• Title/Summary/Keyword: Saturated adsorption value

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Surface Characterization of Low Temperature Plasma Treated Wool Fiber - The Effect of the Nature of Gas-

  • Kan, C.W.;Chan, K.;Yuen, C.W.M.
    • Fibers and Polymers
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    • v.5 no.1
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    • pp.52-58
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    • 2004
  • Previous investigation results revealed that after the Low Temperature Plasma (LTP) treatment, the hydrophilicity of wool fiber was improved significantly. Such improvement enhances the wool dyeing and finishing processes which might be due to the changes of the wool surface to a more reactive one. In this paper, wool fibers were treated with LTP with different gases, namely, oxygen, nitrogen and gas mixture (25 % hydrogen/75 % nitrogen). Investigations showed that chemical composition of wool fiber surface varied differently with the different plasma gas used. The surface chemical composition of the different LTP-treated wool fibers was evaluated with different characterization methods, namely FTIR-ATR, XPS and saturated adsorption value. The experimental results were thoroughly discussed.

Removal Characteristics of Copper Ion in Wastewater by Employing a Biomass from Liquor Production Process as an Adsorbent (주류 제조과정에서 발생하는 바이오매스를 흡착제로 한 구리 제거 특성)

  • Baek, Mi-Hwa;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.22 no.4
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    • pp.626-631
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    • 2006
  • The adsorption features of copper ion have been investigated by taking the barley residue which occurring from the beer production process as an adsorbent. Under the experimental conditions, adsorption equilibrium of copper ion was attained within 30 minutes after the adsorption started and the adsorption reaction was observed to be first order. As the temperature increased, the adsorbed amount of copper ion at equilibrium was also increased, which indicated that the adsorption reaction was endothermic. Based on the experimental results which obtained by varying the temperatures, several thermodynamic parameters for copper adsorption reaction were estimated. Regarding the electrokinetic behavior of barley residue, its electrokinetic potential was observed to be positive below pH 5 and turned into negative above this pH. In the pH range from 1.5 to 4, copper adsorption was found to be increased, which was well explained by the electrokinetic behavior of barley residue in the pH range. When nitrilotriacetic acid, which is a complexing agent, was coexisted with copper ion, equilibrium adsorption of copper ion was decreased and this was presumed to be due to the formation of metal complex. In addition, the adsorbed amount of copper ion was examined to be increased when $KNO_3$ was coexisted, however, it approached a saturated value above a certain concentration of $KNO_3$.

Work Function Change of W(123) Plane Due to Hydrogen and Deuterium Adsorption at 78K (78K에서 수소 혹은 중수소 흡착으로 인한 W(123)면의 일함수 변화)

  • 박노길;김기석;김성수;정광호;황정남;최대선
    • Journal of the Korean Vacuum Society
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    • v.1 no.1
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    • pp.78-82
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    • 1992
  • The changes in work function due to hydrogen and deuterium adsorption on W(123) plane are measured by means of Field Emission Method. In the case of hydrogen or deuterium adsorption, work function of W(123) plane at 78 K increase and after a maxium value, it decrease and saturated as increasing coverage. After annealing the tungsten emission tip at 200 K, the coverage corresponding to maximum change in work function was shifted toward low coverage and the effect of work function by terraces or steps of which orientation is [ O l l ] was observed.

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Design and Fabrication of MOSFET Type Hydrogen Gas Sensor Using MEMS Process (MEMS 공정기술을 적용한 MOSFET형 수소센서의 설계, 제작에 관한 연구)

  • Kim, Bum Joon;Kim, Jung Sik
    • Korean Journal of Metals and Materials
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    • v.49 no.4
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    • pp.304-312
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    • 2011
  • In this study, MOSFET type micro hydrogen gas sensors with platinum catalytic metal gates were designed, fabricated, and their electrical characteristics were analyzed. The devised MOSFET Hydrogen Sensors, called MHS-1 and -2, were designed with a platinum gate for hydrogen gas adsorption, and an additional sensing part for higher gas sensitivity and with a micro heater for operation temperature control. In the electrical characterization of the fabricated Pt-gate MOSFET (MHS-1), the saturated drain current was 3.07 mA at 3.0 V of gate voltage, which value in calculation was most similar to measurement data. The amount of threshold voltage shift and saturated drain current increase to variation of hydrogen gas concentration were calculated and the hydrogen gas sensing properties were anticipated and analyzed.

Adsorption of methyl 2-benzimidazole carbamate on clay minerals (점토광물(粘土鑛物)에 의(依)한 methyl 2-benzimidazole carbamate의 흡착(吸着))

  • Kim, Bark-Jung;Park, Man;Hur, Nam-Ho;Choi, Jung
    • Applied Biological Chemistry
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    • v.34 no.2
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    • pp.125-129
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    • 1991
  • This experiment was carried out to examine the MBC adsorption on clay minerals by the slurry method. The adsorption of MBC on Kaolinite nearly reached equilibrium after shaking lot 2hrs. but on Bentonite and Zeolite, 10hrs., respectively. The adsorption amount was in the order of Zeolite>Bentonite>Kaolinite, and Na-saturated clay mineral adsorbed more MBC than Mg-saturated clay mineral did. The more the amount of clay minerals, the more MBC was adsorbed by clay minerals, whereas the amount of MBC adsorbed per unit gram of clay minerals reduced and Kd value cf MBC was greatest on the Na-Zeolite. The lower the pH of the water-clay system at each concentration, the more MBC was adsorbed by clay minerals. The pH dependence of the adsorption of MBC may be due to protonation of MBC in acid solution.

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$Co_2$ Corrosion Mechanism of Carbon Steel in the Presence of Acetate and Acetic Acid

  • Liu, D.;Fu, C.Y.;Chen, Z.Y.;Guo, X.P.
    • Corrosion Science and Technology
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    • v.6 no.5
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    • pp.227-232
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    • 2007
  • The corrosion behavior of carbon steel (N80) in carbon dioxide saturated 1%NaCl solution with and without acetic acid or acetate was investigated by weight-loss test, electrochemical methods (polarization curve, Electrochemical impedance spectroscopy). The major objective is to make clear that the effect of acetic acid and acetate on the corrosion of carbon steel in $Co_2$ environments. The results indicate that either acetic acid or acetate accelerates cathodic reducing reaction, facilitates dissolution of corrosion products on carbon steel, and so promotes the corrosion rate of carbon steel in carbon dioxide saturated NaCl solution. All Nyquist Plots are consisting of a capacitive loop in high frequency region, an inductive loop in medial frequency region and a capacitive arc in low frequency region. The high frequency capacitive loop, medial frequency inductive loop and low frequency capacitive arc are corresponding to the electron transfer reaction, the formation/adsorption of intermediates and dissolution of corrosion products respectively. All arc of the measured impedance reduced with the increase of the concentration of Ac-, especially HAc. However, the same phenomenon is not notable after reducing pH value by adding HCl. HAc is a stronger proton donor and can be reduced directly by electrochemical reaction firstly. Ac- can't participate in electrochemistry reaction directly, but $Ac^-$ an hydrate easily to create HAc in carbon dioxide saturated environments. HAc is as catalyst in $Co_2$ corrosion. As a result, the corrosion rate was accelerated in the presence of acetate ion even pH value of solution increased.

Characteristics of a Filter Module Adsorption for Fine Dust Removal on Road (도로 미세먼지 저감을 위한 필터 모듈의 흡착 특성)

  • Lee, Jai Yeop;Kim, Ilho
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.1
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    • pp.19-25
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    • 2017
  • In this study, a electrostatic filter which could be applicable to road environment was developed and evaluated in adsorption capacity. The evaluation were performance for removal by particle size and adsorption amount by pressure using ASERAE 52.1 and 52.2. The range of size for removal test was $0.3{\mu}m{\sim}10.0{\mu}m$ which had 12 steps. The filter showed 91.3% removal efficiency from $2.5{\mu}m$ and under the size, average 53.5% proportional to decreasing size value. The weight removal was 96.7% from 22.6 mmaq, initial pressure to 35 mmaq, end pressure with $715.9g/m^2$, the adsorption amount. The shape of isotherm was expressed as Langmuir's one. After washing saturated filter with dust to end pressure, the initial pressure and adsorption amount of the filter showed a light drop with no removal efficiency decline.