• Title/Summary/Keyword: Self-reaction

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Fabrication of TiO2 Thin Films Using UV-enhanced Atomic Layer Deposition at Room Temperature (자외선 활성화 원자층 성장 기술을 이용한 상온에서 TiO2 박막의 제조)

  • Lee, Byoung-H.;Sung, Myung-M.
    • Journal of the Korean Vacuum Society
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    • v.19 no.2
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    • pp.91-95
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    • 2010
  • A UV-enhanced atomic layer deposition (UV-ALD) process was developed to deposit $TiO_2$ thin films on Si substrates using titanium isopropoxide(TIP) and $H_2O$ as precursors with UV light. In the UV-ALD process, the surface reactions were found to be self-limiting and complementary enough to yield a uniform, conformal, pure $TiO_2$ thin film on Si substrates at room temperature. The UV light was very effective to obtain the high-quality $TiO_2$ thin films with good adhesive strength on Si substrates. The UV-ALD process was applied to produce uniform and conformal $TiO_2$ coats into deep trenches with high aspect ratio.

Synthesis Behavior of Ti-50.0 ~ 66.7at%Si Powders by In situ Thermal Analysis during Mechanical Alloying (기계적 합금화과정에서의 in situ 열분석에 의한 Ti-50.0~66.7at%Si 분말의 합성거동)

  • Byun Chang Sop;Lee Sang Ho;Lee Wonhee;Hyun Chang Yong;Kim Dong Kwan
    • Korean Journal of Materials Research
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    • v.14 no.5
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    • pp.310-314
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    • 2004
  • Mechanical alloying (MA) of Ti-50.0~66.7at%Si powders was carried out in a high-energy ball mill, and in situ thermal analysis was also made during MA. In order to classify the synthesis behavior of the powders with respect to at%Si, the synthesis behavior during MA was investigated by in situ thermal analysis and X-ray diffraction (XRD). In situ thermal analysis curves and XRD patterns of Ti-50.0~59.6at%Si powders showed that there were exothermic peaks during MA, indicating TiSi, $TiS_2$, and $Ti_{5}$ $Si_4$ phase formation by a rapid exothermic reaction of self-propagating high-temperature synthesis (SHS). Those of Ti-59.8~66.7 at%Si powders, however, showed that there were no peaks during MA, indicating any Ti silicide was not synthesised until MA 240 min. For Ti-50.0~59.6at%Si powders, the critical milling times for SHS increased from 34.5 min to 89.5 min and the temperature rise, $\Delta$T (=peak temperature-onset temperature) decreased form $26.2^{\circ}C$ to $17.1^{\circ}C$ as at%Si increased. The critical composition of Si for SHS reaction was found to be 59.6at% and the critical value of the negative heat of formation of Ti-59.6at%Si to be -1.48 kJ/g.

Preparation of ZrB2 by Self-propagating Synthesis and Its Characteristics (자전연소합성법에 의한 ZrB2 세라믹분말합성 및 NaCl의 영향)

  • Kim, Jinsung;Nersisyan, Hayk;Won, Changwhan
    • Korean Journal of Materials Research
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    • v.24 no.5
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    • pp.255-258
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    • 2014
  • Zirconium boride is an artificial or which is rarely found in the nature. $ZrB_2$ is popular in the hard material industry because it has a high melting point, excellent mechanical properties and chemical stability. There are two known methods to synthesize $ZrB_2$. The first involves direct reaction between Zr and B, and the second is by reduction of the metal halogen. However, these two methods are known to be unsuitable for mass production. SHS(Self-propagating High-temperature Synthesis) is an efficient and economic method for synthesizing hard materials because it uses exothermic reactions. In this study, $ZrB_2$ was successfully synthesized by subjecting $ZrO_2$, Mg and $B_2O_3$ to SHS. Because of the high combustion temperature and rapid combustion, in conjunction with the stoichiometric ratio of $ZrO_2$, Mg and $B_2O_3$; single phase $ZrB_2$ was not synthesized. In order to solve the temperature problem, Mg and NaCl additives were investigated as diluents. From the experiments it was found that both diluents effectively stabilized the reaction and combustion regime. The final product, made under optimum conditions, was single-phase $ZrB_2$ of $0.1-0.9{\mu}m$ particle size.

Pathologic characteristics for the Rhodococcus equi infection in foals in Jeju (제주지역 망아지에서 Rhodococcus equi 감염증의 병리학적 특징)

  • Song, Kyung-Ok;Yang, Hyoung-Seok;Son, Won-Geun;Kim, Jae-Hoon
    • Korean Journal of Veterinary Research
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    • v.59 no.3
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    • pp.141-149
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    • 2019
  • From 1996 to 2014, 14 foals from nine farms in Jeju were diagnosed with a Rhodococcus equi infection. Clinically, most foals showed characteristic respiratory signs, including hyperthermia and dyspnea. The seasonal occurrence of R. equi infection in foals was higher in summer, such as June (eight foals; 57.1%) and July (four foals; 28.6%), than in the other seasons. The major cases of R. equi infections were observed among two-month-old (eight foals; 57.1%) and three-month-old (three foals; 21.4%) foals. Histopathologically, bronchopneumonia, abscess, and granulomatous pneumonia were the most prevalent lesions in the lungs of foals. Colonic ulcers and submucosal abscesses were found in a foal. Some foals showed granulomatous lymphadenitis and abscesses in the mesenteric and other lymph nodes. According to the polymerase chain reaction using 10 tissue samples of foals and nine R. equi isolates, the vapA gene was detected in 11/11 (100%) foals. Immunohistochemical staining using the anti-VapA monoclonal antibody was applied to detect the R. equi VapA antigen in the organs of foals. R. equi VapA antigens were demonstrated in most lungs and some mesenteric and hilar lymph nodes of 13 foals. Isolated virulent R. equi VapA bacteria showed high sensitivity to gentamicin, quinolones, rifampin, and vancomycin.

Breeding of Self-compatible Pear "Wonkyo Na-jasoojung 2" (배 자가결실성 "원교 나-자수정 2호")

  • Shin, Il Sheob;Shin, Yong Uk;Hwang, Hae Sung;Heo, Seong;Kim, Ki Hong;Kang, Sam Seok;Kim, Yoon Kyeong
    • Korean Journal of Breeding Science
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    • v.41 no.2
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    • pp.154-157
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    • 2009
  • Pear has a gametophytic self-incompatibility (SI) system and its SI reaction is controlled by a single multi-allelic S-locus. 'Wonkyo Na-jasoojung 2' was selected from a cross between 'Wonwhang', early season major pear cultivar with high fruit quality and self-incompatible, and 92-18-79 (${S_4}^{sm}{S_4}^{sm}$) obtained from self cross of 'Osa-nijisseiki' (${S_2S_4}^{sm}$) (SM, stylar-part mutant), self-compatible bud mutant that originated from self-incompatible 'Nijisseiki' ($S_2S_4$) made in 2001 at the National Institute of Horticultural and Herbal Science, Rural Development Administration in Korea. '92-18-79' was selected as a self-compatible source through field investigation. It bloomed 1 day earlier than 'Osa-Nijisseiki' and similar to 'Wonwhang' in 2008. It is medium in tree vigor and spreading in tree habit. 'Wonkyo Na-jasoojung 2' is classified as highly susceptible to pear scab (Venturia nashicola) similar to 'Osa-Nijisseiki' and as resistant to black spot (Alternaria kikuchiana) similar to 'Wonwhang'. It had 65.7% fruiting rate by self pollination. The average optimum harvest time of 'Wonkyo Na-jasoojung 2' was 148 days after full bloom and it matured 2 days earlier than 'Osa-Nijisseiki' and 11 days later than 'Wonwhang'. The fruit is roundish oblate in shape and yellowish brown in skin color. Average fruit weight was 445 g and soluble solids content was 13.3 $^{\circ}Brix$. The flesh had abundant juice and negligible grit.

Thermal Characteristics of LaMnO3 Non-isothermal Synthesis Reaction (LaMnO3 비등온 합성반응의 열적특성)

  • Jeon, Jong Seol;Lee, Jung Hun;Yoon, Chang Hyeok;Yoo, Dong Jun;Lim, Dae Ho;Kang, Yong
    • Korean Chemical Engineering Research
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    • v.54 no.3
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    • pp.404-409
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    • 2016
  • Thermal Characteristics and kinetic parameters of $LaMnO_3$ synthesis reaction were investigated by means of TGA (Thermogravimetric analysis) at non-isothermal heating conditions (5.0, 10.0, 15.0 and 20.0 K/min). The reaction was occurred rapidly at 450~600K (X=0.4~0.7) depending on the heating rate. Activation energy for the synthesis of $LaMnO_3$ from the precursor, which was determined by different method such as Friedman, Ozawa-Flynn-Wall and Vyazovkin methods, was in the range of 23~243 kJ/g-mol depending on the fractional conversion level and estimation method. The reaction order decreased with increasing heating rate and fractional conversional level. The average reaction order was 4.50 in case of X=0.1~0.3, while it was 1.87 in case of X=0.7~0.9, respectively. The value of frequency factor of reaction rate increased with inceasing heating rate and fractional conversion level. The aveage value of frequency factor was 205.6 ($min^{-1}$) when X=0.1~0.3, while it was 475.2 ($min^{-1}$) when X=0.7~0.9, respectively.

Aspects of the Urban Life in Tokyo! (영화 <도쿄!>에 나타난 도시적 삶의 양상)

  • Shin, Jung-A;Choi, Yong-Ho
    • Cross-Cultural Studies
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    • v.45
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    • pp.245-268
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    • 2016
  • Tokyo! is a 2008 French / Japanese / South Korean / German anthology film containing "Interior Design" by Michel Gondry, "Merde" by Leos Carax, and "Shaking Tokyo" by Joon-ho Bong, all of which were filmed in Tokyo. This cinematic triptych of three Tokyo-set stories is concerned with how the experience of self-alienation is related to urban life, that is, how to survive in a city as a self. The problem of life is the struggle for self-preservation. In Tokyo! the three film directors have shown that urban life is both self-deconstructing and self-preserving. In this paper, our purpose is to examine different modes of urban life by using two concepts reformulated by the French philosopher Jacques Derrida: the urban ipseity and auto-immunity. According to Derrida, ipseity is a system subjected to a circular structure. Such a system cannot avoid the general logic of auto-immunity; i.e., the structure of ipseity functions as both self-deconstructing and self-preserving. The three episodes contained in Tokyo! testify, each in its own way, to the function of that logic. In bringing to light the three modes of self: appropriation, dis-appropriation, and in-appropriation, we claim that the modality of urban life is confronted with the autoimmune reaction.

A Bayesian Poisson model for analyzing adverse drug reaction in self-controlled case series studies (베이지안 포아송 모형을 적용한 자기-대조 환자군 연구에서의 약물상호작용 위험도 분석)

  • Lee, Eunchae;Hwang, Beom Seuk
    • The Korean Journal of Applied Statistics
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    • v.33 no.2
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    • pp.203-213
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    • 2020
  • The self-controlled case series (SCCS) study measures the relative risk of exposure to exposure period by setting the non-exposure period of the patient as the control period without a separate control group. This method minimizes the bias that occurs when selecting a control group and is often used to measure the risk of adverse events after taking a drug. This study used SCCS to examine the increased risk of side effects when two or more drugs are used in combination. A conditional Poisson model is assumed and analyzed for drug interaction between the narcotic analgesic, tramadol and multi-frequency combination drugs. Bayesian inference is used to solve the overfitting problem of MLE and the normal or Laplace prior distributions are used to measure the sensitivity of the prior distribution.

Responses of self-anchored suspension bridge to sudden breakage of hangers

  • Qiu, Wenliang;Jiang, Meng;Zhang, Zhe
    • Structural Engineering and Mechanics
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    • v.50 no.2
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    • pp.241-255
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    • 2014
  • The girder of self-anchored suspension bridge is subjected to large compression force applied by main cables. So, serious damage of the girder due to breakage of hangers may cause collapse of the whole bridge. With the time increasing, the hangers may break suddenly for their resistance capacities decrease due to corrosion. Using nonlinear static and dynamic analysis methods and adopting 3D finite element model, the responses of a concrete self-anchored suspension bridge to sudden breakage of hangers are studied in this paper. The results show that the sudden breakage of a hanger has significant effects on tensions of the hangers next to the broken hanger, bending and torsion moments of the girder, moments of the towers and reaction forces of the bearings. The results obtained from dynamic analysis method are very different from those obtained from static analysis method. The maximum tension of hanger produced by breakage of a hanger exceeds 2.2 times of its initial value, the maximum dynamic amplification factor reaches 2.54, which is larger than the value of 2.0 recommended for cable-stayed bridge in PTI codes. If two adjacent hangers on the same side of bridge break one after another, the maximum tension of other hangers exceeds 3.0 times of its initial value. If the safety factor adopted to design hanger is too small, or the hangers have been exposed to corrosion, the bridge may collapse due to breakage of two adjacent hangers.

A Study on Self-Similarity in Turbulent Hydrogen Jet Flames with Coaxial Air (동축공기 수소확산 화염의 자기상사성에 대한 연구)

  • Kim, Mun-Ki;Kim, Seung-Han;Yoon, Young-Bin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.5
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    • pp.71-78
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    • 2002
  • Experiments have been performed using two-color PIV in hydrogen non-premixed flames with various conditions of coaxial air, which was classified into three cases with/without reaction. Mean velocity, turbulence intensity and Reynolds stress were analyzed using flow fields from PIV measurement First, the similarity of pure jet had a good agreement with previous results of other researchers. It was found that the decay of centerline velocity was proportional to $x^{-1}$ in coaxial air conditions. By normalizing axial distance with effective jet diameter defined by effective density, the data of centerline velocity collapsed a single line. And the radial profiles of mean velocity showed that they didn't become self-similar because the curves differed from each other as coaxial air velocity increased at fixed fuel velocity. Also, turbulence intensity became self-similar further downstream than mean velocity.