• Korean Chemical Engineering Research
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• v.57 no.5
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• pp.679-686
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• 2019

Characteristics of adsorption equilibrium, kinetic and thermodynamic of aniline blue onto activated carbon from aqueous solution were investigated as function of initial concentration, contact time and temperature. Adsorption isotherm of aniline blue was analyzed by Langmuir, Freundlich, Redlich-Peterson, Temkin and Dubinin-Radushkevich models. Langmuir isotherm model fit better with isothermal data than other isotherm models. Estmated Langmuir separation factors ($R_L=0.036{\sim}0.068$) indicated that adsorption process of aniline blue by activated carbon could be an effective treatment method. Adsorption kinetic data were fitted to pseudo first order model, pseudo second order model and intraparticle diffusion models. The kinetic results showed that the adsorption of aniline blue onto activated carbon well followed pseudo second-order model. Adsorption mechanism was evaluated in two steps, film diffusion and intraparticle diffusion, by intraparticle diffusion model. Thermodynamic parameters such as Gibbs free energy, enthalpy and entropy for adsorption process were estimated. Enthalpy change (48.49 kJ/mol) indicated that this adsorption process was physical adsorption and endothermic. Since Gibbs free energy decreased with increasing temperature, the adsorption reaction became more spontaneously with increasing temperature. The isosteric heat of adsorption indicated that there is interaction between the adsorbent and the adsorbate because the energy heterogeneity of the adsorbent surface.

• Journal of the Korean Association of Geographic Information Studies
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• v.22 no.2
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• pp.50-64
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• 2019

According to the Maritime Safety Act, there are all 34 routes including 5 traffic safety zones, 3 traffic separation schemes, 26 routes designated by regional maritime affairs departments in the Republic of Korea. In the SOLAS convention, the route information should be is effectively used for the safe navigation. However, the route information is complicatedly composed of the location of the route, the navigation rule by each route, the restriction of the navigation, and the anchorages. Moreover, the present method of providing information using the navigational chart and other publications is not effective for users to grasp the navigational information. Therefore, it was conducted to study the design of the S-100 based routing information data model developed by the International Hydrographic Organization to find ways to more effectively provide route information. To do this, the analysis of route requirement, selection of items, encoding test and users' review were carried out. Through expert user review, it was evaluated that the study on the design of the route information data model can be utilized as a good basic data for the route information integration service. Future research on the development of route information data models is expected to provide integrated route information services.

• Clean Technology
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• v.25 no.1
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• pp.56-62
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• 2019

The equilibrium, kinetic and thermodynamic parameters of adsorption of murexide by granular activated carbon were investigated. The experiment was carried out by batch experiment with the variables of the amount of the adsorbent, the initial concentration of the dye, the contact time and the temperature. The isothermal adsorption equilibrium was best applied to the Freundlich equation in the range of 293 ~ 313 K. From the separation factor (${\beta}$) of Freundlich equation, it was found that adsorption of murexide by granular activated carbon could be the appropriate treatment method. The adsorption energy (E) obtained from the Dubinin- Radushkevich equation shows that the adsorption process is a physical adsorption process. From the kinetic analysis of the adsorption process, pseudo second order model is more consistent than pseudo first order model. It was found that the adsorption process proceeded to a spontaneous process and an endothermic process through Gibbs free energy change ($-0.1096{\sim}-10.5348kJ\;mol^{-1}$) and enthalpy change ($+151.29kJ\;mol^{-1}$). In addition, since the Gibbs free energy change decreased with increasing temperature, adsorption reaction of murexide by granular activated carbon increased spontaneously with increasing temperature. The entropy change ($147.62J\;mol^{-1}\;K^{-1}$) represented the increasing of randomness at the solid-solution interface during the adsorption reaction of murexide by activated carbon.

• Journal of Korean Society on Water Environment
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• v.27 no.2
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• pp.200-209
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• 2011

The purpose of the study is to optimally manage sewage treatment plant with analysis of phosphorus contribution and improvement of water quality contributing rate in the effect of inflowing point of effluent and Pal-Dang lake after reducing T-P discharge from large scale public sewage treatment plant at upstream of Pal-Dang lake. Also, this study, for enforcement of T-P in effluent, plans optimal management of effluent T-P through examining propriety of environmental, technological, and economical aspect such as water quality standard of domestic and foreign T-P and related policy. In regarding optimal management of T-P discharged from public sewage treatment plant located in upstream of Pal-Dang lake, the study drew following conclusions. With the optimal management of public sewage treatment plant, it showed that a pollution level became higher in the order of Sumgang E in South-Han river, C in Dalcheon, B1 B2, A in North-Han river, and J in Kyungancheon, and it is required reduction of T-P first. The highest value in analysis of benefit-costs from sewage treatment plant in the selected research area was Kyungan B, and the others are with the order of Jojong A, Bokha A, Kyungan A, and Yanghwa A. With result of this study, all 14 areas are required more enforced phosphorus treatment. The study resulted that the most top priority areas were Hangang F, Sumgang B, and Gyungan A, top priority areas were Bokha A, Dalcheon B, and Cheongmi A, priority areas were Hangang E, Heukcheon A, Gyungan B, and Jojong A, and potential areas were Sumgang A, Yanghwa A, Dalcheon A, and Hangang D. It seems to be appropriate to apply 0.2 mg/L of T-P treatment for water supply source reservation, 0.5 mg/L for the other areas by locally, and 0.2~0.5 mg/L for biological nitrogen phosphorus treatment method and 0.5~1 mg/L for Conventional Activated Sludge by technologically. Also, it may be appropriate to apply 0.2 mg/L for the most top priority area(I), 0.3 mg/L for the top priority area(II), 0.4 mg/L for priority area(III), and 0.5 mg/L for potential area(IV) by the separation of priority area.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.41 no.6
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• pp.655-662
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• 2021

This study aimed to estimate exploitable groundwater for the sustainable supply of groundwater in the Jinju region of South Gyeongsang Province. As an integrated hydrologic analysis model, SWAT-MODFLOW was used to estimate the distributed groundwater recharge in consideration of land use and soil distribution. As a result of calibration of the model, the coefficient of determination between the observed flow and the simulated flow was 0.75-0.80, which was good. The simulated groundwater recharge rate showed a spatio-temporal distribution due to heterogeneous watershed characteristics. The amount of groundwater recharge shows lower values over winter and spring, but it increases according to the pattern of precipitation in summer and autumn. The calculated average annual groundwater recharge was compared with the result using the baseflow separation method of natural flow, and the deviation of both results was small, within 3 %, confirming the validity of the estimated groundwater recharge. Exploitable groundwater is defined as the amount of recharge corresponding to low flow with 10 years of return period. Therefore, in this study, 14.2 % of the annual precipitation was found to be exploitable as a result of calculating the amount of recharge at a 10-year frequency using a statistical frequency analysis technique.

• Journal of the Society of Disaster Information
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• v.18 no.3
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• pp.646-659
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• 2022

Purpose: In this study, we developed a 4-way sway prevention brace that efficiently reduces the installation area and has excellent stability and seismic performance compared to the conventionl sway prevention brace used in existing firefighting facilities. The performance and reliability of the developed 4-way way prevention brace were analyzed by the tensile, compression tests and seismic tests. Method: As the static test, 4-way sway prevention braces were installed on the horizontal and vertical pipes to perform the tensile and compression tests based on the KFI certification standard and the maximum movement was measured at the rated load. As a dynamic test, 4-way sway prevention braces were installed in the pipes filled with water, and the test response spectrum to the input excitation wave were measured through the acceleration sensors. After the seismic tests, separation, failure, and local deformation of the pipes, and 4-way sway prevention braces were not observed. Result: The results of the tensile and compression tests indicated that the maximum movement of the pipe during tension and compression was 50% to 70% or less compared to the certification values, indicating that the performances of the 4-way sway prevention braces were very excellent. The results of the the seismic tests indicated that the test response spectrum of the 4-way sway prevention braces is within the required response spectrum. Conclusion: In this study, it was found that the 4-way sway prevention braces satisfied the KFI certification standard and were superior compared to the existing sway prevention brace in terms of the stability, cost, and installation area.

• Membrane Journal
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• v.32 no.2
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• pp.150-162
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• 2022

In the field of water treatment and pharmaceutical bio an alumina hollow fiber membrane used for mixture separation. However, due to the lack of strengths it is very brittle to handle and apply. Therefore, it is necessary to study and improve the bending strength of the membrane to 100 MPa or more. In this study, as the mixing ratio of the nano-particles increased to 0, 1, 3, and 5 wt%, the viscosity of the fluid mixture increased. The pore structure of the hollow membrane produced by interrupting the diffusion exchange rate of the solvent and non-solvent during the spinning process suppresses the formation of the finger-like structure and gradually increases the ratio of the sponge-like structure to improve the membrane mechanical strength to more than 100 MPa. As a result, an interparticle space was ensured to improve the porosity of the sponge-like structure with high permeability, and it showed excellent N2 permeability of about 100000 GPU and high water permeability of 3000 L/m² h. Therefore, it can be concluded, that the addition of γ-Al₂O₃ nanoparticles as sintering aid is an important method to enhance the mechanical strength of the α-alumina hollow fiber membrane to maintain high permeability.

• Journal of Software Assessment and Valuation
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• v.17 no.2
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• pp.11-17
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• 2021

In this study, problems of software completeness appraisal are pointed out and their solutions are presented by analyzing appraisal cases and judicial precedents. Completeness appraisal, ready-made appraisal, defect appraisal, and cost appraisal have been classified as and have been evaluated with extant software completeness appraisals. From a legal point of view, and in judicial precedents, however, there is a big difference between the definition of completeness and the completion rate. This is because the degree of completeness is evaluated under the premise that the software's development is complete, whereas the ready-made appraisal inspects the development progress of unfinished software. Often, in cases involving software completion rate, the total completion level is calculated by weighting each step of the software development process. However, completeness evaluations use the software's realization-operation as its sole criterion. In addition, another issue not addressed in existing software completeness appraisal cases is that there is no mention of who is responsible for software defects, whereas in case law, the responsible party is determined by finding who caused the dispute. In this paper, we systematically classify these problems, and present a novel evaluation method that separates software completeness evaluations from software completion evaluations.

• The Journal of the Acoustical Society of Korea
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• v.42 no.3
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• pp.250-261
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• 2023

In this study, the noise contributions by the duct, stator and rotor, which are the propulsor components, are evaluated to identify the flow noise source in cavitation and non-cavitation conditions on pumpjet propulsion and the noise levels in both conditions are compared. The unsteady incompressible Reynolds averaged Navier-Stokes (RANS) equation based on the homogeneous mixture assumption is applied on the suboff submarine hull and pumpjet propeller in the cavitation tunnel, and the Volume of Fluid (VOF) method and Schnerr-Sauer cavitation model are used to describe the two-phase flow. Based on the flow simulation results, the acoustic analogy formulated by Ffowcs Williams and Hawkings (FW-H) equation is applied to predict the underwater radiated noise. The noise contributions are evaluated by using the three types of impermeable integral surface on the duct, stator and rotor, and the two types of permeable integral surface surrounding the propulsor. As a result of noise prediction, the contribution by the stator is insignificant, but it affects the generation of flow noise source due to flow separation in the duct and rotor, and the noise is predominantly radiated into the upward and right where the flow separations are. Also, the noise is radiated into the thrust direction due to pressure fluctuation between suction and pressure sides on the rotor blades, and the it can be seen that the cavitation effect into the noise can be considered through the permeable integral surface.

• Resources Recycling
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• v.32 no.2
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• pp.3-11
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• 2023

The aim of this study was to develop a physical treatment method for obtaining iron concentrate with a grade higher than 60% from slag generated in the Waelz Kiln (WK) process. The size of the WK slag used in this work was several millimeters, with T-Fe and ZnO contents of 40.24% and 1.03%, respectively. The slag samples were pulverized in a laboratory rod mill for various grinding times, followed by a magnetic separation test under a low magnetic intensity of 0.05 T initially. The results showed that the highest iron grade was obtained from samples with a grinding time of 10 min. Additionally, for a grinding time of 20 min, the highest grade and recovery ratios were achieved at a magnetic intensity of 0.8 T. Based on these findings, the optimal physical treatment process proposed in this study resulted in iron concentrates with a grade of 61.34% and an enrichment ratio of 1.52.