• Title/Summary/Keyword: Salt transport

Search Result 160, Processing Time 0.022 seconds

Poly(vinyl alcohol) based Solid Polymer Electrolyte with Fast Cationic Transport Process

  • Jo, Yun-Kyung;Lee, Yu-Jin;Jo, Nam-Ju
    • Proceedings of the Polymer Society of Korea Conference
    • /
    • 2006.10a
    • /
    • pp.187-187
    • /
    • 2006
  • A new type solid polymer electrolyte (SPE) composed of poly (vinyl alcohol) (PVA) and lithium trifluoromethanesulfonate ($LiCF_{3}SO_{3}$) was prepared by means of the solution cast technique to observe that Li ion can move by ion hopping decoupled from polymer segmental motion inside of the 'fast cationic transport process'. The highest ion conductivity of the SPEs obtained from ac impedance measurements was $1.42{\times}10^{-3}S/cm$ at room temperature for SPE with 80wt% of salt concentration. Using LSV, we found that the SPEs had good electrochemical stabilities and using FT-IR and AFM, we found the formation of network-like structure.

  • PDF

Electrochemical Properties of Polypyrrole Enzyme Electrode Immobilized Glucose Oxidase with Different Ligand (포도당 산화효소를 고정화한 Polypyrrole 효소전극의 배위자 변화에 다른 전기화학적 특성)

  • Kim, Hyun-Cheol;Gu, Han-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.11b
    • /
    • pp.529-532
    • /
    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/ AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-TS Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

  • PDF

Organic Pollutant Transport in Unsaturated Porous Media by Atmospheric Breathing Processes( I ) - Partition Coefficient -

  • Ja-Kong;Lim, Jae-Shin;Do, Nam-Young
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 1996.11a
    • /
    • pp.50-53
    • /
    • 1996
  • This paper reports the experimental results for the determination of the overall partition coefficient of VOCs in unsaturated soil, A chromatographic method was used for the determination of gaseous partition coefficients to natural soil under various water content conditions. The equilibrium vapor pressure of water over saturated salt solution was used to fix the relative humidity of the air and control the water content of the soil systems. The transport behavior was studied for dichloromethane, trichloroethane and dichlorobenzene pollutants, with log octanol-water partition coefficients(log $K_{ow}$ ) which range from 1.25 to 3.39, or water to soil partitioning which varies by 135 times; water solubility constants which vary by 3 times; and vapor pressures which range from 1 to 362 torr. Water content of the soil had a pronounced effect on the effective partition coefficient(between gas and soil + water stationary phase) as well as on the effective dispersion coefficient.

  • PDF

Electrochemical Properties of Polypyrrole Enzyme Electrode Immobilized Glucose Oxidase with Different Ligand (포도당 산화효소를 고정화한 Polypyrrole 효소전극의 배위자 변화에 따른 전기화학적 특성)

  • 김현철;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.11a
    • /
    • pp.529-532
    • /
    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-75, the redox potential was about -0.3 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-TS Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a tent of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

  • PDF

UPHILL TRANSPORT PHENOMENA THROUGH LIQUID SEPARATION MEMBRANE

  • 양원강
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 1993.10a
    • /
    • pp.59-60
    • /
    • 1993
  • 막을 도구로 하여 물가등(Ion, Molecular)의 선택 분리 및 정제과정법에 대한 연구는 눈부신 발전을 가져 왔다. 콜로디온 막으로 투석과 한외 여과법이 나온 이래 1950년대 Juda의 연구 이온 교환법의 보고 후 전기투석법에 의한 바닷물의 담수화 농축 방법이 개발되고 Soeb, Sourirajan의 초산 셀루로즈 막의 보고는 Salt의 배제율이 높은 베막 법이 소개 된 후에 다양한 막의 응용법이 전개되었다. 막소제, 제막법, 고 분리기능막, 막형태, 얇은막, 막장치에 이르기 까지 막학 연구의 관심을 모아졌다.

  • PDF

The Movement of the Cold Water in the Korea Strait

  • Lim, Du Byung
    • 한국해양학회지
    • /
    • v.8 no.1
    • /
    • pp.46-52
    • /
    • 1973
  • From available data, the movement of the cold water in the Korea Strait was investigated. The cold water forms an undercurrent with a speed of 0.10knots near Ulgi in June. Sometimes it reaches a speed of 0.35knots. The cold water forms a sharp wdege in the western channel like a salt wedge in an estuary. The calculated volume transport of the cold water is 17,135 cubic meters per second in June. The external influences are also discussed.

  • PDF

Analysis of AM and AEM Oxides Behavior in a SF Electrolytic Reduction Process (사용후핵연료 전기환원 공정에서의 알카리, 알카리토 금속 산화물들의 거동 분석)

  • 박병흥;강대승;서중석;박성원
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 2004.06a
    • /
    • pp.268-277
    • /
    • 2004
  • process (ACP), electrochemical properties of high heat-generating alkali and alkali earth oxides in molten salt were measured and the behavior of those elements were analyzed. The reduction potentials of Cs, Sr, and Ba in a molten LiCl-$Li_2O$ system were more cathodic than that of Li and closely located one another. Thus, it is expected that the alkali and alkali earth would not hinder the reaction mechanism which is via lithium reduction. Alkali and alkali earth metals are likely to recycle into molten salt when the process is operated beyond metal reduction potentials and the effect of electric current on the mass transport is also determined by measuring the metal concentrations in the molten salt phase at different current conditions.

  • PDF

Stress responses of coho salmon, Oncorhpchus kisutch, to transport in fresh water or salt water (담수 및 염수 수송이 은연어의 스트레스 반응에 미치는 영향)

  • JEON Joong-Kyun;KIM Pyong-Kih;PARK Yong-Joo;MYOUNG Jung-Goo;KIM Jong-Man
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.33 no.2
    • /
    • pp.119-123
    • /
    • 2000
  • To study the stress response of coho salmon (Oncorhpohus kisutch) during transportation, the stress responses of the fish confined in a container box filled with freshwater or $5{\%{\circ}}$ salt-water were monitored pre and post 10 hours transportation. Changes of cortisol as the first stress indicator, and glucose (GLC), lactate (LAC), triglyceride (TG), cholesterol (CHOL), sodium ($Na^+$), chloride ($Cl^-$), alanine aminotransferase (ALT), aspartate aminotransferase (AST) and lactate dehydrogenase (LDH) as the second stress indicators were compared between the fish in two hauling media. Results showed significantly lower levels of cortisol, GLC, LAC, TG, CHOL and AST in salt-water group than freshwater group, It was shown that using salt-water for transportation could lessen the stress level of the coho salmon.

  • PDF

PVDF/h-BN hybrid membranes and their application in desalination through AGMD

  • Moradi, Rasoul;Shariaty-Niassar, Mojtaba;Pourkhalili, Nazila;Mehrizadeh, Masoud;Niknafs, Hassan
    • Membrane and Water Treatment
    • /
    • v.9 no.4
    • /
    • pp.221-231
    • /
    • 2018
  • A new procedure to produce poly(vinylidene fluoride)/boron nitride hybrid membrane is presented for application in membrane distillation (MD) process. The influence of hexagonal boron nitride (h-BN) incorporation on the performance of the polymeric membranes is studied through the present investigation. For this aim, h-BN nanopowders were successfully synthesized using the simple chemical vapor deposition (CVD) route and subsequent solvent treatments. The resulting h-BN nanosheets were blended with poly(vinylidene fluoride) (PVDF) solution. Then, the prepared composite solution was subjected to phase inversion process to obtain PVDF/h-BN hybrid membranes. Various examinations such as scanning electron microscopy (SEM), wettability, permeation flux, mechanical strength and liquid entry pressure (LEP) measurements are performed to evaluate the prepared membrane. Moreover, Air gap membrane distillation (AGMD) experiments were carried out to investigate the salt rejection performance and the durability of membranes. The results show that our hybrid PVDF/h-BN membrane presents higher water permeation flux (${\sim}18kg/m^2h$) compared to pristine PVDF membrane. In addition, the experimental data confirms that the prepared nanocomposite membrane is hydrophobic (water contact angle: ${\sim}103^{\circ}$), has a porous skin layer (>85%), as well competitive fouling resistance and operational durability. Furthermore, the total salt rejection efficiency was obtained for PVDF/h-BN membrane. The results prove that the novel PVDF/h-BN membrane can be easily synthesized and applied in MD process for salt rejection purposes.