• 약학회지
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• 제27권1호
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• pp.1-10
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• 1983

Voltammetric deposition and differential pulse anodic stripping (DPASV) of Ge(IV)at a gold electrode was investigated. Germanium (IV) exhibits two stripping peaks by DPASV in sodium borate solution, the first peak at about -1.1v. vs SCE and the second one, in the range of -0.6 to -0.2v. vs SCE. Factors affecting the sensitivity and precision included the nature of working electrode, supporting electrolytes, deposition potential, deposition time, pH, pulse height, voltage scan rate. The relative standard deviation of the measurements of the peak currents, for 100ng/ml Ge(IV), was less than ${\pm}3%$. The detection limit of Ge(IV) was 0.01ng/ml. Percent recovery in the extraction procedure of Ge(IV) from matrices by benzene in c-HCl, followed by back extraction with saturated borax solution, ranged from 96 to 104%.

• Geomechanics and Engineering
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• 제25권4호
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• pp.283-294
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• 2021

This paper presents a rigorous solution for spherical cavity expansion in unsaturated soils under constant suction condition. The hydraulic behavior that describes the saturation-suction relationship is modeled by a void ratio-dependent soil-water characteristic curve, which allows the hydraulic behavior to fully couple with the mechanical behavior that is described by an extended critical state soil model for unsaturated soil through the specific volume. Considering the boundary condition and introducing an auxiliary coordinate, the problem is formulated to a system of first-order differential equations with three principal stress components and suction as basic unknowns, which is solved as an initial value problem. Parameter analyses are conducted to investigate the effects of suction and the overconsolidation ratio on the overall expansion responses, including the pressure-expansion response, the distribution of the stress components around the cavity, and the stress path of the soil during cavity expansion. The results reveal that the expansion pressures and the distribution of the stress components in unsaturated soils are generally higher than those in saturated soils due to the existence of suction.

• 한국지반환경공학회 논문집
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• 제11권5호
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• pp.35-43
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• 2010

불포화 투수계수는 모관흡수력(또는 함수비)과 간극률의 함수로 정의되어야 한다. 그러나 기존 상용프로그램이나 문헌에 개발된 모델들은 모관흡수력 만의 함수로써 정의 되어왔다. 사면의 안정성은 수리학적인 측면과 흙의 전단강도 특성들이 모두 고려되어야 한다. 이 두 가지 특성에 대한 해석은 상용 프로그램인 Seep/W, Sigma/W 그리고 Slope/W(Geo-Slope, 2007) 같은 상호 연계가능한 해석 프로그램을 이용한다. 이런 해석 방법으로 강우시 불포화 침투수를 고려하고 흙의 변형을 예측하며 결국에는 사면의 안정성 평가에 예측하고 있다. 불포화 침투수를 해석하는 Seep/W 프로그램은 흙의 변형은 고려하지 못하고 단지 불포화 침투해석만을 수행한다. 그래서 흙의 변형을 고려하기 위해 Sigma/W 프로그램을 연계하여 실제 사면에서 발생하는 침투에 의한 흙의 변형을 모사하고 있다. 이와 같이 동시에 발생하는 침투와 흙의 변형을 구현하기 위해 여러 연구자들이 새로운 모델들을 개발하고 있지만, 현재로서는 각각의 해석을 연계하여 실제로 일어나는 현상에 접근하고 있는 실정이다. 본 연구는 기존 프로그램을 이용하여 연계해석에 의한 결과와 동시해석과 유사한 알고리즘을 이용하여 해석한 결과를 비교하여 동시해석의 타당성을 검증하고자 하였다.

• 한국초등과학교육학회지:초등과학교육
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• 제28권3호
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• pp.292-303
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• 2009

In this study, we investigated the characteristics of the analogies, the mapping understanding, and the mapping errors on saturated solution of scientifically-gifted and general elementary students. Fifth graders (n=60) at four scientifically-gifted education institutes in Seoul and/or Gyeonggi province and fifth graders (n=91) at three elementary schools in Seoul were selected and assigned to the scientifically-gifted group and the general group respectively. After the students of each group performed the experiment and were taught about the target concept in the first class, they administered the test on the self-generating analogies on the target concept in the second class. The results revealed that the students in the scientifically-gifted group made more analogies, especially verbal/pictorial, structural/functional, enriched, and higher systematic ones, and had deeper understanding of the analogy than those in the general group. The numbers of the shared attributes included in the student-generated analogies and the scores of the mapping understanding of the students in the scientifically-gifted group were significantly higher than those in the general group. The students in the scientifically-gifted group had fewer mapping errors than those in the general group. However, not a few students in the scientifically-gifted group had at least one mapping error. Educational implications of these findings are discussed.

• 한국해양공학회지
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• 제4권1호
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• pp.88-100
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• 1990

Among the test methods to evaluate stress-corrosion cracking(SCC) on the basis of fracture mechanics, constant displacement(bolt) loading method using modified-WOL specimen is practically convenient. In this test method, compliance formula is generally required to calculate load(consequently $K_{ISCC}$). There are many problems in using the analytic compliance formula to calculate $K_{ISCC}$, so we had proposed the experimental $K_{ISCC}$ evaluation technique in the previous report. This study has employed the slightly altered configuration of modified-WOL specimen made of weldable structural stee(BS360-50D). With these specimens, stress-corrosion tests have been performed in $H_2S$ gas saturated 20% HCl solution. Through the test, the problems as mentioned earlier have been discussed again, and the proposed evaluation technique has been verified. And the stress-corrosion cracks and hydrogen blisters have been investigated in the initiation step with the aids of metallurgical micrographs, SEM fractographs, and EPMA analysis. The inclusions segregated in the mid-thickness region traps hydrogen to produce the hydrogen blistering. The applied or residual stress does not contribute the occurrence of the blister. Hydrogen absorbed into the mid-thickness region is consumed to produce the blistering so that stress-corrosion crack could hardly be detected at that region. The stress-corrosion cracks initiate from the inclusions and propagate in radial pattern. And the initiation site is remote from the crack tip and is inclined from the crack plane, which is assumed to be caused by the triaxial stress and the amount of the absorbed hydrogen.

• 보존과학회지
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• 제29권4호
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• pp.421-435
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• 2013

본 연구는 수중 발굴 도자기에 있어 상대습도 조건에 따른 수용성 염의 표면거동을 조사하여 도자기 보존관리에 적합한 환경기준을 제시하고자 한다. 실험 24주간 전기전도도 누적총량(${\mu}s/cm$)으로 [고습조건(RH70%+RH80%)/저습조건(RH20%+RH40%)]의 상대적 비율 분석결과, 고습조건이 저습조건에 비해 이온용출량이 증가하였고, 특히 청자 시료의 경우 그 증가폭이 두드러졌다. 또한 고습조건 시편들의 전기전도도 누적총량을 시료의 물리적 특성과 비교한 결과, 이온용출량은 시료의 흡수율 및 기공률의 증가에 따라 비례하였다. 수중 발굴 도자기는 매장환경의 특성상 염에 의한 물리 화학적 손상 및 2차오염이 크게 우려된다. 따라서 도자기의 이상적인 보존에는 습도변화에 비교적 안정적인 저습조건의 항온항습 수장고가 권장되며, 수장고 설비에 있어 시료의 재질특성에 따른 사전분류가 선행될 필요가 있다.

• 한국구조물진단유지관리공학회 논문집
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• 제17권4호
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• pp.66-74
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• 2013

본 연구에서는 부동태피막형 무기계 방청제와 흡착형 유기계 방청제를 대상으로, 시멘트세공용액을 모사한 포화 수산화칼슘 수용액내에서 염화물이온 농도와 방청성분 몰비를 변수로 하여 Potentiostat을 사용하여 부식전위, 부식속도, 분극저항을 측정하여 방식성능을 평가하였다. 그 결과, 무기계 방청제는 방청몰비 약 1.2 이상에서 방식성능을 확보하는 것으로 나타났고, 유기계 방청제는 방청몰비 약 0.3 이상에서 방식성능을 확보하는 것으로 나타났다. 또한, 부식속도와 분극저항, 부식속도와 부식전위의 관계는 선형 반비례 경향을 나타냈고, 분극저항과 부식전위는 선형 비례하는 것을 알 수 있었으며, 부식전위, 부식속도, 분극저항과의 상관관계는 유기계와 무기계 방청제에서 큰 차이가 없는 것으로 나타났다.

• 열처리공학회지
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• 제9권4호
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• pp.281-288
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• 1996

This study has been investigated the influence of solid solution treatment on the microstructure of Mg-6Al-xZn(x=0,1,2) alloys fabricated by squeeze casting process. The products having clean surface and fine microstructure are fabricated by adopting the liquid metal forging method. The microstructures of as-fabricated state show ${\beta}(Mg_{17}Al_{12})$ precipitates between the dendrite boundaries. It is found that the hardness of the alloys is increased with increasing amount of zinc due to the solid solution hardening effect of zinc. In the changes of microstructure upon solid solution treatment time at $405^{\circ}C$, ${\beta}$ phases are dissolved in ${\alpha}$ matrix up to 1hr and the microstructure are coarsened rapidly after 2hrs. The microhardness are decreased rapidly until 1hr of solution treatment time and then stabilized. From the above results, it is concluded that the optimum solid solution treatment condition for Mg-6Al-xZn alloys is at $405^{\circ}C$ for 1hr. The solution treatment time is greatly reduced comparing to conventional casting(at $385{\sim}418^{\circ}C$ for 10~14hrs) due to the formation of the super-saturated solid solution by liquid metal forging.

• 한국균학회지
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• 제15권4호
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• pp.254-259
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• 1987

4가지 균주의 포자를 4가지의 용액으로 Non-leaching과 Leaching하에서 배양하고 발아율을 조사한 결과 다음과 같다. Non-leaching배양된 Fusarium solani f. sp. pisi의 경우 포자발아율은 pfeffer's solution에서 90%로 가장 낮았으며 Buffer solution에서 99%로 가장 높았다. Leaching배양의 경우 subsoil extract에서 51%로 포자발아가 억제되었고 pfeffer's solution에서 63%로 덜 억제되었다. Non-leaching배양한 Fusarium oxysporum f. sp. cucumerium의 경우 포자발아율은 증류수에서 31%로 가장 적게 억제되었고 Buffer solution에서 45%로 가장 많이 억제되었다. Leaching배양의 경우 Buffer solution에서 17.5%로 가장 억제되었고 증류수에서 25%로 덜 억제되었다. Non-leaching배양한 Helminthosporium sativa의 경우 증류수에서 86.1%로 발아가 낮았고 Buffer solution에서 98%로 높았다. Leaching배양의 경우 Buffer solution에서 47%로 발아가 억제되었고 증류수에서 80.4%로 덜 억제되었다. Non-leaching배양한 Mortierella n. sp.의 경우 발아율은 subsoil extract에서 38.5%로 낮았고 증류수에서 62.5%로 높았다. Leaching배양의 경우 발아율은 증류수에서 15%로 크게 억제되었고 pfeffer's solution에서 37.5%로 덜 억제되었다.

• Nuclear Engineering and Technology
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• 제50권3호
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• pp.432-438
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• 2018

The occurrence of saturation in the CR-39 detector reduces and limits its detection dynamic range; nevertheless, this range could be extended using spectroscopic techniques and by measuring the net bulk rate of the saturated CR-39 detector surface. CR-39 detectors were irradiated by 1.5 MeV high alpha-particle fluence varying from $0.06{\times}10^8$ to $7.36{\times}10^8\;alphas/cm^2$ from Am-241 source; thereafter, they were etched in a 6.25N NaOH solution at a temperature of $70^{\circ}C$ for different durations. Net bulk etch rate measurement of the 1.5 MeV alpha-irradiated CR-39 detector surface revealed that rate increases with increasing etching time and reaches its maximum value at the end of the alpha-particle range. It is also correlated with the alpha-particle fluence. The measurements of UV-Visible (UV-Vis) absorbance at 500 and 600 nm reveal that the absorbance is linearly correlated with the fluence of alpha particles at the etching times of 2 and 4 hour. For extended etching times of 6, 10, and 14.5 hour, the absorbance is saturated for fluence values of $4.05{\times}10^8$, $5.30{\times}10^8$, and $7.36{\times}10^8\;alphas/cm^2$. These new methods pave the way to extend the dynamic range of polymer-based solid state nuclear track detectors (SSNTDs) in measurement of high fluence of heavy ions as well as in radiation dosimetry.