• Title/Summary/Keyword: Segregated Structure

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Electromagnetic Shielding Polymer Composites with Segregated Structure for Automotive Part Application: A Review (자동차 부품 적용을 위한 Segregated structure를 갖는 전자파 차폐용 고분자 복합소재 연구동향)

  • Lee, Jinwoo;Suhr, Jonghwan
    • Composites Research
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    • v.35 no.4
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    • pp.223-231
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    • 2022
  • With the rapid growth of the future mobility market, a large number of electronic parts are being used in automobile, and the importance of electromagnetic interference (EMI) shielding in the automobile market is growing to minimize malfunctioning among the parts. Accordingly, conductive polymer composites (CPCs) are getting a lot of attention as EMI shielding materials for the automotive, but there are still challenges in CPCs like high content of conductive filler to achieve proper EMI shielding effectiveness, and poor mechanical properties. This paper introduces main methods to manufacture CPCs with segregated filler structure, which can significantly reduce the filler content, and analyzes EMI shielding performance of each manufacturing method.

Electronic structure and magnetism of catalytic material Pt3Ni surfaces: Density-functional study

  • Sharma, Bharat Kumar;Kwon, Oryong;Odkhuu, Dorj;Hong, Soon Cheol
    • Proceedings of the Korean Magnestics Society Conference
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    • 2012.11a
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    • pp.172-172
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    • 2012
  • A Pt-skin $Pt_3Ni$(111) surface was reported to show high catalytic activity. In this study, we investigated the magnetic properties and electronic structures of the various oriented surfaces of bulk-terminated and Pt-segregated $Pt_3Ni$ by using a first-principles calculation method. The magnetic moments of Pt and Ni are appreciably enhanced at the bulk-terminated surfaces compared to the corresponding bulk values, whereas the magnetic moment of Pt on the Pt-segregated $Pt_3Ni$(111) surface is just slightly enhanced because of the reduced number of Ni neighboring atoms. Spin-decomposed density of states shows that the dz2 orbital plays a dominant role in determining the magnetic moments of Pt atoms in the different orientations. The lowering of the d-band center energy (-2.22 eV to -2.46 eV to -2.51 eV to -2.65 eV) in the sequence of bulk-terminated (100), (110), (111), and Pt-segregated (111) may explain the observed dependence of catalytic activity on surface orientation. Our d-band center calculation suggests that an observed enhanced catalytic activity of a $Pt_3Ni$(111) surface originates from the Pt-segregation.

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Magnetism during adsorption of oxygen in Pt segregated $Pt_3Ni$ (111): Density Functional Study

  • Kumar, Sharma Bharat;Kwon, O-Ryong;Odkhuu, Dorj;Hong, Soon-Cheol
    • Proceedings of the Korean Magnestics Society Conference
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    • 2011.12a
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    • pp.14-14
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    • 2011
  • Limited understanding of the surface properties of $Pt_3Ni$ for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cell (PEMFC) has motivated the study of magnetic properties and electronic structures of Pt segregated $Pt_3Ni$ (111) surface during adsorption of oxygen molecule on it. The first principle method based on density functional theory (DFT) is carried out. Nonmagnetic Pt has induced magnetic moment due to strong hybridization between Ni 3d and Pt 5d. It is found that an oxygen molecule prefers bridge site with Pt rich subsurface environment for adsorption on the surface of Pt segregated $Pt_3Ni$ (111). It is seen that there is very small charge transfer from $O_2$ to Pt. The curve of energy versus magnetic moment of the oxygen explains the magnetic moments in transition states. We found the dissociation barrier of 1.07eV significantly higher than dissociation barrier 0.77eV on Pt (111) suggesting that the dissociation is more difficult on Pt segregated $Pt_3Ni$ (111) surface. The spin polarized densities of states are presented in order to understand electronic structures of Pt and $O_2$ during the adsorption in detail.

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Examining the Residential Patterns of Urban Immigrants in Seoul Metropolitan Area

  • Kim, Hyejin;Lee, Jawon
    • International Journal of Advanced Culture Technology
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    • v.6 no.3
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    • pp.37-43
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    • 2018
  • This paper measures and maps multi-dimensional residential segregation of immigrants in Seoul metropolitan area at city/county/district level as well as town level, thereby adding to our understanding of the urban structure and its spatial distribution impacted by immigration. The perspective offered here focuses on the segregation spurred by transnational migrants and their urban settlement. By drawing population data for 79 city/county/district administrative units from the Korea Immigration Service, residential segregation of immigrants in Seoul metropolitan area is measured based on Massey & Denton's four segregation indices: evenness, exposure, concentration and clustering. The empirical findings suggest that Seoul metropolitan area is highly segregated and the areas showing hyper-segregation appear in Seoul city and Gyeonggi province. As immigrants are foreseen to continue to increase in the future, this research contributes both empirically and theoretically to preliminary research on spatial segregation of immigrants by showing how ethnic places are segregated spatially through ethnic networks that support the geographic concentration of minority groups.

Stucture and Intergranular Segregation of WC/WC Grain Boundaries in WC-Based Cemented Carbides (WC기 초경합금중 WC/WC界面의 구조와 입계편석)

  • Sin, Sun-Gi
    • Korean Journal of Materials Research
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    • v.10 no.9
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    • pp.612-618
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    • 2000
  • The WC/WC grain boundary structure and intergranular segregation in WC-Co and WC-VC-Co cemented carbides were investigated by high-resolution transmission electron microscopy and energy dispersive X-ray spectroscopy in order to elucidate whether contiguous boundaries were present or not at the atomic level. Some grain boundaries were separated by liquid phase, while others were contiguous at the atomic level. Cobalt was found to be segregated to WC/WC grain boundaries in WC-Co. Cobalt and vanadium were co-segregated to grain boundaries in WC-VC-Co. The segregation width in both materials was about 6 nm. These results suggest that the vanadium present in contiguous boundaries acts as an effective barrier to the migration of boundaries during sintering and annealing. This could explain the grain growth inhibiting mechanism of VC added to WC-Co.

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Imprinting of Liquid Crystal Alignment on Polymer Layers

  • Wook, Jung-Jong;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.611-614
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    • 2003
  • We have investigated electric field effect on the formation of phase separated composite organic film structure which is utilized by anisotropic phase separation from LC and prepolymer mixtures. Application of bias field resulted in a significant change in liquid crystal alignment between glass substrate and polymer layer. The liquid crystal molecules segregated into the inter-electrodes and formed twisted structure which is the result of imprinting of LC alignment by the bias field on polymer layers during polymerization process.

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The application of BEM in the Membrane structures interaction with simplified wind

  • Xu, Wen;Ye, Jihong;Shan, Jian
    • Structural Engineering and Mechanics
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    • v.31 no.3
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    • pp.349-365
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    • 2009
  • Membrane structures are quite sensitive to wind and therefore the fluid-solid interaction can not be neglected in dynamic analysis. A boundary element method (BEM) for 3D simulation of wind-structure interaction in tensile membrane structures is presented in this paper. The flow is treated as incompressible and potential. The flow field is solved with boundary element method codes and structural simulation is performed by finite element method software ANSYS. The nonlinear equations system is solved iteratively, with segregated treatment of the fluid and structure equations. Furthermore this method has been demonstrated to be effective by typical examples. Besides, the influence of several parameters on the wind-structure interaction, such as rise-span ratio, prestress and the wind velocity are investigated according to this method. The results provide experience in wind resistant researches and engineering.

Software Complexity Measure Based on Program Control Structure Using Petri Nets (패트리넷트를 이용한 프로그램의 제어구분적 복잡도)

  • Lee, Jong-Geun;Song, Yu-Jin
    • The Transactions of the Korea Information Processing Society
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    • v.2 no.3
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    • pp.335-342
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    • 1995
  • In this pater, we present a syntactic software complexity measure based on program control structure using Petri Nets. Since control structure in program may be segregated by three structures such as sequence, condition and iteration structures, we are proposed a structured complexity measure based on program control structure after represented by Petri Nets. Finally, we compare our result with other measures of program complexity.

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Microstructural Features of Al Alloy 7N01 Welded by $CO_2$ Laser - Microsturctural Features of Full Penetration Joints - ($CO_2$ 레이저 용접한 7N01 Al합금의 미세조직 특징(I) - 완전용입 용접부의 미세조직 -)

  • 윤재정;강정윤;김인배;김대업
    • Journal of Welding and Joining
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    • v.19 no.4
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    • pp.429-436
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    • 2001
  • The effect of welding condition on the microstructures of the weld metal in A7N01 welded by $CO_2$ laser was investigated. The number of ripples was increased with decreasing power and increasing welding speed. In the bead without ripple lines, the subgrain microstructures distribution from the fusion line toward the center of the bead were in the order of cellular, dendritic and equiaxed dendrite. However, in the bead with ripple lines, cellular and dendritic were formed between the fusion boundary and the ripple line. Inaddition, those structures were also observed between the ripple line. Equiaxed dendrites were formed only at the center line region. Cellular and dendritics formed near the ripple line were larger than those formed near the fusion boundary. The cooling rates estimated by the dendrite arm spacing were in the range of 200 to 1150oC/s. Cooling rate was increased with decreasing the power and increasing the welding speed. Mg and Zn segregated at the boundaries of cellulars and dendritics, Mg was segregated more than Zn. The segregation of Mg and Zn decreased with increasing cooling rate. Hardness of the weld metal was lower than that of the base metal in all welding conditions and increased as the cooling rate increased.

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Effects of Center Segregation on Weld Cold Cracking Susceptibility (용접 저온균열 감수성에 미치는 중심 편석의 영향)

  • 안영호;이종봉;장래웅;소문섭
    • Journal of Welding and Joining
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    • v.12 no.2
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    • pp.87-96
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    • 1994
  • Correlation between microstructural features and segregation of elements (Si, Mn, P and S) near the mid of thickness in the base metal and the synthetic HAZ was investigated. Furthermore, the relationship between the degree of center segregation and weld cold cracking susceptibility in the thickness direction was also conducted by evaluating the effect of P concentration on the critical applied stress. The results obtained are as follows: 1) Pearlite band, containing the MnS type inclusion and a locally transformed structure with a higher hardness, was observed in the center segregation region. 2) By the weld thermal cycle, center segregation region was transformed to the white band which had a higher hardness than that of base metal due to a greater hardenability of concentrated Mn, P etc.. 3) Weld cold cracking susceptibility in the thickness direction was mainly dependent on the concentration of impurity elements rather than on the number of the segregated particles near the mid of thickness. 4) During welding, the higher concentrated region was easily changed into white band. Therefore, it could be predicted that the initiation and propagation of a cold crack would be promoted by increasing the restraint stress and hydrogen content.

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