• 제목/요약/키워드: Semi-empirical

검색결과 425건 처리시간 0.025초

A Semi-empirical Equation for Activity Coefficients of Ions with One Parameter

  • Lee, Jai-Yeop;Han, Ihnsup
    • Bulletin of the Korean Chemical Society
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    • 제34권12호
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    • pp.3709-3714
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    • 2013
  • Based on the Debye-H$\ddot{u}$ckel equation, a semi-empirical equation for activity coefficients was derived through empirical and theoretical trial and error efforts. The obtained equation included two parameters: the proportional factor and the effective radius of an ionic sphere. These parameters were used in the empirical and regression parameter fitting of the calculated values to the experimental results. The activity coefficients calculated from the equation agreed with the data. Transforming to a semi-empirical form, the equation was expressed with one parameter, the ion radius. The ion radius, ${\alpha}$, was divided into three parameters, ${\alpha}_{cation}$, ${\alpha}_{anion}$ and ${\delta}_{cation}$, representing parameters for the cation, anion and combination, respectively. The advantage of this equation is the ability to propose a semi-empirical equation that can easily determine the activity coefficient with just one parameter, so the equation is expected to be used more widely in actual industry applications.

A Semi-empirical Mass-loss Rate in Short-period CVs

  • Kim, Woong-Tae;Sirotkin, Fedir V.
    • 천문학회보
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    • 제35권2호
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    • pp.76.2-76.2
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    • 2010
  • We present the final results of our study on the mass-loss rate of donor stars in cataclysmic variables (CVs). Observed donors are oversized in comparison with those of isolated single stars of the same mass, which is thought to be a consequence of the mass loss. Using the empirical mass-radius relation of CVs and the homologous approximation for changes in effective temperature T2, orbital period P, and luminosity of the donor with the stellar radius, we find the semi-empirical mass-loss rate M2dot of CVs as a function of P. The derived M2dot is at ~10-9.5-10-10 $M\odot$/yr and depends weakly on P when P > 90 min, while it declines very rapidly towards the minimum period when P < 90 min. The semi-empirical M2dot is significantly different from, and has a less-pronounced turnaround behavior with P than suggested by previous numerical models. The semi-empirical P-M2dot relation is consistent with the angular momentum loss due to gravitational wave emission, and strongly suggests that CV secondaries with 0.075 $M\odot$ < M2 < 0.2 $M\odot$ are less than 2 Gyrs old. When applied to selected eclipsing CVs, our semi-empirical mass-loss rates are in good agreement with the accretion rates derived from the effective temperatures T1 of white dwarfs. Based on the semi-empirical M2dot, SDSS 1501 and 1433 systems that were previously identified as post-bounce CVs have yet to reach the minimal period.

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반경험적 공력 해석도구의 주날개-꼬리날개 간섭 효과 보정에 대한 연구 (Study on the Correction of a Wing-tail Interference Effect in a Semi-empirical Aerodynamic Analysis Tool)

  • 이대연;김재현;강동기
    • 한국항공우주학회지
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    • 제49권2호
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    • pp.85-93
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    • 2021
  • 본 논문에서는 반경험적 해석도구를 이용하여 일반적인 형상의 꼬리날개 조종 유도무기의 공력 특성을 예측하고 그 결과를 보정하는 연구를 수행하였다. 반경험적 해석도구의 공력 특성 예측 결과를 풍동시험 결과와 비교하여 오차 원인을 확인하였으며, 반경험적 해석도구의 주요 오차 요인은 주날개-꼬리날개 간 간섭 성분임을 확인하였다. 반경험적 해석 결과를 풍동시험 결과와 전산해석 결과를 이용하여 보정하였으며, 보정된 데이터가 풍동시험 결과와 잘 일치함을 확인하였다. 본 연구를 통해 일반적인 꼬리날개 조종 유도무기의 공력 특성을 반경험적 해석도구를 이용하여 예측할 때 날개 간 간섭 성분 보정이 필요함을 확인하였다.

Study on slamming pressure calculation formula of plunging breaking wave on sloping sea dike

  • Yang, Xing
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제9권4호
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    • pp.439-445
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    • 2017
  • Plunging breaker slamming pressures on vertical or sloping sea dikes are one of the most severe and dangerous loads that sea dike structures can suffer. Many studies have investigated the impact forces caused by breaking waves for maritime structures including sea dikes and most predictions of the breaker forces are based on empirical or semi-empirical formulae calibrated from laboratory experiments. However, the wave breaking mechanism is complex and more research efforts are still needed to improve the accuracy in predicting breaker forces. This study proposes a semi-empirical formula, which is based on impulse-momentum relation, to calculate the slamming pressure due to plunging wave breaking on a sloping sea dike. Compared with some measured slamming pressure data in two literature, the calculation results by the new formula show reasonable agreements. Also, by analysing probability distribution function of wave heights, the proposed formula can be converted into a probabilistic expression form for convenience only.

광파이프 시스템의 채광성능 예측모델의 검증 및 적용 (Evaluation and Application of Prediction Models for the Daylight Performance of a Light-Pipe System)

  • 윤근영;신주영;김정태
    • KIEAE Journal
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    • 제10권1호
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    • pp.65-72
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    • 2010
  • The use of natural light has the potential for improving both the energy efficiency and indoor environmental quality in buildings. A light-pipe system can introduce daylight to spaces that would otherwise not be able to benefit from the advantages of daylight penetration. For the light-pipe system to be widely used in Korea, it is important to quantify its daylighting performance with due consideration regarding the effects imposed by the local climate conditions. This paper presents the evaluation results of existing semi-empirical models to predict daylighting performance of a light-pipe system. The evaluation of the existing models was based on the monitoring data obtained from a underground parking lot in which the light-pipe system was installed. Comparisons were made between the predicted and the monitored data obtained from the study. The results indicated that semi-empirical models which was developed using the experimental data obtained under the Korean climatic conditions had a good prediction performance. We also quantified the effects caused by sky conditions, solar altitudes, room dimensions, and the aspect ratio of a light-pipe system on both the daylighting performance of the light-pipe system and the indoor illuminance distributions of the space using the semi-empirical model. Finally, this paper provides the design guideline of the light-pipe system for its application to an underground parking lot space.

Semi-Empirical 기법을 이용한 미사일 형상의 공력특성 해석 (Analysis of the Aerodynamic Characteristics of Missile Configurations Using a Semi-Empirical Method)

  • 한명신;명노신;조태환;황종선;박찬혁
    • 한국항공우주학회지
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    • 제33권3호
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    • pp.26-31
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    • 2005
  • 미사일 형상의 공력특성을 효율적으로 계산하는 문제는 예비설계 단계에서 아주 중요하다. 본 연구에서는 반 실험적 기법에 기초한 Missile DATCOM 계열 코드를 이용하여 공력특성에 관한 계산을 수행하였다. 코드의 정확도와 신뢰도를 점검하기 위해, 고앙각 아음속 유동과 중간 정도의 받음각을 갖는 초음속 유동장 해석에 적용하였다. 실험이나 다른 연구자의 결과와 비교적 정성적으로 일치하는 예측결과를 얻을 수 있었다. 마지막으로 캐나드와 자유롭게 회전하는 꼬리날개를 갖는 보다 복잡한 미사일 유동장 해석에 적용하였다.

CFD와 공간분포를 고려한 반경험식을 이용한 해머헤드 발사체의 천음속 압력섭동 예측 (Prediction of Pressure Fluctuations on Hammerhead Vehicle at Transonic Speeds Using CFD and Semi-empirical Formula Considering Spatial Distribution)

  • 김영화;남현재;김준모;선철
    • 한국항공우주학회지
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    • 제49권6호
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    • pp.457-464
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    • 2021
  • 위성발사체에 심각한 진동하중을 발생시키는 버펫 현상을 해석하기 위하여, CFD 해석과 반경험식을 결합하여 천음속 영역 해머헤드 발사체에서 발생할 수 있는 압력섭동을 예측하였다. RANS 해석을 수행하여 충격파 진동 영역, 박리영역, 박리 재부착 지점 등을 확인하였으며, 경계층 두께, 배제 두께, 경계층 끝단에서의 유동 정보를 계산하였다. RANS 결과와 공간 분포를 고려한 반경험식을 결합하여 해머헤드 페어링 주위의 압력 섭동과 파워스펙트럼을 예측하였고 시험 결과와 비교하였다.

준 경험 생물막 모델(Semi-Empirical Biofilm Model)을 이용한 BAF 운전평가 및 적정 운전방안 도출 (A Study on Performance Estimation and Operation Strategy of Biological Aerated Filter Using Semi-Empirical Biofilm Model)

  • 유광태;김종락;윤주환;황호재;이한샘;김성표
    • 한국물환경학회지
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    • 제30권3호
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    • pp.269-282
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    • 2014
  • The objective of this study is to find out whether the developed semi-empirical biofilm model can be applicable to real BAF pilot-scale wastewater treatment. In addition, the optimum operating conditions of BAF as a function of process variables such as organic loading change can be drawn based on the simulation results of model. The results will provide the economic and efficient BAF process design and operating control. As a result, developed semi-empirical biofilm model which is relatively simple compared to mathematical model can simulate three BAF processes consisted of 25 layers within 1 seconds. When this model was used for simulating real pilot scale BAF process and the simulated water quality values were compared to experimental ones, simulated TCOD, SCOD, TN, $NH_4{^+}$-N, $NO_x{^-}$-N, alkalinity values were different to experimental ones within 21%, 20%, 8.1%, 48%, 10%, and 23%, respectively. Therefore, if the BAF system was equipped with automatic control, the BAF process can be better efficiently adapted under the condition of significant change of influent loading.

Assessment of the effect of fines content on frost susceptibility via simple frost heave testing and SP determination

  • Jin, Hyunwoo;Ryu, Byung Hyun;Lee, Jangguen
    • Geomechanics and Engineering
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    • 제30권4호
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    • pp.393-399
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    • 2022
  • The Segregation Potential (SP) is one of the most widely used predictors of frost heave in cold regions. Laboratory step-freezing tests determining a representative SP at the onset of the formation of the last ice lens (near the thermal steady state condition) can predict susceptibility to frost heave. Previous work has proposed empirical semi-log fitting for determination of the representative SP and applied it to several fine-grained soils, but considering only frost-susceptible soils. The presence of fines in coarse-grained soil affects frost susceptibility. Therefore, it is required to evaluate the applicability of the empirical semi-log fitting for both frost-susceptible and non-frost-susceptible soils with fines content. This paper reports laboratory frost heave tests for fines contents of 5%-70%. The frost susceptibility of soil mixtures composed of sand and silt was classified by the representative SP, and the suitability of the empirical semi-log fitting method was assessed. Combining semi-log fitting with simple laboratory frost heave testing using a temperature-controllable cell is shown to be suitable for both frost-susceptible and non-frost-susceptible soils. In addition, initially non-frost-susceptible soil became frost susceptible at a 10%-20% weight fraction of fines. This threshold fines content matched well with transitions in the engineering characteristics of both the unfrozen and frozen soil mixtures.

준 경험법을 이용한 유체내부 온도계의 동적 특성에 관한 연구 (A Study on the Dynamic Characteristics of Thermowell by Flow fluid using Semi-Empirical Method)

  • 김강부;이홍기
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2002년도 춘계학술대회논문집
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    • pp.147-152
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    • 2002
  • It has tried to predict dynamic response and establish answering about global or local dynamic problem in structures using experimental and analysis method. One of such a try, it be proposed Semi-Empirical Method that reduce error element of input information about dynamic analysis using dynamic experimental study and measurement data in the basis of real-structure. In this paper, the dynamic response problem about piping system that be set-up THERMOWELL produce flow fluid dynamic force using Semi-Empirical Method

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