• 제목/요약/키워드: Scattering efficiency

검색결과 303건 처리시간 0.023초

Enhancement of Dye-Sensitized Solar Cell Efficiency by Spherical Voids in Nanocrystalline ZnO Electrodes

  • Hieu, Hoang Nhat;Dao, Van-Duong;Vuong, Nguyen Minh;Kim, Dojin;Choi, Ho-Suk
    • 한국재료학회지
    • /
    • 제24권9호
    • /
    • pp.458-464
    • /
    • 2014
  • Light scattering enhancement is widely used to enhance the optical absorption efficiency of dye-sensitized solar cells. In this work, we systematically analyzed the effects of spherical voids distributed as light-scattering centers in photoanode films made of an assembly of zinc oxide nanoparticles. Spherical voids in electrode films were formed using a sacrificial template of polystyrene (PS) spheres. The diameter and volume concentration of these spheres was varied to optimize the efficiency of dye-sensitized solar cells. The effects of film thickness on this efficiency was also examined. Electrochemical impedance spectroscopy was performed to study electron transport in the electrodes. The highest power conversion efficiency of 4.07 % was observed with $12{\mu}m$ film thickness. This relatively low optimum thickness of the electrode film is due to the enhanced light absorption caused by the light scattering centers of voids distributed in the film.

Improved Energy Conversion Efficiency of Dye-sensitized Solar Cells Fabricated using Open-ended TiO2 Nanotube Arrays with Scattering Layer

  • Rho, Won-Yeop;Chun, Myeoung-Hwan;Kim, Ho-Sub;Hahn, Yoon-Bong;Suh, Jung Sang;Jun, Bong-Hyun
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권4호
    • /
    • pp.1165-1168
    • /
    • 2014
  • We prepared dye-sensitized solar cells (DSSCs) with enhanced energy conversion efficiency using open-ended $TiO_2$ nanotube arrays with a $TiO_2$ scattering layer. As compared to closed-ended $TiO_2$ nanotube arrays, the energy conversion efficiency of the open-ended $TiO_2$ nanotube arrays was increased from 5.63% to 5.92%, which is an enhancement of 5.15%. With the $TiO_2$ scattering layer, the energy conversion efficiency was increased from 5.92% to 6.53%, which is an enhancement of 10.30%. After treating the open-ended $TiO_2$ nanotube arrays with $TiCl_4$, the energy conversion efficiency was increased from 6.53% to 6.89%, a 5.51% enhancement, which is attributed to improved light harvesting and increased dye adsorption.

Glass Frit을 이용한 염료감응 태양전지의 광 특성 연구 (Effect of Glass Frit in $TiO_2$ Electrode for DSSCs)

  • 김종우;전재승;김동선;황성진;김형순
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
    • /
    • pp.75.1-75.1
    • /
    • 2010
  • Dye sensitized solar cells(DSSCs) have been extensively studied due to their various advantages such as low production cost, colorful design, and eco-friendly process. Long optical path length is one of the most effective method to improve light harvest efficiency for DSSCs. Multi-layered $TiO_2$ nano-structured film with scattering layer has been studied to generate scattering effect by many researchers. It was expected that the difference of refractive index between $TiO_2$ particles and glass frit would generate the light scattering effect and provide the long optical path length. Therefore, to enhance the scattering effect, the frits of $Bi_2O_3-B_2O_3$-ZnO glass system that has the different refractive index were added to $TiO_2$ pastes in this study. First of all, the absorbance and haze factor of $TiO_2$ electrode with dyes and the refractive index of glass frit and $TiO_2$ were measured, respectively. To study the effect of frits, the efficiencies of DSSCs added glass frit and without glass frit were compared. Our results showed slightly higher efficiency with the different absorbance and haze factor of $TiO_2$ and glass frit. It was considered that the light scattering effect would be improved with adding frits to $TiO_2$ paste. Our preliminary studies will be useful for increasing efficiency of DSSCs.

  • PDF

OLED의 광 효율 향상 기술: 랜덤 나노 외부 광 추출 복합 층 제작 (Light Efficiency Enhancement Technology of OLED: Fabrication of Random Nano External Light Extraction Composite Layer)

  • 최근수;장은비;서가은;박영욱
    • 반도체디스플레이기술학회지
    • /
    • 제21권3호
    • /
    • pp.39-44
    • /
    • 2022
  • The light extraction technology for improving the light efficiency of OLEDs is the core technology for extracting the light inside the OLEDs to the outside. This study demonstrates a simple method to generate random nanostructures (RNSs) containing high refractive index nanoparticles to improve light extraction and viewing angle characteristics. A simple dry low-temperature process makes the nanostructured scattering layer on the polymer resin widely used in the industry. The scattering layer has the shape of randomly distributed nanorods. To control optical properties, we focused on changing the shape and density of RNSs and adjusting the concentration of high refractive index nanoparticles. As a result, the film of the present invention exhibits a perpendicular transmittance of 85% at a wavelength of 550 nm. This film was used as a scattering layer to reduce substrate mode loss and improve EL efficiency in OLEDs.

LCD backlight unit의 고분자 산란형 도광판에 관한 연구 (A study on the LCD backlight unit using polymer)

  • 정일용;박우상
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
    • /
    • pp.578-581
    • /
    • 1999
  • Dot pattern print methods composed of a diffusion film and two prism sheets, have been generally used for backlighting systems of LCDs. However, this methods require complex structures and show high power consumption and optical loss. To improve these disadvantages of conventional backlight units, light guides using highly scattering optical transmissions (HSOT) polymer as scatters, have been introduced. In this study we analyzed multiple scattering effect in light guide by means of Monte carlo simulation based on Mie scattering theory and ray tracing method. As a result it was revealed that scattering intensity depends on the size of scatters. On the other hands, it was shown that scattering efficiency depends on the wavelength of fluorescent lamp as well as the size of scatters.

  • PDF

Enhancement of Wireless Power Transfer Efficiency Using Higher Order Spherical Modes

  • Kim, Yoon Goo;Park, Jongmin;Nam, Sangwook
    • Journal of electromagnetic engineering and science
    • /
    • 제13권1호
    • /
    • pp.38-43
    • /
    • 2013
  • We derive the Z-parameters for the two coupled antennas used for wireless power transfer under the assumption that the antennas are canonical minimum scattering antennas. Using the Z-parameter and the maximum power transfer efficiency formula, we determine the maximum power transfer efficiency of wireless power transfer systems. The results showed that the maximum power transfer efficiency increases as the mode number or the radiation efficiency increases. To verify the theory, we fabricate and measure two different power transfer systems: one comprises two antennas generating $TM_{01}$ mode; the other comprises two antennas generating $TM_{02}$ mode. When the distance between the centers of the antennas was 30 cm, the maximum power transfer efficiency of the antennas generating the $TM_{02}$ mode increased by 62 % compared to that of the antennas generating the $TM_{01}$ mode.

Scattering Model for Electrical-Large Target Employing MLFMA and Radar Imaging Formation

  • Wu, Xia;Jin, Yaqiu
    • Journal of electromagnetic engineering and science
    • /
    • 제10권3호
    • /
    • pp.166-170
    • /
    • 2010
  • To numerically calculate electromagnetic scattering from the electrical-large three-dimensional(3D) objects, the high-frequency approaches have been usually applied, but the accuracy and feasibility of these geometrical and physical optics(GO-PO) approaches, to some extent, are remained to be improved. In this paper, a new framework is developed for calculation of the near-field scattering field of an electrical-large 3D target by using a multilevel fast multipole algorithm(MLFMA) and generation of radar images by using a fast back-projection(FBP) algorithm. The MPI(Message Passing Interface) parallel computing is carried out to multiply the calculation efficiency greatly. Finally, a simple example of perfectly electrical conducting(PEC) patch and a canonical case of Fighting Falcon F-16 are presented.

Methods to Improve Light Harvesting Efficiency in Dye-Sensitized Solar Cells

  • Park, Nam-Gyu
    • Journal of Electrochemical Science and Technology
    • /
    • 제1권2호
    • /
    • pp.69-74
    • /
    • 2010
  • Methodologies to improve photovoltaic performance of dye-sensitized solar cell (DSSC) are reviewed. DSSC is usually composed of a dye-adsorbed $TiO_2$ photoanode, a tri-iodide/iodide redox electrolyte and a Pt counter electrode. Among the photovoltaic parameters of short-circuit photocurrent density, open-circuit voltage and fill factor, short-circuit photocurrent density is the collective measure of light harvesting, charge separation and charge collection efficiencies. Internal quantum efficiency is known to reach almost 100%, which indicates that charge separation occurs without loss by recombination. Thus, light harvesting efficiency plays an important role in improvement of photocurrent. In this paper, technologies to improve light harvesting efficiency, including surface area improvement by nano-dispersion, size-dependent light scattering efficiency, bi-functional nano material, panchromatic absorption by selective positioning of three different dyes and transparent conductive oxide (TCO)-less DSSC, are introduced.

Improved Power Conversion Efficiency of Dye-Sensitized Solar Cells Assisted with phosphor materials Scattering layer

  • Lee, Yong-Min;Choi, Hyun Ji;Kim, Dong In;Lee, Yul Hee;Yu, Jung-Hoon;Kim, Jee Yun;Seo, Hyeon Jin;Hwang, Ki-Hwan;Nam, Sang Hun;Boo, Jin-Hyo
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
    • /
    • pp.408.2-409
    • /
    • 2016
  • Theoretically, the dye-sensitized solar cells (DSSCs) are high efficiency solar cells. However DSSCs have low power conversion efficiency (PCE) than silicon based solar cells. In this study, we use the phosphor materials, such as $Y_2O_3:Eu$ (Red), $Zn_2SiO_4:Mn$ (Green), $BaMgAl_{14}O_{23}:Eu$ (Blue), to enhance the PCE of DSSCs. Three phosphors were prepared and used as an effective scattering layer on the transparent $TiO_2$ with doctor blade method. We confirmed that the three scattering layers improve the PCE and Jsc due to the light harvesting enhancement via increased the scattering and absorbance in visible range. Under the sun illumination AM 1.5 conditions, the PCE of the mesoporous $TiO_2$ based DSSCs is 5.18 %. The PCE of the DSSCs with Y2O3:Eu, $Zn_2SiO_4:Mn$ and $BaMgAl_{14}O_{23}:Eu$ as scattering layer were enhanced to 5.66 %, 5.72% and 5.82%, respectably. In order to compare the optical properties change, DSSCs were measured by EQE, reflectance and PCE. At the same time, FE-SEM and XRD were used to confirm the structural changes of each layer.

  • PDF