• Title/Summary/Keyword: Separation Factor

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Solvent Extraction for the Separation of Nd and Pr from Chloride Leaching Solution of Monazite Sand (모나자이트 샌드의 염산침출용액으로부터 용매추출에 의한 Nd와 Pr의 분리)

  • Park, Ju-Ho;Jeon, Ho-Seok;Lee, Man-Seung
    • Resources Recycling
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    • v.23 no.1
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    • pp.17-24
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    • 2014
  • Solvent extraction experiments have been performed to separate Nd and Pr from chloride leaching solution of monazite sand using PC88A and D2EHPA. For this purpose, the effect of the saponification of PC88A and D2EHPA on the extraction and separation of the two metals were studied by varying the pH of aqueous solution. In the experimental ranges conducted in this study, the distribution coefficients of Nd were higher than those of Pr and separation factor value increased with the increase of solution pH. Saponification of PC88A enhanced the distribution coefficients of Nd and Pr as well as the separation factor. Saponification of D2EHPA had some effect on the extraction of the two metals but little effect on the separation factor.

An Analysis for the Characteristics of Headward Erosion and Separation Zone due to Bed Discordance at Confluence (합류부 하상고 불일치에 의한 두부침식 및 분리구역 특성분석)

  • Choi, Heung Sik;Mo, Sun Jea;Lee, Sam Hee
    • Journal of Korea Water Resources Association
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    • v.48 no.11
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    • pp.879-889
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    • 2015
  • The pattern of headward erosion at tributary and the separation zone formation in a loosed bed at confluence according to the confluence angle, discharge ratio, and dredging depth ratio have been analyzed. The separation zone is defined the inside of zero velocity boundary at downstream of confluence. The limit of separation zone occurrence is presented with dredging depth ratio. The propagation length of knickpoint increases as the confluence angle, discharge ratio, and dredging depth ratio increase in general and its regression equation has been suggested. The length and width ratios of separation zone in a loosed bed increase as discharge ratio and confluence angle increase as well as in a fixed bed. The length ratio decreases and the width ratio increases as dredging depth ratio increases results in great increase of shape factor and backwater rise by the conveyance reduction at confluence. The regression equation of shape factor with confluence angle, discharge ratio, and dredging depth ratio has been suggested.

A Study on Temperature and Retaining Ion Effect on the Separation of Lanthanides (란탄계열원소들의 양이온교환분리에서의 온도와 보유이온의 영향에 관한 연구)

  • Young-Gu Ha;Bong-Il Ji
    • Journal of the Korean Chemical Society
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    • v.33 no.6
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    • pp.601-606
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    • 1989
  • The effects of temperature and retaining ion on the separation factor (${\alpha}$) and distribution ratio (D) of some lanthanides ($Pr^{3+},\;Nd^{3+},\;Sm^{3+},\;and\;Er^{3+}$) have been studied in the EDTA solution as an elutant by using Amberite IR 120 + resin. The retaining ions on the resin were ${NH_4}^+,\;Na^+,\;K^+,\;Mg^{2+},\;Ca^{2+},\;Zn^{2+}$and $Ce^{3+}$. Separation factor of Nd/Pr is much improved by using $Ce^{3+}$ as retaining ion. The distribution ratios were decreased with the increase of temperature, but separation factors did not always increase with the increase of temperature. However, in the case of $Ce^{3+}$ as retaining ion, separation factors of Nd/Pr and Sm/Nd were increased with the increasing of temperature. And also in the case of $Zn^{2+}$ as retaining ion, separation factor of Er/Sm was increased with the increasing of temperature.

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Effect of Cu(II) and Al(III) on the Extraction and Separation of Pt(IV) and Pd(II) from Concentrated Hydrochloric Acid Solution with Alamine336 (진한 염산용액에서 구리(II)와 알루미늄(III)이 Alamine336에 의한 백금(IV)과 팔라듐(II)의 추출 및 분리에 미치는 영향)

  • Lee, Manseung;Ahn, Jonggwan;Sun, Panpan
    • Korean Journal of Metals and Materials
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    • v.48 no.2
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    • pp.148-153
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    • 2010
  • The effects of Cu(II) and Al(III) on the extraction and separation of Pt(IV) and Pd(II) have been investigated in a mixed chloride solution using Alamine336 as the extractant. In the HCl concentration range of 1 to 5 M, more than 99% of Pt and Pd could be extracted by Alamine336 from all of the mixed chloride solutions investigated in this study. Lower HCl concentration led to a higher separation factor between Pd and Pt when Alamine336 concentration was constant. Extraction percentage of Cu increased with the increase of HCl concentration, while that of Al was nearly constant at 33% in our experimental range. The optimum conditions to extract Pt and Pd from Cu or Al and the separation factor under these conditions were obtained.

Molybdenum isotopes separation using squared-off optimized cascades

  • Mahdi Aghaie;Valiyollah Ghazanfari
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3291-3300
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    • 2023
  • Recently molybdenum alloys have been introduced as accident tolerating materials for cladding of fuel rods. Molybdenum element has seven stable isotopes with different neutron absorption cross section used in various fields, including nuclear physics and radioisotope production. This study presents separation approaches for all intermediate isotopes of molybdenum element by squared-off cascades using a newly developed numerical code with Salp Swarm Algorithm (SSA) optimization algorithm. The parameters of cascade including feed flow rate, feed entry stage, cascade cut, input feed flow rate to gas centrifuges (GCs), and cut of the first stage are optimized to maximize both isotope recovery and cascade capacity. The squared off and squared cascades are studied, and the efficiencies are compared. The results obtained from the optimization showed that for the selected squared off cascade, Mo94 in four separation steps, Mo95 in five steps, Mo96 in six steps, Mo97 in seven steps, and Mo98 in two steps are separated to the desired concentrations. The highest recovery factor is obtained 63% for Mo94 separation and lowest recovery factor is found 45% for Mo95.

Consumer Evaluation on Visual Sensibility of Stripe Pattern Shirts - Focusing on Separation Coloration - (줄무늬 셔츠의 시각적 감성에 대한 소비자 평가 - 세퍼레이션 배색을 중심으로 -)

  • Choi, Soo-Kyoung
    • Journal of the Korea Fashion and Costume Design Association
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    • v.16 no.2
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    • pp.71-80
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    • 2014
  • The purpose of this study was to investigate consumer evaluation on visual sensibility of stripe pattern shirts for separation coloration. The experimental materials developed for this study were a set of clothing stimuli and response scales. The clothing stimuli were 27 color pictures, in which separation color(white: W, gray: G, black: B), separation width(small: S, medium: M, large: L), and combination color(magenta and yellow: MY, magenta and cyan: MC, yellow and cyan: YC) were manipulated. The subjects of this research were female in their 20s to 30s living in Seoul, Gwangju, Daegu, Busan, and Changwon. The investigation was carried out at December 2013. The data were analyzed by using SPSS program. Analysis methods were factor analysis, ANOVA, and Duncan-test. Results of this study were as follow.; The factors of visual sensibility according to separation color, separation width, and combination color consisted of four dimensions of attractiveness, appeal, individuality freshness, and grace. Separation color showed an independent effect on appeal and individuality freshness. Combination color showed an independent effect on individuality freshness. Interaction effects of separation color and separation width on appeal were found. Interaction effects of separation color and combination color on individuality freshness and grace were found. The study results are highly expected to be used as useful sources in a fashion product.

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A Study of Interpretation of Separation Behavior in Gas Expansion Separation(GES) Bolt (가스팽창분리형 볼트 분리거동 해석 연구)

  • Lee Young Jo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.9 no.1
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    • pp.27-34
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    • 2005
  • The present work has been developed the study of interpretation of separation behavior in gas expansion separation(GES) bolt which has the separation characteristics without fragmentation and minimum pyre-shock during the operation of the explosive bolt. In order to obtain the performance of minimum pyre-shock, the present work used non-compressive material instead of separation explosives. The use of the interpretation processor could be extensively helped to design the shape and the amount of explosives in the explosive bolt having complex geometry, and to analyse the separation behavior during the operation. It is also proved that the GES bolt is the most suitable the separation system necessary to minimum pyre-shock and non fragmentation compare with others.

The Relationship between Affinity of Membrane and Optimum Operation Conditions in the Pervaporation of Aqueous Ethanol (에탄올 수용액의 투과증발에 있어서 막의 친화성과 최적 조업조건의 관계)

  • 전종기;명완재;임선기
    • Membrane Journal
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    • v.1 no.1
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    • pp.34-43
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    • 1991
  • The relationships between affinity of membranes and optimum operation conditions were investigated in the pervaporation of water(1)/ethanol(2) mixture through cellulose acetate(CA) membranes having more affinity to water and silicone rubber(SR) membranes having more affinity to ethanol. CA and SR membranes were prepared and amount of sorption, sorption selectivity, pervaporation separation factor and pervaporation rate in both of membranes were determined and compared. The effects of downstream pressure were analyzed using Thompson diagram and the sorption and pervaporation characteristics with composition of feed and operation temperature were examined in terms of affinity, activity coefficient, plasticizing effect and activation energy of individual species. In the separation of water through CA membranes, high performance of both pervaporation separation factor (water to ethanol, $[\alpha^2_1]_{PV}$) and pervaporation rate was obtained in the conditions of low downstream pressure, middle range of feed concentration and high temperature. In the separation of ethanol through SR membranes, pervaporation separation factor(ethanol to water, $[\alpha^2_1]_{PV}$) increased with downstream pressure and decreased with concentration of ethanol in feed and operation temperature, while pervaporation rate showed opposite trends to those of ($[\alpha^2_1]_{PV}$).

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Pervaporation Separation of Water/Ethanol Mixture Using PVA/PSSA-MA Ion Exchange Membranes (PVA/PSSA-MA 이온교환막을 이용한 물/에탄올 계의 투과증발분리)

  • Rhim Ji-Won;Cho Hyun-Il;Seo Moo-Young;Kim Dae-Hoon;Park In-Cheul;Nam Sang-Yong
    • Membrane Journal
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    • v.16 no.3
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    • pp.235-239
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    • 2006
  • This study illustrated the results of pervaporation separation using crosslinked poly(vinyl alcohol) (PVA) with poly(styrene sulfonic acid-co-maleic acid) (PSSA-MA) for water-ethanol system at 25, 35, and $45^{\circ}C$. The contents of the crosslinking agents were 7, 9, and ll wt% against PVA and the feed compositions of 50, 20, 10 and 4.4% in water were investigated. Typical trends of permeability and separation factor in pervaporation were observed for both the crosslinking agents and operating temperatures. For water : ethanol = 10 : 90, and at $45^{\circ}C$, PSSA-MA 11 wt% membrane showed the permeability $58.92g/m^2{\cdot}hr$ and the separation factor 12003 respectively.