• 제목/요약/키워드: Second derivative

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Highly Selective Derivative Spectrophotometry for Determination of Nickel Using 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Solutions

  • Eskandari, Habibollah
    • Bulletin of the Korean Chemical Society
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    • v.25 no.8
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    • pp.1137-1142
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    • 2004
  • A spectrophotometric and first derivative spectrophotometric method was developed in aquatic Tween 80 micellar solutions for selective determination of nickel without using any pre-separation step. 1-(2-Pyridylazo)-2-naphthol (PAN), as a sensitive chromogenic complexing agent formed a red-colored Ni(II)-PAN complex in Tween 80 media with satisfactory solubility and stability. Conditions such as pH, PAN concentration, type and concentration of micellizing agent were optimized. Molar absorptivity of Ni-PAN complex was found $4.62\;{\times}\;10^4L\;cm^{?1}\;mol^{?1}$ at 569 nm, under the optimum condition. Calibration graphs were derived by zero, first and second derivative spectrophotometry at maximum wavelengths of 569, 578 and 571 nm with linear ranges of 30-1800, 20-2500 and 30-2000 ng $mL^{?1}$ , respectively. Precision as standard deviation as well as accuracy as recovery percent were in the range of 1-20 ng $mL^{?1}$, and 93.3-103.3%, respectively, for the entire of the linear ranges. Spectrophotometric detection limit was 3 ng $mL^{?1}$ and effects of diverse ions on the first derivative determination of nickel were studied to investigate selectivity of the method. Interferences of cobalt and copper on the nickel determination were prevented using o-phenanthroline as masking agent. The recommended procedures were applied to the various synthetic and stainless steel alloys, tea leaves and human hair, with satisfactory results.

A Model reference adaptive speed control of marine diesel engine by fusion of PID controller and fuzzy controller

  • Yoo, Heui-Han
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.7
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    • pp.791-799
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    • 2006
  • The aim of this paper is to design an adaptive speed control system of a marine diesel engine by fusion of hard computing based proportional integral derivative (PID) control and soft computing based fuzzy control methods. The model of a marine diesel engine is considered as a typical non oscillatory second order system. When its model and the actual marine diesel engine ate not matched, it is hard to control the speed of the marine diesel engine. Therefore, this paper proposes two methods in order to obtain the speed control characteristics of a marine diesel engine. One is an efficient method to determine the PID control parameters of the nominal model of a marine diesel engine. Second is a reference adaptive speed control method that uses a fuzzy controller and derivative operator for tracking the nominal model of the marine diesel engine. It was found that the proposed PID parameters adjustment method is better than the Ziegler & Nichols' method, and that a model reference adaptive control is superior to using only PID controller. The improved control method proposed here, could be applied to other systems when a model of a system does not match the actual system.

A surface extension method using several functions

  • 김회섭
    • Proceedings of the Korean Society of Computational and Applied Mathematics Conference
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    • 2003.09a
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    • pp.3.2-3
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    • 2003
  • We propose a method of surface extension method using several functions. Interpolation theory is well developed in curve and surface. But extrapolation theory is not well developed because it is not unique outside the useful domain. It requires continuous, first derivative, second derivative continuous extension for matching in NC(Numerical Control) machine. In the past, we generate data outside the useful area and refit those data using least squares method. this has some problems which have some errors within the useful area. We keep the useful area and extend the unuseful area by a function

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BEHAVIOR OF HOLOMORPHIC FUNCTIONS ON THE BOUNDARY OF THE UNIT DISC

  • Ornek, Bulent Nafi
    • The Pure and Applied Mathematics
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    • v.24 no.3
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    • pp.129-145
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    • 2017
  • In this paper, we establish lower estimates for the modulus of the non-tangential derivative of the holomorphic functionf(z) at the boundary of the unit disc. Also, we shall give an estimate below |f''(b)| according to the first nonzero Taylor coefficient of about two zeros, namely z = 0 and $z_0{\neq}0$.

CONCERNING THE RADIUS OF CONVERGENCE OF NEWTON'S METHOD AND APPLICATIONS

  • Argyros, Ioannis K.
    • Journal of applied mathematics & informatics
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    • v.6 no.3
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    • pp.685-696
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    • 1999
  • We present local and semilocal convergence results for New-ton's method in a Banach space setting. In particular using Lipschitz-type assumptions on the second Frechet-derivative we find results con-cerning the radius of convergence of Newton's method. Such results are useful in the context of predictor-corrector continuation procedures. Finally we provide numerical examples to show that our results can ap-ply where earlier ones using Lipschitz assumption on the first Frechet-derivative fail.

SEMILOCAL CONVERGENCE THEOREMS FOR A CERTAIN CLASS OF ITERATIVE PROCEDURES

  • Ioannis K. Argyros
    • Journal of applied mathematics & informatics
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    • v.7 no.1
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    • pp.29-40
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    • 2000
  • We provide semilocal convergence theorems for Newton-like methods in Banach space using outer and generalized inverses. In contrast to earlier results we use hypotheses on the second instead of the first Frechet-derivative. This way our Newton-Kantorovich hypotheses differ from earlier ones. Our results can be used to solve undetermined systems, nonlinear least square problems and ill-posed nonlinear operator equations.

Edge Detection using Second Order Derivative Strain (미분방식을 이용한 에지 추출)

  • Kim, Alla;Lee, Hyun-Jik;Kim, Yoon-Ho
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2008.10a
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    • pp.165-167
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    • 2008
  • 본 논문에서는 기존의 에지 추출 알고리즘을 비교하여 알고리즘이 영상 처리 과정에 미치는 영향을 분석하였다. 기존의 에지 추출 알고리즘인 Sobel, Prewitt, Roberts 등을 비교 분석 한 뒤 1차 미분 조건에 2차 미분의 단점을 보완한 에지 추출 마스크 방식을 제안한다.

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Modern Pretreatment methods in NIR Spectroscopy

  • Yukiteru Katsumoto;Jian Hui Jiang R.;James Berry;Yukihiro Ozaki
    • Near Infrared Analysis
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    • v.2 no.1
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    • pp.29-36
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    • 2001
  • This review paper outlines modern pretreatment methods used in NIR spectroscopy. The pretreatment methods can be divided into four categories. One method in is noise reduction. Smoothing is a representative method for the noise reduction. Another is baseline correction. The second derivative and multiplicative scatter correction (MSC) are most frequently employed for baseline correction. The third is centering and normalization and the last is resolution enhancement. Difference spectra, mean centering and second derivative are used in NIR spectroscopy as resolution enhancement methods. In this paper advantages and drawbacks of pretreatment methods currently used in NIR spectroscopy are discussed with many examples of NIR spectra.

FRACTIONAL EULER'S INTEGRAL OF FIRST AND SECOND KINDS. APPLICATION TO FRACTIONAL HERMITE'S POLYNOMIALS AND TO PROBABILITY DENSITY OF FRACTIONAL ORDER

  • Jumarie, Guy
    • Journal of applied mathematics & informatics
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    • v.28 no.1_2
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    • pp.257-273
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    • 2010
  • One can construct a theory of probability of fractional order in which the exponential function is replaced by the Mittag-Leffler function. In this framework, it seems of interest to generalize some useful classical mathematical tools, so that they are more suitable in fractional calculus. After a short background on fractional calculus based on modified Riemann Liouville derivative, one summarizes some definitions on probability density of fractional order (for the motive), and then one introduces successively fractional Euler's integrals (first and second kind) and fractional Hermite polynomials. Some properties of the Gaussian density of fractional order are exhibited. The fractional probability so introduced exhibits some relations with quantum probability.