• Title/Summary/Keyword: Sea Water Condition

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GC-MS Analysis of Organophosphorus Pesticide Residue in Seawater From the Kwangyang Bay, Korea (광양만 해수 중 유기인 잔류 농약성분의 GC-MS 분석)

  • Park, Mi-Ok;Park, Jeom-Sook
    • Journal of Environmental Science International
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    • v.15 no.4
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    • pp.293-304
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    • 2006
  • Sea water samples collected in August, 1994 from 20 stations in the Kwangyang Bay were analyzed by gas chromatography/mass spectrometry-selected ion monitoring (GC/MS-SIM) to investigate persistence and distribution pattern of four organophosphorus pesticides (DDVP, Diazinon, IBP, EDDP). Except for IBP, the contamination by DDVP, Diazinon, and EDDP in marine aquatic environment in Korea has not been reported previously. In this study, however, all these four pesticides were detected in all stations (except DDVP) and their concentrations were in ng/L level. The concentrations ranged from detection limit to 15.3ng/L for DDVP, 1.8-27.7ng/L for Diazinon, 7.3-63.5ng/L for IBP, and 22.2-1100.1ng/L for EDDP. It is noteworthy that the measured concentrations of IBP and EDDP in this study would be much lower than usual, since the use of IBP and EDDP was less than 50% of average annual consumption due to unusually dry and hot weather condition in the summer of 1994. It was very surprising to find that the highest concentrations of organophosphorus pesticides were observed at stations near Daesa Streamlet instead of Seomjin River, which has more point source of the pesticides. This result suggests that the small river discharge during heavy ram period in summer can give harmful effect on marine biota (both wild and aqua-cultured) with its organophosphorus pesticide residue, despite of their short residence time in aquatic environment. In order to protect the marine life properly from acute toxicity of the organophosphorus pesticides, it needs to be emphasized that monitoring the level of agricultural pesticides in river run-off should be done during active consumption period rather at regular intervals.

Growth of Axenic Rotifer Brachionus rotundiformis (무균 로티퍼 Brachionus rotundiformis의 증식)

  • Jung, Min-Min;Rho, Sum;Kim, Pil-Yun
    • Journal of Aquaculture
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    • v.11 no.1
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    • pp.91-97
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    • 1998
  • This paper introduces to a simple culture method and growth of axenic (bacteria-free) rotifer Brachionus rotundiformis for seed stock of rotifer mass culture. This rotifer axenic culture method is based on the washing and transferring with sterilized sea water and modified antibiotic mixture AM9 solution. Population growth (final density on day 16) of axenic cultured rotifer were maintained with a high density and stable growth compared with the control of non-axenic culture (general culture style) through the 3 times-rerunning experiments (trial 1, 2 and 3). But the egg carrying rates of amictic females were not different between the axenic-and non-axenic culture condition. Although, rotifer density was higher in axenic culture, the food (Nannochloropsis oculata) was still remained unutilized than that of the non-axenic culture in third trial culture. These results suggest the possible existence of harmful bacteria for the rotifer population growth in the trial 1 and 3 of non-axenic culture compared to the trial 2. This axenic rotifer culture method is valuable for seed stock of the stable rotifer mass cultures.

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Methane hydrate : The state of the art of Production technologies and environmental issues (메탄 하이드레이트의 생산 기술 현황과 환경에 미치는 영향)

  • Chang Seung yong
    • The Korean Journal of Petroleum Geology
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    • v.7 no.1_2 s.8
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    • pp.13-18
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    • 1999
  • Methane hydrate is an ice-like solid material and it has a structure which water molecules enclose gas molecules. For low temperature and high pressure, hydrocarbon gas forms hydrate and due to this condition, it is existed in the arctic region or deep sea. Presently, the amount of methane hydrate is unpredictable, but it is assumed that the amount will be enormous. For this reason, it is expected that it will play a major role as natural gas resources in the future. However, the production technologies are stayed on the low level and the economical technology was not developed yet. Also, emission of natural gas from methane hydrate will cause global warming and thus it is considered as a critical environmental problem. In this paper, the state of the art of the production technologies and environmental effects of methane hydrate were summarized.

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Wind-induced Spatial and Temporal Variations in the Thermohaline Front in the Jeju Strait, Korea

  • Han, In-Seong;Suh, Young-Sang;Seong, Ki-Tack
    • Fisheries and Aquatic Sciences
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    • v.16 no.2
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    • pp.117-124
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    • 2013
  • We investigated the short-term and local changes in the thermohaline front in the Jeju Strait, Korea, which is usually formed during winter and spring. To do so, we compared Real-Time Observation System by Ferryboat (RTOSF) data with wind data and routinely collected oceanographic data. During February and April 2007, a thermohaline front formed in the Jeju Strait around the 13-$14^{\circ}C$ isotherms and 33.0-33.5 isohalines. The thermohaline was clearly weakened and began moving southward in mid-March. The variations in the surface temperature and salinity showed a continuous north-south oscillation of the thermohaline front with a period of 3-10 days. The speed of the short-term and local fluctuation of thermohaline front was about 5-30 cm/s. We confirmed these findings by examining the variation in the maximum temperature gradient and $14^{\circ}C$ isotherm during the study period. These short-term and local changes had not been previously detected using serial oceanographic and satellite data. Analysis of local wind data revealed a northerly wind fluctuation with a period of 3-10 days, which was clearly related to the short-term and local changes in the thermohaline front. The short-term and local changes of the thermohaline front in the Jeju Strait originated from local changes in the winter monsoon in this area.

Isolation of Oil-Degrading Bacterium, Providencia rettagei 4A3 and Characterization of Crude Oil Degradation (유류분해균 Providencia rettgeri 4A3의 분리 및 원유분해 특성)

  • 김상우;유주순;이상철;조영수;이영춘
    • Journal of Life Science
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    • v.11 no.6
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    • pp.530-536
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    • 2001
  • Several bacterial strains utilizing crude oil as their sole carbon and energy source were isolated from marine environment polluted by crude oil. Among them, the selected strain 4A3 showed strong degradation activity for crude oil. This strain was identified as a Provindencia rettgeri 4A3 based on the morphological, biochemical, and physiological characteristics. The optimum cultural conditions was as follows; 26$^{\circ}C$ for temperature and 7.0 for initial pH. Additionally, the optimal concentration of sodium chloride was 2.0%, indicating that this strain was derived from sea water. The emulsifying activity of 4A3 was the highest after 3 days of cultivation under the condition of 2.0% sodium chloride, pH 7.0 and 26$^{\circ}C$. This strain had one cryptic plasmid in 7.0kb size.

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A Study of Weldability for Pure Titanium by Nd:YAG Laser(IV) - Lap Welding and Application for Heat Exchanger - (순티타늄판의 Nd:YAG 레이저 용접성에 관한 연구(IV) - 겹치기 용접 및 실물 열교환기로의 적용 -)

  • Kim, Jong-Do;Kwak, Myung-Sub;Lee, Chang-Je;Kil, Byung-Lea
    • Journal of Welding and Joining
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    • v.28 no.1
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    • pp.66-71
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    • 2010
  • With large specific strength and outstanding corrosion resistance and erosion resistance in sea water, titanium and titanium alloy are widely used in heat exchanger production. In particular, pure titanium demonstrates outstanding molding performance and may be considered optimal for production of heat exchanger. Since titanium is very vulnerable to oxidation and embrittlement during welding, processes with less heat input are widely used, and laser welding is widely applied by considering production performance and shield etc in atmosphere. So far, 1st report and 2nd report compared and analyzed embrittlement degrees by bead colors of weldment through oxygen and nitrogen quantitative analysis and hardness measurement, and evaluated welding performance and mechanical properties of butt welding. This study evaluated field applicability of lap welding to heat exchange plate of LPG re-liquefaction device for ships through tensile stress test, hardness test and internal pressure test etc after deducing optimal weding condition and applying to actual heat exchange plate. In bead overlap area, the experiment produced sound welds with no porosity or defect by increasing and decreasing laser power, and tensile-shear test results indicated virtually the same tension and yield strength as base metal. As a result of measuring hardness at lateral cross section and bead overlap zone of actual heat exchanger welds, hardness difference within 20Hv was produced at base metal, HAZ and weldment, and as a result of pneumatic and hydraulic pressure test, no leakage occurred.

An Example of Internal Wave Detection in North Coastal Waters of Cheju Island Using a SAR Image (SAR를 이용한 제주도 북부해역에서의 내부파 관측예)

  • Kim, Tae-Rim;Won, Joong-Sun
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.4 no.1
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    • pp.18-24
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    • 1999
  • The satellite image acquired by RADARSAT SAR on August 15, 1996 reveals internal waves in north coastal waters of Cheju Island. It is indicated from the image data, the tidal elevation data, and the bottom topography data, the internal waves seem to be generated by interaction between shallow bottom and tidal currents travelling in the stratified water in the summer time during the tidal changeovers from ebb to flood. The internal waves generated in such condition show patterns of trains of solitons. Probable amplitude of observed solitons is calculated using estimation of the soliton wave length from SAR image data and K-dV equation. Detection of the internal waves is very significant not only to military strategist for underwater maneuvers such as operation of submarines, but also to physical and biological oceanographers. Temporal and spatial variation of the internal waves are needed to be measured by simultaneous in-situ field study together with SAR to examine the nature of these internal waves.

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The Effect of Wave Pressure on Stability Rubble Mound Breakwater (사석식 경사방파제에 작용하는 파압이 제체 안정성에 미치는 영향)

  • Cheong, Gyu-Hyang;Lee, Yong-Dae;Lee, Byong-Moon;Jeong, Sam-Gi;Kim, Keun-Sup
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.03a
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    • pp.579-584
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    • 2009
  • Arrangement of the facilities for improving harbor functions depends on sea and land conditions such as the ship's arrival and departure conditions, waves and tide. And the plan and the size of the facilities depend much on harbor and marine environment condition such as cargo quantity, ship size, ship traffic and seawater circulation. Among these, waves have so much effect on a breakwater design that it is the most important to understand their characteristics and to apply them to breakwater design. Therefore, to analyze the effect of waves characteristics over a rubble mound breakwater, we have calculated wave pressure by using numerical analysis at each tide level and have analyzed the effect of wave pressure on structure stability by conducting the stability analysis with the wave pressure. As a result, it is found that during low and mean tide level time the biggest wave pressure is estimated near calm water level. But during high tide time, the biggest wave pressure is estimated in front of capping. And the stability analysis indicates also that a structure is most unstable when low tide time wave pressure is acting on. After reviewing the stability of a structure by applying vertical and horizon wave forces, it is concluded that safety factor is lower than ordinary time(max. about 15%), is also reviewed when designing a rubble mound breakwater.

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Analysis of Effectiveness of Tandem Oil Fences (이중유벽의 유효성에 관한 해석)

  • Han Dong Gi;Lee Choung Mook
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.4 no.1
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    • pp.38-46
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    • 2001
  • To assess the oil-containment effectiveness of tandem oil fences placed in currents, the movement of oil droplets in the fore and aft region of the fences is investigated by experimental and numerical methods. The effect of the flexibility of the fence skirt of single fence on the fence effectiveness is also investigated. Laboratory experiment is conducted to trace the path of a spherical solid particle of equivalent density to an oil droplet which was released in a uniform stream ahead of a model oil fence. Depending upon the releasing position and the flow condition there, it was observed that the particle floated up to the free surface, collided with the fence, or escaped below the fence. By analyzing the droplet trajectories, a numerical method is developed to predict the region ahead of the fore fence where an oil droplet initiating its motion eventually escapes beneath the fence. The effect of the relative sizes of the drafts of the fore and aft fences, the fence separation, and the bottom depth of the sea bed on the effectiveness of tandem fences is investigated using the numerically obtained trajectories of oil droplets.

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Effect of Anodizing Current Density on Anti-Corrosion Characteristics for Al2O3 Oxide Film (Al2O3 산화 피막의 내식성에 미치는 양극산화 전류밀도의 영향)

  • Lee, Seung-Jun;Jang, Seok-Gi;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.153-153
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    • 2016
  • Aluminum alloys have poor corrosion resistance compared to the pure aluminum due to the additive elements. Thus, anodizing technology artificially generating thick oxide films are widely applied nowadays in order to improve corrosion resistance. Anodizing is one of the surface modification techniques, which is commercially applicable to a large surface at a low price. However, most studies up to now have focused on its commercialization with hardly any research on the assessment and improvement of the physical characteristics of the anodized films. Therefore, this study aims to select the optimum temperature of sulfuric electrolyte to perform excellent corrosion resistance in the harsh marine environment through electrochemical experiment in the sea water upon generating porous films by variating the temperatures of sulfuric electrolyte. To fabricate uniform porous film of 5083 aluminum alloy, we conducted electro-polishing under the 25 V at $5^{\circ}C$ condition for three minutes using mixed solution of ethanol (95 %) and perchloric (70 %) acid with volume ratio of 4:1. Afterward, the first step surface modification was performed using sulfuric acid as an electrolyte where the electrolyte concentration was maintained at 10 vol.% by using a jacketed beaker. For anode, 5083 aluminum alloy with thickness of 5 mm and size of $2cm{\times}2cm$ was used, while platinum electrode was used for cathode. The distance between the two was maintained at 3 cm. Afterward, the irregular oxide film that was created in the first step surface modification was removed. For the second step surface modification process (identical to the step 1), etching was performed using mixture of chromic acid (1.8 wt.%) and phosphoric acid (6 wt.%) at $60^{\circ}C$ temperature for 30 minutes. Anodic polarization test was performed at scan rate of 2 mV/s up to +3.0 V vs open circuit potential in natural seawater. Surface morphology was compared using 3D analysis microscope to observe the damage behavior. As a result, the case of surface modification presented a significantly lower corrosion current density than that without modification, indicating excellent corrosion resistance.

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