• Clean Technology
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• v.16 no.4
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• pp.258-264
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• 2010

This study estimated the possibility of phosphate removal characteristics to utilize EAF(electric arc furnace) slag as submarine cover material. The major phosphate removal mechanism was a certain formation of HAP precipitation occurred by the ionization reaction between $Ca^{2+}$ and $OH^-$, which were leached from the EAF Slag. Another phosphate removal mechanism was the adsortion of EAF slag surface. As a result of $PO_4{^-}-P$ removal characteristics using continuous column reactor, $PO_4{^-}-P$ concentration decreased rapidly after 3 days and 10 days later, it show under 0.5 ppm. The result as applied in real sea water, shows that the phosphate removal effects were 93~98% by the subaqueous sediment removal using the EAF slag. In conclusion, EAF slag is useful in $PO_4{^-}-P$ removal and control and it is possible to use without additional process like crush and selection.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.32 no.5
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• pp.680-687
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• 1999

To understand the role of shelf sediment in phosphorus biogeochemical cycle, we carried out sequential sediment extraction (SEDEX) of P and porewater analysis on 14 core samples collected in the South Sea of Korea, SEDEX classified P-pools into 5 phases and results are grouped into two categories: reactive P (loosely sorbed-P and Fe bound-P) and refractory P (detrital inorganic-p, authigenic mineral-P and organic-P). Total P concentrations are decreased with sediment depth in all samples as a result of dissolution to porewater. Reactive P comprises about $20\~50\%$ of total P, and iron bound-P is the major form consisting $70\~80\%$ of reactive P-pool. Iron bound-P decreases sharply with depth. Depth profiles of dissolved P concentration in porewater show mirror image of iron bound-P, revealing the role of FeOOH as a regulator of reactive P supply to overlying water column. Authigenic mineral-P consists less than $5\%$ of total P, thus removal of reactive P by converting into refractory P seems inefficient in shelf sediment. This implies that continental shelf sediment sequesters P temporarily rather than permanently. Results show local variation. Nakdong estuary receiving large amount of terrigenous input shows the highest concentration of total P and reactive P. Here iron oxyhydroxides at the surface sediment control the water column flux of P from sediment. Although total P content at the surface is comparable (500$\~$600 ${\mu}g{\cdot}g^{-1}$) between the South Sea and East China Sea, the former contains more iron bound-P and less derital inorganic-P than the latter. Reasons for the difference seem due in part to particle texture, and to biological productivity which depends roughly on the distance from land.

• Journal of Soil and Groundwater Environment
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• v.14 no.1
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• pp.68-77
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• 2009

For the reservoir sediment highly contaminated with total Cr, Pb, and Cd, the applicability of electrokinetic remediation method was evaluated. Also, BCR sequential extraction method was adopted to compare the heavy metal speciation in between before and after electrokinetic reaction that is operated under constant current condition for the sediment. After reaction, total Cr and Pb moved toward the direction of anode, while Cd tended to cathode and stayed highest in the midst of sediment specimen. From the BCR sequential extraction analysis, it was known that for total Cr and Pb the residual fraction that showed high fraction before reaction decreased and changed to the oxidation fraction. On the other hand, for Cd the fraction of exchangeable/carbonate that dominated most fractions before reaction changed to the residual and oxidation fractions.

• Journal of the Korean Geotechnical Society
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• v.27 no.10
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• pp.5-12
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• 2011

This study was focused on the reactivity of furnace slag against cadmium to design the vertical drain method with reactive column for improving contaminated sea shore sediment. The kinetic sorption test was performed by changing the initial concentration and pH. Using pseudo-second-order model, the reactivity of furnace slag was quantitatively analyzed. Equilibrium removal amount ($q_e$) of furnace slag increased and rate constant ($k_2$) decreased with the increase of initial cadmium concentration. With the increase of pH, the equilibrium removal amount ($q_e$) and rate constant ($k_2$) increased in the same initial concentration. Required retention time was related to the inverse of the product of the equilibrium removal amount ($q_e$) multiplied by rate constant ($k_2$). The required retention time could be used to design the length of reactive column.

• Journal of Korean Society of Water and Wastewater
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• v.20 no.5
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• pp.667-676
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• 2006

This study was conducted to evaluate the effect of longitudinal baffle on hydrodynamic behavior within a certain full-scale sedimentation basin (flow rate per basin; $1,000m^3/d$). Comparative experimental investigations have been carried out on the sediment removal efficiencies and the sludge deposit distribution in the baffled and un-baffled sedimentation basin, respectively. From the results derived in the baffled and un-baffled sedimentation, the turbidity removal rate in the baffled sedimentation basin is about 38% higher than that in un-baffled. Also, the height of sludge deposit in the baffled sedimentation basin is approximately 20% lower, and the sludge concentration is 10% higher than those in un-baffled sedimentation basin. In order to explain the experimental results and investigate the effect of longitudinal baffle in more detail, we conducted Computational Fluid Dynamics (CFD) simulation. From the results of CFD simulation, the flow, especially in the near of outlet orifice, was more stable in the case of longitudinal baffled sedimentation basin than that in un-baffled basin. Also, it could be concluded that the longitudinal baffle made a fully developed flow more effective for sedimentation.

• Korean Journal of Ecology and Environment
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• v.33 no.4 s.92
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• pp.358-365
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• 2000

To evaluate the influences of stocking and removal of silver carp on plankton communities and physicochemical parameters, fish biomanipulation was conducted in six enclosures constructed on the coast of a hypertrophic lake during the summer of 1997. Of these, three enclosures were established for the fish-stocking experiment; one fishless enclosure used as a control and two enclosures with high and low densities of fish. The other three enclosures for the fish-removal experiment were prepared in an entirely converse process compared to that for fish stocking. The results of randomized intervention analysis (${\alpha}=0.05$) showed significant changes in several physicochemical parameters and plankton communities after fish stocking and removal. Fish stocking decreased water transparency, DO, pH and chi-a (> $40\;{\mu}m$), while increasing the concentration of nitrogen and chi-a (<$2\;{\mu}m$). However, water transparency did not increase by fish removal. Small plankton communities, such as picocyanobacteria, eukaryotic picoplankton and ciliates (<$2\;{\mu}m$) showed significant reciprocal changes after both fish treatments: increase by the presence of fish and decrease by the absence of fish. No count of large sized phytoplankton and zooplankton showed significant change in the presence of fish, while large zooplankton, Diaphanosoma, Cyclopida and nauplii were significantly increased by fish removal. Although the frequent heavy-winds and endless supply of phosphorus from the lake sediment strongly disturbed the fish behavior and enclosure management, the stocking and removal of silver carp showed an obvious reciprocal influences on plankton communities and its physico-chemical parameters in a shallow-hypertrophic lake.

• ALGAE
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• v.19 no.1
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• pp.7-14
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• 2004

Blue-Min was initially developed as an adsorbent for harmful gas removal and recently improved to apply to livestock, agriculture and aquaculture as an assistant feed. In the Blue-Min treatment, growth of harmful algae (Cochlodinium polykrikoides and the others causing the red-tide in the ocean) were inhibited below 10% in comparison with control and coagulation removal of harmful alge with Blue-Min treatment was more efficient than that of yellow loess treatment. It would be expected that the Ble-Min can be useful for the extirpator against the red-tide organisms and restrain the toxic algal growth around the fish aquaculture using the assistant feed. Recently, its utility has become to be diverse as it was revealed that aquaculture productivity increase by its application and, in addition, that it improve the water quality or sediment conditions in the aquaculture of Chinese White Shrimp. When Blue-Min was treated with the proper dose, the growth inhibition of Microcystis aeruginosa and lsochrysis galbana, which are typical red-tide organisms in freshwaters and food organisms in aquaculture, respectively, were less than that of marine red-tide organisms, while their growth slightly increased with low concentration treatiment. In addition, polyunsaturated fatty acids (PUFA) content of I. galbana slightly increase with the Blue-Min treatment. Through our research, the Blue-Min has diverse and comples function against various biological organisms and is proved as a biological activator or depressor.

• Journal of Korean Society on Water Environment
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• v.26 no.3
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• pp.387-398
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• 2010

SWAT model would be applied to evaluate the pollutant removal capacity with various best management practices (BMPs) in Kyongan stream watershed which plays an important role in water quality conservation and improvement of Paldang reservoir. The methods for the representation of various BMPs scenarios with SWAT is developed and evaluated. Riparian buffer strip, agricultural conservation practices to reduce fertilizer, sediment, and nutrients occurring from farm field (Grassed swale, Contour farming/Parallel terrace, Field border, Farm retention pond, Grade stabilization structure), and washland such as wetland and pond to extend detention and improve water quality are represented in SWAT. And to represent the expansion of existing Waste Water Treatment Plants (WWTPs) in Soil and Water Assessment Tool (SWAT), reduction effect for point source pollutants was simulated. As the result of simulation, the removal rates of SS, TN, TP from scenarios of Kyongan stream watershed are the average annual SS yield by 5.2% to 69.2%, the average annual TN yield by 0.5% to 26.3%, and the average annual TP yield by 1.3% to 32.5%, respectively. This study has demonstrated that the SWAT is a very reliable and useful water quality and quantity assessment tool, and the BMPs representation in SWAT for watershed management is able to effectively simulate in Kyongan Stream watershed.

• Journal of Korean Society of Water and Wastewater
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• v.24 no.4
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• pp.443-451
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• 2010

This study was conducted to confirm the CSOs characteristics, and to estimate treatment efficiency of CSO treatment process. Flowrate was average $53,500m^3$/d, maximum $58,100m^3$/d during dry season, but after rain-fall, the flowrate was increased more than twice that of the dry season. And, water pollution concentrations, such as $COD_{Cr}$, SS, $BOD_5$, TN and TP of after rain-fall, were also increased. Thus, for more efficient treatment of pollutants during rainy season, The vortex separator and continuous fiber filter devices were used. From the results on particle range, removal efficiency of particle was 99.7% at the particle size range of $40{\sim}100{\mu}m$ but decreased as 55-80% at the below $40{\mu}m$. The removal efficiencies of $COD_{Cr}$, SS, TN and TP were approx. 70, 60, 70 and 50, respectively during the dry season and approx. 50, 50, 8 and 18% during the rainy season. Also, when compared with the primary sediment basin, $COD_{Cr}$, SS, TN and TP removal efficiencies were high. especially, at the case of TN and TP, TN was more removed than TP because of higher conversion factor value. But we needed more study for the injection of a coagulants to get more stable treatment efficiency for soluble pollutants. Consequently, This process can be used for CSOs treatment as well as replace the primary sedimentation basin during the dry season.

• Journal of the Korean Society for Marine Environment & Energy
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• v.16 no.2
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• pp.115-120
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• 2013

This study examined the removal rate of mixed heavy metals from aqueous solution using recycled aggregate. The recycled aggregate is favorable for the absorbent because it contains about 95% (CaO, $SiO_2$, $Al_2O_3$ and $Fe_2O_3$), which are major ingredient of adsorbent for heavy metal. The kinetic data presented that the slow course of adsorption follows the Pseudo first and second order models. The equilibrium data were well fitted by the Langmuir model and showed the affinity order: $Cu^{2+}$ > $Pb^{2+}$ > $$Zn^{2+}{\simeq_-}Ni^{2+}$$ > $Cd^{2+}$. The results also showed that adsorption rate slightly increased with increasing pH from 6 to 10. Moreover, this trend is similar to results obtained as function of loading amount of recycled aggregate. Meanwhile, an unit adsorption rate was slightly decreased. From these results, it was concluded that the absorbents can be successfully used the removal of the heavy metals from the aqueous solutions.