• Journal of the Korean Institute of Gas
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• v.10 no.2 s.31
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• pp.22-26
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• 2006

In this study, modeling and simulation works using Aspen Plus were carried out for DME separation and purification process of pilot plant for the daily production of 50 kg of DME. For modeling of the entire DME separation unit, NRTL liquid activity coefficient model was used for the prediction of liquid phase non-idealities, Henry's law option was also used for the estimation of solubilities of light gases in solvents and SRK equation of state model was utilized for the description of vapor phase non-idealities. DME having over 98 wt% purity was obtained as a side distillate product in a DME purification column.

• Journal of computational fluids engineering
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• v.18 no.2
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• pp.66-71
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• 2013

In this paper, the supersonic flows around space launch vehicles have been numerically simulated by using a 3-D RANS flow solver. The focus of the study was made for investigating plume-induced flow separation(PIFS). For this purpose, a vertex-centered finite-volume method was utilized in conjunction with 2nd-order Roe's FDS to discretize the inviscid fluxes. The viscous fluxes were computed based on central differencing. The Spalart-Allmaras model was employed for the closure of turbulence. The Gauss-Seidel iteration was used for time integration. To validate the flow solver, calculation was made for the 0.04 scale model of the Saturn-5 launch vehicle at the supersonic flow condition without exhaust plume, and the predicted results were compared with the experimental data. Good agreements were obtained between the present results and the experiment for the surface pressure coefficient and the Mach number distribution inside the boundary layer. Additional calculations were made for the real scale of the Saturn-5 configuration with exhaust plume. The flow characteristics were analyzed, and the PIFS distances were validated by comparing with the flight data. The KSLV-1 is also simulated at the several altitude conditions. In case of the KSLV-1, PIFS was not observed at all conditions, and it is expected that PIFS is affected by the nozzle position.

• Membrane and Water Treatment
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• v.7 no.3
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• pp.223-240
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• 2016

In this study, poly(vinyl-alcohol) and water insoluble ${\beta}$-cyclodextrin polymer (${\beta}$-CDP) cross-linked with citric acid, have been used as macrocyclic carrier in the preparation of polymer inclusion membranes (PIMs) for aniline (as molecule model) extraction from aqueous media. The obtained membranes were firstly characterized by X-ray diffraction, Fourier transform infrared and water swelling test. The transport of aniline was studied in a two-compartment transport cell under various experimental conditions, such as carrier content in the membranes, stirring rate and initial aniline concentration. The kinetic study was performed and the kinetic parameters were calculated as rate constant (k), permeability coefficient (P) and flux (J). These first results demonstrated the utility of such polymeric membranes for environmental decontamination of toxic organic molecules like aniline. Predictive modeling of transport flux through these materials was then studied using design of experiments; the design chosen was a two level full factorial design $2^k$. An empirical correlation between aniline transport flux and independent variables (Poly ${\beta}$-CD membrane content, agitation speed and initial aniline concentration) was successfully obtained. Statistical analysis showed that initial aniline concentration of the solution was the most important parameter in the study domain. The model revealed the existence of a strong interaction between the Poly ${\beta}$-CD membrane content and the stirring speed of the source solution. The good agreement between the model and the experimental transport data confirms the model's validity.

• Korean Chemical Engineering Research
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• v.59 no.1
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• pp.106-111
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• 2021

In this study, an ultrasound-assisted micellar extraction process was developed to efficiently purify the anticancer substance paclitaxel from the plant cell Taxus chinensis. The problem of many extraction steps and long phase separation time in the traditional micellar process could be dramatically improved. The highest paclitaxel yield (~96%, extracted twice) was obtained at 180 W of ultrasonic power and 1.5 h of ultrasonic irradiation time, which was 24.7% higher than that of the traditional method. In addition, the partition coefficient (K) showed a maximum value (24.0) at 180 W of ultrasonic power and 1.5 h of irradiation time. There was no significant difference in the purity of paclitaxel, and the purity of initial paclitaxel (6.81%) increased to 22.0% after purification. Compared to the traditional method, the phase separation time of the back extraction decreased by 40.7-56.2% (ultrasonic power 80 W), 46.3-67.6% (ultrasonic power 180 W), and 51.9-67.6% (ultrasonic power 250 W), respectively. The phase separation time decreased as the ultrasonic power (80-250 W) and irradiation time (0.5-2.5 h) increased.

• Advances in nano research
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• v.10 no.3
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• pp.295-312
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• 2021

A new ionic liquid functionalized magnetic silica nanoparticle was synthesized and characterized and tested as an adsorbent. The adsorbent was used for magnetic solid phase extraction on ICP-MS method. Simultaneous determination of precious metal Au has been addressed. The method is simple and fast and has been applied to standard water and surface water analysis. A new method for separation/analysis of trace precious metal Au by Magnetron Solid Phase Extraction (MSPE) combined with ICP-MS. The element to be tested is rapidly adsorbed on CoFe2O4@SiO2@[BMIM]PF6 composite nano-adsorbent and eluted with thiourea. The method has a preconcentration factor of 9.5-fold. This method has been successfully applied to the determination of gold in actual water samples. Hydrophobic Ionic Liquids (ILs) 1-butyl-3-methylimidazole hexafluorophosphate ([BMIM]PF6) coated CoFe2O4@SiO2 nanoparticles with core-shell structure to prepare magnetic solid phase extraction agent (CoFe2O4@SiO2@ILs) and establish a new method of MSPE coupled with inductively coupled plasma mass spectrometry for separation/analysis of trace gold. The results showed that trace gold was adsorbed rapidly by CoFe2O4@SiO2@[BMIM]PF6 and eluanted by thiourea. Under the optimal conditions, preconcentration factor of the proposed method was 9.5-fold. The linear range, detection limit, correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.01~1000.00 ng·mL-1, 0.001 ng·mL-1, 0.9990 and 3.4% (n = 11, c = 4.5 ng·mL-1). The CoFe2O4@SiO2 nanoparticles could be used repeatedly for 8 times. This proposed method has been successfully applied to the determination of trace gold in water samples.

• Wind and Structures
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• v.34 no.5
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• pp.437-450
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• 2022

Vortex-induced vibration (VIV) is a significant concern when designing slender structures with square cross sections. VIV strongly depends on structural dynamics and flow states, which depend on the conditions of the approaching flow and shape of a structure. Therefore, the effects of the angle of attack on the coupling effects of VIV for a square cylinder are expected to be significant in practice. In this study, the aerodynamic forces for a fixed and elastically mounted square cylinder were measured using wind pressure tests. Aerodynamic forces on the stationary cylinder are firstly discussed by comparisons of variation of statistical aerodynamic force and wind pressure coefficient with wind angle of attack. The coupling effect between the aerodynamic forces and the motion of the oscillating square cylinder by VIV is subsequently investigated in detail at typical wind angels of attack with occurrence of three typical flow regimes, i.e., leading-edge separation, separation bubble (reattachment), and attached flow. The coupling effect are illustrated by discussing the onset of VIV, characteristics of aerodynamic forces during VIV, and interaction between motion and aerodynamic forces. The results demonstrate that flow states can be classified based on final separation points or the occurrence of reattachment. These states significantly influence coupling effects of the oscillating cylinder. Vibration enhances vortex shedding, which creates strong fluctuations in aerodynamic forces. However, differences in the lock-in range, aerodynamic force, and interaction process for angles of attack smaller and larger than the critical angle of attack revealed noteworthy characteristics in the VIV of a square cylinder.

• Resources Recycling
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• v.25 no.6
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• pp.50-57
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• 2016

This work was examined the extraction and stripping behavior of rare earths (La, Ce, Pr, Nd, Sm) from the hydrochloric acid solution by Cyanex 572 and compared to the results that of PC88A. Experimental parameters such as equilibrium pH, extractant & strip reagent concentration were observed and extraction percentage, distribution coefficient, stripping percentage and the separation factor of the adjacent element were analyzed. The $pH_{50}$ values was more higher using Cyanex 572 than that of PC88A. As the increase of the extractant concentration, the distribution coefficient of rare earth elements was increased. Stripping percentage of rare earth elementss from the Cyanex 572 was 85% to 95% and PC88A showed 80% to 87%. Separation factor of Ce/La, Ce/Pr, Pr/Nd, Nd/Sm was enhanced about 1.0-5.0 using Cyanex 572 as an extractant in mixture solution.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2267-2272
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• 2007

The present study investigates the two dimensional flow and heat/mass transfer characteristics of wavy duct with various corrugation angles. For the heat/mass transfer coefficients, a naphthalene sublimation technique is used. Numerical analysis and wall pressure measurement show detailed two dimensional flow features. The corrugation angles change from 145$^{\circ}$ to 100$^{\circ}$. The operating Reynolds numbers based on the duct hydraulic diameter vary from 700 to 3,000. The duct aspect ratio maintains 7.3. On the pressure wall, strong flow mixing enhances heat/mass transfer coefficients at the front position. In addition, the rear side of pressure wall, the near of peak, is affected by the acceleration and the shedding of main flow. On the suction wall, however, flow separation and reattachment lead to the valley and the peak of heat/mass transfer coefficient. Also, highly increasing boundary layer at the suction wall affects the decrease of heat/masst transfer. As decreasing corrugation angles, the spanwise average Sherwood number increases and the peak or the valley positions of the local Sherwood number are varied.

• Proceedings of the IEEK Conference
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• 2004.08c
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• pp.653-657
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• 2004

The average bit error rate (HER) performance of a Gray coded arbitrary rectangular quadrature amplitude modulation (AR-QAM) signal with maximal ratio combining (MRC) diversity in an arbitrarily correlated Nakagami-m fading channel is derived and analyzed. The derived two types of general solutions are a simple closed-form and an integral form, depending on the types of the values (integer and non-integer) of the fading parameter. Using the derived equations in this paper, we analyzed the HER performances numerically based on the practical base station antenna configuration. The results show that MRC reception is a very effective scheme so far even though the combined signals are not independent each other because of the correlation values. The antenna height and separation of the MRC system relate to the correlation coefficient value between antennas, and go a long way with the diversity advantage. In particular, it is needed to be determined the antenna height that is carefully do for the diversity advantage because the correlation coefficient and the antenna height gain are contrary to each other from the aspect of the system performance. The expressions presented here can offer a convenient way to evaluate the exact HER performance of an arbitrary rectangular QAM signal with MRC diversity reception for various cases of practical interest on a correlated Nakagami fading channel.

• KSBB Journal
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• v.14 no.5
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• pp.633-637
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• 1999

Supercritical fluid of carbon dioxide was used to investigate the effects of its temperature and density on the distribuion coefficients of fatty-acid esters composing fish oil. The distribution coefficient of fatty acid ester was greatly different from each other according to the temperature and density of the supercritical fluid. The possibility of separation of a certain fatty acid from the mixture of fatty acids was tested. The density of the supercritical fluid showing the great differences ofthe distribution coefficients among the fatty acid esters ranged from 0.3 g/mL to 0.4 g/mL. The retrograde condensation took place at high densities of the supercritical fluid.