• The Korean Journal of Quaternary Research
• /
• v.22 no.1
• /
• pp.1-12
• /
• 2008

We investigated metal concentrations and oceanic environment changes that have occurred over the past several years by studying the hard coral Porites lutea, which inhabits tropical and subtropical areas. Soft X-radiographs clearly showed distinctive annual bands within 71 mm coral sample, which reflect changes in the oceanic environment over this period. There were large fluctuations in the major and minor element concentrations. Considering the physicochemical partition coefficient, some elements accumulated in the aragonite matrix in a mechanical manner, while others were affected by environmental factors. The concentrations of some heavy metals varied over a wide range, implying local environmental effects. The variation of Sr/Ca and Mg/Ca in coral skeleton clearly showed large-scale fluctuation over the specific intervals, implying environmental changes during this period. The concentrations of heavy metals also show high fluctuations, and roughly accord with Mg/Ca variation. In addition, Cu and Zn seem to show cyclicity-like peaks, coincide with Mg/Ca variation over the specific intervals. Such variation might be related to local pollution and oceanographic changes. More detailed investigation is necessary, including the pretreatment of coral skeleton sediment.

• Journal of Korean Society on Water Environment
• /
• v.31 no.5
• /
• pp.523-532
• /
• 2015

Hydrocyclone is widely used in industry, for its simple design, high capacity, low maintenance and low operational cost. The objective of this study is to develop hydrocyclone coagulation and filtration system. The system is made of hydrocyclone ballasted coagulation with polyaluminium chloride silicate (PACS) and upflow filter to treat micro particles in urban storm runoff. Roadside sediment particles (< $200{\mu}m$) was mixed with tap water to make various turbid suspensions to simulate urban storm runoff. The filter cartridge was filled with polyethylene media system and ran 1hr per everyday and total operation time were 8.19hrs and backwashing everyday after end of operation. The operation condition of flowrate was $8.2{\sim}11.9m^3/day$ (mean $10.1m^3/day$) and surface overflow rate (SOR) based on filter surface area was $45.5{\sim}65.9m^3/m^2/day$ (mean $55.7m^3/m^2/day$). The range of PACS dosage concentration was 14.0~31.5 mg/L. As the results of operation, the range of removal efficiency of turbidity, SS were 81.0~95.8% (mean 89.5%) 81.8~99.0% (mean 91.4%), respectively. An increase of filtration basin retention time brought on increased of removal efficiency of turbidity and SS, and increase of SOR brought on decreased of removal efficiency. During the first flush in urban area, storm runoff have an high concentration of SS (200~600 mg/L) and the filtration bed becomes clogged and decreased of removal efficiency. Backwashing begins when the drainage pipe valve at the filtration tank bottom is completely open (backwashing stage 1). Backwashing stage 2 was using air bubbles and water jet washing the media for 5 mins and open the drainage valve. After backwashing stage 1, 2, 61.83~64.04%, 18.53~27.51% of SS loading was discharged from filtration tank, respectively. Discharged SS loading from effluent was 7.12~14.79% and the range of residual SS loading in fliter was 2.26~5.00%. The backwashing effects for turbidity, SS were 89.5%, 91.4%, respectively. The hydrocyclone coagulation and filtration with backwashing system, which came out to solve the problems of the costly exchange filter media, and low efficiency of removing micro particles of filter type nonpoint treatment devices, is considered as an alternative system.

• Journal of Korean Society of Environmental Engineers
• /
• v.37 no.1
• /
• pp.45-51
• /
• 2015

PBDEs (polybrominated diphenyl ehters) are rarely dissolved in water due to their strong hydrophobicity and large molecular mass so not many researches were done in aqueous environment compared to other environmental compartments. However, the mass loading from wastewater treatment plant into aquatic environment, re-suspension from bottom sediment and partitioning from floating particles and colloids may not be negligible. It is, therefore, important but also difficult to investigate PBDEs in water environment. Recent overcoming resolution towards this barrier to monitor hydrophobic organic compounds in aquatic environment is using passive sampling technique like semipermeable membrane device. By using passive sampling, it might be possible to obtain long-term reproducible monitoring result and detect the trace amounts of PBDEs, with controlling fluctuation of surrounding environmental factors during the sampling event. So therefore, this study is purposed to confirm the possibility of using SPMD (semi-permeable membrane device) as water monitoring tool. Grab samples, composite samples and SPMDs were applied in river bank to evaluate the concentration difference and temporal fluctuation by various water sampling method, and to assess the water concentration prediction capability of SPMD for the PBDEs.

• Journal of the Korean GEO-environmental Society
• /
• v.11 no.6
• /
• pp.69-75
• /
• 2010

Total suspendid solid (TSS) of non point source pollutants in construction site are in higher concentration than others (BOD, COD etc). Also, the TSS concentration is very sensitive to the rainfall intensity in early stage of construction. There are two methods for treatment of non point source pollutants, which are temporary treatment facility and filtering one. But they have disadvantages. Temporary facility system has very low efficiency and filtering system consumes high energy and takes up large footprint. This study shows how prefabricated flocculation/coagulation system is developped to cover the above weakness and evaluation of the system performance in construction site. The prefabricated flocculation/coagulation system has very high treatment efficiency comparing with temporary and filtering system and takes small footprint. Therefore, it expects that the system leads to prevention of pollution near construction site and reduction of public grievance. Proper coagulant dosage and sludge circulation facility application, controlling the height of sludge interfacial are necessary to maximize the system efficiency.

• Korean Journal of Environmental Agriculture
• /
• v.30 no.4
• /
• pp.424-431
• /
• 2011

BACKGROUND: Tributyltin chloride is among the most toxic compounds known for aquatic ecosystems. Microorganisms are responsible for removal of TBTCl. Nevertheless, only a limited number of marine bacteria were investigated for biodegradation of TBTCl in Korea. METHODS AND RESULTS: The number of TBTCl resistant bacteria ranged from $2.5{\times}10^3$ to $3.8{\times}10^3$ cfu/mL in the seawater, and ranged from $3.2{\times}10^5$ to $9.1{\times}10^5$ cfu/g in the surface sediment, respectively. The morphological, physiological, and biochemical characteristics of TBTCl resistant bacteria were investigated by API 20NE and other tests. The most abundant species of TBTCl resistant bacteria were Vibrio spp. (19.2%), Bacillus spp. (16.2%), Aeromonas spp. (15.2%), and Pseudomonas spp. (13.1%), etc. Eleven TBTCl resistant isolates also had a resistance to heavy metals (Cd, Cu, Hg, and Zn). Among them, isolate T7 showing the strong TBTCl-resistance was selected. This isolate was identified as the genus Pantoea by 16S rRNA gene sequencing and designated as Pantoea sp. T7. In addition, this bacterium was cultivated up to the growth of 50.7% after 60 hrs at TBTCl concentration of $500{\mu}M$. TBTCl-degrading activity of Pantoea sp. T7 was measured by GC-FPD analysis. As a result of biological TBTCl-degradation at TBTCl concentration of $100{\mu}M$, TBTCl-removal efficiency of Pantoeasp. T7 was 62.7% after 40 hrs. CONCLUSION(S): These results suggest that Pantoea sp. T7 is potentially useful for the bioremediation of TBT contamination.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.20 no.7
• /
• pp.299-309
• /
• 2019

This study was designed to assess the quality and quantity of food resources such as the chlorophyll a concentration (Chl-a), the particulate organic carbon (POC) and the particulate organic nitrogen (PON), on blood cocke (Tegillarca granosa Linnaeus) farms from May to November 2017 in the northwestern area of Yeoja Bay, Korea. The values of Chl-a, POC and PON were $1.69-7.68{\mu}g{\cdot}L^{-1}$ (average: $3.48{\mu}g{\cdot}L^{-1}$ in the surface), 0.88-2.58 mM (average: 1.97 mM) and 0.17-0.90 mM (average: 0.54 mM), respectively, and these values were higher in the spring and summer and lower in the autumn. Furthermore, Chl-a and POC had higher values on the bottom layer than those vales on the surface, while PON had higher values on the surface than those values on the bottom. The POC/PON ratio and POC/Chl-a ratio were 1.56-7.88 (average: 3.71 on the surface of the water) and 216-967 (average: 700 on the bottom of the water), respectively, with most of the carbon sources being sediment-accumulated particle organic matter, and the contribution by phytoplankton was assessed as being low. These results show that the food source of the blood cockle farms in the northwest area of Yeoja Bay seems to be abundant in quantity, but this is considered to be very poor in quality.

• Land and Housing Review
• /
• v.13 no.3
• /
• pp.125-140
• /
• 2022

Road Deposited Sediment (RDS) is the solids formed from the wear of road, wear of vehicles, exhausts, and the input of the emissions from various sources out of the roads. RDS is seriously polluted by organic matter, nutrients, and metals. RDS plays an important role as the sink and the transport medium of the associated pollutants because RDS can be carried to the adjacent water system via stormwater runoff. In this regard, the heavy metals in RDS were investigated based on the publications. The contents of the metals in RDS were highly variable. The concentration of Cr, Ni, Cu, Fe, Zn, As, Cd, and Pb in urban RDS in various regions was in a range of 3.16-3,410, 1.15-1,382, 20.2-9,069, 2,980-124,853, 81-2,550, 2.3-214, 0.19-21.3, and 15.21-1,125 mg/kg, respectively. The anthropogenic enrichment of the metals in RDS was confirmed by the high concentration of Cu, Zn, Cd, and Pb. The contents of the metals were higher in industrial and traffic areas than in residential areas, while they were generally increased with decreasing particle size. It is believed that this study's results would contribute to quantifying the metals' load via RDS and establishing control strategies.

• Microbiology and Biotechnology Letters
• /
• v.50 no.4
• /
• pp.557-562
• /
• 2022

In this study we evaluated biohydrogen production potential as operational parameters (substrate, salt concentration, and temperature) using eight inoculum sources. While the volumetric biohydrogen production rate was significantly affected by temperature and inoculum sources, substrate and salt concentration did not have a significant effect on the biohydrogen production. Mesophilic temperature (37℃) was also found more appropriate for the hydrogen production than thermophilic temperature (50℃). Rate, while the eight inoculum sources, anaerobic digestion sludge exhibited the fastest biohydrogen production. The maximum production rate from anaerobic digestion sludge was 2,729 and 1,385 ml-H₂·l^-1·d^-1 at mesophilic and thermophilic temperature, respectively.

• Analytical Science and Technology
• /
• v.22 no.5
• /
• pp.360-368
• /
• 2009

Tributyltin (TBT) use has been prohibited by the IMO (International Maritime Organization), as well as Korea, since 2003. This prohibition has affected a gradual reduction in TBT use in maritime environs (seawater, sediment, and biosamples) in several countries. In this study, Crassostrea gigas (oyster) and Tapes philippinarum (manila clam) were chosen and measured for butyltin compound concentrations to verify TBT pollution levels since its 2003 ban. Specimens were taken directly from farms for concentration measurement, where Crassostrea gigas and Tapes philippinarum are cultivated, as well as prevalent locations predicted to have been polluted. Concentrations of MBT, DBT, and TBT of Crassostrea gigas were measured to be N.D -N.D., N.D. -N.D., and N.D. -60.21 ng Sn $g^{-1}$ (wet wt), respectively. Regarding Tapes philippinarum, MBT, DBT, and TBT were N.D. -12.27 ng Sn $g^{-1}$ (wet wt), N.D. -45.95 ng Sn $g^{-1}$ (wet wt), and N.D.-7.30 ng Sn $g^{-1}$ (wet wt), respectively. For this research, a correlative study was conducted to determine butyltin compound concentration in Crassostrea gigas at the locations where measurements were made in 1994 to determine to what extent TBT pollution level decreased. A decrease in all 7 sites was observed. In 4 of the 7 samples, butyltin compounds were measured to be below the detection limit, while that of the Tapes philippinarum did not appear high compared to foreign research data.

• Economic and Environmental Geology
• /
• v.39 no.1 s.176
• /
• pp.63-74
• /
• 2006

In order to identify the Pb pollution and its sources in continental shelf and slope areas, Pb concentration and Pb isotope ratios ($^{207}Pb/^{206}Pb\;and\;^{208}Pb/^{206}Pb$) were determined far 6 box corer sediments collected from the southern East/japan Sea. Pb concentration, and $^{207}Pb/^{206}Pb\;and\;^{208}Pb/^{206}Pb$ ratios were constant at around $25\pm5 ppm$ and 0.842 and 2.092 from 1700 to 1930 year, respectively and increased steadily up to $40\pm5 ppm$ and 0.867 and 2.123 at the beginning of 1990s', respectively. The increase of concentration and isotope ratios in the labile fraction (leached by 2M HC1+0.5M $HNO_3$) explains their increase in bulk sediments, while Pb concentration and isotope ratios in the residual fraction were nearly constant during 300yrs. Temporal variation of Pb isotope ratios was explained by simple two end-members mixing of geo-genic and anthropogenic sources because isotope ratios and the inverse of Pb concentration showed the good linear relationships. Using Pb isotope ratios, we can constrain two Pb sources in the study area. The one is atmospheric particulates, compared with mean values of isotope ratios in atmospheric particulates collected at Jeju and Oki ;stands, based on the history of Pb emmission in Korea and China, and judged by oceanographic processes capable of homogenizing many sources. The other is local sources related to iron mills, refineries of Pb ore and of petroleum located at the coast of the study area. Isotope ratios of anthropogenic Pb can be estimated using two end-members mixing equation and were $0.879\pm0.005\;and\;2.144\pm0.008$ before 1950s' while they increased up to $0.900\pm0.008\;and\;2.162\pm0.011$ after 1980s', respectively.