• Bulletin of the Korean Chemical Society
• /
• v.34 no.7
• /
• pp.2167-2170
• /
• 2013

A low-cost and simple recycling process of waste thermoelectric modules has been investigated using chemical reduction methods. The recycling is separated by two processes, such as dissolving and reduction. When the waste thermoelectric chips are immersed into a high concentration of $HNO_3$ aqueous solution at $100^{\circ}C$, oxide powders, e.g., $TeO_2$ and $Sb_2O_3$, are precipitated in the $Bi^{3+}$ and $HTeO{_2}^+$ ions contained solution. By employing a reduction process with the ions contained solutions, $Bi_2Te_3$ nanoparticles are successfully synthesized. Due to high reduction potential of $HTeO{_2}^+$ to Te, Te elements are initially formed and subsequently $Bi_2Te_3$ nanoparticles are formed. The average particle size of $Bi_2Te_3$ was calculated to be 25 nm with homogeneous size distribution. On the other hand, when the precipitated powders reduced by hydrazine, $Sb_2O_3$ and Te nanoparticles are synthesized because of higher reduction potentials of $TeO_2$ to Te. After the washing step, the $Sb_2O_3$ are clearly removed, results in Te nanoparticles.

• Membrane and Water Treatment
• /
• v.11 no.3
• /
• pp.189-193
• /
• 2020

In this study, electrokinetic remediation equipment was used to remove cesium (Cs) from clay soil and waste solution was treated with sorption process. The influence of electrokinetic process on the removal of Cs was evaluated under the condition of applied electric voltage of 15.0-20.0 V. In addition to monitoring the Cs removal, electrical current and temperature of the electrolyte during experiment were investigated. The removal efficiency of Cs from soil by electrokinetic method was more than 90%. After electrokinetic remediation, Cs was selectively separated from soil waste solution using sorbents. Various adsorption agents such as potassium nickel hexacyanoferrate (KNiHCF), Prussian blue, sodium tetraphenylborate (NaTPB), and zeolite were compared and KNiHCF showed the highest Cs removal efficiency. The Cs adsorption on KNiHCF reached equilibrium in 30 min. The maximum adsorption capacity was 120.4 mg/g at 0.1 g/L of adsorbent dosage. These results demonstrated that our proposed process combined electrokinetic remediation of soil and waste solution treatment with metal ferrocyanide can be a promising technique to decontaminate Cs-contaminated fine soil.

• Membrane and Water Treatment
• /
• v.11 no.1
• /
• pp.25-29
• /
• 2020

The purpose of this study was to investigate the characteristics of lignin fractionated from waste wood (WW) using a two-step process of ethanol organosolv pretreatment followed by ultrafiltration with membranes of different molecular weight cut-offs (1, 5 and 20 kDa). The different permeates obtained were characterized by fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA) and gel permeation chromatography (GPC). The analysis by FT-IR and NMR of these lignins showed that the lignin core was successfully separated from WW. TGA curves confirmed that the thermal properties of lignin fractionated by ultrafiltration were almost identical to each other. The results from GPC confirmed that fractionating of lignin was achieved by ultrafiltration. For the membrane fractionation process, values of molecular weight decreased as the cut-offs used to obtain the fractions became smaller. As a result, fractionating lignin by a two-step process allowed separating different fractions of lignin of different molecular weights yielded high purity without interference from existing pollutants in WW. The two-step process offers the possibility of using fractionated WW as an untapped source of lignin.

• Journal of ILASS-Korea
• /
• v.7 no.2
• /
• pp.7-15
• /
• 2002

A particle flow visualization, electrostatic charging measurement and separation of triboelectrically charged particles in the external electric field by a fluidized bed tribocharger are conducted for the removal of PVC particles from mixed waste plastics. The laboratory-scale triboelectrostatic separation system consists of the fluidized bed tribocharger, a separation chamber, a collection chamber and a controller. PVC and PET particles can be imparted negative and positive surface charges respectively due to the difference of triboelectric charging series between particles and particles in the fluidized bed tribocharger, and can be separated by passing them through an external electric field. To visualize these charged particles, He-Ne laser is used with cylindrical lenses to generate a sheet beam. In the charging measurement, the particle motion analysis system (PMAS), capable of determining particle velocity and diameter. is used to non-intrusively measure particle behavior in high strength electric field. The average charge-to-mass ratios of PVC and PET particles are $1.4\;and\;1.2{\mu}C/kg$, respectively. The highly concentrated PVC (91.9%) can be recovered with a yield of about 96.1% from the mixture of PVC and PET materials for a single-stage processing. The triboelectrostatic separation system using the fluidized tribocharger shows the potential to be an effective method for removing PVC from mixed plastics for waste plastic recycling.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2008.06a
• /
• pp.295-295
• /
• 2008

This study introduced waste water treatment method applied superconductor HGMS(High Gradient Magnetic Separation). HGMS method treat high efficient method for various waste water. we have surveyed superconducting magnetic separation technology and reviewed the status of related industries using applied superconductivity. We fabricated the prototypes of magnetic matrix filter consisting of stainless steel mesh, which is a core component in the magnetic separation system. In our basic preliminary experiment using HGMS, it was made clear that the fine para-magnetic particles in the rolling colling wasted water obtained from rolling process of POSCO can be separated with high efficiency.

• Korean Journal of Agricultural Science
• /
• v.37 no.2
• /
• pp.267-270
• /
• 2010

This study was carried out to manufacture black charcoal board from domestic wood waste by using serum protein adhesive which is natural, environment-friendly and human-friendly. For the preparation of the serum protein adhesive, pig blood from slaughterhouse was centrifuged and serum was separated from corpuscles and concentrated to 30% by dry weight basis. The particle size of charcoal from domestic wood waste for this study was #6-60. Hot pressing schedule was $170^{\circ}C$ and 40kgf/$cm^2$ (1 min)-10kgf/$cm^2$ (2.5 min)-40kgf/$cm^2$ (5 min). The black charcoal board made by the addition of 13% serum protein adhesive on dry weight basis gave 41.76kgf/$cm^2$ of bending strength, 8.12kgf/$cm^2$ of internal bonding strength, and excellent gas adsorption and workability.

• Journal of the Korean Ceramic Society
• /
• v.48 no.5
• /
• pp.454-457
• /
• 2011

We report the preparation of nanocrystalline cobalt ferrite, $CoFe_2O_4$, particles using recycled $Co_3O_4$ and their surface coating with silica using micro emulsion method. Firstly, the $Co_3O_4$ powders were separated from waste cemented carbide with acid-base chemical treatment. The cobalt ferrite nanoparticles with the size 10 nm are prepared by thermal decomposition method using recycled $Co_3O_4$. $SiO_2$ was coated onto the $CoFe_2O_4$ particles by the micro-emulsion method. The $SiO_2$-coated $CoFe_2O_4$ particles were studied their physical properties and characterized by X-ray diffraction (XRD), high resolution-transmission electron microscopy (TEM) analysis and CIE Lab value.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.4 no.1
• /
• pp.89-95
• /
• 2009

The current enforce decree of "The Act on the Promotion of Construction Waste Recycling" divides seventeen kinds of construction wastes by property and configuration. Mixed construction waste, one of them classified by the enforce decree, is composed two more than justified construction wastes except refuse soil and rock. In construction wastes justified by enforce decree of this law, most refuse concrete and asphalt concrete of construction wastes are recycled. As well as refuse metal is separated, sorted from bulk them, and merchandised for value. Finally this is used the secondary manufactured products. Even though combustible construction wastes like refuse wood, plastics, fiber can be recycled RDF(Refuse derived fuel) or RPF(Refuse plastic fuel) because of high caloric value and low heavy metal but most of them are discharged as mixed construction waste and then treated by treated by incineration and landfill. Therefore, to control construction waste flow efficiently, construction wastes are classifies first combustible, incombustible, mixed combustible, incombustible and etc. in this study. The combustible waste is consisted refuse wood, plastics, fiber and etc. and incombustible waste contains refuse concrete, asphalt, and etc. Mixed construction is construction waste that can not separate from mixed waste bulk with different kinds.

• Resources Recycling
• /
• v.15 no.1 s.69
• /
• pp.28-36
• /
• 2006

The development of material separation technique for waste plastic recycling are the necessary situation restricted by law the reclamation and incineration of waste plastic after 2004, with enforcement of EPR (Extended Producer Responsibility) system. As the this study is the research on the development of electrostatic separation techniques for recycling of life circles waste plastic by development of charging material and charger, the separation efficiency can be improved. Therefore, we developed the charger and electrostatic separator to increase charging efficiency and material separation per object plastics, rising these equipments, we removed PVC up to $99\%$ from two kinds of mixed plastics. And in case of restricting PVC content such as PET, we developed the separation technique that can remove PVC up to $99.99\%$ from PET with PET recovery about $80\%$. Also, as we separated over $98\%$ for three kinds of mixed plastics, and then established material separation technique to increase recycling of plastic.

• Proceedings of the Korean Institute of Resources Recycling Conference
• /
• 2005.10a
• /
• pp.23-33
• /
• 2005

The development of material separation technique for waste plastic recycling are the necessary situation according to restrict by law the reclamation and incineration of waste plastic after 2004 year, pith enforcement of EPR (Extended Producer Responsibility) system. As the this study is the research on the development of electrostatic separation techniques for recycling of life circles waste plastic, it can improve separation efficiency according to development of charging material and charger. Therefore, we developed the charger and electrostatic separator to increase charging efficiency and material separation per object plastics, using these equipments, we removed PVC up to 99% from two kinds of mixed plastics. And in case of restricting PVC content such as PET, we developed the separation technique that can remove PVC up to 99.99% from PET with PET recovery about 80%. Also, as we separated over 98% for three kinds of mixed plastics, and then established material separation technique to increase recycling of plastic.