• 제목/요약/키워드: Separation of particles

검색결과 449건 처리시간 0.026초

이산화탄소 분리용 혼합 매질 분리막 최신 연구 동향 (Recent Research Trends of Mixed Matrix Membranes for CO2 Separation)

  • 지원석;이재훈;박민수;김종학
    • 멤브레인
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    • 제25권5호
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    • pp.373-384
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    • 2015
  • 지난 수십 년 동안, 고분자막은 기체 분리 분야에서 큰 역할을 해왔다. 온실가스의 주범인 이산화탄소를 분리하기 위해서는 더 높은 투과선택도와 장수명 및 대면적 등을 요구한다. 하지만 기존 고분자 분리막들은 투과도와 선택도의 역상관 관계 특징을 지니고 있으며, 무기물질은 투과성능이 우수하지만 가격이 비싸다는 단점이 있다. 최근 많은 연구가 진행되어온 혼합 매질 분리막은 고분자와 무기물질의 이점들을 혼합하여 기체 분리막의 차세대로서 큰 이목을 이끌고 있다. 혼합 매질 분리막은 대칭적인 구조 또는 비대칭적인 구조를 가지고 있으며, 투과량을 증가시키기 위해서는 비대칭적인 구조가 바람직하다. 혼합 매질 분리막에서 가장 중요한 변수로는 무기입자의 균일한 분산과 무기물과 고분자 사이의 좋은 계면을 형성하는 것이다. 최근에 새로운 분류의 다공성 결정성 물질인 금속 유기 구조체(MOF)는 이산화탄소 분리용 소재로써 많은 관심을 끌고 있다. MOF의 한 종류 중, zeolitic imidazolate frameworks (ZIF)는 가장 흔하게 사용되는 무기입자이며 이는 입자의 크기를 작게 만들 수 있으며, $CO_2$를 분리하기에 적절한 기공의 크기를 가지고 있기 때문이다. 이 밖에 혼합 매질 분리막에 사용되는 특정 물질들을 적용하기 위해서는 선택도와 크기, 호환성, 안정성 등을 동시에 최적화시켜야 한다. 이와 같이 본 총설에서는, 혼합 매질 분리막에 관련된 주요 연구내용과 이러한 연구를 수행하는 대표적인 전략들을 소개하였다.

수산화코발트의 초음파 폴리올 합성과 자성 선별법을 이용한 코발트 나노 분말의 제조 (The Fabrication of Cobalt Nanopowder by Sonochemical Polyol Synthesis of Cobalt Hydroxide and Magnetic Separation Method)

  • 변종민;최명환;심창민;김지영;김영도
    • 한국분말재료학회지
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    • 제22권1호
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    • pp.39-45
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    • 2015
  • In this study, cobalt nanopowder is fabricated by sonochemical polyol synthesis and magnetic separation method. First, sonochemical polyol synthesis is carried out at $220^{\circ}C$ for up to 120 minutes in diethylene glycol ($C_4H_{10}O_3$). As a result, when sonochemical polyol synthesis is performed for 50 minutes, most of the cobalt precursor ($Co(OH)_2$) is reduced to spherical cobalt nanopowder of approximately 100 nm. In particular, aggregation and growth of cobalt particles are effectively suppressed as compared to common polyol synthesis. Furthermore, in order to obtain finer cobalt nanopowder, magnetic separation method using magnetic property of cobalt is introduced at an early reduction stage of sonochemical polyol synthesis when cobalt and cobalt precursor coexist. Finally, spherical cobalt nanopowder having an average particle size of 22 nm is successfully separated.

Some theoretical and experimental aspects of a new electrodynamic separator

  • Kachru, Rajinder-P
    • 한국농업기계학회:학술대회논문집
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    • 한국농업기계학회 1993년도 Proceedings of International Conference for Agricultural Machinery and Process Engineering
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    • pp.979-983
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    • 1993
  • A power operated (0.5 hp electric motor) grain flour separator was designed and developed for separation of grain (wheat, corn, chickpea and soybean) flour it no various fractions based on the size of the particles of the product. The separator is made of mild steel and consists of a hopper, power driven agitating mechanism, feed control , cylindrical separator unit and an eccentric mechanism. The machine was tested for wheat (variety : Subjata) flour separation into four fraction, viz : semolina ; Gr-I and II, flour (coarse) and white (fine) flour. Wheat samples (6.8% m.c., db) were first pearled by CIAE pearler for 15.8% bran removal . The product and machine characteristics were determined at different capacities varying from 24 kg/h to 143 kg/h. It was found that 76 kg/h capacity gave reasonably best results in terms of purity and recovery of semolina vis-a-vis the market product. The energy requirement of the machine at no-load was found to be 230 w and at load conditio s, it varied between 36.3-6.4kj per kg of feed separation. The machine could be used by small flour millers, small/medium size traders and retailers and other processors for making available various flour products of different particle size in the market for ready use fo the consumers.

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전도성 액체기반 정상표면탄성파(CL-SSAW)를 이용한 백혈구로부터의 말라리아 기생충 분리 (Malaria Parasite Separation from White Blood Cells Using Conductive Liquid-Based Standing Surface Acoustic Wave (CL-SSAW))

  • 지현슬;남정훈;임채승
    • 대한의용생체공학회:의공학회지
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    • 제40권5호
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    • pp.151-157
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    • 2019
  • An acoustofluidic device using conductive liquid-based electrodes was developed for malaria parasite separation from white blood cells. In this device, the electrode channels filled with a conductive liquid were used to generate standing surface acoustic waves (SSAWs) in a fluidic channel, which can overcome the limitation of conventional patterned metal electrodes. Separation performance of the device was evaluated using fluorescent polystyrene particles with two different sizes (2 and $10{\mu}m$ diameters), which were successfully separated. In addition, a mixture of malaria parasites and white blood cells were also efficiently separated with high purity of ~98% in the CL-SSAW device at the flow rate of $12{\mu}l/min$.

기체 분리용 고분자 분리막의 분자동력학 연구 (Molecular Dynamics (MD) Study of Polymeric Membranes for Gas Separation)

  • 박치훈;김득주;남상용
    • 멤브레인
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    • 제24권5호
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    • pp.341-349
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    • 2014
  • 분자 동력학(Molecular dynamics; MD) 전산모사 기술은 대상이 되는 입자(일반적으로, 원자)의 위치와 속도를 계산하여, 원자 및 분자들의 다양한 구조 및 동적 특성을 분석하는 데에 있어서 매우 유용한 기술이다. 기체 분리막 연구에 있어서도 MD는 그동안 free volume 분석, conformation search 등과 같은 고분자 구조 분석 및 permeability, diffusivity와 같은 기체 투과 거동을 연구하는 데 널리 사용되어 왔다. 본 총설에서는 기체 분리막 분야에 MD를 적용하는 일반적인 방법론에 대하여 서술하고, 다양한 관련 연구들을 소개하고자 한다.

Dependence of the peak fluxes of solar energetic particles on CME parameters and magnetic connectivity

  • Park, Jinhye;Moon, Yong-Jae;Lee, Harim;Kahler, S.W.
    • 천문학회보
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    • 제42권2호
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    • pp.82.3-83
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    • 2017
  • We investigate the relationships between the peak fluxes of 18 solar energetic particle (SEP) events and associated coronal mass ejection (CME) 3D parameters (speed, angular width, and separation angle) obtained from SOHO, STEREO-A and/or B for the period from 2010 August to 2013 June. We apply the STEREO CME Analysis Tool (StereoCAT) to the SEP-associated CMEs to obtain 3D speeds and 3D angular widths. The separation angles are determined as the longitudinal angle between flaring regions and magnetic footpoints of the spacecraft, which are calculated by the assumption of Parker spiral field. The main results are as follows. 1) We find that the dependence of the SEP peak fluxes on CME 3D speed from multi-spacecraft is similar to that on 2D CME speed. 2) There is a positive correlation between SEP peak flux and 3D angular width from multi-spacecraft, which is much more evident than the relationship between SEP peak flux and 2D angular width. 3) There is a noticeable anti-correlation (r=-0.62) between SEP peak flux and separation angle. 4) The multiple regression method between SEP peak fluxes and CME parameters shows that the longitudinal separation angle is the most important parameter, and the CME 3D speed is secondary on SEP peak flux.

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Improvement of Separation of Polystyrene Particles with PAN Membranes in Hollow Fiber Flow Field-Flow Fractionation

  • Shin, Se-Jong;Chung, Hyun-Joo;Min, Byoung-Ryul;Park, Jin-Won;An, Ik-Sung;Lee, Kang-Taek
    • Bulletin of the Korean Chemical Society
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    • 제24권9호
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    • pp.1333-1338
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    • 2003
  • Hollow Fiber flow field-flow fractionation (HF-FlFFF) has been tested in polyacrylonitrile (PAN) membrane channel in order to compare it with polysulfone (PSf) membrane channel. It has been experimentally shown that the separation time of 0.05-0.304 ${mu}m$ polystyrene latex (PSL) standards in PAN membrane channel is shorter than that in PSf channel by approximately 65%. The optimized separation condition in PAN membrane is ${\dot V}_{out}/{\dot V}_{rad}=1.4/0.12\;mL/min$, which is equal to the condition in PSf membrane channel. In addition both the resolution ($R_s$) and plate height (H) in PAN membrane channel are better than that in PSf membrane channel. The membrane radius was obtained by back calculation with retention time. It shows that the PSf membrane is expanded by swelling and pressure, but the PAN membrane doesn't expand by swelling and pressure.

실린더 헤드커버 내장형 오일분리 장치의 오일 직경별 분리효율에 관한 해석적 연구 (A Numerical Analysis of Oil Separation Performance Classified by Oil Mist Diameter for Cyclone Oil Separator)

  • 김형구;윤여빈;박영준;이성욱;조용석
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.3026-3031
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    • 2008
  • In conventional closed-loop crankcase ventilation systems, the lubrication oil had to be re-circulated to the intake manifold, in the form of oil mist mixed with the blow-by gas. This blow-by gas containing the engine lubricant oil affects on the engine problems and the exhaust emissions. A high-efficient oil separator is required to minimize consumption of engine oil and reduce harmful emissions. In the conventional oil separator of CI engines, it has good oil separation performance even though separator design is simple, due to lots of the blow-by gas. As the emission regulation becomes severe, the oil separator for SI engines is also required. But in SI engines, separator design should be optimized, due to small size of oil particles and little amount of blow-by gas. In this study, oil separation performance classified by diameter of oil mist in cylinder head cover internal model which has three cyclones and two baffle plates for SI engine is calculated with CFD methodology.

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MgxNiyZn1-x-yFe2O4나노입자 제조를 위한 초음파 습식 자기분류법의 적용 (Application of Ultrasonic Wet-Magnetic Separation Method to Prepare Nano-sized MgxNiyZn1-x-yFe2O4)

  • 구문선;최용
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2016년도 추계학술대회 논문집
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    • pp.201.2-201.2
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    • 2016
  • $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrite powders were prepared by self-propagating high temperature synthesis followed by classified by ultrasonic wet-magnetic separation method to get nano-sized particles with high purity. The $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrites were well formed by using several powders like iron, nickel oxide, zinc oxide and magnesium oxide at 0.1 MPa of oxygen pressure. The ultrasonic wet-magnetic separation of pre-mechanical milled ferrite powders produced the powders with average size of $3.7-0.8{\mu}m$. The addition of a surfactant during the separation process improved productivity more than twice. The coercive force, maximum magnetization and residual magnetization of the $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ nano-powders with 810 nm size were 45.89 Oe, 53.92 emu/gOe, 0.4 emu/Oe, respectively.

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$CO_2$/NOx-free 50kW 매체순환식 가스연소기 산화-환원 연속반응 실증 (Continuous Operation of $CO_2$/NOx-free 50kW Checmial-Looping Combustor)

  • 류호정;진경태;이창근
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.227-234
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    • 2004
  • For gaseous fuel combustion with inherent $CO_2$ capture and low NOx emission, chemical-looping combustion(CLC) may yield great advantages of savings of energy to $CO_2$ separation and suppressing the effect on environment. In chemical-looping combustor, fuel is oxidized by metal oxide medium (oxygen carrier particle) in a reduction reactor. Reduced particles are transported to oxidation reactor and oxidized by air and recycled to reduction reactor. The fuel and the air are never mixed, and the gases from reduction reactor, $CO_2$ and $H_2O$, leave the system as separate stream. The $H_2O$ can be easily separated by condensation and pure $CO_2$ is obtained without any loss of energy for separation. The purpose of this study is to demonstrate inherent $CO_2$ separation and no NOx emission and to confirm high $CO_2$ selectivity, no side reaction (i.e., carbon deposition, hydrogen generation) by continuous reduction and oxidation experiment in a 50kWtb chemical-looping combustor. NiO/bentonite particle was used as a bed material and $CH_4$ and air were used as reacting gases for reduction and oxidation respectively.

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