of the most important components of lab-on-a-chip, because effective separation method can simplify the design and can provide better sensitivity. The electrokinetic separation based on capillary electrophoresis is most widely employed technique in lab-on-a-chip for the control of fluids and the separation of molecules. In this article, bioseparation techniques and its applications realized in lab-on-a-chip are reviewed.