• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
• /
• pp.281-281
• /
• 2012

연꽃잎 효과(Lotus effect)라 불리는 자가 세정 효과(self cleaning effect)는 연꽃이 항상 깨끗한 상태를 유지하는 것이 관찰되면서 꾸준히 관심에 대상이 되어 왔었다. 자가 세정 효과는 접촉각 $150^{\circ}$ 이상의 초소수성 표면에서 구현이 가능하며 이런 표면을 일상생활부터 산업분야까지 응용하고자 하는 많은 노력들이 있었다. 물질의 친수성 또는 소수성은 표면의 거칠기(roughness)와 표면에너지(surface energy)의 두 가지 특성에 의해 결정된다. 하지만 낮은 표면에너지 물질을 사용해도 접촉각 $150^{\circ}$ 이상의 초소수성 표면을 얻긴 힘들며, 표면의 거칠기를 증가시켜야 한다. PTFE (polytetrafluoroethylene)는 낮은 표면에너지를 가진 소수성 물질로 bulk일 경우 접촉각이 약 $108^{\circ}$이지만 거친 표면을 가진 박막으로 만들 경우 접촉각이 $150^{\circ}$ 이상의 값을 가지는 초수수성 표면이 가능한 물질이다. 특히, 초소수성 표면 이외에 우수한 내열성 및 내화학성 특성을 가지고 있어 디스플레이 및 태양전지 등의 자가세정(self cleaning) 보호막으로써 응용이 기대되고 있다. 본 연구에서는 HFPO (hexafluoropropylene)를 원료 가스로 이용하여, Si(100)과 유리 기판위에 Cat-CVD (Catalytic Chemical Vapor Deposition)법으로 PTFE 박막을 증착하였다. 텅스텐(W)을 촉매로 사용하였으며, 촉매온도가 $850^{\circ}C$이상인 조건에서 접촉각이 $150^{\circ}$ 이상인 초소수성 PTFE 표면을 쉽게 얻을 수 있었다. 특히 본 연구에서는 제막압력을 300 mTorr에서 700 mTorr까지 변화시켜 가며 유리와 Si 기판위에 증착하였다. Cat-CVD 제막압력을 변화시켜가며 증착된 PTFE 박막의 접촉각을 측정한 결과, 제막압력이 300 mTorr일 때 glass와 Si 기판위에 증착된 PTFE박막 표면에서의 접촉각은 각각 133, $117^{\circ}$였지만, 제막압력이 400 mTorr이상일 땐 $150^{\circ}$ 이상의 높은 접촉각을 갖는 초소수성 표면을 얻을 수 있었다.

• 한국조리학회지
• /
• 제22권1호
• /
• pp.126-134
• /
• 2016

This study examines effect in customer satisfaction of the emotional intelligence of members at service providing department in the hotel; A case of five star hotels in Dajeon Research hypotheses were developed based on previous literature, and data were collected from 350 employees working at the hotel restaurant service business located in Daejeon, ROK, were investigated herein The collected data were then analysed using frequence reliability For this research analysis, a self-recording method was used where and examiner explains the survey and respondents writhen down their answers to survey questions Statistical processing in this study was done through data cidubg and data cleaning then with the SPSS(Statistical Package for Social Science)v. 18.0. This result the emotional intelligence of service-providing employees at food service department of hotel was found to have a positive effect on customer satisfaction via understanding of others and emotional control. And the understanding of oneself, understanding of others and emotional control in emotional intelligence had a positive effect on job satisfaction. Emotional control, and emotioal use were found to affect organizational commitment positively.

• 치위생과학회지
• /
• 제16권6호
• /
• pp.409-414
• /
• 2016

본 연구의 목적은 천연 식물 중 허브의 일종인 티트리 성분이 함유된 의치세정제를 제조하고 레진의 표면을 분석하고 항균 효과를 평가하고자 하였으며, 다음과 같은 결과를 얻었다. 티트리 오일이 각각 30 vol%, 50 vol% 첨가된 실험군 의치세정제를 제조하였으며 실험군 티트리 오일에서 24시간, 48시간 보관한 후 표면 경도를 확인한 결과 대조군 생리식 염수와 유의한 차이가 없었으며, 시간에 따른 변화 역시 유의한 차이가 없었다. 의치상의 색상변화를 확인하기 위해 색차색도계를 이용하여 24시간, 48시간에 따른 전체변화량 ${\Delta}E^*$값을 확인한 결과 대조군 생리식염수와 유의한 차이가 없어 티트리 의치세정제가 의치표면의 색변화를 나타내지 않았다. 마지막으로 항균력을 평가한 결과 실험군인 티트리 50%군에서는 $3.18{\pm}2.59CFU/ml$로 원액과 유의차를 확인 할 수 없었지만 30%군보다는 높은 항균력을 보였다. 30%군에서는 $36.81{\pm}28.42CFU/ml$로 대조군보다는 높은 항균력을 보였지만 50%군과 티트리 원액 실험군보다는 낮은 항균력을 나타냈다. 따라서 티트리 오일이 함유된 의치세정제는 의치상용레진에 물리적 기계적 변화 없이 우수한 항진균력을 보여 향후 천연성분인 티트리 오일이 함유된 의치세정제 개발을 위한 기초 자료로 활용될 수 있을 것이라 생각된다.

• Restorative Dentistry and Endodontics
• /
• 제48권3호
• /
• pp.28.1-28.13
• /
• 2023

Objectives: This study aimed to investigate the effect of the application method of 2% chlorhexidine (CHX) and its influence on the adhesion of fiberglass posts cemented with a self-adhesive resin cement. Materials and Methods: Sixty human mandibular premolars were endodontically treated and divided into 5 groups (n = 12), according to the canal irrigant and its application method: 2 groups with conventional syringe irrigation (CSI)-2.5% sodium hypochlorite (NaOCl) (control) and 2% CHX- and 3 groups with 2% CHX irrigation/activation-by passive ultrasonic irrigation (PUI), Easy Clean file, and XP-Endo Finisher file. Two roots per group were evaluated for smear layer (SL) removal by scanning electron microscopy. For other roots, fiber posts were luted using a self-adhesive resin cement. The roots were sectioned into 6 slices for push-out bond strength (BS) (7/group) and nanoleakage (NL) (3/group). Data from SL removal were submitted to Kruskal-Wallis and Student-Newman-Keuls tests (α = 0.05). Data from BS and NL were evaluated by 2-way analysis of variance and Tukey's test (α = 0.05). Results: For SL removal and BS, the CHX irrigation/activation promoted better values than CSI with CHX (p < 0.05), but it was not significantly different from CSI with NaOCl (p > 0.05). For NL, the lowest values were obtained by the chlorhexidine irrigation/activation groups (p < 0.05). Conclusions: Active 2% CHX irrigation can be used to improve the post space cleaning and adhesion before fiber post cementation with self-adhesive resin cements.

• 한국건축시공학회:학술대회논문집
• /
• 한국건축시공학회 2020년도 가을 학술논문 발표대회
• /
• pp.85-86
• /
• 2020

With the increasing importance of environmental issues, the cementitious materials with self-cleaning or photocatalytic properties by introducing TiO₂ materials have been gaining a lot of attention. In this work, the influence of TiO₂ particle size and structure on its photocatalytic effect in cement paste was investigated. The degradation of methylene blue solution was used as the parameter for evaluating the photocatalytic effect of micro-TiO2 (m-TiO₂), nano-TiO2 (n-TiO₂), and TiO₂ nanotube (TNT). Moreover, the effect of these three TiO₂ materials on the cement hydration products was characterized by X-ray diffraction (XRD) and thermgravimetric analysis (TG). According to the results, it can be found that all of the TiO₂ materials promoted the formation of hydration products, especially TNT. On the other hand, the m-TiO₂ exhibited a better photocatalytic effect compared to other materials.

• Corrosion Science and Technology
• /
• 제20권5호
• /
• pp.256-265
• /
• 2021

Titanium is applied in various industries due to its valuable properties and abundant reserves. Generally, if a highly uniform oxide structure and a high-density oxide film is formed on the surface through anodization treatment, the utility value such as color appearance and corrosion inhibition efficiency is further increased. The objective of this study was to determine improvement of water-repellent property by controlling titanium oxide parameters such as pore size and inter-pore distance to improve corrosion resistance. Oxide film structures of different shapes were prepared by controlling the anodization processing time and voltage. These oxide structures were then analyzed using a Field Emission Scanning Electron Microscope (FE-SEM). Afterwards, a Self-Assembled Monolayer (SAM) coating was performed for the oxide structure. The contact angle was measured to determine the relationship between the shape of the oxide film and the water-repellency. The smaller the solid fraction of the surface, the higher the water-repellent effect. The surface with excellent hydrophobic properties showed improved corrosion resistance. Such water-repellent surface has various applications. It is not only useful for corrosion prevention, but also useful for self-cleaning. In addition, a hydrophobic titanium may open up a new world of biomaterials to remove bacteria from the surface.

• 전기화학회지
• /
• 제3권2호
• /
• pp.81-84
• /
• 2000

This article deals with various photochemical processes occurring at $TiO_2$ surface and its applications in practical living conditions. In the first part, we present an overview of $TiO_2$ photocatalysis under weak W illumination with a special emphasis on bactericidal and detoxification properties of $TiO_2$ films. The second part deals with the photoinduced super hydrophilic TiCt surftce which has a wide commercial applications. In the last part, we present our recent work on boehmite-based super hydrophobic surfaces containing small amount of $TiO_2$ to obtain self-cleaning effect.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2011년도 춘계학술발표대회
• /
• pp.21.2-21.2
• /
• 2011

에어로졸 데포지션(Aerosol deposition) 기술은 상온에서 초음속 유동을 통해 분사된 미세 입자가 기판에 충돌하면서 강력한 결합을 형성하는 방식으로 코팅이 이루어진다. 이 방법은 별도의 소결과정 없이 상온에서도 조밀하고 균일한 박막을 형성할 수 있다. 또한 세라믹, 금속 재질의 다양한 입자를 사용할 수 있을 뿐만 아니라 금속, 유리 기판등에 적용이 가능하다. 본 논문은 이러한 에어로졸 데포지션 기술을 이용하여 광촉매 효과가 뛰어난 $TiO_2$ 입자를 대면적 코팅에 적용가능한 초음속 노즐을 통해 분사하여 ITO기판 위에 박막을 형성하였다. $TiO_2$ 입자의 크기, 기판의 이송 속도와 왕복횟수, 공급 유량 등이 코팅면의 특성과 조성 등에 미치는 영향을 분석하였다. $TiO_2$ 박막층의 형상과 두께는 주사전자현미경(SEM)을 통해 확인하였고, X-ray diffraction (XRD)를 이용하여 코팅 입자와 박막 층의 조성을 각각 확인하였다. 에어로졸 데포지션을 이용한 $TiO_2$ 코팅층은 염료감응형 태양전지(DSSC), 자정작용(self-cleaning), 살균작용(antibacterial effect) 등의 적용분야에 적용 가능할 것으로 판단된다.

• 센서학회지
• /
• 제25권3호
• /
• pp.213-217
• /
• 2016

The superhydrophobic and superoleophobic meshes surfaces have been used in various applications such as self-cleaning, anti-icing, gas exchange, oil-water separation, sound-wave penetrable anti-wetting structures, etc. In particular, there are many studies for oil-water separation with environmental issues. Because of high pressure and dynamic environment, oil-water separation filters must have stable surface properties as super-hydrophobicity and superoleophobicity. The oleophobicity of surface depends on the surface chemistry and roughness of the surface. The roughness of oleophobic surface enhances its static contact angle and stability. The multi-scale hierarchical structure provides a stable superhydrophobic state by maintaining a Cassie state. In this research, we fabricated a superoleophobic mesh with a multi-scale hierarchical structure to increase the pressure resistance and adjusted a size of the mesh hole.

• 센서학회지
• /
• 제29권4호
• /
• pp.227-231
• /
• 2020

Silver nanowire random networks are promising candidates for replacing indium tin oxide (ITO) as transparent and conductive electrodes. They can also be used as transparent heating films with self-cleaning and defogging properties. By virtue of the Joule heating effect, silver nanowire random networks can be heated when voltage bias is applied; however, they are unsuitable for long-term use. In this work, we study the Joule heating of silver nanowire random networks embedded in polymers. Silver nanowire random networks embedded in polymers exhibit breakdown under the application of electric current. Their surface morphological changes indicate that nanoparticle formation may be the main cause of this electrical breakdown. Numerical analyses are used to investigate the temperatures of the silver nanowire and substrate.