• Resources Recycling
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• v.33 no.1
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• pp.22-30
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• 2024

To synthesize the Ti₃AlC₂ MAX phase, a crucial precursor for generating the two-dimensional material MXene, the use of Ti scrap as an initial material is an economically feasible approach. This study aims to optimize the synthesis conditions for the phase fraction of the Ti₃AlC₂ MAX phase utilizing Ti scrap as the Ti source. The deoxidation of Ti powders, prepared through the hydrogenation-dehydrogenation process from Ti scrap, was effectively accomplished using the deoxidation in solid-state (DOSS) process. The optimal synthesis conditions were established by blending DOSS-Ti, Al, and graphite powders with particle sizes ranging from 25 ~ 32 ㎛ in a molar ratio of 3:1.1:2. The resulting phase fractions were as follows: Ti₃AlC₂ at 97.25 wt.%, TiC at 0.93 wt.%, and Al₃Ti at 1.82 wt.%. Furthermore, the oxygen content of the Ti₃AlC₂ MAX powder, spanning from 25 ~ 45 ㎛, was measured at 4,210 ppm.

• Resources Recycling
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• v.7 no.3
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• pp.42-51
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• 1998

Hydrogen in atmosphere can easily dissolve in melt of light metal alloys. Increasing demand for recycling of light metal a alloys has, therefore, focused attention on the removal of hydrogen gas, and alloy addition in melt has become an imporLant r refining process. For this purpose behaviors of mixing and hydrogen degassing in impeller agitated refming vessel with/without barnes were investigated. Flow patterns, mixing time behavior and kinetics of degassing in various agitating conditions were analysed in watet model experiments. And, numerical analysis on turbulent flow pattern in impeller agitated vessels was performed.

• Resources Recycling
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• v.32 no.1
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• pp.50-59
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• 2023

The amount of dust generated during the dissolution of scrap in an electric arc furnace is approximately 1.5% of the scrap metal input, and it is primarily collected in a bag filter. Electric arc furnace dust primarily consists of zinc and ion. The processing of zinc starts with its conversion into pellet form by the addition of a carbon-based reducing agent(coke, anthracite) and limestone (C/S control). These pellets then undergo reduction, volatilization, and re-oxidation in rotary kiln or RHF reactor to recover crude zinc oxide (60%w/w). Next, iron is discharged from the electric arc furnace dust as a solid called Fe clinker (secondary by-product of the Fe-base). Several methods are then used to treat the Fe clinker, which vary depending on the country, including landfilling and recycling (e.g., subbase course material, aggregate for concrete, Fe-source for cement manufacturing). However, landfilling has several drawbacks, including environmental pollution due to leaching, high landfill costs, and wastage of iron resources. To improve Fe recovery in the clinker, we pulverized it into optimal -sized particles and employed specific gravity and magnetic force selection methods to isolate this metal. A carbon-based reducing agent and a binding material were added to the separated coarse powder (>10㎛) to prepare briquette clinker. A small amount (1-3%w/w) of the briquette clinker was charged with the scrap in an electric arc furnace to evaluate its feasibility as an additives (carbonaceous material, heat-generating material, and Fe source).

• Journal of Korean Society of Environmental Engineers
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• v.35 no.5
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• pp.350-355
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• 2013

Little information is available for emission pathway even if HFC-134a that is known as one of the major greenhouse gases has been broadly used in Korea. This paper attempts to clarify the emission characteristics of HFC-134a used for refrigerant of cold drinking vending machines (CDVMs) at the use- and disposal-phase. We measured the residual amounts in the scrap CDVMs of 47 by applying commercial recover for refrigerant. The first-order kinetic model was introduced and the emission rate would be proportional to the remaining quantity of refrigerant. The emission factor at the use-phase was determined indirectly to be $6.9{\pm}0.7$ %/yr within a confidence interval of 95%, using information on residual amount and elapsed operation time at the disposal point. Correspondingly, the annual emission rate of HFC-134a per CDVM was determined to be 11.6 g. The average residual rate of HFC-134a in scrap CDVMs was assessed to be $62.5{\pm}2.2%$, leading to a potential emission amount of 144.8 g per scrap CDVM. The chemical compositions of refrigerants from scrap passenger vehicles are quite similar to those of new refrigerants, suggesting that the refrigerants from scrap passenger vehicles could be reused. During the recovering process of refrigerant, the recovered refrigerant was contaminated by compressor lubricant that accounted for about 30% in weight. It is necessary to separate the refrigerant from the recovered material contaminated by lubricant for recycling and reuse the refrigerant.

• Resources Recycling
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• v.30 no.1
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• pp.92-101
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• 2021

The status of waste generation and recycling in 32 countries in the European Union (EU), Japan, and the United States was investigated and summarized to encourage overseas market expansion for domestic urban mining industries. Among the 32 EU countries, Germany has the highest amount of material consumption and generates the largest quantity of waste. Minerals such as mine and soil wastes constitute the largest type of waste in the EU. With respect to waste treatment techniques, landfill and recycling are applied to 39% and 38% of the waste, respectively, implying the necessity to promote recycling. Japan's total waste generation declined recently to less than 400 million tons. The largest amount of waste is generated by the manufacturing industries. The proportion of total recycled waste is estimated to be slightly over 50%, but the proportions are greater than 90% for metal scrap and 60% for waste plastics. The amount of waste produced in the United States recently exceeded 265 million tons; 52.1% of the waste is landfilled, while only 25.1% is recycled. Therefore, the recycling industry has to be developed further.

• Resources Recycling
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• v.23 no.2
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• pp.26-36
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• 2014

The materials flow of copper can be analyzed into up-stream and down-stream stages based on the literature survey. Discharge and recycling stages in the down-stream have been particularly analyzed through the field survey. The waste nickel resources circulation flow may conveniently be grouped into 4 stages discharge import, collection disuse, resource recovery and product production export, the resources mainly consist of copper scrap and stainless steel scrap in 2010. The resource circulation rate of 36.83% is obtained from the above flow. Various plans are therefore, suggested in each stage to increase resource circulation rate. At discharge import stage, it is suggested to consider this kind of waste as an important resources if it is appropriately classified in detail, basides applying quota tariff to this kind of waste. At collection disuse stage, the plan of stabilizing supply and demand is suggested through the improvement of bidding system. Resources professional cycling stage crushing and grinding companies foster coexistence between large and small plans and strategies were suggested. At product production export stage, the integrated approval is suggested approval for licensing to register units as waste-treating facilities instead of exempting registration under the present condition to activate recycling industries.

• Resources Recycling
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• v.27 no.1
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• pp.31-37
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• 2018

To enhance the recycling rate of used metal resources, it is strongly desired to develop a metal sorting system that can automatically identify metal type from mixed metal scraps and sort them separately. Laser-induced breakdown spectroscopy(LIBS) is a technique that enables real time classification of different metals based on multi-elemental and in-air analysis. In this work, we report the results of LIBS elemental analysis of field scrap samples acquired from a recycling company. By applying multivariate analysis, it was found that the LIBS signals of five different metals could be perfectly classified if surface contamination was removed. The classification accuracy degraded for LIBS signals including contaminant emission, which however could be overcome by performing the multivariate analysis using properly selected emission lines of higher correlation only. The significant improvement in classification accuracy and process speed by the selection of proper emission lines demonstrated the feasibility of LIBS technique as an industrial tool for metal scrap sorting.

• Elastomers and Composites
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• v.29 no.5
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• pp.431-435
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• 1994

For recycling of the waste tires, polyurethane binder mixed with the scrapped rubber powders which obtained from tread part of waste tire. This study covered the effect of the binder contents on the mechanical properties of the blend. We also studied the change of the properties after aging on properties compared with those of before aging. The curing reaction of the binder was also investigated in this study. We obtained conclusions the suitable binder content was 15phr in this system.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.209-209
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• 2006

Ultra-fine fibers are spun by expensive fiber spinning technology using special spinnerets. Ultra-fine fibrous materials have attracted considerable attentions because of their potential applications as high performance wiping cloths, water absorbent sound proofing materials and moisture transfer sporting good. However, production expense of ultra-fine fibers is 5 to 7 times higher than general textile materials. The objective of this research is to develop cost-effective recycling process to produce multi-functional ultra-fine fibrous material in terms of the development of garnetting and carding machines for ultra-fine fibrous material waste and scrap. The efficiency of sound absorption for the recycled polyester nonwoven increased with decreasing length and thickness of component fibers, which was attributed to the reduction of air permeability. It is expected that high value and cost-effective textile products are developed using ultra-fine fibrous wastes and that sound proofing material and oil absorbent f

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2004.05a
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• pp.74-81
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• 2004