• Title/Summary/Keyword: Secondary Sources

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A Review on the Photochemical Oxidant Modeling as Applied to Air Quality Studies in Complex Terrain

  • Lee Hwa-Woon;Kim Yoo-Keun;Won Gyeong-Mee;Park Jong-Kil
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.1 no.1
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    • pp.19-33
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    • 1997
  • The high oxidants, which occur the daily maximum concentrations in the afternoon, are transported into the other region via long range transport mechanisms or trapped within the shallow mixing boundary layer and then removed physically (deposition, transport by mountain wind, etc.) and chemically (reaction with local sources). Therefore, modeling formation of photochemical oxidants requires a complex description of both chemical and meteorological processes. In this study, as a part of air quality studies, we reviewed various aspects of photochemical modeling on the basis of currently available literature. The result of the review shows that the model is based on a set of coupled continuity equations describing advection, diffusion, transport, deposition, chemistry, emission. Also photochemical oxidant models require a large amount of input data concerned with all aspects of the ozone life cycle. First, emission inventories of hydrocarbon and nitrogen oxides, with appropriate spatial and temporal resolution. Second, chemical and photochemical data allowing the quantitative description of the formation of ozone and other photochemically-generated secondary pollutants. Third, dry deposition mechanisms particularly for ozone, PAN and hydrogen peroxide to account for their removal by absorption on the ground, crops, natural vegetation, man-made and water surfaces. Finally, meteorological data describing the transport of primary pollutants away from their sources and of secondary pollutants towards the sensitive receptors where environmental damage may occur. In order to improve our present study, shortcomings and limitation of existing models are pointed out and verification process through observation is emphasized.

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Comparison of Source Apportionment of PM2.5 Using PMF2 and EPA PMF Version 2

  • Hwang, In-Jo;Hopke, Philip K.
    • Asian Journal of Atmospheric Environment
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    • v.5 no.2
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    • pp.86-96
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    • 2011
  • The positive matrix factorization (PMF2) and multilinear engine (ME2) models have been shown to be powerful environmental analysis techniques and have been successfully applied to the assessment of ambient particulate matter (PM) source contributions. Because these models are difficult to apply practically, the US EPA developed a more user-friendly version of the PMF. The initial version of the EPA PMF model does not provide any rotational capabilities; for this reason, the model was upgraded to include rotational functions in the EPA PMF ver. 2.0. In this study, PMF and EPA PMF modeling identified ten particulate matter sources including secondary sulfate I, vehicle gasoline, secondary sulfate II, secondary nitrate, secondary sulfate III, incinerators, aged sea salt, airborne soil particles, oil combustion, and diesel emissions. All of the source profiles determined by the two models showed excellent agreement. The calculated average concentrations of $PM_{2.5}$ were consistent between the PMF2 and EPA PMF ($17.94{\pm}0.30{\mu}g/m^3$ and $17.94{\pm}0.30\;{\mu}g/m^3$, respectively). Also, each set of estimated source contributions of the PMF2 and EPA PMF showed good agreement. The results from the new EPA PMF version applying rotational functions were consistent with those of PMF2. Therefore, the updated version of EPA PMF with rotational capabilities will provide more reasonable solutions compared with those of PMF2 and can be more widely applied to air quality management.

A Qualitative Study on Utilizing Peer Mentoring for Teachers' Self-efficacy Improvement and Peer Metoring Perception of Pre-Service Music Teachers (동료멘토링을 활용한 중등 예비음악교사들의 교사로서의 자기효능감 향상과 동료멘토링 인식에 대한 질적연구)

  • Kim, Eunjin
    • The Journal of the Korea Contents Association
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    • v.17 no.3
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    • pp.305-318
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    • 2017
  • The purpose of this study is improving the teachers' self-efficacy for pre-secondary music teachers. The research questions for this study were the improvement for teachers' self-efficacy for pre-secondary music teachers and the pre-secondary music teachers' perception about peer mentoring. In this study performed the interview and analyzed the in self-reflection journal in order to identify the improvement effect of teachers' self-efficacy and the participants' perception change in the peer mentoring. As the results from analyzing the change in participant's perception about peer mentoring the mentors had the opportunity to review previous learning contents and practice experiences while developing their team activity and for the mentees. Mentees said that they were given various help from the mentors' advices and their interactions and communication with mentors. From these results, it could identify that there was positive change in participant's perception about the peer mentoring. Based on these results, this study analyzed that it would need to require some chances for pre-secondary music teachers to be given some educational practice and field experience utilizing various teaching methods in order to improve their self-efficacy and the perception of peer mentoring.

Growth and N, P removal efficiency of Chlorella vulgaris according to the nitrogen sources and pH condition (질소원 및 pH 조절빈도에 따른 Chlorella vulgaris의 성장특성 및 하수고도처리능 평가)

  • Han, Su-Hyun;Kim, Sun-Jin;Kim, Tae-Hyeong;Cho, Ki-Ju;Lee, Yunhee;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.6
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    • pp.833-840
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    • 2012
  • This study aimed to investigate growth rate and nutrient removal efficiency of Chlorella vulgaris according to nitrogen sources and frequency of pH adjustment. Nitrogen and phosphorus removal efficiencies were evaluated in the three different conditions using $NO_3{^-}$, $NH_4{^+}$ as a sole nitrogen source and mixed condition. Initial nutrient concentrations in artificial wastewater were 30 mg-N/L and 3 mg-P/L similar to secondary wastewater effluent. When nitrogen source was $NO_3{^-}$, there was no inhibition on the growth of C. vulgaris with adjusting pH every 24 hr while growth inhibition occurred with $NH_4{^+}$ caused by pH drop. N, P removal efficiencies were no significant depending on the nitrogen sources. As pH was adjusted to 7 by pH-stat, growth rate and nutrient removal efficiencies were increased compared to adjusting pH every 24 hr, however, growth rate and nutrient removal efficiencies were no significant depending on the nitrogen sources.

Source Identification of Ambient PM-10 Using the PMF Model (PMF 모델을 이용한 대기 중 PM-10 오염원의 확인)

  • 황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.701-717
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    • 2003
  • The objective of this study was to extensively estimate the air quality trends of the study area by surveying con-centration trends in months or seasons, after analyzing the mass concentration of PM-10 samples and the inorganic lements, ion, and total carbon in PM-10. Also, the study introduced to apply the PMF (Positive Matrix Factoriza-tion) model that is useful when absence of the source profile. Thus the model was thought to be suitable in Korea that often has few information about pollution sources. After obtaining results from the PMF modeling, the existing sources at the study area were qualitatively identified The PM-10 particles collected on quartz fiber filters by a PM-10 high-vol air sampler for 3 years (Mar. 1999∼Dec.2001) in Kyung Hee University. The 25 chemical species (Al, Mn, Ti, V, Cr, Fe, Ni, Cu, Zn, As, Se, Cd, Ba, Ce, Pb, Si, N $a^{#}$, N $H_4$$^{+}$, $K^{+}$, $Mg^{2+}$, $Ca^{2+}$, C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, TC) were analyzed by ICP-AES, IC, and EA after executing proper pre - treatments of each sample filter. The PMF model was intensively applied to estimate the quantitative contribution of air pollution sources based on the chemical information (128 samples and 25 chemical species). Through a case study of the PMF modeling for the PM-10 aerosols. the total of 11 factors were determined. The multiple linear regression analysis between the observed PM-10 mass concentration and the estimated G matrix had been performed following the FPEAK test. Finally the regression analysis provided source profiles (scaled F matrix). So, 11 sources were qualitatively identified, such as secondary aerosol related source, soil related source, waste incineration source, field burning source, fossil fuel combustion source, industry related source, motor vehicle source, oil/coal combustion source, non-ferrous metal source, and aged sea- salt source, respectively.ively.y.

Estimation of PM10 Source Contributions on Three Cities in the Metropolitan Area by Using PMF Model (PMF 모델을 이용한 수도권 내 3개 도시에서의 PM10 오염원의 기여도 추정)

  • Lee, Tae-Jung;Huh, Jong-Bae;Yi, Seung-Muk;Kim, Shin-Do;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.4
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    • pp.275-288
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    • 2009
  • The Korean government strengthened the environmental polices to manage and enhance Metropolitan Area air quality, and also has enforced "Special Act on Seoul Metropolitan Air Quality Improvement (SASMAQI)" issued in Dec. 2004. Recently government expanded the Seoul Metropolitan Air Quality Management District (SMAQMD) to the outskirts satellite cities of Seoul area through the "Revised Law Draft of SASMAQI". The SMAQMD has been alloted the allowable emission loads to the local governments on the basis of the carrying $PM_{10}$ capacity. However, in order to establish the effective air quality control strategy for $PM_{10}$, it is necessary to understand the corresponding sources which have a potential to directly impact ambient $PM_{10}$ concentration. To deal with the situations, many receptor methodologies have been developed to identify the origins of pollutants and to determine the contributions of sources of interests. The objective of this study was to extensively identify $PM_{10}$ sources and to estimate their contributions at the metropolitan area. $PM_{10}$ samples were simultaneously collected at the 3 semi-industrialized local cities in the Seoul metropolitan area such as Hwasung-si, Paju-si, and Icheon-si sites from April 15 to May 31, 2007. The samples collected on the teflon membrane filter by one $PM_{10}$ cyclone sampler were analyzed for trace metals and soluble ions and samples on the quartz fiber filter by another sampler were analyzed for OC and EC. Source apportionment study was then performed by using a positive matrix factorization (PMF) receptor model. A total of 6 sources were identified and their contributions were estimated in each monitoring site. Contribution results on Hwasung, Paju, and Icheon sites were as follows: 33%, 27%, and 27% from soil source, 26%, 26%, and 21% from secondary aerosol source, 11%, 11%, and 12% from biomass burning, 12%, 6%, and 5% from sea salt, 7%, 15%, and 19% from industrial related source, and finally 11%, 15%, and 16% from mobile and oil complex source, respectively. This study provides information on the major sources affecting air quality in the receptor sites and thus it will help to manage the ambient air quality in the metropolitan area by establishing reasonable control strategies, especially for the anthropogenic emission sources.

Synthesis of Alcohol-oxidase in Pichia pastoris on Various Carbon Sources (여러가지 탄소원에 의한 Pichia pastoris의 Alcohol-oxidase 생성)

  • Lee, Myung-Suk;Hur, Sung-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.18 no.4
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    • pp.435-443
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    • 1989
  • The regulation of the synthesis of alcohol-oxidase(E. C. 1. 1. 3. 13) was investigated in the methanol-utilizing yeasts during growth on different carbon sources. For this experiment, Pichia pastoris CBS 2612 and Pichia pastoris CBM 10 were cultured in mineral salt medium by changing its carbon sources. The production of alcohol-oxidase was varied by the carbon sources. For example, alcohol-oxidase was undetectable in all strains submitted to the test in the medium with glucose, but its production was rapidely increased when the carbon source was changed from glucose to methanol after 48hrs of incubation. Moreover, this enzyme was not synthesized during growth on the primary aliphatic alcohols alone(ethanol, propanol, butanol or pentanol) or on the mixed substrates(0.5% methanol+0.5% primary aliphatic alcohols). When cells were grown on the various carbon sources(glucose, xylose, lactose, glycerol, galactose, saccharose, sorbose, lactic acid or acetic acid), The alcohol-oxidase activity was detected a very little amounts. These carbon sources together with methnol yieled far better synthesis of alcohol-oxidase than in case of carbon sources alone. Especially, the alcohol-oxidase activity of the cells grown on sorbose, lactose or lactic acid together with methanol was far better or similar than that of cells grown on methanol alone. The apparent Km values for the methanol of Pichia pastoris CBS 2612 and Pichia pastoris CBM 10 enzymes were 1.92 and 210 mM, respectively. It is also active towards alcohols of shorter alkyl-chain length than $C_7$, insaturated alcohols(allylalcohol, crotyl-alcohol) and secondary alcohols (iso-amylacohol, iso-butylalcohol). The affinity of alcohol-oxidase for this alcohols decreased with the increasing length of the alkyl-chain.

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Source Identification and Estimation of Source Apportionment for Ambient PM10 in Seoul, Korea

  • Yi, Seung-Muk;Hwang, InJo
    • Asian Journal of Atmospheric Environment
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    • v.8 no.3
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    • pp.115-125
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    • 2014
  • In this study, particle composition data for $PM_{10}$ samples were collected every 3 days at Seoul, Korea from August 2006 to November 2007, and were analyzed to provide source identification and apportionment. A total of 164 samples were collected and 21 species (15 inorganic species, 4 ionic species, OC, and EC) were analyzed by particle-induced x-ray emission, ion chromatography, and thermal optical transmittance methods. Positive matrix factorization (PMF) was used to develop source profiles and to estimate their mass contributions. The PMF modeling identified nine sources and the average mass was apportioned to secondary nitrate (9.3%), motor vehicle (16.6%), road salt (5.8%), industry (4.9%), airborne soil (17.2 %), aged sea salt (6.2%), field burning (6.0%), secondary sulfate (16.2%), and road dust (17.7%), respectively. The nonparametric regression (NPR) analysis was used to help identify local source in the vicinity of the sampling area. These results suggest the possible strategy to maintain and manage the ambient air quality of Seoul.

Incremental Cooperative Transmission of Bidirectional Relaying Schemes in Underlay Cognitive Radio (언더레이 인지기술에서 양방향 릴레이 증분 협력 전송에 관한 연구)

  • Kong, Hyung-Yun
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.13 no.3
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    • pp.47-53
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    • 2013
  • In this paper, we propose an incremental cooperative transmission protocol in two-way underlay cognitive radio networks. In the proposed protocol, two secondary sources attempt to transmit their packet to each other with help of a secondary relay under interference constraint. For performance evaluation, we derive exact closed-form expressions of average outage probability over Rayleigh fading channel. Then, we perform Monte Carlo simulations to verify the derivations. Results present that the simulation and theoretical results are in good agreement and the outage performance of the proposed protocol is better than that of two-way direct transmission protocol.

A case of subcutaneous cervicofacial and mediastinal emphysema secondary to third molar extraction (제 3대구치 발치 후 발생한 피하 경안면부 및 종격동 기종 1예)

  • Cho, Sung-Ho;Kim, Dong-Wook;Lee, Byung-Don;Chang, Hyuck-Soon
    • Korean Journal of Bronchoesophagology
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    • v.14 no.1
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    • pp.50-53
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    • 2008
  • Subcutaneous cervicofacial, mediastinal emphysemas are complications associated with head and neck surgery, trauma, infectious processes, tooth extraction. Drill cooling stream and dental syringe air ject are the sources of high pressure air that may enter exposed soft tissue. Since the introduction of the high-speed air turbine drill in the 1960s, The incidence of iatrogenic subcutaneous emphysema has increased. Most cases begin to resolve after 2 to 3 days and residual swelling is usually minimal at the end of 7 to 10 days. Surgical approach is not advised because it is likely to be ineffective. The differential diagnosis of neck swelling after dental procedure includes hematoma, cellulitis, angioedema, allergic reaction, subcutaneous emphysema. We report a rare case of patient with subcutaneous cervicofacial emphysema and mediastinal emphysema secondary to third molar extraction.

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