• Title/Summary/Keyword: Self quenching

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신소호구조가 차단성능에 미치는 영향

  • Kim, Gil-Su;Lee, Seung-Su;Im, Gi-Jo;Gang, Seong-Hwa
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.227-227
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    • 2009
  • To prevent such accidents, molded case circuit breakers with improved short-circuit current interrupting capacity are needed. This paper is focused on understanding the interrupting capability with respect to double contact structure and puffer assisted self quenching that are based on the shape of the contact system in the current molded case circuit breaker. The new arc quenching structure for increasing the interrupting capacity of molded case circuit breakers is investigated by simulation and experiment.

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Low Strain Rate Flame Extinction Characteristic of Oxygen Enhanced Opposed Flow Partially Premixed Flame in a Mesoscale Channel (채널 내부 대항류 산소부화 부분예혼합 화염의 저신장율 소화특성)

  • Lee, Min Jung;Kim, Nam Il
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.243-244
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    • 2014
  • The opposed flow flame in a mesoscale channel was constructed to observe the flame stabilization behaviors at low strain rate conditions (<$10s^{-1}$). The purpose of this study is to get the overall flame behaviors of partially premixed flames with oxygen enhanced conditions at low strain rates. The oxygen ratio in oxidizer was changed from 18 to 30 %. Conclusively, the flame extinction limit approached to about $1s^{-1}$, and divided into three representative regimes corresponding to self propagating flame, transitional flame, quenching flame regimes.

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The Production Technology of High-Strength Round Bar by QST Rolling (QST압연법에 의한 고장력봉강 제조기술)

  • 신정호;한철호;이종수;장병록
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1997.03a
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    • pp.240-243
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    • 1997
  • The Quenching and Self Tempering (QST) rolling is treated in terms of an advance process on Controlled Rolling and Cooling Technology (CRCT). In the analysis, the effect of this process is governed by both quenching and finishing conditions in the related with temperature. The objective of the QST model is to simulate the temperature gradient of the stock being rolled in the rolling mill. A comparison of computer simulated and manufactured micro structure as well as mechanical properties shows a good consistency. The micro structure of this high-strength round bar consists of tempered martensite and ferrite + pearlite phases.

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The crystallinity and electrical characteristics of low density polyetylene thin film (저밀도 폴리에틸렌 필림의 결정화도 및 전기적 특성)

  • 윤중락;권정열;이헌용
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.164-168
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    • 1996
  • The relation between crystallinity and thermal history in low density polyethylene thin films and their effect on electric conduction phenomena and dielectric breakdown was studied. The low density polythylene thin films obtained by the solution growth method heat-treated at 140[$^{\circ}C$] for 2 h and subsequently cooling to various ways. The degree of crystallinity was estimated by the X-ray diffraction measurement for the specimen of slowly cooling, ICE quenching and liquid nitrogen quenching. The result shows that the crystallinity decreases become faster as the cooling speed increased, and that conduction phenomenon is governed by the space charge limited current in high field. It was found that the dielectric breakdown field increases with an increase in cooling speed and test number in self-healing breakdown method.

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Prediction of Performance considering Ablated PTFE in High Voltage Self-blast Circuit Breaker (PTFE 용삭을 고려한 초고압 복합소호 차단기의 성능 예측)

  • Kim, Jin-Bum;Kweon, Ki-Yeoung;Lee, Hahk-Sung
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.695-698
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    • 2008
  • Self-blast circuit breakers utilize the energy dissipated by the arc itself to create the required conditions for arc quenching during the current zero. During the arcing period, high pressure, temperature and radiation of the arc could burn in pure SF6 gas and PTFE nozzle. Ablated nozzle shape and $SF_6$-PTFE mixture vapor affect the performance of an self-blast circuit breaker. After a number of tests, nozzle in circuit breaker is disassembled, a section of ablated nozzle is investigated precisely. Using computational fluid dynamics, the conservation equation for the gas and temperature, velocity and electric fields within breaker is solved. Before applying a section model, developed program is verified with experimental data. Performance of ablated nozzle shape is compared with original model through analysis program.

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Bacterial Quorum Sensing and Quorum Quenching for the Inhibition of Biofilm Formation (박테리아의 Quorum Sensing 및 생물막 형성 억제를 위한 Quorum Quenching 연구 동향)

  • Lee, Jung-Kee
    • Microbiology and Biotechnology Letters
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    • v.40 no.2
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    • pp.83-91
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    • 2012
  • Quorum sensing (QS) is a cell-to-cell communication system, which is used by many bacteria to regulate diverse gene expression in response to changes in population density. Bacteria recognize the differences in cell density by sensing the concentration of signal molecules such as N-acyl-homoserine lactones (AHL) and autoinducer-2 (AI-2). In particular, QS plays a key role in biofilm formation, which is a specific bacterial group behavior. Biofilms are dense aggregates of packed microbial communities that grow on surfaces, and are embedded in a self-produced matrix of extracellular polymeric substances (EPS). QS regulates biofilm dispersal as well as the production of EPS. In some bacteria, biofilm formations are regulated by c-di-GMP-mediated signaling as well as QS, thus the two signaling systems are mutually connected. Biofilms are one of the major virulence factors in pathogenic bacteria. In addition, they cause numerous problems in industrial fields, such as the biofouling of pipes, tanks and membrane bioreactors (MBR). Therefore, the interference of QS, referred to as quorum quenching (QQ) has received a great deal of attention. To inhibit biofilm formation, several strategies to disrupt bacterial QS have been reported, and many enzymes which can degrade or modify the signal molecule AHL have been studied. QQ enzymes, such as AHL-lactonase, AHL-acylase, and oxidoreductases may offer great potential for the effective control of biofilm formation and membrane biofouling in the future. This review describes the process of bacterial QS, biofilm formation, and the close relationship between them. Finally, QQ enzymes and their applications for the reduction of biofouling are also discussed.

Prediction of Hot Gas Behavior in High Voltage Self-blast Circuit Breaker (초고압 복합소호 차단부의 열가스 거동 예측)

  • Kim, Jin-Bum;Yeo, Chang-Ho;Seo, Kyoung-Bo;Kweon, Ki-Yeoung;Lee, Hahk-Sung
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2494-2499
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    • 2007
  • Self-blast circuit breakers utilize the energy dissipated by the arc itself to create the required conditions for arc quenching during the current zero. The high-current simulation provides information about the mixing process of the hot PTFE cloud with $SF_6$ gas which is difficult to access for measurement. But it is also hard to simulate flow phenomenon because the flow in interrupter with high current, $SF_6$-PTFE mixture vapor and complex physical behavior including radiation, calculation of electric field. Using a commercial computational fluid dynamics(CFD) package, the conservation equation for the gas and temperature, velocity and electric fields within breaker can be solved. Results show good agreement between the predicted and measured pressure rise in the thermal chamber.

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Relaxation Process of the Photoexcited State and Singlet Oxygen Generating Activity of Water-soluble meso-Phenanthrylporphyrin in a DNA Microenvironment

  • Hirakawa, Kazutaka;Ito, Yusuke;Yamada, Takashi;Okazaki, Shigetoshi
    • Rapid Communication in Photoscience
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    • v.3 no.4
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    • pp.81-84
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    • 2014
  • To examine the microenvironmental effect of DNA on the photosensitized reaction, the electron-donor-connecting porphyrin, meso-(9-phenanthryl)-tris(N-methyl-p-pyridinio) porphyrin (Phen-TMPyP), was synthesized. Phen-TMPyP can bind to oligonucleotides with two binding modes, depending on the DNA concentration. The fluorescence lifetime measurement of Phen-TMPyP shows a shorter component than that of the reference porphyrin without the phenanthryl moiety. However, the observed value is much longer than those of previously reported similar types of electron-donor-connecting porphyrins, suggesting that electron-transfer quenching by the phenanthryl moiety is not sufficient. The fluorescence quantum yield of Phen-TMPyP ($5{\mu}M$) decreased with an increase in DNA concentration of up to $5{\mu}M$ base pair (bp), possibly due to self-quenching through an aggregation along the DNA strand, increased with an increase in DNA concentration of more than $5{\mu}M$ bp and reached a plateau. The fluorescence quantum yield of Phen-TMPyP with a sufficient concentration of DNA was larger than that of the reference porphyrin. The singlet oxygen ($^1O_2$) generating activity of Phen-TMPyP was confirmed by the near-infrared emission spectrum measurement. The quantum yield of $^1O_2$ generation was decreased by a relatively small concentration of DNA, possibly due to the aggregation of Phen-TMPyP, and recovered with a sufficient concentration of DNA. The recovered quantum yield was rather smaller than that without DNA, indicating the quenching of $^1O_2$ by DNA. These results show that a DNA strand can stabilize the photoexcited state of a photosensitizer and, in a certain case, suppresses the $^1O_2$ generation.

Photochemical Property and Photodynamic Activity of Tetrakis(2-naphthyl) Porphyrin Phosphorus(V) Complex

  • Hirakawa, Kazutaka;Aoki, Shunsuke;Ueda, Hiroyuki;Ouyang, Dongyan;Okazaki, Shigetoshi
    • Rapid Communication in Photoscience
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    • v.4 no.2
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    • pp.37-40
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    • 2015
  • To examine the photosensitized biomolecules damaging activity, dimethoxyP(V)tetrakis(2-naphthyl)porphyrin (NP) and dimethoxyP(V)tetraphenylporphyrin (PP) were synthesized. The naphthyl moiety of NP hardly deactivated the photoexcited P(V)porphyrin ring in ethanol. In aqueous solution, the naphthyl moiety showed the quenching effect on the photoexcited porphyrin ring, possibly through electron transfer and self-quenching by a molecular association. Binding interaction between human serum albumin (HSA), a water soluble protein, and these porphyrins could be confirmed by the absorption spectral change. The apparent association constant of NP was larger than that of PP. It is explained by that more hydrophobic NP can easily bind into the hydrophobic pockets of HSA. The photoexcited PP effectively induced damage of the tryptophan residue of HSA, through electron transfer-mediated oxidation and singlet oxygen generation. NP also induced HSA damage during photo-irradiation and the contributions of the electron transfer and singlet oxygen mechanisms were speculated. The electron transfer-mediated mechanism to the photosensitized protein damage should be advantageous for photodynamic therapy in hypoxic condition. The quantum yield of the HSA photodamage by PP was significantly larger than that of NP. The quenching effect of the naphthyl moiety is considered to suppress the photosensitized protein damage. In conclusion, the naphthalene substitution to the P(V)porphyrins can enhance the binding interaction with hydrophobic biomacromolecules such as protein, however, this substitution may reduce the photodynamic effect of P(V)porphyrin ring in aqueous media.

A Study on the Diode Laser Surface Hardening Treatment of Cast Iron for Die Material(II) -Comparison of Hardening Characteristics by the Parts Applied Heat Treatment- (금형재료용 주철의 다이오드 레이저 표면경화처리에 관한 연구(II) - 표면경화의 적용 부위에 따른 열처리 특성의 차이 -)

  • Kim, Jong-Do;Song, Moo-Keun;Hwang, Hyun-Tae
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.8
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    • pp.1048-1054
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    • 2011
  • Laser surface hardening process is the method of hardening surface by inducing rapid self quenching of laser injected area through transfer of surface heat to inside after rapid heating of laser injected area only by high density energy heat source. This surface treatment method does not involve virtually any thermal deformation by heat treatment nor accompanies any other process after surface hardening treatment. In addition, allowing local machining, this method is a surface treatment method suitable for die with complicated shape. In this study, die material cast iron was surface-treated by using high power diode laser with beam profile suitable for heat treatment. Since the shapes of die differ by press die process, specimens were heat-treated separately on plane and corner depending on the applied parts. At this time, corner heat treatment was done with optic head inclined at $10^{\circ}$. As a result, corner heat treatment easily involves concentration of heat input due to limitation of heat transfer route by the shapes compared with plane part, so the treatment accomplished hardening at faster conveying speed than plane heat treatment.