• Title/Summary/Keyword: Separation ratio

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A Simultaneous Improvement in $CO_2$ Flux and $CO_2/N_2$ Separation Factor of Sodium-type FAU Zeolite Membranes through 13X Zeolite Beads Embedding (13X 제올라이트 흡착제 충진에 의한 Na형 Faujasite 제올라이트 분리막의 $CO_2/N_2$ 선택도 및 $CO_2$ 투과도 동시 증가 현상)

  • Cho, Churl-Hee;Yeo, Jeong-Gu;Ahn, Young-Soo;Han, Moon-Hee;Moon, Jong-Ho;Lee, Chang-Ha
    • Membrane Journal
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    • v.17 no.3
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    • pp.269-275
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    • 2007
  • Sodium type faujasite(FAU) zeolite membranes with a thickness of 5${\mu}m$ and a Si/Al molar ratio of 1.5 were prepared by the secondary growth process. The $CO_2/N_2$ separation in the vacuum mode was investigated at $30^{\circ}C$ for an equimolar $CO_2-N_2$ mixed gas before and after embedding 13X zeolite beads in the permeate side. The embedded 13X zeolite beads improved both $CO_2$ permeance and $CO_2/N_2$ separation factor, simultaneously. The phenomenon was explained by an increment in the $CO_2$ desorption rate at the FAU zeolite/$\alpha-Al_2O_3$ phase boundary due to an enhanced $CO_2$ escaping through the pore channels of the $\alpha-Al_2O_3$ support layer. In the present paper, it will be emphasized that a hybridization of a membrane with an adsorbent can provide a key to break through the trade-off between permeance and separation factor, generally shown in a membrane separation.

Analysis of the Optimal Separation Distance between Multiple Thermal Energy Storage (TES) Caverns Based on Probabilistic Analysis (확률론적 해석에 기반한 다중 열저장공동의 적정 이격거리 분석)

  • Park, Dohyun;Kim, Hyunwoo;Park, Jung-Wook;Park, Eui-Seob;Sunwoo, Choon
    • Tunnel and Underground Space
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    • v.24 no.2
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    • pp.155-165
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    • 2014
  • Multiple thermal energy storage (TES) caverns can be used for storing thermal energy on a large scale and for a high-aspect-ratio heat storage design to provide good thermal performance. It may also be necessary to consider the use of multiple caverns with a reduced length when a single, long tunnel-shaped cavern is not suitable for connection to aboveground heat production and injection equipments. When using multiple TES caverns, the separation distance between the caverns is one of the significant factors that should be considered in the design of storage space, and the optimal separation distance should be determined based on a quantitative stability criterion. In this paper, we described a numerical approach for determining the optimal separation distance between multiple caverns for large-scale TES utilization. For reliable stability evaluation of multiple caverns, we employed a probabilistic method which can quantitatively take into account the uncertainty of input parameters by probability distributions, unlike conventional deterministic approaches. The present approach was applied to the design of a conceptual TES model to store hot water for district heating. The probabilistic stability results of this application demonstrated that the approach in our work can be effectively used as a decision-making tool to determine the optimal separation distance between multiple caverns. In addition, the probabilistic results were compared to those obtained through a deterministic analysis, and the comparison results suggested that care should taken in selecting the acceptable level of stability when using deterministic approaches.

Effect of Separation Between Main and Divergent Tunnels in Divergence Section of Double-Deck Tunnel on the Stability (복층터널 분기구에서의 터널 이격에 따른 안정성 영향)

  • La, You-Sung;Kim, Bum-Joo
    • Journal of the Korean Geosynthetics Society
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    • v.15 no.2
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    • pp.45-54
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    • 2016
  • Double deck tunnels are considered to have a large demand in a near future for solving traffic congestion problems and overcoming the limitations in constructing new tunnels. This study presents a numerical investigation using finite element (FE) analysis on the behaviors of the tunnels and the stability of pillars in a divergence section where single tunnel is diverged from a main line double deck tunnel. The effects of the separation distance between the diverged and the main tunnels and the ground condition were examined through the FE analysis by varying the separation distance from 0.1D to 2.0D (D: diameter of main tunnel) and the rock class from class I to V, respectively, and the analysis results were compared with those using empirical methods, strength-stress ratio, and the volume of interference. The FE analysis results indicated that the separation distance has a larger effect on tunnel behaviors, compared with the rock strength, and a single tunnel with a large cross section is more favorable than two separated tunnels for tunnel stability when the separation distance is below 0.7D.

Effect of Ionic Molar Conductivity on Separation Characteristics of Heavy Metals by Nanofiltration Membranes in Waste Water (이온 몰 전도도가 나노여과막에 의한 폐수 중의 중금속 분리특성에 미치는 영향)

  • Oh, Jeong-Ik
    • Land and Housing Review
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    • v.4 no.1
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    • pp.119-124
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    • 2013
  • Generally, the characteristic of nanofiltration membranes were catagorized into charged membrane, sieve effect, interaction between membarnes and target solutes. This study aims to investigate the effect item of heavy metal separation with view of charge nanofiltration membranes. The experiments of nanofiltration were conducted by nanofiltration set-up with operational pressure of 0.24 MPa at $25^{\circ}C$ by using synthetic wastewater containing 0.1mg/L of Cr, Fe, Cu, Zn, As, Sn, Pb. Nanofiltration membranes rejected heavy metals much better than chloride, sulfate and TOC, of which concentration in synthetic wastewater was higher than that of heavy metals. To consider rejection characteristics of various metals by nanofiltration membranes, separation coefficient, which is the molar conductivity ratio of the metal permeation rate to the chloride ion or TOC permeation rate, was introduced. In spite of different materials and different nominal salt rejection of nanofiltration membrane used, the separation coefficients of metals were nearly the same. These phenomena were observed in the relationship between the molar conductivity and the separation coefficient for heavy metals.

Pervaporation Separation of MTBE-Methanol Mixtures Using PVA/PAA Crosslinked Membranes (가교된 PVA/PAA 막을 이용한 MTBE-Methanol 혼합물에 대한 투과증발분리)

  • 임지원;김연국
    • Membrane Journal
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    • v.8 no.4
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    • pp.235-242
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    • 1998
  • Pervaporation separation of methyl tert-butyl ether (MTBE) and methanol (MeOH) mixture, of which the former compound is well known as the octane booster was carried out. Poly(vinyl alcohol) (PVA) membranes crosslinked with poly(acrylic acid) which have been successfully applied on the water-alcohol mixtures were used in this study. The PVA/PAA ratio in the crosslinked membranes was 95/5, 90/10, 85/15, 80/20, and 75/25 by weight. The operating temperatures were 30, 40, and 50$\circ$C, and the compositions of MTBE and MeOH to be separated were 95/5, 90/10, and 80/20 (MTBE/MeOH) solutions. PVA/PAA=85/15 membrane showed the separation factor $\alpha_{MeOH/MTBE}$=4000 and the permeation rate of 10.1 g/m$^2$hr for MTBE/MeOH=80/20 solution at 50$\circ$. When the same membrane was used, the separation factor and permeation rate for MTBE/MeOH=90/10 solution at 40$\circ$C were $\alpha_{MeOH/MTBE}$=6000 and 8.5 g/m$^2$hr, respectively. Also, the hydrophilic/hydrophobic balance of the membranes would take an important role in the relationships between the membranes and separation performances in terms of the flux and the separation factor.

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Characteristic of Wind Flow around Building Structures for Wind Resource Assessment (풍자원 평가를 위한 건축물 주변의 유동특성)

  • Cho, Kang-Pyo;Jeong, Seung-Hwan;Shin, Seung-Hwa
    • The KSFM Journal of Fluid Machinery
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    • v.14 no.3
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    • pp.50-58
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    • 2011
  • To utilize wind resources effectively around buildings in urban area, the magnitudes of wind velocity and turbulence intensity are important, which means the need of the information about the relationship between the magnitude of wind velocity and that of fluctuating wind velocity. In the paper, wind-tunnel experiments were performed to provide the information about Characteristic of Wind flow around buildings with the spanwise distance and the side ratio of buildings as variables. For a single building with the side ratios of one and two, the average velocity ratio was 1.4 and the velocity standard deviation ratio ranged from 1.4 to 2.6 at the height of 0.02m at the corner of the windward side, in which flow separation occurred. For twin buildings with the side ratios of one and two, the velocity ratio ranged from 2 to 2.5 as the spanwise distance varied at the height of 0.02m, and the velocity standard deviation ratio varied near 1.25. For twin buildings with the side ratios of one and two, the maximum velocity ratio was 1.75 at the height of 0.6m, and the maximum velocity standard deviation ratio was 2.1. It was also found from the results of CFD analysis and wind-tunnel experiments that for twin buildings with the side ratios of one and two, the difference between the velocity ratio of CFD analysis and that of wind-tunnel experiments at streamwise distances was near 0.75.

Pharmaceutical Studies on Microencapsulated Propranolol Hydrochloride (염산프로프라놀롤의 마이크로캅셀에 관한 약제학적 연구)

  • Yoon, Mi-Ae;Yong, Jae-Ick
    • Journal of Pharmaceutical Investigation
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    • v.17 no.2
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    • pp.67-73
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    • 1987
  • Propranolol hydrochloride was microencapsulated with ethylcellulose by means of phase separation from cyclohexane. The surface of the microcapsules examined using scanning electron microscope was porous. The dissolution rate of drug from microcapsules decreased as the weight ratio of propranolol hydrochloride to ethylcellulose decreased and as the size of microcapsules increased. The dissolution rate of drug from microcapsules decreased as the viscosity of ethylcellulose and pH of dissolution medium decreased.

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4-channel optical frequency division multiplexing using the fiber Fabry-Perot filter (광섬유 파브리-페로 필터를 이용한 4채널 광주파수 다중화)

  • 류갑열;주무정;박창수
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.32A no.8
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    • pp.133-139
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    • 1995
  • In this paper, the frequency separation locking and interval stabilization of 4-channel DFB-LDs have been demonstrated using a fiber Fabry-Perot filter with an free spectral range of 100GHz. Frequency fluctuation and locking range of each channel were appeared to be within 15MHz and over 12GHz, respectively. Back-reflection curve from the fiber Fabry-Perot filter was used for the extraction of an error signal in order to increase the number of accomodable channels and extinction ratio.

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Three-Dimensional Performance Analysis of a Thermally Asymmetric Rectangular Fin

  • Kang, Hyung-Suk
    • International Journal of Air-Conditioning and Refrigeration
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    • v.9 no.2
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    • pp.94-101
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    • 2001
  • Fin effectiveness and efficiency of a thermally asymmetric rectangular fin are represented as a function of non-dimensional fin length, width, fip tip surface Biot number and the ratio of fin bottom surface Biot number to top surface Biot number. For this analysis, three dimensional separation of variables method is used. One of the results shows that fin effectiveness can be increased or decreased depending on the fin length as the fin tip surface Biot number increases while fin efficiency decreases without depending on that as the fin tip surface Biot number increases.

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Study on the Several Factors in the Fractional Leaching Method of Mixed Hydrated Oxides of Monazite Sand (Monazite로 부터 유도된 혼합수산화물에 대한 분별 용출법의 검토)

  • Rhee, Chin-Taik;Ko, Hyo-Tae;Chun, Sang-Moon
    • Journal of the Korean Chemical Society
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    • v.14 no.3
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    • pp.257-261
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    • 1970
  • Some factors such as the weight ratio, reaction time and temperature for the separation of rare earth elements from monazite are studied. The influence of the inorganic phosphate for the leaching is also studied.

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