• Applied Chemistry for Engineering
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• 제26권6호
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• pp.631-639
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• 2015

Extraction/separation of cobalt by solvent extraction is reviewed. Separation of cobalt using various reagents and also cobalt recovery from scrap using commercial extractant were analyzed. The separation ability for cobalt followed the order of phosphinic > phosphonic > phosphoric acid due to the increasing stabilization of tetrahedral coordination of cobalt complexes with the extractant in the organic phase. Depending upon the solution composition, commercial extractants like Cyanex 272, D2EPHA and PC 88A should primarily be used for commercial extraction processes and also the efficient management of their combination could address various separation issues associated with cobalt bearing scrap.

• Proceedings of the IEEK Conference
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.259-263
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• 2001

There are several steps such as slicing, lapping, chemical etching and mechanical polishing in the silicon wafer production process. The chemical etching step is necessary to remove damaged layer caused In the slicing and lapping steps. The typical etching liquor is the acid mixture comprising nitric acid, acetic acid and hydrofluoric acid. At present, the waste acid is treated by a neutralization method with a high alkali cost and balky solid residue. A solvent extraction method is applicable to separate and recover each acid. Acetic acid is first separated from the waste liquor using 2-ethlyhexyl alcohols as an extractant. Then, nitric acid is recovered using TBP(Tri-butyl phosphate) as an extractant. Finally hydrofluoric acid is separated with the TBP solvent extraction. The expected recovered acids in this process are 2㏖/l acetic acid, 6㏖/1 nitric acid and 6㏖/l hydrofluoric acid. The yields of this process are almost 100% for acetic acid and nitric acid. On the other hand, it is important to recover and reuse the metal values contained in various industrial wastes in a viewpoint of environmental preservation. Most of industrial products are made through the processes to separate impurities in raw materials, solid and liquid wastes being necessarily discharged as industrial wastes. Chemical methods such as solvent extraction, ion exchange and membrane, and physical methods such as heavy media separation, magnetic separation and electrostatic separation are considered as the methods for separation and recovery of the metal values from the wastes. Some examples of the application of solvent extraction to the treatment of wastes such as Ni-Co alloy scrap, Sm-Co alloy scrap, fly ash and flue dust, and liquid wastes such as plating solution, the rinse solution, etching solution and pickling solution are introduced.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 한국소성가공학회 2002년도 제5회 압출 및 인발가공 심포지엄
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• pp.43-49
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• 2002

A7003 alloy has characteristics of their excellent weldability, high corrosion resistance and superior plastic working however the broadening of application for the alloy has been hampered by the lower extrudability associated by Mg content. For improvement of extrudability and enhanced recovery efficiency during Al scrap recyeling, it has been generally practiced to reduce Mg content in A7003 alloy. Therefore, it is necessary to investigate the influence of Mg content on mechanical strength and extrudability of A7003 alloy. For efficient material processing which has small amounts, life cycle assessment in material processing(MLCA) is evaluated. The quantitative analysis of energy requirements and $CO_2$ emission for production of A7003 extruded bar are estimated with different Mg content and billet pre-heating process (heating source by light oil or LPG). In particular, the estimation of energy requirements was performed within shipping and gating range (except the mining and extraction stages)to investigate the influence of the variables on energy requirements and $CO_2$ emission in detail. As Mg content increased, the flow stress and the extrusion pressure for A7003 alloy increased. It has been thought that an increment in extrusion pressure with increasing Mg content is caused by the solid solution hardening of Mg atoms in the matrix and increment in volume fraction of intermetallic compound, $Mg_2Si$. The extrudability and the tensile strength are equal to, or above that of conventional A 7003 alloy even the content of Mg varied from $1.1wt.\%\;to\;0.5wt.\%$ alloy. This means that minimizing the content of Mg in A7003 alloy can enhance recovery efficiency during Al scrap recycling. It can be quoted that rather than Mg content energy source for billet heating is a prime factor to determine the atmospheric $CO_2$ emission.

• Elastomers and Composites
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• 제35권2호
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• pp.115-121
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• 2000

In comparison with thermosetting rubber, thermoplastic elastomer (TPE) has various advantages such as simple processing, short cycle time and recycling of scrap. These advantages can lead to development of the high value-added rubber products due to reduction of the waste material, manufacturing cost and the defected product. This article involves a dynamic vulcanization method for EPDM/polypropylene blend, and the manufacturing of a fixed glass weather-strip by glass insert molding method using the blend. In order to investigate mechanical properties of the product, tensile strength, elongation, hardness and specific gravity were measured. Also morphological study was carried out using SEM. Developments of an efficient system of production and automatic process by molding of TPE and glass simultaneously are expected.

• Journal of the Korea Fashion and Costume Design Association
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• 제23권2호
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• pp.165-176
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• 2021

To solve environmental problems, research and efforts are required to reduce leather waste that is generated in large quantities during the leather manufacturing process. Leatherboard is a plate-like material that is made by crushing leather waste, such as trimming or shaving scraps and mixing fibers, pulp, rubber, and adhesives. The aim of this study is to provide basic data on the localization of leatherboard manufacturing technology for outsoles, which are increasingly in demand due to their excellent performance and price competitiveness. Interviews with experts and related organizations were conducted to investigate the related global technology trends. Also, the performance of three products that can be used as reference materials were evaluated and compared. As part of the research and efforts to reduce the amount of leather waste generated, high-performance materials using leather waste were developed and commercialized by major western companies. In Korea, various efforts have been made since 2000, and some companies have produced leatherboard for interior uses. However, the amount of waste recycled relative to that generated is not large due to the limited demand. Natural leather soles perform better than leatherboard soles in all evaluation aspects. In the case of leatherboard, performance varied by manufacturer. German products showed flexibility resistance and dimensional stability, thereby meeting performance requirements. However, abrasion resistance and cleavage resistance were slightly below the required performance standards, and research and development is needed to improve performance in those areas. Currently, it is impossible to evaluate the performance of domestic products due to underdevelopment. However, if the development of process technology continues based on the performance evaluation results of the best leatherboard in the shoe industry, materials for outsoles will be able to be produced domestically with prices competitiveness while realizing natural leather materials performance to some extent.

• Journal of the Korean Society for Marine Environment & Energy
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• 제11권1호
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• pp.50-54
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• 2008

There are several basic classes of recycling methods for FRP boats. The main one is 'Mechanical recycling' which involves shredding and grinding of the scrap FRP in a new product. That is one of the simpler and more technically proven methods. It recently has been reported that FRP can be recycled by separating into layers instead of crushing into powder. Many researchers should be more interested in these mechanical recycling for the eligibility. Nevertheless, because resins is very useful renewable energy, most of waste FRP regenerating methods depend on incineration (reclamation) or thermal recycling (pyrolysis). FRP is made up of laminated glass- fiber (roving cloth layer) which is also very unlikely to break into each layer. If there is an extracting method which is efficient and environment friendly removing glass fiber from waste FRP, it should also solve the another urgent problem. Laminated glass-fiber which is very limited renewable, is a serious barrier to wast FRP boat regenerating. This study is to propose a new extracting method which is efficient and environment friendly waste FRP regenerating system. And it should be applied to renewable energy applications with the waste resins of FRP. Also recycling glass fiber obtained by the separation of the roving layer from waste FRP will be consider to be useful for concrete products or structures.

• Resources Recycling
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• 제22권3호
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• pp.73-80
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• 2013

Metal prices are rapidly rising due to increasing demand of metals and limited available resources according to the industrial requirement. As a result, securing a stable supply of these metal resources has been recognized as a core element of national competitiveness and sustained economic growth. In the case of magnesium and its alloys which are entirely depending on import, low-grade magnesium scraps from end-of-life vehicles and 3C(Camera, Computer, Communication) parts and magnesium wastes such as sludge and dross generated during melting process are hardly recycled. Accordingly, the development and commercialization of recycling technology of low-grade magnesium scrap is desperately needed to improve efficiency of resource circulation and to establish the required proprietary of resource metal supply and demand. In this study, papers and patents on recycling technologies of waste magnesium were analyzed. The range of search was limited in the open patents of USA (US), European Union (EP), Japan (JP), Korea (KR) and SCI journals from 1974 to 2012. Patents and journals were collected using key-words searching and filtered by filtering criteria. The trends of the patents and journals was analyzed by the years, countries, companies, and technologies.

• Resources Recycling
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• 제13권5호
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• pp.37-44
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• 2004

In this study, neodymium oxalate powders were prepared by injecting oxalic acid to the neodymium chloride solution resulted from the acid leaching solution of NdFeB magnet scrap. The effect of experimental conditions on the characteristics of neodymium oxalate powders were investigated. Neodymium oxalate was aggregated by primary particles formed by nucleation, and average size of aggregates was affected by experimental conditions. In a constant volume, increase of reactants affected the average size of aggregate formed by collision of primary particles. In a constant concentration of reactants, agitation speed decreased the size of aggregate due to breakage of particles attached on the surface of aggregate. The number of primary particles decreased with increasing reaction temperature, and the size of aggregates decreased due to the decrease of collision probability. From the results of decomposition behavior of neodymium oxalate, oxalate decomposed from $400^{\circ}C$, and neodymium oxide began to crystallize at above $620^{\circ}C$.

• Resources Recycling
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• 제26권5호
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• pp.39-47
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• 2017

In this study, the precipitation of rare earth-sodium sulfate with sodium sulfate was conducted in order to separate rare earth from Fe in rare earth sulfate solution. Neodymium (Nd) was easily precipitated as Nd-sulfate salt with sodium sulfate, on the other hand, excessive sodium sulfate was needed for the precipitation of Dy-sulfate salt. Also neodymium not only promoted the precipitation of dysprosium sulfate salt but also increased recovery of dysprosium sulfate salt in sulfuric acid solution. At the condition of $60^{\circ}C$ precipitation temperature, 3 h reaction time, 7 equivalents sodium sulfate, the recovery of neodymium and dysprosium sulfate salt was 99.7% and 94.3% respectively from the sulfuric acid solution containing Nd of 23.39 mg/ml and Dy of 8.67 mg/ml. Lastly, from the results of separation of Dy to Nd by the method of sulfate double salt, the effect of salting out with NaCl is important to increase the grade of Dy, and 98.7% of Dy grade could be obtained in this study.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• 제2권1호
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• pp.60-67
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• 2004

The exposure dose form recycling of a large amount of the steel scrap from the KRR-1＆2 decommissioning activities was evaluated, and also the clearance level(draft) was derived. The maximum individual dose and collective dose were evaluated by modifying internal dose conversion factor which was based on the concept of effective dose in ICRP 60, applied to the RESRAD-RECYCLE ver 3.06 computing code, IAEA Safety Series 111-P-1.1 and NUREG-1640 as the assessment tool. The result of assessment for individual dose and collective dose is 23.9 $\mu$Sv per year and 0.11 man$.$Sv per year respectively. The clearance levels were ultimately determined by extracting the most conservative value form the results of the generic assessment and specific assessment methodologies. The result of clearance level for radionuclides( $Co^{60}$ , C $s^{l37}$) is less than 1.14${\times}$10$^{-1}$ Bq/g to comply with the clearance criterion(maximum individual dose : 10 $\mu$Sv per year, collective dose : 1 man$.$Sv per year) provided for Korea Atomic Energy Act and relevant regulations.s.