• Bulletin of the Korean Chemical Society
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• v.27 no.3
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• pp.403-406
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• 2006

The surface structure and electrochemical behavior of self-assembled monolayers (SAMs) formed by aromatic thiols on Au(111) were investigated by scanning tunneling microscopy (STM) and cyclic voltammetry. Benzenethiol (BT) forms disordered phases on Au(111) which are composed of many bright domains, while benzyl mercaptan (BM), with a methylene unit between the aromatic group and sulfur atom, forms twodimensional ordered SAMs on Au(111). In addition, two phase-separated domains consisting of disordered and ordered phases were observed in binary SAMs formed from a 1 : 1 mixed ethanol solution of BT and BM. From STM and CV measurements, we found that the blocking efficiency of aromatic thiol SAMs coated on an Au(111) electrode for an electron transfer reaction decreases as the structural order of the SAMs increases. Molecular-scale STM and CV results obtained here will be very useful in designing functional SAMs for further applications, such as the improvement of corrosion passivation of Au(111) on an aromatic thiolmodified Au(111) surface.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.19 no.6
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• pp.1182-1189
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• 1994

In this paper, we evaluate the performance of a fuzzy controller with a self-learning structure. The fuzzy controller is based on a fuzzy logic that approximates and effectively represents the uncertain phenomena of the real world. The fuzzy controller has control of a plant with a fuzzy inference logic. However, it is not easy to decide the membership function of a fuzzy controller and its controlrule. This problem can be solved by designing a self-learning controller that improves its own contropllaw to its goal with a performance table. The fuzzy controller is implemented with a 386PC, an interface board, a D/A converter, a PWM(Pulse Width Modulation) motor drive-circuit, and a sensing circuit, for error and differential of error. Since a Ball and Beam System is used in the experiment, the validity of the fuzzy controller with the self-learning structure can be evaluated through the actual experiment and the computer simulation of the real plant. The self-learning fuzzy controller reduces settling time by just under 10%.

• Journal of the Korean Institute of Intelligent Systems
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• v.7 no.3
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• pp.21-33
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• 1997

In this paper, a method of self-organizing for fuzzy logic controller(FLC) through learning of the proper direction of coritrol is proposed. In case of designing a self-organizing FLC for unknown dynamic plants based on the gradient descent method, it is difficult to identify the desirable direction of the change of control inpul. in which the error would be decreased. To resolve this problem, we propose a method as fo1lows:at first, assign representative values for the direction of change of error with respect to control input to each partitioned region of the states, and then, learn the fuzzy control rules using the reinforced representative values through iterative trials. 'The proposed self-organizing FLC has simple structure and it is easy to design. The validity of the proposed method is proved by the computer simulation for an inverted pendulum system.

• Structural Engineering and Mechanics
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• v.63 no.1
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• pp.55-64
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• 2017

The paper concerns concrete carbonation, the phenomena that occurs in every type of climate, especially in urban-industrial areas. In European Standards, including Eurocode (EC) for concrete structures the demanded durability of construction located in the conditions of the carbonation threat is mainly assured by the selection of suitable thickness of reinforcement cover. According to EC0 and EC2, the thickness of the cover in the particular class of exposure depends on the structural class/category and concrete compressive strength class which is determined by cement content and water-cement ratio (thus the quantitative composition) but it is not differentiated for various cements, nor additives (i.e., qualitative composition), nor technological types of concrete. As a consequence the selected thickness of concrete cover is in fact a far estimation - sometimes too exaggerated (too safe or too risky). The paper presents the elaborated "self-terminated carbonation model" that includes abovementioned factors and enables to indicate the maximal possible depth of carbonation. This is possible because presented model is a hyperbolic function of carbonation depth in time (the other models published in the literature use the parabolic function that theoretically assume the infinite increase of carbonation depth value). The paper discusses the presented model in comparison to other models published in the literature, moreover it contains the algorithm of concrete cover design with use of the model as well as an example of calculation of the cover thickness.

• Advances in nano research
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• v.13 no.1
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• pp.87-96
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• 2022

Drug self-delivery systems can easily realize combination drug therapy and avoid carrier-induced toxicity and immunogenicity because they do not need non-therapeutic carrier materials. So, designing appropriate drug self-delivery systems for specific diseases can settle most of the problems existing in traditional drug delivery systems. Retinal pigment epithelium is very important for the homeostasis of retina. However, it is vulnerable to oxidative damage and difficult to repair. Worse still, the antioxidants can hardly reach the retina by non-invasive administration routes due to the ocular barriers. Herein, the targeted group (folic acid) and antioxidant (melatonin) have been grafted on the surface of ZnO quantum dots to fabricate a new kind of drug self-delivery systems as a protectant via eyedrops. In this study, the negative nanoparticles with size ranging in 4~6 nm were successfully synthesized. They could easily and precisely deliver drugs to retinal pigment epithelium via eyedrops. And they realized acid degradation to controlled release of melatonin and zinc in retinal pigment epithelium cells. Consequently, the structure of retinal pigment epithelium cells were stabilized according to the expression of ZO-1 and β-catenin. Moreover, the antioxidant capacity of retinal pigment epithelium were enhanced both in health mice and photic injury mice. Therefore, such new drug self-delivery systems have great potential both in prevention and treatment of oxidative damage induced retinal diseases.

• Journal of Korean Academy of Nursing
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• v.40 no.3
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• pp.389-399
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• 2010

Purpose: The aim of this study was to construct a structural equation model that would further explain the mental health status of Korean immigrants living in Canada. Methods: Survey using a structured questionnaire was conducted with 386 people in Canada (Vancouver and Toronto). Six instruments were used in this model. The analysis of data was done with both SPSS 14.0 for descriptive statistics and AMOS 5.0 for covariance structure analysis. Results: Based on the constructed model, physical health status, immigrant life stress, self esteem, and quality of life were found to have significant direct effect on mental health. In addition, factors such as physical health status, immigrant life stress, quality of life, English proficiency, family cohesion and social support were found to indirectly affect mental health. The final modified model yielded Chi-square=34.79 (p<.001), df=13, $x^2$/df=2.68, GFI=0.98, AGFI=0.94, NFI=0.95, PNFI=0.44, PGFI=0.35, RMSE=0.07 and exhibited good fit indices. Conclusion: This structural equation model is a comprehensive theoretical model that explains the related factors and their relationship with mental health in Korean immigrants. Findings of this study can contribute to the designing of an appropriate prevention strategy to further improve the mental health of immigrants in Canada.

• Journal of Mechanical Science and Technology
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• v.15 no.4
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• pp.413-421
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• 2001

A simple procedure to add and remove material simultaneously along the boundary is developed to optimize the shape of a two dimensional elastic problems and to minimize the maximum von Mises stress. The results for the two dimensional infinite plate with a hole, are close to the theoretical results of an elliptical boundary and the stress concentration is reduced by half for the fillet problem. The proposed shape optimization method, when compared with existing derivative based shape optimization methods has many features such as simplicity, applicability, flexibility, computational efficiency and a much better control on stresses on the design boundary.

• Computers and Concrete
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• v.1 no.1
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• pp.15-30
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• 2004

In this study, a design process for reinforced concrete structures using the nonlinear FEM analysis is developed. Instead of using the nonlinear analysis to evaluate the required performance after design process, the nonlinear analysis is applied before designing the reinforcement arrangement inside the RC structures. An automatic reinforcement generator for computer aided reinforcement agreement is developed for this purpose. Based on a nonlinear FEM program for analyzing the reinforced concrete structure, a smart fictitious material model of steel, is proposed which can self-adjust the reinforcement to the required amount at the cracking location according to the load increment. Using this tool, the reinforcement ratio required at design load level can be decided automatically. In this paper, an example of RC beam with opening is used to verify the proposed process. Finally, a trial design process for a real size underground RC LNG tank is introduced.

• Journal of the Korean Vacuum Society
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• v.8 no.3B
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• pp.257-261
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• 1999

The claw pump, one of oil-less dry pumps developed to solve problems found in vacuum systems pumped by oil-sealed rotary pumps, has been widely used separately or as a part of compound structure with a roots pump. The claw pump has some merits such as a high pumping speed, a high compression ratio, and relatively little heat generation. The high compression ratio of the claw pump is compression ratio, and relatively little heat generation. The high compression ratio of the claw pump is based on efficient sweeping action of the special type rotor and an intrinsic self-valving mechanism. The contour of the rotor with claw-type blade is designed basically to make two rotors revolve smoothly without touching with each other, and related dimensions are determined by required pumping speed, compression ratio, power demand and diameter of the rotor axis. In this paper the procedure of designing the rotor of the claw pump is described and factors influencing the pump performance are analyzed.

• Journal of Electrical Engineering and Technology
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• v.13 no.4
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• pp.1724-1731
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• 2018

The conventional polynomial neural network (PNN) is a classical flexible neural structure and self-organizing network, however it is not free from the limitation of overfitting problem. In this study, we propose a space search-optimized polynomial neural network (ssPNN) structure to alleviate this problem. Ranking selection is realized by means of ranking selection-based performance index (RS_PI) which is combined with conventional performance index (PI) and coefficients based performance index (CPI) (viz. the sum of squared coefficient). Unlike the conventional PNN, L2-norm regularization method for estimating the polynomial coefficients is also used when designing the ssPNN. Furthermore, space search optimization (SSO) is exploited here to optimize the parameters of ssPNN (viz. the number of input variables, which variables will be selected as input variables, and the type of polynomial). Experimental results show that the proposed ranking selection-based polynomial neural network gives rise to better performance in comparison with the neuron fuzzy models reported in the literatures.