• Title/Summary/Keyword: Sediments Analysis

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The Spatial and Vertical Variations of Metal Pollution in Sediments after Tidal Power Plant Operation in Shihwa Lake (시화호 조력발전소 가동으로 인한 퇴적물 내 중금속 오염 특성 변화)

  • LEE, JIHYUN;JEONG, HYERYEONG;CHOI, JIN YOUNG;RA, KONGTAE
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.24 no.4
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    • pp.535-547
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    • 2019
  • In this study, the heavy metal analysis in sediments (surface sediments, sediments cores and settling particles) from Shihwa Lake has been carried out to evaluate the changes of metal pollution levels in sediments after the operation of Tidal Power Plant (TPP). The average concentrations of metals in surface sediments sampled in 2015 were 8% (Cd)~31% (Zn, Hg) lower than in 2009 before TPP operation. Results of calculating the pollution load index (PLI) with 8 metals, the PLI value in 2015 showed a 18% decrease compared to 2009. However, Cu, Zn, Pb concentrations of surface sediments in 2015 at the upper region around industrial complex still exceeded the TEL (threshold effect level) values for sediment quality guideline in Korea. After the operation of TPP, the metal contaminated depths were increasing from 15 cm to 30 cm at S6 site and from 8 cm to 20 cm at S7 site, respectively. Our data showed that the mean concentration of heavy metals in core samples decreased but the contaminated depth increased. The average of the total sedimentation flux for particulate matter increased by 3.2 times from 32.5 g/㎡/d in 2009 to 103.5 g/㎡/d in 2015. This showed that the bottom sediments were resuspended by the operation of TPP, resulting in an increase of particulate matter in the water column. These results suggest that the sediments contaminated with heavy metals seem to be resuspended and relocated due to the water current caused by the operation of TPP. Cr, Cu, Zn, Pb and Cd were highly exceeding the TEL values in the upstream region and accumulated more than 40 cm of sediment depth, indicating that heavy metal contamination through industrial activity were still a serious environmental problem of Shihwa Lake. Although the metal pollution of Shihwa Lake has been slightly reduced, the contaminated sediments with heavy metals inside of Shihwa Lake might be discharged to outer sea after the resuspension by TPP operation. It is necessary for the advanced scientific approach and political decision to drastically reduce the heavy metal pollution of the study region.

The Effects of Mean Grain Size and Organic Matter Contents in Sediments on the Nutrients and Heavy Metals Concentrations (퇴적물 내 입도와 유기물 함량이 영양염류 및 중금속 농도에 미치는 영향)

  • Kim, Seog-Ku;Lee, Mi-Kyung;Ahn, Jae-Hwan;Kang, Sung-Won;Jeon, Sang-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.9
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    • pp.923-931
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    • 2005
  • A study was carried out to identify the major causes of sediments pollution in the Paldang Lake in the vicinity of Gyeongan river. Samples from 40 sites were collected and analyzed to characterize the regional distributions of grain size, organic matter contents, and concentrations of T-N, T-P and heavy metals. contaminations. The mean grain size(Mz) ranged from sand type(Mz, $1{\sim}3\;{\phi}$) where Bukhan River and Namhan River converges at a high flow rate to silt type(Mz, $5{\sim}10\;{\phi}$) at the downstream of Gyeongancheon and Paldang lake, reflecting the water circulation in the area. Except sampling point St. 36 near the wetland, the determination coefficient($r^2$) of Mz and organic matter(LOI) was 0.88, showing that more organic matters are concentrated inside finer sediments. The concentrations of T-N and T-P in sediments were higher in the area at which Mz and organic matters are also higher. High concentrations of T-P analyzed in the sediments, ranging from $216{\sim}1,623\;{\mu}g/g$ (Avg. $769\;{\mu}g/g$) could be considered as a critical level. Adsorbed-P and NAI-P, which are easily released to the surrounding environments when physico-chemical characteristics of sediments are changed, was found to be around 20%, which was showed by the result of fractionated-P. Moreover, Principle Component Analysis(PCA), showed that high concentrations of T-N, T-P, organophilic metals (Cd, Cu, Pb, Zn) are distributed in the areas where high organic matter contents and fine grain-sized sediments are found. However, results of $I'_{geo}$ (Geoaccumulation Index) that considers the grain size of sediments showed that heavy metal concentrations in the lake was low enough to be considered as Class 1 indicating the relative degree of pollution was less than zero.

Sedimentological Characteristics of the Surface Sediments in the Southern Sea off Cheju Island, Korea. (제주남방해역 표층퇴적물의 특성)

  • 윤정수;고기원
    • 한국해양학회지
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    • v.22 no.3
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    • pp.130-142
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    • 1987
  • Sedimentological characteristics of the surface sediments in the southern sea off Cheju Island are described from analyses of bottom sediments. The sediments are subdivided into seven textural classes, muddy sand, slightly gravelly muddy sand, sand, clayey sand, sandy clay, sandymud, silty sand. Sand-size sediments are distributed in the southeastern part and/or around the Island, whereas sandy and muddy sediments are mainly distributed in the central and southern parts of the study area. A small portion of mud patch is located in the southwestern part of the area. According to the textural parameters analysis, sediments in the study area are poorly sorted(av.2.52 ), positive skewed(av.1.61 ), leptokurtic(av.1.74 ), transported by saltation and/or suspension, and roundness of quartz is varied from angular to surrounded, which suggesting that the depositional environment is not simple. The calcium carbonate content is on the average 26.99%, and commonly abundant in sand-size sediments, whereas organic matter content in the bulk sediment is on the average 6.70% and usually dominant in fine-grained sediments.Light minerals consist of quartz(av56.01%),Na-Ca feldspar(av.6.15%),K-feldspar(av.9.22%) and rock fragments(av28.11%).The contect onquartz and K-feldspar increases continuously away from the Cheju Island. As a result of geochemical analysis,concentrations of the elements are as follow:Zn:19.42-43.52 ppm (av.30.67ppm),Mn:50-304 ppm(av139.39ppm),Cr:3.54-10.68ppm(av6.50ppm),Pb:5.52-41.68ppm(av.15.60ppm), Co:7.08-14.68ppm (av.10.78ppm),Ni:19.70-42.42ppm(av.29.57ppm),Cu:3.14-9.12ppm(av.5.14ppm),Fe:0.48-2.08% (av1.22%),Ca:0.32-13.16%(av6.60%),Al:0.06-0.08%(av.0.27%),Mg:0.12-0.76%(av.0.53%)na:0.11-0.51%(av.0.36%) Ag:0.48-4.08ppm(av.1.22ppm).Among these elements,the content of Zn,Cu,Cr,Mn,Fe,Al,Mg,Pb and Na increase toward the southwestern area,while the content of Ca and Ag SHOWS the reversed distribution trend.Such a distribution pattern seems to imply that spatial distrivution of heavy metals is closely related to the variation in grain size. X-ray diffractogram show that the minerals in clay from the southwestern mud patch are illite ,chlorite, kaolinte,feldspar and calcite.The bulk of illite in th mud zone is believed to be originated from Huanghe and Yangytze River.The mud patch in this region contains the diagnostic calcite peak,and the concentration of Ca,ni,Pb,Ag are similar to Huanghe type,which indicates that the greater part of these clay fractions may have been derived from the Huanghe River.

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Depositional Environment and Formation Ages of Eurimji Lake Sediments in Jaechon City, Korea (제천 의림지 호저퇴적물 퇴적환경과 형성시기 고찰)

  • 김주용;양동윤;이진영;김정호;이상헌
    • The Korean Journal of Quaternary Research
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    • v.14 no.1
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    • pp.7-31
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    • 2000
  • Quaternary Geological and geophysical investigation was performed at the Eurimji reservoir of Jaechon City in order to interprete depositional environment and genesis of lake sediments. For this purpose, echo sounding, bottom sampling and columnar sampling by drilling on board and GPR survey were employed for a proper field investigation. Laboratory tests cover grain size population analysis, pollen analysis and $^{14}C$ datings for the lake sediments. The some parts of lake bottom sediments anthropogenically tubated and filled several times to date, indicating several mounds on the bottom surface which is difficult to explain by bottom current. Majority of natural sediments were accumulated both as rolling and suspended loads during seasonal flooding regime, when flash flow and current flow are relatively strong not only at bridge area of the western part of Eurimji, connected to stream valley, but at the several conduit or sewage system surrounding the lake. Most of uniform suspend sediments are accumulated at the lake center and lower bank area. Some parts of bottom sediments indicate the existence of turbid flow and mudflow probably due to piezometric overflowing from the lake bottom, the existence of which are proved by CM patterns of the lake bottom sediments. The columnar samples of the lake sediments in ER-1 and ER-3-1 boreholes indicate good condition without any human tubation. The grain size character of borehole samples shows poorly sorted population, predominantly composed of fine sand and muds, varying skewness and kurtosis, which indicate multi-processed lake deposits, very similar to lake bottom sediments. Borehole columnar section, echo sounding and GPR survey profilings, as well as processed data, indicate that organic mud layers of Eurimji lake deposits are deeper and thicker towards lower bank area, especially west of profile line-9. In addition the columnar sediments indicate plant coverage of the Eurimji area were divided into two pollen zones. Arboreal pollen ( AP) is predominant in the lower pollen zone, whreas non-aboreal pollen(NAP) is rich in the upper pollen zone. Both of the pollen zones are related to the vegetation coverage frequently found in coniferous and deciduous broad-leaved trees(mixed forest) surrounded by mountains and hilly areas and prevailing by aquatic or aquatic margin under the wet temperate climate. The $^{14}C$ age of the dark gray organic muds, ER1-12 sample, is 950$\pm$40 years B.P. As the sediments are anthropogenetically undisturbed, it is assumed that the reliability of age is high. Three $^{14}C$ ages of the dark gray organic muds, including ER3-1-8, ER3-1-10, ER3-1-11 samples, are 600$\pm$30 years B.P., 650$\pm$30 years B.P., 800$\pm$40 years B.P. in the descending order of stratigraphic columnar section. Based on the interpretation of depositional environments and formation ages, it is proved that Eurimji reservoir were constructed at least 950$\pm$40 years B.P., the calibrated ages of which ranges from 827 years, B.P. to 866 years B.P. Ancient people utilize the natural environment of the stream valley to meet the need of water irrigation for agriculture in the local valley center and old alluvium fan area.

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Sediment Provenance of Southwestern Cheju Island Mud using Principal Component Analysis (통계적 주성분분석법을 활용한 제주 남서 이질대 퇴적물의 기원지 연구)

  • Lee, Yun Ji;Cho, Hyen Goo;Kim, Soon-Oh;Ahn, Sung Jin;Choi, Hunsoo
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.3
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    • pp.189-196
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    • 2013
  • In this study, we tried to define the origin of fine-grained sediments in Southwestern Cheju Island Mud (SWCIM) using principal component analysis. We used relative clay mineral compositions using 138 marine surface sediments, 4 Huanghe sediments and 3 Changjiang river sediments by the semi-quantitative X-ray diffraction analysis. We made bioplot diagram using R program with principal component 1 and component 2 because they might contain more than 90% of all data. Although the distribution pattern of each clay minerals in SWCIM is so intricate, smectite and kaolinite contents are high in the west region, but illite and chlorite contents are rich in the east region. In the biplot, the east region of SWCIM distribute around Changjiang river, whereas west region of SWCIM disperse around Huanghe. Our results might reveal that west region of SWCIM is mainly originated by Huanghe, but east region of SWCIM by Changjiang River.

A Comparison of Silk Fibroin Hydrolysates by Hydrochlonic Acis and Proteolytic Enzymes

  • Sh. R. Madyarov;Yeo, Joo-Hong;Lee, Kwang-Gill;Lee, Yong-Woo
    • International Journal of Industrial Entomology and Biomaterials
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    • v.2 no.1
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    • pp.7-13
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    • 2001
  • Enzymatic hydrolysis of different forms of silk fibroin (soluble, gel and insoluble forms) by industrial and commercial enzyme preparations to obtain aqueous and powdered silk fibroin in relatively mild conditions was investigated. A mono-enzymatic hydrolysate systems were tested for hydrolysis of water-soluble form of fibroin as most productive form of protein substrate. Insoluble forms of substrate usually were hydrolyzed less effective. In some cases from soluble fibroin substrate gel was formed during hydrolysis process. This hindered intermixing and decreased rates of hydrolysis. Insoluble sediments were formed in enzymatic hydrolysates in other cases. These sediments and also sediment after chemical hydrolysis were purified and tested on amino acids content for comparison. Sediments formation in these conditions are considered as pure tyrosine isolation method. Obtained hydrolysates were characterized by gel-chromatography analysis and other standard biochemical methods. Possibility of application of enzymatic hydrolysis for preparation of silk fibroin hydrolysates is discussed.

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Evolution of Glaucony in the Tertiary Marine Sediments in the Pohang Area, SE Korea (포항지역 제3기 해성퇴적층에서의 해록석 진화)

  • Byeong-Kook Son;Sang-Mo Koh;Hag-Ju Kim
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.3
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    • pp.171-181
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    • 2002
  • Glauconization was investigated by morphological and chemical analysis of glaucony from the Pohang Tertiary marine sediments. The glaucony, which is present sparsely in turbidite sandstones, shows two distinct stages in morphology and chemistry. Crystallization of glaucony starts preferentially from the interior of pellet-like grains, then to the outer region of the grains with increasing K and Fe, and decreasing Al. Furthermore, smectite-like glaucony is evolved into illite-like glaucony through interstratified glauconite-smectite with increases in K and Al, and decrease in Fe.

Variation of Physical Characteristic of Tidal Flat's Environment by Water Level Change (수위변동에 따른 갯벌의 물리적 환경특성의 변화)

  • Park, Jong-Hwa
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.2 no.3
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    • pp.1-9
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    • 1999
  • This paper described the results of the characteristics of the near-bottom flow and field analysis of the tidal flats sediment. It was the aim of this paper to grasp current flow of tidal flat's environment and influence factor for environmental change forecast of tidal flats. Field measurement of water velocity, water elevation, bed materials test, and temperature distribution of tidal flat were conducted. Thereafter, current flow, turbidity and temperature distribution of tidal flat sediment have been discussed. The field research results showed that the fluctuating velocity near the seabed before and after its appearance at low tide was strongly affected by the wind wave. The resuspension of the sea-bottom sediment took place with great intensity before and after the appearance of the seabed at low tide. Both the sea water level and the weather condition were a significant influential factors. Such as, temperature and turbidity just on the surface and the shallow layer of seabed sediments were varied largely with time and weather conditions, but that its deeper layers was almost constant. Temperature on the seabed sediments was strongly influenced by irradiance and water depth. The temperature variation of the tidal flat and the variation characteristics of the current flow and turbidity depend greatly on the inhabiting environment of the tidal flat benthic organism.

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