• Title/Summary/Keyword: Semipermeable

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The effect of backing layer for pro membranes and modules (PRO 분리막 및 모듈성능에 지지체가 미치는 영향)

  • Han, Man Jae;Jeon, Eun Joo;Sim, Yeon-Ju;Lee, Jong Hwa
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.5
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    • pp.553-559
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    • 2016
  • There has been increasing global interest in the environmental pollution problems produced by fossil fuel consumption and greenhouse gas emissions. In order to tackle these issues, new renewable energy such as solar, wind, bio gas, fuel cell and pressure retarded osmosis(PRO) have been developed extensively. Among these energy sources, PRO is one of the salinity gradient power generation methods. In PRO, energy is obtained by the osmotic pressure generated from the concentration difference between high and low concentration solutions separated by a semipermeable membrane. The development for high power density PRO membranes is imperative with the purpose of commercialization. This study investigates development of thin film composite PRO membrane and spiral wound module for high power density. Also, the influence of membrane backing layer on power density was identified, and the characteristic factors of PRO membranes was determined. Different backing layers were used to improve power density. As expected, the PRO membrane with more porous backing layer showed higher power density.

Dialysis Related Treatment to Increase Elimination of Toxic Agent (독성 물질 제거에 있어서 투석과 연관된 치료)

  • Kim, Heung-Soo;Shin, Gyu-Tae
    • Journal of The Korean Society of Clinical Toxicology
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    • v.1 no.1
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    • pp.6-11
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    • 2003
  • Various forms of dialytic techniques are available for detoxification. Hemodialysis, hemoperfusion and hemofiltration (hemodialfiltration) are the main treatment modalities. Because these modalities are rather invasive and expensive, it must be decided in balance of the risk and benefit to the patient. The prime consideration in the decision is based on the clinical features of poisoning; hemodialysis or hemoperfusion should be considered in general if the patient's condition progressively deteriorates despite intensive supportive therapy. The hemodialysis technique relies on passage of the toxic agent through a semipermeable membrane so that it can equilibrate with the dialysate and subsequently removed. It needs a blood pump to pass blood next to a dialysis membrane, which allows agents permeable to the membrane to pass through and reach equilibrium. Solute (or drug) removal by dialysis has numerous determinants such as solute size, its lipid solubility, the degree to which it is protein bound, its volume of distribution etc. The technique of hemoperfusion is similar to hemodialysis except there is no dialysis membrane or dialysate involved in the procedure. The patient's blood is pumped through a perfusion cartridge, where it is in direct contact with adsorptive material (usually activated charcoal) that has a coating material such as cellulose. This method can be used successfully with lipid-soluble compounds and with higher-molecular-weight compounds than for hemodialysis. Protein binding does not significantly interfere with removal by hemoperfusion. In conclusion, hemodialysis, hemoperfusion and hemofiltration can be used effectively as adjuncts to the management of severely intoxicated patients.

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Development of Osmotic Infusion Pump (삼투압 약물주입 펌프의 개발)

  • Kim, Dong Sun;Choi, Seong Wook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.6
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    • pp.471-475
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    • 2015
  • Because of increasing demand, a small portable drug injector that uses osmotic pressure for its operation force is developed, and its performance is evaluated. The osmotic drug injector can be small and lightweight because it does not require heavy batteries and an actuator, unlike previous electromechanical drug injectors. Moreover, its injection pressure can be sustained longer than that of previous elastic drug injectors. The new device is composed of a drug sac, osmotic pressure chamber, semipermeable membrane, and solvent chamber. To evaluate its performance, an in-vitro experiment was designed to measure the outflow and the injection pressure with respect to time. The experimental results show that the new drug infuser can continuously deliver 20 ml drug over a period of 20 h. The maximum injecting pressure was over 400 mmHg. Which prevents backflow caused by changes in the outlet pressure resulting from changes to the position of the device and the patient's posture.

Electricity Generation Coupled with Wastewater Treatment Using a Microbial Fuel Cell Composed of a Modified Cathode with a Ceramic Membrane and Cellulose Acetate Film

  • Seo, Ha-Na;Lee, Woo-Jin;Hwang, Tae-Sik;Park, Doo-Hyun
    • Journal of Microbiology and Biotechnology
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    • v.19 no.9
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    • pp.1019-1027
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    • 2009
  • A noncompartmented microbial fuel cell (NCMFC) composed of a Mn(IV)-carbon plate and a Fe(III)-carbon plate was used for electricity generation from organic wastewater without consumption of external energy. The Fe(III)-carbon plate, coated with a porous ceramic membrane and a semipermeable cellulose acetate film, was used as a cathode, which substituted for the catholyte and cathode. The Mn(IV)-carbon plate was used as an anode without a membrane or film coating. A solar cell connected to the NCMFC activated electricity generation and bacterial consumption of organic matter contained in the wastewater. More than 99% of the organic matter was biochemically oxidized during wastewater flow through the four NCMFC units. A predominant bacterium isolated from the anode surface in both the conventional and the solar cell-linked NCMFC was found to be more than 99% similar to a Mn(II)-oxidizing bacterium and Burkeholderia sp., based on 16S rDNA sequence analysis. The isolate reacted electrochemically with the Mn(IV)-modified anode and produced electricity in the NCMFC. After 90 days of incubation, a bacterial species that was enriched on the Mn(IV)-modified anode surface in all of the NCMFC units was found to be very similar to the initially isolated predominant species by comparing 16S rDNA sequences.

Estimation of PCBs Concentrations in Ambient Air Using Pine Needles as a Passive Air Sampler (PAS) (소나무잎을 Passive Air Sampler(PAS)로 이용하여 대기 중 PCBs 농도 추정)

  • Chun, Man-Young
    • Journal of Environmental Health Sciences
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    • v.38 no.4
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    • pp.360-368
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    • 2012
  • Objective: This study was carried out to use pine needles as a passive air sampler (PAS) of atmospheric Polychlorinated Biphenyls (PCBs). Methods: PCB concentrations in ambient air ($C_a$, ng/$m^3$) and deposited on pine needles ($C_p$, ng/g dry) were analyzed simultaneously from June 1 to December 31. Air samples were taken using a low volume PUF active air sampler and the overall average air volume was about 900-1,000 $m^3$. Pine needles were collected at the end of August and December near the air sampler. Results: $C_a$ were higher at higher air temperature and lower chlorinated PCB congeners, but $C_p$ showed irregular distribution. The average PCB sampling rates from air to pine needles were 0.116 (0.002-0.389) $m^3$/day - g dry. Conclusions: A poor correlation was shown between $C_a$ and $C_p$. However, a good correlation was shown between the logarithm of octanol-air partitioning coefficient ($logK_{oa}$) and log ($C_p/C_a$), and the interrelation was better with longer sampling time (June to December) than shorter sampling time (June to August). The average PCB sampling rates from air to pine needles were the lowest with respect to PUF disk, XAD-2 resin and semipermeable membrane devices (SPMDs) PAS. The average ratio ($C_{a-calc}/C_{a-meas}$) of calculated ($C_{a-calc}$) and measured ($C_{a-meas}$) PCB concentration was 0.69 with a shorter sampling time and 1.24 with a longer, so $C_{a-calc}$ was close to $C_{a-meas}$. It was found that pine needles can be used as PAS of atmospheric PCBs, and are especially suitable for long-time PAS.

Recent Progress in Qantum Dots Containing Thin Film Composite Membrane for Water Purification (양자점이 합체된 복합 박막을 이용한 정수의 최근 발전)

  • Park, Shinyoung;Patel, Rajkumar
    • Membrane Journal
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    • v.30 no.5
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    • pp.293-306
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    • 2020
  • Increasing harmful effects of climate change, such as its effect on water scarcity, has led to a focus on developing effective water purification methods to obtain pure water. Additionally, rising levels of water pollution is increasing levels of environmental degradation, calling for sources of water treatment to remove contaminants. To purify water, osmotic processes across a semipermeable membrane can take place, and recent studies are showing that incorporating nanoparticles, including carbon quantum dots (CQDs), graphene carbon dots (GQDs), and graphene oxide quantum dots (GOQDs) are making thin film composite (TFC) membranes more effective by increasing water flux while maintaining similar levels of salt rejection, increasing the hydrophilicity of the membrane surface, showing bactericidal properties, exhibiting antifouling properties to prevent accumulation of bacteria or other microorganisms from reducing the effectiveness of the membrane, and more. In the review, the synthesis process, applications, functionality, properties, and the role of several types of quantum dots are discussed in the composite membrane for water purification.

The development of high-performance PRO module and effects of operating condition on the performance of PRO module (고성능 PRO 모듈 개발 및 운전조건이 모듈 성능에 미치는 영향)

  • Han, Man Jae;Sim, Yeonju;Lee, Jong Hwa
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.4
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    • pp.303-310
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    • 2017
  • Pressure retarded osmosis(PRO) has attracted much attention as potential technology to reduce the overall energy consumption for reverse osmosis(RO) desalination. The RO/PRO hybrid process is considered as the most logical next step for future desalination. The PRO process aims to harness the osmotic energy difference of two aqueous solutions separated by a semipermeable membrane. By using the concentrated water(RO brine) discharged from existing RO plants, the PRO process can effectively exploit a greater salinity gradient to reduce the energy cost of processing concentrated water. However, in order to use RO brine as the draw solution, PRO membrane must have high water flux and enough mechanical strength to withstand the high operational pressure. This study investigates the development of a thin film composite PRO membrane and spiral wound module for high power density. Also, the influence of membrane backing layer on the overall power density was studied using the characteristic factors of PRO membranes. Finally, the performance test of an 8-inch spiral wound module was carried out under various operating conditions(i.e. hydraulic pressure, flow rate, temperature). As the flow rate and temperature increased under the same hydraulic pressure, the PRO performance increased due to the growth of water permeability coefficient and osmotic pressure. For a high performance PRO system, in order to optimize the operating conditions, it is highly recommended that the flow pressure be minimized while the flow rate is maintained at a high level.

Effects of coagulation-UF pretreatment on pressure retarded osmosis membrane process (응집-UF 전처리 공정이 압력지연삼투 공정에 미치는 영향)

  • Goh, Gilhyun;Kim, Suhyun;Kim, Jungsun;Kang, Limseok
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.4
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    • pp.285-292
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    • 2021
  • Osmotic power is to produce electric power by using the chemical potential of two flows with the difference of salinity. Water permeates through a semipermeable membrane from a low concentration feed solution to a high concentration draw solution due to osmotic pressure. In a pressure retarded osmosis (PRO) process, river water and wastewater are commonly used as low salinity feed solution, whereas seawater and brine from the SWRO plant are employed as draw solution. During the PRO process using wastewater effluent as feed solution, PRO membrane fouling is usually caused by the convective or diffusive transport of PRO which is the most critical step of PRO membrane in order to prevent membrane fouling. The main objective of this study is to assess the PRO membrane fouling reduction by pretreatment to remove organic matter using coagulation-UF membrane process. The experimental results obtained from the pretreatment test showed that the optimum ferric chloride and PAC dosage for removal of organic matter applied for the coagulation and adsorption process was 50 mg/L as FeCl3 (optimum pH 5.5). Coagulation-UF pretreatment process was higher removal efficiency of organic matter, as also resulting in the substantial improvement of water flux of PRO membrane.

Minimally Invasive Techniques for the Treatment of Mucoceles in Young Patients: A Case Series (소아환자의 점액종 치료 시 최소침습적 방법: 증례 보고)

  • Kim, Jongsung;Kim, Gimin;Lee, Jaesik;Kim, Hyunjung;Nam, Soonhyeun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.49 no.1
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    • pp.113-120
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    • 2022
  • Oral mucocele is a common exophytic lesion resulting from the accumulation of saliva due to pathological changes in the minor salivary glands. It is typically asymptomatic and painless and characterized by semipermeable, fluctuant nodules. General treatment methods for mucocele include surgical excision, marsupialization, cryosurgery, and steroid injection. This case report presents the treatment of oral mucocele using micro-marsupialization and a tying method as minimally invasive techniques rather than surgical treatment. Based on this case report, it is suggested that micro-marsupialization and the tying method can be used as alternative methods for the treatment of oral mucocele infants and children with behavioral control problems.

Assessment of Power Generation by Pressure Retarded Osmosis Process from Spiral-Wound Membrane Pilot-Plant (나권형 모듈을 이용한 압력지연삼투 공정의 에너지생산에 관한 연구)

  • Go, Gil hyun;Park, Tae shin;Kang, Lim seok
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.9
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    • pp.476-481
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    • 2016
  • Pressure retarded osmosis (PRO) is a quite new technique for power generation using an osmotically driven membrane process. In the PRO process, water permeates through a semipermeable membrane from a low concentration feed solution to a high concentration draw solution due to osmotic pressure. This study carried out to evaluate the performance of the 8 in spiral wound membrane module using reverse osmosis concentrate for a draw solution and reverse osmosis permeate for a feed solution. Three different flowrates of draw and feed solution, such as 2.4 L/min, 5.0 L/min, and 10.0 L/min were used to estimate the power density and water flux under various range of hydraulic pressure differences between 5 bar and 30 bar. In addition, the effects of feed and draw solution concentration, flowrate, and mixing ratio on 8 in spiral wound PRO membrane module performance were investigated in this study. As major results, increases of the draw solution concentration lead to the improvement of power denstiy, and water flux. Also, increase of flowrate resulted in the improvement of power density and water flux. In addition, optimal mixing ratio of draw and feed solution inlet flowrate was found to be 1:1 to attain a maximum power denstiy.