• Bulletin of the Korean Chemical Society
• /
• 제32권6호
• /
• pp.2039-2044
• /
• 2011

A semi-continuous and automated method for quantifying atmospheric ammonia at the parts per billion level has been developed. The instrument consists of a high efficiency diffusion scrubber, an electrolytic on-line anion exchange device, and a conductivity detector. Water soluble gases in sampled air diffuse through the porous membrane and are absorbed in an absorbing solution. Interferences are eliminated by using an anion exchange devises. The electrical conductivity of the solution is measured without chromatographic separation. The collection efficiency was over 99%. Over the 0-200 ppbv concentration range, the calibration was linear with $r^2$ = 0.99. The lower limit of detection was 0.09 ppbv. A parallel analysis of Seoul air over several days using this method and a diffusion scrubber coupled to an ion chromatography system showed acceptable agreement, $r^2$ = 0.940 (n = 686). This method can be applied for ambient air monitoring of ammonia.

• 한국전산유체공학회:학술대회논문집
• /
• 한국전산유체공학회 2004년도 추계 학술대회논문집
• /
• pp.37-41
• /
• 2004

Liquid injection in a Venturi Scrubber creates great effect on the dust-collection efficiency and operation cost of venturi scrubbers. We have developed a model that can numerically simulate atomization of the liquid jet in the Venturi Scrubber. This simulation consists of models on liquid column, jet surface breakup, column fracture and secondary droplet breakup. These models have been embedded in the KIVA3-V code. We have calculated such parameters as the jet penetration, jet trajectory, droplet size, velocity field and the volume flux distribution. The results are compared with the experimental data in this paper.

• 설비공학논문집
• /
• 제15권4호
• /
• pp.305-311
• /
• 2003

DOP aerosol particles with geometric mean diameter of 0.5-3.0 ${\mu}{\textrm}{m}$, geometric standard deviation of 1.1-1.3 and total number concentration of 1,500-8,000 Particles/㎤ were used to determine collection efficiencies of a packed wet scrubber with respect to particle size. The tested operating variables included air velocity and water injection rate. It was shown from the experimental results that the collection efficiencies increased with increasing water injection rate and decreasing air velocity. Meanwhile, as for the particle size variation, all of the collection efficiency curves increased rapidly between 0.57-1.41${\mu}{\textrm}{m}$ for the range of water injection rate above 30 L/min. It was also seen that the collection efficiency of a packed wet scrubber is mainly governed by the mechanism of inertial impaction.

• 한국대기환경학회지
• /
• 제11권4호
• /
• pp.307-313
• /
• 1995

An automatic method is developed for the determination of SOx in atmosphere. The method involves SOx sampling in diffusion scrubber followed by ion chromatographic analysis. Filtered air is withdrawn at 1.8.ell./min through a diffusion scrubber of which inner tube is made of PTFE(Gore-tex) membrane tubing. 1mM $H_{2}$ $O_{2}$ is used as absorbing solution so that SOx is oxidized to S $O_{4}$$^{2-}$. The scrubbered solution is automatically injected into ion chromatograhpy eith conductivity detection for sulphate determination. Replacement of commonly used polyproplene membrane with PTFE gives several merits such as easy preparation of diffusion scrubber, better collection efficiency. No measurable memory effect is experienced, and this isin contrast to previous work for ammonia. Detection limit of this method defined by three times standard deviation is 0.56ppbv. The precision is 0.4% RSD at SOx concentration of 7.3ppbv Results for Seoulatmosphere ate presented.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2004년도 춘계학술대회
• /
• pp.1795-1800
• /
• 2004

DOS and NaCl aerosol particles with geometric mean diameter of $0.1{\sim}3.0{\mu}m$ geometric standard deviation of $1.1{\sim}1.8$ and total number concentration of $450{\sim}400$ $particles/cm^3$ were used to determine collection efficiencies of a duct-type wet scrubber with respect to particle size. The tested operating variables included air velocity and water injection rate. It was shown from the experimental results that the collection efficiencies increased with increasing water injection rate and decreasing air velocity. It was also seen that the collection efficiency of the Duct-type wet scrubber is mainly governed by the mechanism of inertial impaction.

• 전력전자학회논문지
• /
• 제6권5호
• /
• pp.394-399
• /
• 2001

반도체 생산 공정에 있어, 저압 화학적 기상 증착(Low Pressure Chemical Vapor Deposition)과 프라즈마 강화 화학적 기상 증착(Plasma Enhanced Chemical Vapor Deposition) 공정 후 발생된 환경 유해 가스를 효과적으로 세정하기 위한 장비인 건식 세정기(dry scrubber)의 전원장치에 대한 연구이다. 주 전력회로는 1500W, 스위칭주파수 100kHz의 위상 변위 풀 브리지(Phase Shift Full-Bridge)방식의 인버터와 100kHz 저역 통과 필터 및 임피던스 변환기로 구성되었다 모드해석과 모의실험을 통하여 회로방식의 타당성을 확인하였고 50$\Omega$ dummy load 및 chamber 실험을 통하여 다양한 부하조건에서도 프라즈마를 안정되게 발생시킬 수 있음을 확인하였다.

• 설비공학논문집
• /
• 제18권9호
• /
• pp.745-752
• /
• 2006

DOS and NaCl aerosol particles were used to determine collection efficiencies of a 2-stage electrostatic wet scrubber with respect to particle size. The DOS and NaCl aerosols have geometric mean diameters of 0.1-3.0 urn, geometric standard deviations of $1.1{\sim}1.8$ and total number concentrations of $450{\sim}2,400\;particles/cm^3$. The tested operating variables for the electrostatic wet scrubber included air velocity and water injection rate. It was shown from the experimental results that particle collection efficiencies increased in the submicron particle size range when different polarities were applied on the water nozzle and corona wire, respectively. This increase in the collection efficiency is attributed to strong electrostatic attraction between the negative water droplets and positive submicron particles. The collection efficiencies also increased when water injection rate was increased or air velocity was decreased. Meanwhile, the pressure drop across the wet scrubber decreased by 90% compared with the existing mechanical wet scrubber. Finally, ammonia gas was used to determine gas removal efficiencies. It was observed that the gas removal efficiencies increased when the air velocity was decreased or the water injection rate was increased.

• 한국마린엔지니어링학회:학술대회논문집
• /
• 한국마린엔지니어링학회 2002년도 춘계학술대회논문집
• /
• pp.75-82
• /
• 2002

The effects of intake mixture temperature on performance and exhaust emissions under four kinds of engine loads were experimentally investigated by using a four-cycle four-cylinder, swirl chamber type, water-cooled diesel engine with scrubber EGR system operating at three kinds of engine speeds. The purpose of this study is to develop the scrubber exhaust gas recirculation(EGR) control system for reducing $NO_x$ and soot emissions simultaneously in diesel engines. The EGR system is used to reduce NOx emissions. And a novel diesel soot-removal device with a cylinder-type scrubber which has five water injection nozzles is specially designed and manufactured to reduce soot contents in the recirculated exhaust gas to the intake system of the engine. The influences of cooled EGR and water injection, however, would be included within those of scrubber EGR system. In order to study the effect of intake mixture temperature, a intake mixture heating device which has five heating coils is made of a steel drum. It is found that the specific fuel consumption rate is considerably elevated by the increase of intake mixture temperature, and that NOx emissions are markedly decreased as EGR rates are increased and intake mixture temperature is dropped, while soot emissions are increased with increasing EGR rates and intake mixture temperature.

• Journal of Advanced Marine Engineering and Technology
• /
• 제28권2호
• /
• pp.315-331
• /
• 2004

The effects of intake mixture temperature on performance and exhaust emissions under four kinds of engine loads were experimentally investigated by using a four-cycle. four-cylinder. swirl chamber type. water-cooled diesel engine with scrubber EGR system operating at three kinds of engine speeds. The purpose of this study is to develop the scrubber exhaust gas Recirculation (EGR) control system for reducing $\textrm{NO}_{x}$ and soot emissions simultaneously in diesel engines. The EGR system is used to reduce $\textrm{NO}_{x}$ emissions. And a novel diesel soot-removal device of cylinder-type scrubber with five water injection nozzles is specially designed and manufactured to reduce soot contents in the recirculated exhaust gas to the intake system of the engine. The influences of cooled EGR and water injection. however. would be included within those of scrubber EGR system. In order to survey the effects of cooled EGR and moisture on $\textrm{NO}_{x}$ and soot emissions. the intake mixtures of fresh air and recirculated exhaust gas are heated up using a heater with five heating coils equipped in a steel drum. It is found that intake and exhaust oxygen concentrations are decreased, especially at higher loads. as EGR rate and intake mixture temperature are increased at the same conditions of engine speed and load. and that $\textrm{NO}_{x}$ emissions are decreased. while soot emissions are increased owing to the decrease in intake and exhaust oxygen concentrations and the increase in equivalence ratio. Thus ond can conclude that $\textrm{NO}_{x}$ and soot emissions are considerably influenced by the cooled EGR.

• 한국반도체및디스플레이장비학회:학술대회논문집
• /
• 한국반도체및디스플레이장비학회 2002년도 추계학술대회 발표 논문집
• /
• pp.100-111
• /
• 2002

The effects of intake mixture temperature on performance and exhaust emissions under four kinds of engine loads were experimentally investigated by using a four-cycle, four-cylinder, swirl chamber type, water-cooled diesel engine with scrubber EGR system operating at three kinds of engine speeds. The purpose of this study is to develop the scrubber exhaust gas recirculation(EGR) control system for reducing $NO_x$ and soot emissions simultaneously in diesel engines. The EGR system is used to reduce $NO_x$ emissions. And a novel diesel soot-removal device of cylinder-type scrubber with five water injection nozzles is specially designed and manufactured to reduce soot contents in the recirculated exhaust gas to the intake system of the engine. The influences of cooled EGR and water injection, however, would be included within those of scrubber EGR system. In order to survey the effect of intake mixture temperature on performance and exhaust emissions, the intake mixtures of fresh air and recirculated exhaust gas are heated by a heating device with five heating coils made of a steel drum. It is found that the specific fuel consumption rate is considerably elevated by the increase of intake mixture temperature, and that $NO_x$ emissions are markedly decreased as EGR rates are increased and intake mixture temperature is dropped, while soot emissions are increased with increasing EGR rates and intake mixture temperature. Thus one can conclude that the performance and exhaust emissions are considerably influenced by the cooled EGR.