• 제목/요약/키워드: Scattering efficiency

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Application of Polystyrene/SiO2 Core-shell Nanospheres to Improve the Light Extraction of GaN LEDs

  • Yeon, Seung Hwan;Kim, Kiyong;Park, Jinsub
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.314.2-314.2
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    • 2014
  • To improve the optical and electrical properties of commercialized GaN-based light-emitting diodes (LEDs), many methods are suggested. In recent years, great efforts have been made to improve the internal quantum efficiency and light extraction efficiency (LEE) and promising approaches are suggested using a patterned sapphire substrate (PSS), V-pit embedded LED structures, and silica nanostructures. In this study, we report on the enhancement of photoluminescence (PL) intensity in GaN-based LED structures by using the combination of SiO2 (silica) nanospheres and polystyrene/SiO2 core-shell nanospheres. The SiO2 nanospheres-coated LED structure shows the slightly increased PL intensity. Moreover the polystyrene/SiO2 core-shell nanospheres-coated structure shows the more increase of PL intensity comparing to that of only SiO2 spheres-coated structure and the conventional structure without coating of nanospheres. The Finite-difference time-domain (FDTD) simulation results show corresponding result with experimentally observed results. The mechanism of enhancement of PL intensity using the coating of polystyrene/SiO2 core-shell nanospheres on LED surface can be explained by the improvement in extraction efficiency by both increasing the probability of light escape by reducing Fresnel reflection and by multiple scattering within the core-shell nanospheres.

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Affected Enhance of Dye-Sensitized Solar Cells Using Silver Nanoparticle (은 나노 입자를 이용한 염료감응형 태양전지의 효율 향상 효과)

  • Jung, Haeng Yun;Hong, Kyung Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.1
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    • pp.34-39
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    • 2018
  • In this study, e-beam equipment was used to form silver nanoparticles on thin films of $TiO_2$ to increase the efficiency of dye-sensitized solar cells and improve the annealing process. $TiO_2$ thin films with nanoparticle photoelectrodes were fabricated in individual units for use in dye-sensitized solar cells. The characteristics of dye-sensitized solar cells were compared to those of the prepared $TiO_2$ photoelectrode with and without nanoparticles. The dye-sensitized solar cells with silver nanoparticles showed a significant increase in the electric current density compared with the pure $TiO_2$ dye-sensitized solar cell and improved the solar conversion efficiency to 27.89%. The increased density of electric current increased the extent of light absorption of the dye owing to the plasmon resonance of the nanoparticles at the local surfaces. This phenomenon led to increased light scattering, which in turn increased the current density of the dye-sensitized solar cells and improved the solar conversion efficiency.

system performance with different fiber structures in Raman ampliffer (라만 증폭기에서 광섬유 구조에 따른 성능 분석)

  • 박재형;민범기;박남규
    • Korean Journal of Optics and Photonics
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    • v.12 no.2
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    • pp.121-128
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    • 2001
  • We examine the performance of a Raman amplifier as a function of fiber structure with respect to amplifier gain and double Rayleigh crosstalk penalty. Variations on fiber core radius or index affect both the Raman gain efficiency and Rayleigh backscattering. Contrary to the common concept, the penalty from the doubly amplified Rayleigh scattering could exceed the benefits of higher gain efficiency of small effective area fibers. Appropriate fiber designing parameters are required to increase Raman amplifier efficiency without system penalties. lties.

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Preparation and Characterization of Bovine Serum Albumin-loaded Cationic Liposomes: Effect of Hydration Phase

  • Park, Se-Jin;Jeong, Ui-Hyeon;Lee, Ji-Woo;Park, Jeong-Sook
    • Journal of Pharmaceutical Investigation
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    • v.40 no.6
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    • pp.353-356
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    • 2010
  • Although liposomes have been applied as drug delivery systems in various fields, the usage was limited due to the low encapsulation efficiency compared to other carrier systems. Here, cationic liposomes were prepared by mixing 1,2-dioleoyl-3-trimethylammoniopropane (DOTAP) as a cationic lipid, 1,2-dioleoyl-sn-glycerol-phosphoethanolamine (DOPE) and cholesterol (CH), and the liposomes were hydrated by varying the aqueous phases such as phosphate-buffered saline (PBS), 5% dextrose, and 10% sucrose in order to improve the encapsulation efficiency of bovine serum albumin (BSA). The particle size and zeta potential were determined by dynamic light scattering method and in vitro release patterns were investigated by spectrophotometry. Particle size and zeta potential of liposomes were varied depending on the ratio of DOTAP/DOPE/CH in range of 270-350 nm and 0.8-9.7 mV, respectively. Moreover, the addition of polyethylene glycol (PEG) improved the encapsulation efficiency from 37% to 43% as well as reduced particle sizes of liposomes while the liposomes were hydrated in PBS. When the liposomes were hydrated with 10% sucrose, the encapsulation efficiency of BSA was higher than any other groups. Whereas PBS was used as hydration solution, lower encapsulation efficiency was obtained compared with other groups. More than 60% of BSA was released from the liposomes hydrated with 10% sucrose; thereafter another 20% of BSA was released. Therefore, release pattern of BSA from cationic liposomes was extended release in this study. From the results, cationic liposomes dispersed in 10% sucrose would be potential carrier with high encapsulation efficiency.

Performance Evaluation of Component Detectors of Double-scattering Compton Camera (이중 산란형 컴프턴 카메라 구성 검출기 성능 평가)

  • Seo, Hee;Park, Jin-Hyung;Kim, Chan-Hyeong;Lee, Ju-Hahn;Lee, Chun-Sik;Lee, Jae-Sung
    • Journal of Radiation Protection and Research
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    • v.35 no.2
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    • pp.69-76
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    • 2010
  • Prototype double-scattering Compton camera, which consists of three gamma-ray detectors, that is, two double-sided silicon strip detectors (DSSDs) as scatterer detectors and a NaI(Tl) scintillation detector as an absorber detector, could provide high imaging resolution with a compact system. In the present study, the energy resolution and the timing resolution of component detectors were measured, and the parameters affecting the energy resolution of the DSSD were examined in terms of equivalent noise charge (ENC). The energy resolutions of the DSSD-1 and DSSD-2 were, in average, $25.2keV{\pm}0.8keV$ FWHM and $31.8keV{\pm}4.6keV$ FWHM at the 59.5 keV peak of $^{241}Am$, respectively. The timing resolutions of the DSSD and NaI(Tl) scintillation detector were 57.25 ns FWHM and 7.98 ns FWHM, respectively. In addition, the Compton image was obtained for a point-like $^{137}Cs$ gamma source with double-scattering Compton camera. From the present experiment, the imaging resolution of 8.4 mm FWHM (angular resolution of $8.1^{\circ}$ FWHM), and the imaging sensitivity of $1.5{\times}10^{-7}$ (intrinsic efficiency of $1.9{\times}10^{-6}$) were obtained.

Light Scattering Properties of Highly Textured Ag/Al:Si Bilayer Back Reflectors (표면텍스처링된 이중구조 Ag/Al:Si 후면반사막의 광산란 특성)

  • Jang, Eun-Seok;Baek, Sang-Hun;Jang, Byung-Yeol;Park, Sang-Hyun;Yoon, Kyung-Hoon;Rhee, Young-Woo;Cho, Jun-Sik
    • Korean Journal of Materials Research
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    • v.21 no.10
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    • pp.573-579
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    • 2011
  • Highly textured Ag, Al and Al:Si back reflectors for flexible n-i-p silicon thin-film solar cells were prepared on 100-${\mu}m$-thick stainless steel substrates by DC magnetron sputtering and the influence of their surface textures on the light-scattering properties were investigated. The surface texture of the metal back reflectors was influenced by the increased grain size and by the bimodal distribution that arose due to the abnormal grain growth at elevated deposition temperatures. This can be explained by the structure zone model (SZM). With an increase in the deposition temperatures from room temperature to $500^{\circ}C$, the surface roughness of the Al:Si films increased from 11 nm to 95 nm, whereas that of the pure Ag films increased from 6 nm to 47 nm at the same deposition temperature. Although Al:Si back reflectors with larger surface feature dimensions than pure Ag can be fabricated at lower deposition temperatures due to the lower melting point and the Si impurity drag effect, they show poor total and diffuse reflectance, resulting from the low reflectivity and reflection loss on the textured surface. For a further improvement of the light-trapping efficiency in solar cells, a new type of back reflector consisting of Ag/Al:Si bilayer is suggested. The surface morphology and reflectance of this reflector are closely dependent on the Al:Si bottom layer and the Ag top layer. The relationship between the surface topography and the light-scattering properties of the bilayer back reflectors is also reported in this paper.

Preparation and Properties of Soybean Lecithin Liposome using Supercritical Reverse Phase Evaporation Method (초임계 역상 증발법을 이용한 대두 레시틴 리포좀의 제조 및 특성)

  • Lee, Mi-Jin;Jeong, Noh-Hee;Jeang, Boo-Sick
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.391-398
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    • 2010
  • Soybean lecithin liposomes composed phosphatidyl choline, phosphatidyl ethanolamine, phosphatidyl inositol and phosphatidic acid were prepared by using the previously developed supercritical reverse phase evaporation method. The effect of phospholipid composition on the formation of liposomes and physicochemical properties were examined by means of trapping efficiency measurements, transmission electron microscopy, dynamic light scattering and zeta potential measurements. The trapping efficiency of liposomes for D-(+)-glucose made of CNA-Ⅰ which contains approximately 95% phosphatidyl choline is higher than that of CNA-II and CNA-O which contain approximately 32% phosphatidyl choline. However there is no any difference between the trapping efficiency of liposomes for D-(+)-glucose made of CNA-II which has saturated hydrocarbons tails and that of liposomes made of CNA-O which has unsaturated hydrocarbon chains. The electron micrographs of liposomes made of CNA-II and CNA-O show small spherical liposomes with diameter of $0.1\sim0.25{\mu}m$, while that of CNA-I shows large unilamellar liposomes with diameter of $0.2\sim1.2{\mu}m$. These results clearly show that phospholipid structure of phosphatidylcholine allows an efficient preparation of large unilamellar liposomes and a high trapping efficiency for water soluble substances. Liposomes made of CNA-II and CNA-O remained well-dispersed for at least 14 days, while liposome suspension made of CNA-I separated in two phase at 14 days due to aggregation and fusion of liposomes. The dispersibility of liposomes made of CNA-I is lower than that of CNA-II and CNA-O due to the smallar zeta potential of CNA-I.

$TiO_2$ Particle Size Effect on the Performance of Dye-Sensitized Solar Cell ($TiO_2$ 입자 크기에 따른 염료감응태양전지의 성능 변화)

  • Kim, Ba-Wool;Park, Mi-Ju;Lee, Sung-Uk;Choi, Won-Seok;Hong, Byung-You
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.145-146
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    • 2007
  • Dye-Sensitized Solar Cell Solar cells(DSSC) were appeared for overcoming global environmental problems and lack of fossil fuel problems. And it is one of study field that is getting into the spotlight lately because manufacturing method is more simple and inexpensive than existing silicon solar cells. Oxide semiconductor is used for adsorption of dye and electron transfer in DSSC study, and $TiO_2$ is used most usually. Overall light conversion efficiency is changed by several elements such as $TiO_2$ particle size and structure, pore size and shape. In this study, we report the solar cell performance of titania$(TiO_2)$ film electrodes with various particle sizes. $TiO_2$ particle size was 16 nm, 25 nm, and mixture of 16nm and 25 nm, and manufactured using Doctor blade method. When applied each $TiO_2$ film to DSSC, the best efficiency was found at 16nm of $TiO_2$ particle. 16nm of $TiO_2$ particle has the highest efficiency compared to the others, because particles with smaller diameters would adsorb more dye due to larger surface area. And in case of the mixture of 16nm and 25 nm, the surface area was smaller than expected. It is estimated that double layer is adsorbed a large amount of chemisorbed dye and improved light scattering leading due to efficiency concentration light than mono layer.

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Production and Characterization of Beta-lactoglobulin/Alginate Nanoemulsion Containing Coenzyme Q10: Impact of Heat Treatment and Alginate Concentrate

  • Lee, Mee-Ryung;Choi, Ha-Neul;Ha, Ho-Kyung;Lee, Won-Jae
    • Food Science of Animal Resources
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    • v.33 no.1
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    • pp.67-74
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    • 2013
  • The aims of this research were to produce oil-in-water ${\beta}$-lactoglobulin/alginate (${\beta}$-lg/Al) nanoemulsions loaded with coenzyme $Q_{10}$ and to investigate the combined effects of heating temperature and alginate concentration on the physicochemical properties and encapsulation efficiency of ${\beta}$-lg/Al nanoemulsions. In ${\beta}$-lg/Al nanoemulsions production, various heating temperatures (60, 65, and $70^{\circ}C$) and alginate concentrations (0, 0.01, 0.03, and 0.05%) were used. A transmission electron microscopy was used to observe morphologies of ${\beta}$-lg/Al nanoemulsions. Droplet size and zeta-potential values of ${\beta}$-lg/Al nanoemulsions and encapsulation efficiency of coenzyme $Q_{10}$ were determined by electrophoretic light scattering spectrophotometer and HPLC, respectively. The spherically shaped ${\beta}$-lg/Al nanoemulsions with the size of 169 to 220 nm were successfully formed. The heat treatments from 60 to $70^{\circ}C$ resulted in a significant (p<0.05) increase in droplet size, polydispersity, zeta-potential value of ${\beta}$-lg/Al nanoemulsions, and encapsulation efficiency of coenzyme $Q_{10}$. As alginate concentration was increased from 0 to 0.05%, there was an increase in the polydispersity index of ${\beta}$-lg/Al nanoemulsions and encapsulation efficiency of coenzyme $Q_{10}$. This study demonstrates that heating temperature and alginate concentration had a major impact on the size, polydispersity, zeta-potential value and encapsulation efficiency of coenzyme $Q_{10}$ in ${\beta}$-lg/Al nanoemulsions.

Dye-sensitized Solar Cells Utilizing Core/Shell Structure Nanoparticle Fabrication and Deposition Process (코어/쉘 구조의 나노입자 제조 및 증착 공정을 활용한 염료감응 태양전지)

  • Jeong, Hongin;Yoo, Jhongryul;Park, Sungho
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.111-117
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    • 2019
  • This study proposed the fabrication and deposition of high purity crystalline $core-TiO_2/shell-Al_2O_3$ nanoparticles. Morphological properties of $core-TiO_2$ and coated $shell-Al_2O_3$ were confirmed by transmission electron microscope (TEM) and transmission electron microscope - energy dispersive spectroscopy (TEM-EDS). The electrical properties of the prepared $core-TiO_2/shell-Al_2O_3$ nanoparticles were evaluated by applying them to a working electrode of a Dye-Sensitized Solar Cell (DSSC). The particle size, growth rate and the main crystal structure of $core-TiO_2$ were analyzed through dynamic light scattering system (DLS), scanning electron microscope (SEM) and X-ray diffraction (XRD). The $core-TiO_2$, which has a particle size of 17.1 nm, a thin film thickness of $20.1{\mu}m$ and a main crystal structure of anatase, shows higher electrical efficiency than the conventional paste-based dye-sensitized solar cell (DSSC). In addition, the energy conversion efficiency (6.28%) of the dye-sensitized solar cell (DSSC) using the $core-TiO_2/shell-Al_2O_3$ nanoparticles selectively controlled to the working electrode is 26.1% higher than the energy conversion efficiency (4.99%) of the dye-sensitized solar cell (DSSC) using the conventional paste method.