• Bulletin of the Korean Chemical Society
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• 제32권8호
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• pp.2637-2642
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• 2011

A new ultrasonic-assisted micellar extraction and cloud-point pre-concentration method was developed for the determination of major saikosaponins, namely saikosaponins -A, -C and -D, in Radix Bupleuri by high performance liquid chromatography with evaporative light scattering detection (HPLC-ELSD). The non-ionic surfactant Genapol X-080 (oligoethylene glycol monoalkyl ether) was chosen as the extraction additive and parameters affecting the extraction efficiency were optimized. The highest yield was obtained with 10% (w/v) Genapol X-080, a liquid/solid ratio of 200:1 (mL/g) and ultrasonic-assisted extraction for 40 min. In addition, the optimum cloud-point pre-concentration was reached with 10% sodium sulfate and equilibration at $60^{\circ}C$ for 30 min. Separation was achieved on an Ascentis Express C18 column (100 ${\times}$ 4.6 mm i.d., 2.7 ${\mu}M$) using a binary mobile phase composed of 0.1% acetic acid and acetonitrile. Saikosaponins were detected by ELSD, which was operated at a $50^{\circ}C$ drift tube temperature and 3.0 bar nebulizer gas ($N_2$) pressure. The water-based solvent modified with Genapol X-080 showed better extraction efficiency compared to that of the conventional solvent methanol. Recovery of saikosaponins ranged from 93.1 to 101.9%. An environmentally-friendly extraction method was successfully applied to extract and enrich major saikosaponins in Radix Bupleuri.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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• pp.23-23
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• 2009

It has been challenging to increase the thermoelectric figure of merit ($ZT=S^2{\sigma}T/\kappa$) of materials, which determine the efficiency of thermoelectric devices, because the three parameters Seebeck coefficient (S), electrical conductivity ($\sigma$), and thermal conductivity ($\kappa$) of bulk materials are inter-dependent. With the development of nanotechnology, ZT values of nanostructured materials are predicted to be enhanced by classical size effects and quantum confinement effects. In particular, Bi nanowires were suggested as one of ideal thermoelectric materials due to the expected quantum confinement effects for the simultaneous increase in Sand. In this work, we have investigated the thermal conductivity of individual single crystalline Bi nanowires with d = 98 nm and d = 327 nm in the temperature range 40 - 300 K using MEMS devices. The for the Bi nanowire with d = 98 nm was observed to be ~ 1.6 W/m-K at 300 K, which is much lower than that of Bi bulk (8 W/m-K at 300 K). This indicates that the thermal conductivity of the Bi suppressed due to enhanced surface boundary scattering in one-dimensional structures. Our results suggest that Bi nanowires grown by stress-induced method can be used for high-efficiency thermoelectric devices.

• 대한방사선기술학회지:방사선기술과학
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• 제43권4호
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• pp.259-264
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• 2020

Radiation causes radiation hazards in the human body. In Korea, a case of radiation necrosis occurred in 2014. In this study, the scatter and shielding efficiency according to lead shielding were classified into epidermis and dermis for 0.511 MeV used in nuclear medicine. In this study, experiments were conducted using the slab phantom that represents calibration and the dose of human trunk. Experimental results showed that the shielding rate of 0.25 mmPb was 180% in the epidermis and 96% in the dermis. Shielding at 0.5mmPb showed shielding rates of 158%in the epidermis and 82% in the dermis. As a result of measuring the absorbed dose by subdividing the thickness of the dermis into 0.5 mm intervals, when the shielding was carried out at 0.25 mmPb, the dose appeared to be about 120% at 0.5 mm of the dermis surface, and the dose was decreased at the subsequent depth. Shielding at 0.5 mmPb, the dose appeared to be about 101% at the surface 0.5 mm, and the dose was measured to decrease at the subsequent depth. This result suggests that when lead aprons are actually used, the scattering rays would be sufficiently removed due to the spaces generated by the clothes and air, Therefore, the scattered ray generated from lead will not reach the human body. The ICRU defines the epidermis (0.07), in which the radiation-induced damage of the skin occurs, as the dose equivalent. If the radiation dose of the dermis is considered in addition, it will be helpful for the evaluation of the prognosis for radiation hazard of the skin.

• 한국BIM학회 논문집
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• 제12권4호
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• pp.104-115
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• 2022

Fine Dust in Korea has been classified as a social disaster since 2019 due to continuous increase in concentration of Particulate Matter 10(PM 10) and PM 2.5. The fine dust issue has negative physical and mental impacts, especially on vulnerable population including children and the elderly. Seoul metropolitan government have installed fine dust shelters since 2019. However, there is a lack of research that evaluates spatiotemporal distribution of these facilities. Therefore, the first aim of this study is to find the relationship between PM levels and dust scattering construction sites, or air pollutant emission sites through in depth spatial analyses. The second purpose is to analyze the spatial distribution of PM shelters in Seoul, and to evaluate the location efficiency of them. Kernel density, krigging, and network analyses were conducted, and floating population was considered instead of census data for this research. The reults of network analysis based on the road system showed that Yangcheon-gu, Songpa-gu, Seongbuk-gu, and Dobong-gu were found to need additional fine dust shelters. Also, the results from analyzing the floating population that includes children and the elderly showed that Songpa-gu, Seodaemun-gu, Gangdong-gu, Seocho-gu, and Dongdaemun-gu need more placements of find dust shelters. The results of this study are expected to provide implications for urban planners to enhance find dust shelter placement in urban areas, and vulnerable population issues would be considered in many ways.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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• pp.880-882
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• 2002

We have proposed a novel optical design technique of light-guide plates(LGPs) which can able to improve the optical efficiency of transflective LCDs. The basic concepts of our design technique are that we make the groove-pattern of LGP pixels resemble the pixel-array-pattern of transflective LCDs in shape and size and make the surface of the groove scatter (front scattering). In simulated and measured results, we ensure that our design of LGP in backlight unit for transflective LCDs can improve the optical efficiency of LCDs.

• Applied Science and Convergence Technology
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• 제27권2호
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• pp.42-45
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• 2018

Photovoltaic and optoelectronic devices based on hybrid metal halide perovskites ($MAPbX_3$; $MA=CH_3NH_3{^+}$, $X=Cl^-$, $Br^-$, or $I^-$) are rapidly improving in power conversion efficiency. Also, during recent years, perovskite single crystals have emerged as promising materials for high-efficiency photovoltaic and optoelectronic devices because of their low defect density. Here we show that the light soaking effect of mixed halide perovskite ($MAPbBr_{3-x}I_x$) single crystals can be explained using photoluminescence, time-resolved photoluminescence, and Raman scattering measurements. Unlike Br-based single crystal, Br/I mixed single crystal show a strong light soaking effect under laser irradiation condition that was related to the existence of multiple phases.

• 통합자연과학논문집
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• 제2권4호
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• pp.237-242
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• 2009

As semitransparent dye-sensitized solar cells (DSSCs) have advanced to large-scale applications from lab-level research, the large-scale performance has attracted much attention. Modules of DSSCs have been investigated to optimize the efficiency as a $TiO_2$ systhesis temperature and a surface treatment of $TiCl_4$ aqueous solution. Essentially, these semitransparent modules have an extended structure with lab-scale works with the exception of the dimensions and methods for the series connection. The $5cm{\times}6.5cm$ modules have shown an efficiency of about 6% without a scattering layer. While the fill factors of modules depend on the width of each $TiO_2$ unit cell, they are much less dependent on the lengths of the unit cells.

• 한국환경복원기술학회지
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• 제6권3호
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• pp.56-68
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• 2003

The main purpose of this study was to verify the shore margin protection effect of the root system of Salix gracilistyla Miq. developed from direct sticking cuttings on wetland, through the measurement of root growth and comparison of soil slaking rate depending on the planting method applied to shore-marginal slope. Comparison of growth rate and soil dispersion rate was made between five planted slope and one naked slope. The planting methods applied to the planted slope were (a) horizontally layed burying of stick(45cm) bundle (b) horizontally layed covering the slope with sticks (c) horizontally fencing with normal cuttings(20cm) (d) elected sticking of normal cutting at equal distances (e) random scattering short cuttings(3-4cm). As results, the most effective planting method was horizontally layed burying, and in order to increase its efficiency scattering the live stem chips in 2-3cm on the slope is recommended. The growth of root was negatively regressive to the distance from water floor.

• Journal of Mechanical Science and Technology
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• 제16권9호
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• pp.1112-1120
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• 2002

Numerical investigations on air staging and fuel staging were carried out with a newly designed coaxial cyclone combustor, which uses the method of two stage coal combustion composed of pre-combustor and main combustor. The pre-combustor with a high air/fuel ratio is designed to supply gas at high temperature to the main combustor. To avoid local high temperature region in this process, secondary air is injected in the downstream. Together with the burned gas supplied from the pre-combustor and the preheated air directly injected into main combustor, coals supplied through the main burner react rapidly at a low air/fuel ratio. Strong swirling motion of cyclone combustor keeps the wall temperature high, which makes slagging combustion possible. Alaska, US coal is used for calculations. Predictions were made for various coal flow rates in the main combustor for fuel staging and for the various flow rate of secondary air in the pre-combustor for air staging. In-scattering angles are also chosen as a variable to increase residence times of coal particles. Temperature fields and particle trajectories for various conditions are described. Predicted temperature variations at the wall of the combustor are compared with corresponding experimental data and show a similar trend. The in-scattering angle of 20° is recommended to increase the combustion efficiency in the main chamber.

• 천문학회보
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• 제41권2호
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• pp.40.2-40.2
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• 2016

The attenuation of starlight by dust in galactic environments is investigated through models of radiative transfer in a spherical, clumpy interstellar medium (ISM). We show that the attenuation curves are primarily determined by the wavelength dependence of absorption rather than by the underlying extinction (absorption+scattering) curve; the observationally derived attenuation curves cannot constrain a unique extinction curve unless the absorption or scattering efficiency is specified. Attenuation curves consistent with the Calzetti curve are found by assuming the silicate-carbonaceous dust model for the Milky Way (MW), but with the $2175{\AA}$ bump suppressed or absent. The discrepancy between our results and previous work that claimed the Small Magellanic Cloud dust to be the origin of the Calzetti curve is ascribed to the difference in adopted albedos; we use the theoretically calculated albedos whereas the previous ones adopted empirically derived albedos from observations of reflection nebulae. It is found that the model attenuation curves calculated with the MW dust are well represented by a modified Calzetti curve with a varying slope and UV bump strength. The strong correlation between the slope and UV bump strength, as found in star-forming galaxies at 0.5 < z < 2.0, is well reproduced if the abundance of the UV bump carriers is assumed to be 30-40% of that of the MW-dust; radiative transfer effects lead to shallower attenuation curves with weaker UV bumps as the ISM is more clumpy and dustier. We also argue that some of local starburst galaxies have a UV bump in their attenuation curves, albeit very weak.