• 제목/요약/키워드: Self-Assembly

검색결과 695건 처리시간 0.025초

Selective Growth of Nanosphere Assisted Vertical Zinc Oxide Nanowires with Hydrothermal Method

  • Lee, Jin-Su;Nam, Sang-Hun;Yu, Jung-Hun;Yun, Sang-Ho;Boo, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
    • /
    • pp.252.2-252.2
    • /
    • 2013
  • ZnO nanostructures have a lot of interest for decades due to its varied applications such as light-emitting devices, power generators, solar cells, and sensing devices etc. To get the high performance of these devices, the factors of nanostructure geometry, spacing, and alignment are important. So, Patterning of vertically- aligned ZnO nanowires are currently attractive. However, many of ZnO nanowire or nanorod fabrication methods are needs high temperature, such vapor phase transport process, metal-organic chemical vapor deposition (MOCVD), metal-organic vapor phase epitaxy, thermal evaporation, pulse laser deposition and thermal chemical vapor deposition. While hydrothermal process has great advantages-low temperature (less than $100^{\circ}C$), simple steps, short time consuming, without catalyst, and relatively ease to control than as mentioned various methods. In this work, we investigate the dependence of ZnO nanowire alignment and morphology on si substrate using of nanosphere template with various precursor concentration and components via hydrothermal process. The brief experimental scheme is as follow. First synthesized ZnO seed solution was spun coated on to cleaned Si substrate, and then annealed $350^{\circ}C$ for 1h in the furnace. Second, 200nm sized close-packed nanospheres were formed on the seed layer-coated substrate by using of gas-liquid-solid interfacial self-assembly method and drying in vaccum desicator for about a day to enhance the adhesion between seed layer and nanospheres. After that, zinc oxide nanowires were synthesized using a low temperature hydrothermal method based on alkali solution. The specimens were immersed upside down in the autoclave bath to prevent some precipitates which formed and covered on the surface. The hydrothermal conditions such as growth temperature, growth time, solution concentration, and additives are variously performed to optimize the morphologies of nanowire. To characterize the crystal structure of seed layer and nanowires, morphology, and optical properties, X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Raman spectroscopy, and photoluminescence (PL) studies were investigated.

  • PDF

An Integrative Review on the Contents and Effectiveness of Depression and Anxiety Interventions applied to Unmarried Mothers Living in Residential Facilities (시설에 거주하는 미혼모에게 적용된 우울 및 불안 감소를 위한 중재의 통합적 문헌고찰)

  • Gwon, Taekyun;Lee, Gumhee;Kang, Eunbyeol;Moon, Jungyi;Jeong, Juae
    • Perspectives in Nursing Science
    • /
    • 제16권1호
    • /
    • pp.45-54
    • /
    • 2019
  • Purpose: The purposes of this study was to review the literature on intervention for treating anxiety and depression among unmarried mothers living in facilities, and to understand core that could promote the development of more effective interventions. Methods: Key words in English and Korean were used to search through eight electronic databases-PubMed, Cochrane Library, EMBASE, CINAHL, RISS, DBpia, NDSL, and the National Assembly Library. Results: Ten studies were ultimately selected for the integrative review and were evaluated in terms of contextual and methodological quality. The studies consisted of seven quasi-experimental studies and three case report studies. The selected studies utilized music, art, forest therapy, dancing, education, and play programs to change mothers' perceptions, emotions, and behavior and to improve their relationships with their babies or others. Conclusion: It is important to consider mothers' self-awareness and emotional expression, and to improve their relationships with their babies or others as core elements when developing intervention programs for anxiety and/or depression among unmarried mothers living in residential facilities.

Nonenzymatic Sensor Based on a Carbon Fiber Electrode Modified with Boron-Doped Diamond for Detection of Glucose (보론 도핑 다이아몬드로 표면처리된 탄소섬유 기반의 글루코스 검출용 비효소적 바이오센서)

  • Song, Min-Jung
    • Korean Chemical Engineering Research
    • /
    • 제57권5호
    • /
    • pp.606-610
    • /
    • 2019
  • In this study, we demonstrated that the nonenzymatic glucose sensor based on the flexible carbon fiber bundle electrode with BDD nanocomposites (CF-BDD electrode). As a nano seeding method for the deposition of BDD on flexible carbon fiber, electrostatic self-assembly technique was employed. Surface morphology of BDD coated carbon fiber electrode was observed by scanning electron microscopy. And the electrochemical characteristics were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. This CF-BDD electrode exhibited a large surface area, a direct electron transfer between the redox species and the electrode surface and a high catalytic activity, resulting in a wider linear range (3.75~50 mM), a faster response time (within 3 s) and a higher sensitivity (388.8 nA/mM) in comparison to a bare CF electrode. As a durable and flexible electrochemical sensing electrode, this brand new CF-BDD scheme has promising advantages on various electrochemical and wearable sensor applications.

Pattern Formation of Highly Ordered Sub-20 nm Pt Cross-Bar on Ni Thin Film (Ni 박막 위 20 nm급 고정렬 Pt 크로스-바 구조물의 형성 방법)

  • Park, Tae Wan;Jung, Hyunsung;Cho, Young-Rae;Lee, Jung Woo;Park, Woon Ik
    • Korean Journal of Metals and Materials
    • /
    • 제56권12호
    • /
    • pp.910-914
    • /
    • 2018
  • Since catalyst technology is one of the promising technologies to improve the working performance of next generation energy and electronic devices, many efforts have been made to develop various catalysts with high efficiency at a low cost. However, there are remaining challenges to be resolved in order to use the suggested catalytic materials, such as platinum (Pt), gold (Au), and palladium (Pd), due to their poor cost-effectiveness for device applications. In this study, to overcome these challenges, we suggest a useful method to increase the surface area of a noble metal catalyst material, resulting in a reduction of the total amount of catalyst usage. By employing block copolymer (BCP) self-assembly and nano-transfer printing (n-TP) processes, we successfully fabricated sub-20 nm Pt line and cross-bar patterns. Furthermore, we obtained a highly ordered Pt cross-bar pattern on a Ni thin film and a Pt-embedded Ni thin film, which can be used as hetero hybrid alloy catalyst structure. For a detailed analysis of the hybrid catalytic material, we used scanning electron microscope (SEM), transmission electron microscope (TEM) and energy-dispersive X-ray spectroscopy (EDS), which revealed a well-defined nanoporous Pt nanostructure on the Ni thin film. Based on these results, we expect that the successful hybridization of various catalytic nanostructures can be extended to other material systems and devices in the near future.

Women's Religious Engagement at Daesoon Jinrihoe's Yeoju Headquarters (大巡真理會的女性宗教參與 : 以驪州本部道場為例)

  • Li, Yuchen
    • Journal of the Daesoon Academy of Sciences
    • /
    • 제34집
    • /
    • pp.75-105
    • /
    • 2020
  • Previous scholars have studied Daesoon Jinrihoe mainly through its scriptures and doctrines; however, in this essay I have combined data from a questionnaire with interviews I conducted to observe women's religious engagement from their own perspectives. I conducted my fieldwork from October 23 to 26 at Yeoju Headquarters in Korea and received 81 questionnaire replies. This ongoing project will shed light on the niche for women in Korean new religious movements. This essay is divided into three parts. First, I reviewed 5 articles on general attitudes towards women within Daesoon Jinrihoe to serve as a doctrinal introduction. Second, I used the Ladies Club, the Women's Assembly of the Department of Social Welfare, and female students from the Inter- national Volunteers Association to better understand women's participation and education in Daesoon Jinrihoe on an institutional level. Third, I issued a questionnaire in order to learn respondents' sex, age, educational background, and birth place and used those data points determine patterns in how the above influence religious participation and positions in Daesoon Jinrihoe. My investigation showed that both the self-expectation and division of labor among the followers at Yeoju Headquarter were affected by and corresponded to social gender roles. Moreover, the emphasis on missionary work rather than centralized hierarchy contributed to a reduction in the influence of gender-segregation and led to relative coherence in terms of gender relations within Daesoon Jinrihoe.

Electrochmical Performance of Silicon/Carbon Anode Materials for Li-ion Batteries by Silicon Content (실리콘 함량에 따른 리튬이온전지용 실리콘/탄소 음극소재의 전기화학적 특성)

  • Choi, Yeon-Ji;Kim, Sung-Hoon;Ahn, Wook
    • Journal of Convergence for Information Technology
    • /
    • 제12권4호
    • /
    • pp.338-344
    • /
    • 2022
  • It is necessarily required in developing Si-based anode materials for lithium ion batteries, and the related researches are actively working especially in Si-carbon composite material. On the other hand, the photovoltaic and semiconductor industries discard huge amount of Si resources, facing the environmental issue. In this study, recycled Si resource is adopted to obtain Si-carbon composite for LIB(Lithium-Ion Batteries). In order to improve high-capacity retention characteristics and cycle stability of a Si anode material for the LIB, two differenct composites having a mass ratio of silicon and pitch of 1:1 and 2:1 are synthesized and electrochemical characteristics of the anode material manufactured by simple self-assembly method. This result in excellent initial capacity with stable cycle life, and confirming the potential use of recycled Si material for LIB.

Self-pressurization Effect and PEMFC Performance Improvement Using Metal Foam Compression (금속 폼 압축에 의한 자가 가압 효과 및 PEMFC 성능 개선)

  • Kim, Hyeonwoo;Kim, Junbom
    • Applied Chemistry for Engineering
    • /
    • 제33권6호
    • /
    • pp.618-623
    • /
    • 2022
  • The bipolar plate is a key component of the polymer electrolyte membrane fuel cell (PEMFC) that transfers reactants and electrons, discharges water and heat as by-products, and serves as a mechanical support for the membrane electrode assembly (MEA). Therefore, the flow field structure of the bipolar plate plays an important role in improving fuel cell performance. In this study, PEMFC performance was investigated with copper foams with different compressibility ratios applied to cathode bipolar plates using a 25 cm2 unit cell. The total resistance decreased as the compressibility ratio of the metal foams increased, and, in particular, the charge transfer and mass transfer resistance were significantly improved compared to the serpentine flow field, lowering voltage loss in medium and high current density region. In the case of pressurized air reactant flow with serpentine structure, fuel cell performance was similar to that of a compressed metal foam flow field (S3) up to the medium current density region, but low performance appeared in the high current density region due to flow field structure limitations.

Introduction and Research Trends on Micro LED Technology (마이크로 LED 기술 소개 및 연구 동향)

  • Moojin Kim
    • Advanced Industrial SCIence
    • /
    • 제3권3호
    • /
    • pp.14-19
    • /
    • 2024
  • Currently, micro LEDs (Light Emitting Diode) are attracting attention in the lighting field along with next-generation displays and have advantages such as high luminance, operating speed, energy efficiency, and long-term driving. It is predicted to bring new innovations in smartphones, televisions, and wearable electronic devices. These micro displays are self-luminous displays that emit light by themselves by being implemented as pixels composed of micrometer-sized LED devices. The main manufacturing processes can be divided into crystal growth, patterning and etching, chip separation and transfer, bonding and wiring, panel assembly and encapsulation, inspection, and quality management. Recently, this technology has developed at a rapid pace, and companies are expanding their investments in these fields. According to recent market research results, the micro LED display market is expected to continue to grow, and the main development direction of development can be summarized as manufacturing process improvement, material innovation, and driving technology development. It is believed that commercialization will accelerate through these studies and lead to innovation in the display industry with high performance and various application possibilities.

Effects of the Particle Size and Shape of Silver Nanoparticles on Optical and Electrical Characteristics of the Transparent Conductive Film with a Self-assembled Network Structure (은 나노입자의 크기 및 형태가 자가조립 망상구조를 갖는 투명전도성 필름의 광학 및 전기 특성에 미치는 영향)

  • Shin, Yong-Woo;Kim, Kyu-Byung;Noh, Su-Jin;Soh, Soon-Young
    • Applied Chemistry for Engineering
    • /
    • 제29권2호
    • /
    • pp.162-167
    • /
    • 2018
  • The effect of the average particle size and shape of silver nanoparticles for the transparent conductive film (TCF) was studied. Optical and electrical properties of silver conductive lines coated on the polyethylene terephthalate (PET) film was also measured. Silver nanoparticles produced by Ag-CM, Ag-ME, Ag-EE methods showed an excellent conductivity compared to those produced by Ag-EB, Ag-CR and Ag-PL methods, but a little difference in the transparency. In the case of the former three silver nanoparticles, the average particle size was about 80 nm or less and the size was uniform. For the latter case, the severe agglomeration phenomena of particles was observed and the average particle size was 100 nm or more. This result was consistent with the result of the uniformity of the pattern shape and thickness on conductive line patterns observed by SEM. Therefore, it was confirmed that the electrical characteristics could be obtained when the average particle size of silver nanoparticles is smaller and the uniformity of the particles is maintained.

Controll over the Au@Ag Core-shell Nanoparticle 2D Patterns via Diblock Copolymer Inverse Micelle Templates and Investigation of the Surface Plasmon Based Optical Property (이중블록공중합체 역마이셀 주형을 이용한 Au@Ag 코어-쉘 나노입자 2차원 패턴 제어 및 표면 플라즈몬 기반 광학적 특성 연구)

  • Yoon, Min Ji;Kim, Jihyeon;Jang, Yoon Hee;Lee, Ji-Eun;Chung, Kyungwha;Quan, Li Na;Kim, Dong Ha
    • Journal of the Korean Chemical Society
    • /
    • 제57권5호
    • /
    • pp.618-624
    • /
    • 2013
  • We demonstrated unique inter- and intra-plasmonic coupling effects in bimetallic Au@Ag core-shell NP arrays which are regularly or randomly arranged on self-assembled block copolymer (BCP) inverse micelle monolayers. Polyvinylpyrrolidone (PVP)-stabilized Au@Ag core-shell NP arrays in regular or disordered configuration were incorporated and assembled on reconstructed PS-b-P4VP inverse micelle templates through two types of processes. The intensively enhanced LSPR coupling properties of individual and assembled Au@Ag NPs were evaluated by UV-visible spectroscopy in terms of the type of ligand stabilizer, coupling between Au and Ag, thickness of Ag shell, and type of array configuration. Finally, Au@Ag core-shell NP arrays were employed as active substrates for surface enhanced Raman spectroscopy (SERS) and a significantly enhanced signal enhancement was observed in accordance with the coupling intensity of Au@Ag NPs patterns.