• Title/Summary/Keyword: Selenium characteristic

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The Study of Reaction Characteristics of V/W/TiO2 Catalyst Using Se-TiO2 Support On NH3-SCR Reaction (Se-TiO2 지지체를 이용한 V/W/TiO2 NH3-SCR 촉매의 반응 특성 연구)

  • Lee, Yeon Jin;Won, Jong Min;Ahn, Suk Hyun;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.599-606
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    • 2021
  • In this study, an experiment and a reaction characteristic study were conducted to enhance the reaction activity of V2O5/WO3/TiO2 at 300 ℃ or less by adding selenium to the support, in a selective catalytic reduction method using ammonia as a reducing agent to remove nitrogen oxides. Se-TiO2 and TiO2 were synthesized using the sol-gel method, and used as a support when preparing V2O5/WO3/TiO2 and V2O5/WO3/Se-TiO2 catalysts. The reaction activity of our catalyst was compared with that of a commercial catalyst. The denitration efficiency of the catalyst using TiO2 prepared by the sol-gel method was lower than that of the catalyst prepared using commercial TiO2, but was improved by the addition of selenium. Thus, the effect of selenium addition on the catalyst structure was analyzed using BET, XRD, Raman, H2-TPR, and FT-IR measurements and the effect of the increase in specific surface area by selenium addition and the formation of monomer and complex vanadium species on reaction characteristics were confirmed.

Determination of Arsenic, Lead and Selenium in Rice Flour by Graphite Furnace Atomic Absorption Spectrometry (흑연로원자흡수분광법에 의한 쌀분말시료중의 비소, 납, 셀레늄의 정량)

  • Cho, Kyung-Haeng;Suh, Jung-Ki
    • Analytical Science and Technology
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    • v.12 no.2
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    • pp.130-135
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    • 1999
  • A graphite furnace atomic absorption spectrometry (GFAAS) with matrix modification has been used to determine trace amounts of arsenic, lead and selenium in rice flour samples. A mixed solution of palladium and magnesium nitrate was used as a matrix modifier to convert the analyte elements into a phase of higher thermostability and to increase the volatility of concomitants in graphite furnace. Matrix modification effects by the mixed solution were investigated for several elements (As, Cd, Cu, Pb, Se, Zn). It has been found that the matrix modifier substantially increase the pyrolysis and atomization temperature, and absorbance for As, Pb and Se. The concentration of As, Pb and Se in rice flour samples were determined by standard addition method with Zeeman background correction after microwave acid digestion. In this method the characteristic concentrations of As, Pb and Se are 26 ng/g, 18 ng/g, 24 ng/g on the basis of dry sample respectively.

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A study on output power characteristic of selenium vapour multiline laser using isotope helium and helium filter (헬륨 동위원소 및 헬륨필터를 사용한 셀레늄증기 다중광선레이저의 출력특성에 관한 연구)

  • 최상태
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.2
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    • pp.16-22
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    • 2004
  • The paper presents the effects of output-coupling power and small signal gain of selenium vapour multiline laser by discharge of either to $^4$He or $^3$He. The purity of the He gas was improved with a special He-fille.. The result shows that compared with those of $^4$He, the output-coupling power and small-signal gain of $^3$He increase in the most of the lines. Especially, the small-signal gain of $^3$He for the strong lines (497.6 nm, 499.3 nm, 506.9 nm, 517.6 nm, 522.8 nm, 530.5 nm) lies about 30% higher than that of $^4$He, and the output-coupling power from doubles to triples.

Image Quality Evaluation of Digital X-Ray Detector Using Amorphous Selenium Layer and Amorphous Silicon TFT Array (비정질 셀레늄층과 비정질 실리콘TFT배열을 사용하는 디지털 X-선 검출기의 영상특성 평가)

  • Kim, Chang-Won;Yoon, Jeong-Key;Kim, Jong-Hyo
    • Progress in Medical Physics
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    • v.19 no.4
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    • pp.219-226
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    • 2008
  • In this study, we have conducted characterization of imaging performance for a flat panel digital X-ray detector using amorphous Selenium and a-Si TFT which was developed by the authors. The procedures for characterization were in concordance with internationally recommended standards such as IEC (international electrotechnical commission). The measures used for imaging performance characterization include response characteristic, modulation transfer function (MTF), detective quantum efficiency (DQE), noise power spectrum (NPS), and quantum limited performance. The measured DQEs at lowest and highest spatial frequencies were 40% and 25% respectively, which was superior to that of commercial products by overseas vendor. The MTF values were significantly superior to that of CR and indirect type DRs. The quantum limited performance showed the detector was limited by quantum noise at the entrance exposure level below 0.023 mR, which is sufficiently low for general X-ray examination.

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Comparison of the I-V Characteristic as Various Composition ratio of Iodine in a-Se of $BrO_2/a-Se$ based Radiation Conversion Sensor ($BrO_2/a-Se$ 구조의 방사선 변환센서에서 a-Se에 첨가된 조성비 변화에 따른 I-V 특성 비교)

  • Choi, Jang-Yong;Park, Ji-Koon;Gong, Hyun-Gi;Ahn, Sang-Ho;Nam, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.440-443
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    • 2002
  • Present1y the X-Ray diagnosis system is a real condition that is changing by digital ways in it's existent analog ways. This digital radiation detector is divided by the direct method and the indirect method. The indirect method of applied voltage has special qualities that the resolution is low than direct method by diffusion effect that happens. The conversion process ( radiation${\rightarrow}$visible ray${\rightarrow}$electrical signal of two times, has shortcomings that the energy conversion efficiency of electrical signal is low. The direct method has shortcomings that need strong electric fie1d to detect electrical signal efficiently. This research achieved to develop digital detector of the Hybrid method that have form that mixes two ways to supplement shortcoming of direct. indirect method. A studied electrical characteristic by Iodine's Mixture ratio change is added to selenium in the detector which has a multi-layer structure (Oxybromide + a-Se). There are 8 kinds of Manufactured compositions to amorphous selenium Iodine each 30ppm, 100ppm, 200 ppm, 300ppm, 400ppm, 500ppm, 600ppm, 700ppm by a doped photoconductor through a vacuum thermal evaporation method. The phosphor layer is consisted of Oxybromide ($BrO_2$) which uses optical adhesives multi-layer structure. The manufactured compositions calculates and compares Net Charge and signal to noise ratio measuring Photocurrent about Darkcurrent and X-ray. When doped Iodine Mixture ratio is 500ppm to the multi-layer structure (Oxybromide + a-Se), applied voltage of $3V/{\mu}m$, leakage current of compositions $2.61nA/cm^2$ and net charge value by 764pC/$cm^2$/mR then the best result appeared.

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The Response Characteristics of as Addition Ratio of Arsenic in $CaWO_4/a-Se$ based X-ray Conversion Sensor ($CaWO_4/a-Se$ 구조의 X선 변환센서에서 a-Se의 Arsenic 첨가량에 따른 반응 특성)

  • Kang, Sang-Sik;Suk, Dae-Woo;Cho, Sung-Ho;Kim, Jae-Hyung;Nam, Namg-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.416-419
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    • 2002
  • There are being two prominent studying for Digital Radiography. Direct and Indirect method of Digital Radiography are announced for producing high quality digital image. The one is using amorphous selenium as photoconductor and the other is using phosphor layer as a light conversion. But each two systems have strength and weakness such as high voltage and blurring effect. In this study, we investigated the electrical characteristic of $multi-layer\left(CaWO_{4}+a-Se \right)$ as a photoconductor according to the changing arsenic composition ratio. This is a basic research for developing of Hybrid digital radiography which is a new type X-ray detector. The arsenic composition ratio of a-Se compound is classified into 7 different kinds which have 0.1%, 0.3%, 0.5%, 1%, 1.5%, 5%, 10% and were made test sample throught thermo-evaporation. The phosphor layer of $CaWO_4$ was overlapped on a-Se using EFIRON optical adhesives. We measured the dark and photo current about the test sample and compared the electrical characteristic of the net charge and signal-to-noise ratio. Among other things, test sample of compound material of 0.3% arsenic showed good characteristic of $2.45nA/cm^2$ dark current and $357.19pC/cm^2/mR$ net charge at $3V/{\mu}m$.

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The Study on Characteristic Composition of As in a-Se with X-ray Detection Sensor using $CaWO_4/a-Se$ (다층구조($CaWO_4/a-Se$) 기반의 X선 검출센서에서 a-Se에 첨가된 As의 특성비 연구)

  • Choe, Jang-Yong;Lee, Dong-Gil;Sin, Jeong-Uk;Kim, Jae-Hyeong;Nam, Sang-Hee;Park, Ji-Koon;Kang, Sang-Sik;Jang, Gi-Won;Lee, Hung-Won
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.432-435
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    • 2002
  • The ultimate study of this research is to improve the properties of digital X-ray receptor based on amorphous selenium. There are being two prominent studying for Digital Radiography. Direct and Indirect method of Digital Radiography are announced for producing high quality digital image. But each two systems have strength and weakness. This is a basic research for developing of Hybrid digital radiography which is a new type X-ray detector. ln this study, we investigated the electrical characteristic of multi-layer$(CaWO_4+a-Se)$ as a photoconductor according to the changing iodine composition ratio. The iodine composition ratio of a-Se compound is classified into 5 different kinds which have 30ppm, 100ppm, 300ppm, 500ppm, 700ppm and were made test sample throught thermo-evaporation. The phosphor layer of $CaWO_4$ was overlapped on a-Se using EFIRON optical adhesives. We measured the dark and photo current about the test sample and compared the electrical characteristic of the net charge and signal-to-noise ratio. Among other things, test sample of compound material of 700ppm iodine showed good characteristic of $2.53nA/cm^2$ dark current and $479nC/cm^2{\cdot}mR$ net charge at $3V/{\mu}m$.

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Comparison of the Detection Efficiency $a-Se_{1-x}As_x$ in X-ray Detection Sensor of $Gd_2O_2S(Eu^{2+})/a$-Se Structure ($Gd_2O_2S(Eu^{2+} )/a$-Se$ 구조의 X선 검출 센서에서 $a-Se_{1-x}As_x$의 검출효율 비교)

  • Kang, Sang-Sik;Park, Ji-Koon;Lee, Dong-Gil;Mun, Chi-Wung;Nam, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.436-439
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    • 2002
  • Recently, It has performed that the basic research of the photoconductive material and the development and application of the digital radiograph detector which is divided into the direct and indirect method. The objective of this study investigate the effect of the electric characteristic about changing the composition of Arsenic in hybrid detector system for compensating a defect of conventional. We fabricated samples using the amorphous Selenium and Arsenic alloy with various concentrations of the Arsenic{seven step 0.1%, 0.3%, 0.5%, 1%, 1.5%, 3%, 5%). And using EFIRON optical adhesives the formed multi-layer$(Gd_{2}O_{2}S(Eu^{2+}))$ composed phosphor layer. X-ray and light sensitivity was measured to study x-ray response characteritics. As results, highest value was measured as output net charge and SNR were $315.7pC/cm^2/mR$ and 99.4 at 0.3%As doping ratio.

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