• Title/Summary/Keyword: Salt transport

Search Result 159, Processing Time 0.028 seconds

Effects of chloride ion transport characteristics and water pressure on mechanical properties of cemented coal gangue-fly ash backfill

  • Dawei Yin;Zhibin Lu;Zongxu Li;Chun Wang;Xuelong Li;Hao Hu
    • Geomechanics and Engineering
    • /
    • v.38 no.2
    • /
    • pp.125-137
    • /
    • 2024
  • In paste backfill mining, cemented coal gangue-fly ash backfill (CGFB) can effectively utilize coal-based solid waste, such as gangue, to control surface subsidence. However, given the pressurized water accumulation environment in goafs, CGFB is subject to coupling effects from water pressure and chloride ions. Therefore, studying the influence of pressurized water on the chlorine salt erosion of CGFB to ensure green mining safety is important. In this study, CGFB samples were soaked in a chloride salt solution at different pressures (0, 0.5, 1.5, and 3.0 MPa) to investigate the chloride ion transport characteristics, hydration products, micromorphology, pore characteristics, and mechanical properties of CGFB. Water pressure was found to promote chloride ion transfer to the CGFB interior and the material hydration reaction; enhance the internal CGFB pore structure, penetration depth, and chloride ion content; and fill the pores between the material to reduce its porosity. Furthermore, the CGFB peak uniaxial compression strain gradually decreased with increasing soaking pressure, whereas the uniaxial compressive strength first increased and then decreased. The resulting effects on the stability of the CGFB solid-phase hydration products can change the overall CGFB mechanical properties. These findings are significant for further improving the adaptability of CGFB for coal mine engineering.

Improvement of K+ and Na+ Ion homeostasis and salt tolerance by Co-inoculation of arbuscular mycorrhizal fungi (AMF) and spore associated bacteria (SAB)

  • Selvakumar, Gopal;Kim, Kiyoon;Roy, C. Aritra;Jeon, Sunyong;Sa, Tongmin
    • Proceedings of the Korean Society of Crop Science Conference
    • /
    • 2017.06a
    • /
    • pp.246-246
    • /
    • 2017
  • Salinity inhibits plant growth and restricts the efficiency of arbuscular mycorrhizal fungi. The selective uptake of nutrients from the soil and their effective transport to host roots make it essential for plant growth and development under salt stress. AMF spore associated bacteria shown to improve mycorrhizal efficiency under stress. Thus, this study aimed to understand the co-inoculation efficiency of AMF and SAB on maize growth and ion homeostasis under salt stress. Two AMF strains and one SAB were inoculated with maize either alone or in combination with one another. The results of our study showed that AMF and SAB co-inoculation significantly improved dry weight and nutrient uptake of maize under salt stress. Co-inoculation significantly reduced proline accumulation in shoots and Na+ accumulation in roots. Co-inoculation treatment also exhibited the high K+/Na+ ratios in roots at 25 mM NaCl. Mycorrhizal colonization showed positive influence for regulation of ZmAKT2, ZmSOS1 and ZmSKOR gene expressions, contributing to K+ and Na+ ion homeostasis. CLSM view showed that SAB were able move and localize into inter and intra cellular spaces of maize roots. In addition, CLSM view of AMF spores showed that gfp-tagged SAB also associated on the spore outer hyaline layer.

  • PDF

Water and Salt Budgets for the Yellow Sea

  • Lee, Jae-Hak;An, Byoung-Woong;Bang, Inkweon;Hong, Gi-Hoon
    • Journal of the korean society of oceanography
    • /
    • v.37 no.3
    • /
    • pp.125-133
    • /
    • 2002
  • Water and salt budgets in the Yellow Sea and Bohai are analyzed based on the historical data and CTD data collected recently using box models. The amounts of volume transport and of water exchange across the boundary between the Yellow and East China Seas are estimated to be 2,330-2,840 $\textrm{km}^3$/yr and 109-133 $\textrm{km}^3$/yr, respectively, from the one-layer box model. Corresponding water residence time is 5-6 years. In the Bohai, water residence time is twice as long as that in the Yellow Sea, suggesting that the Yellow Sea and Bohai cannot be considered as a single system in the view of water and salt budgets. The results indicate that water and salt budgets in the Yellow Sea depend almost only on the water exchange between the Yellow and East China Seas. The computation with the coupled two-layer model shows that water residence time is slightly decreased to 4-5 years for the Yellow Sea. In order to reduce uncertainties for the budgeting results the amount of the discharge from the Changjiang that enters into the Yellow Sea, the vertical advection and vertical mixing fluxes across the layer interface have to be quantified. The decreasing trend of the annual Yellow River outflow is likely to result that water residence time is much longer than the current state, especially for the Bohai. The completion of the Three Gorges dam on the Changjiang may be change the water and salt budgets in the Yellow Sea. It is expected that cutting back the discharge from the Changjiang by 10% through the dam would increase water residence time by about 10%.

Salt treatment for recovery of the mud loach, Misgurnus mizolepis from transport stress

  • Yu, Jin-Ha;Kim, Dae-Hyun;Han, Jung-Jo;Park, Sung-Woo
    • Korean Journal of Veterinary Research
    • /
    • v.56 no.4
    • /
    • pp.215-221
    • /
    • 2016
  • Due to the shortage of the fingerling/juvenile mud loach, Misgurnus mizolepis in Korea, these fish have been imported from China. However, the mortality rate during and after their transportation is very high. In this study, we examined various physiological and histological parameters to evaluate the effect of salt treatment on the survival and recovery of mud loaches in holding farms during the quarantine process. Glucose, osmolality, $Na^+$, $Cl^-$, and histological changes were assessed for three different salinities. Non-treated fish (control 0.0%) exhibited lower levels of osmolality, and $Na^+$ and $Cl^-$ concentrations compared with those kept in solar salt solution (0.5% and 1.0%). Glucose levels in control fish were higher than those in fish exposed to 0.5% and 1.0% solar salt solution. Histologically, control fish showed thinner epidermis of skin, branchial hyperplasia and lamellar fusion with an abundance of eosinophilic granule cell-like cells. After solar salt solution treatment, damaged gill structures in the fish almost recovered within 5 days. The present study demonstrates that mud loaches transported from China suffer from skin and gill damage and physiological dysfunction which may increase the mortality and morbidity. Moreover, saline treatment might alleviate the stress responses and ionic/osmotic imbalances, and help heal gill damage.

Expression analysis and characterization of rice oligopeptide transport gene (OsOPT10) that contributes to salt stress tolerance

  • Jung, Yu-Jin;Lee, In-Hye;Han, Kyung-Hee;Son, Cho-Yee;Cho, Yong-Gu;Lee, Myung-Chul;Kang, Kwon-Kyoo
    • Journal of Plant Biotechnology
    • /
    • v.37 no.4
    • /
    • pp.483-493
    • /
    • 2010
  • Knock-out of a gene by insertional mutagenesis is a direct way to address its function through the mutant phenotype. Among ca. 15,000 gene-trapped Ds insertion lines of rice, we identified one line from selected sensitive lines in highly salt stress. We conducted gene tagging by TAIL-PCR, and DNA gel blot analysis from salt sensitive mutant. A gene encoding an oligopeptide transporter (OPT family) homologue was disrupted by the insertion of a Ds transposon into the OsOPT10 gene that was located shot arm of chromosome 8. The OsOPT10 gene (NP_001062118.) has 6 exons and encodes a protein (752 aa) containing the OPT family domain. RT-PCR analysis showed that the expression of OsOPT10 gene was rapidly and strongly induced by stresses such as high-salinity (250 mM), osmotic, drought, $100\;{\mu}M$ ABA. The subcellular localization assay indicated that OsOPT10 was localized specifically in the plasma membrane. Overexpression of OsOPT10 in Arabidopsis thaliana and rice conferred tolerance of transgenic plants to salt stress. Further we found expression levels of some stress related genes were inhibited in OsOPT10 transgenic plants. These results suggested that OsOPT10 might play crucial but differential roles in plant responses to various abiotic stresses.

Concentration Variations of Trace Elements in Gosan, Jeiu During the Polluted Period in November 2001 and the Yellow Sand Period in Spring 2002 (2001년 11월 오염시기와 2002년 봄 황사시기 제주도 고산에서의 미량원소 농도 변화)

  • Han J.S;Ghim Y.S;Moon K.J;Ahn J.Y;Kim J.E;Ryu S.Y;Kim Y.J;Kong B.J;Lee S.J
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.20 no.2
    • /
    • pp.143-151
    • /
    • 2004
  • The chemical composition of PM$_{2.5}$ was measured at Gosan, Jeju for two weeks each in November 2001 and spring 2002. In the latter part of the measurement period of November 2001, designated as the polluted period in this work, secondarily formed ion components as well as primarily emitted elemental carbon were high. PM$_{2.5}$ mass concentration was also high in this polluted period compared with the yellow sand period, in which daily average of PM $_{10}$ peaked up to 520 $\mu\textrm{g}$/㎥. Increase of major components of anthropogenic origin in the polluted period was not correlated with the variation in sea salt components while increase of crustal components in the yellow sand period was highly correlated with the variation in sea salt components. Trace elements were generally higher in the yellow sand period; however, toxic heavy metals such as zinc, cadmium and lead were the highest in the polluted period.d.d.d.

FT-Raman Studies on Ionic Interactions in ${\pi}$-Complexes of Poly(hexamethylenevinylene) with Silver Salts

  • Kim Jong-Hak;Min Byoung-Ryul;Won Jong-Ok;Kang Yong-Soo
    • Macromolecular Research
    • /
    • v.14 no.2
    • /
    • pp.199-204
    • /
    • 2006
  • Remarkably high and stable separation performance for olefin/paraffin mixtures was previously reported by facilitated olefin transport through ${\pi}$-complex membranes consisting of silver ions dissolved in poly(hexamethylenevinylene) (PHMV). In this study, the ${\pi}$-complex formation of $AgBF_4,\;AgClO_4\;and\;AgCF_{3}SO_3$ with PHMV and their ionic interactions were investigated. FT-Raman spectroscopy showed that the C=C stretching bands of PHMV shifted to a lower frequency upon incorporation of silver salt, but the degree of peak shift depended on the counter-anions of salt due to different complexation strengths. The symmetric stretching modes of anions indicated the presence of only free ions up to [C=C]:[Ag]=1:1, demonstrating the unusually high solubility of silver salt in PHMV. Above the solubility limit, the ion pairs and higher-order ionic aggregates started to form. The coordination number of silver ion for C=C of PHMV was in the order $AgBF_4$ > $AgClO_4$ > $AgCF_{3}SO_3$, but became similar at [C=C]:[Ag]=1:1. The different coordination number was interpreted in terms of the different transient crosslinks of silver cations in the complex, which may be related to both the interaction strength of the polymer/silver ion and the bulkiness of the counteranion.

Transport Rate of Transition Metal Cations through a Bulk Liquid Membrane Containing $NtnOenH_4$ and $NdienOenH_4$ as Carriers (운반체로 $NtnOenH_4$$NdienOenH_4$를 포함한 액체막을 통한 전이금속 양이온의 운반속도)

  • Kim, Hae Joong;Chang, Jeong Ho;Shin, Young Kook
    • Journal of the Korean Chemical Society
    • /
    • v.41 no.2
    • /
    • pp.77-81
    • /
    • 1997
  • The transport rates of transition metal cations were increased in order of Ni(II)$(NtnOenH_4)$and 1,12,15-triaza-3,4;9,10-dibenzo-5,8-dioxacyclo-heptadecane$(NdienOenH_4)$as carriers. The transport rates of transition metal cations was found to be of first order to the salt concentrations. It was also found that the dissociation process in the transport process is rate determining step. From the measurements of the transport rates at various temperatures, the partition free energies of hydration$({\Delta}G_p)$for the transition metal cations were calculated. The results showed that the order of transport rates of transition metal cations was found to be proportional to the magnitudes of negative value of the partition free energies of hydration$({\Delta}G_p)$.

  • PDF

Electrochemical Properties of Polypyrrole-Glucose Oxidase Enzyme Electrode Depending on Dopant Size (Polypyrrole-Glucose Oxidase 효소전극의 배위자 크기에 따른 전기 화학적 특성)

  • 김현철;구할본;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.07a
    • /
    • pp.745-748
    • /
    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-T S. Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

  • PDF

Poly(vinyl alcohol) based Solid Polymer Electrolyte with Fast Cationic Transport Process

  • Jo, Yun-Kyung;Lee, Yu-Jin;Jo, Nam-Ju
    • Proceedings of the Polymer Society of Korea Conference
    • /
    • 2006.10a
    • /
    • pp.187-187
    • /
    • 2006
  • A new type solid polymer electrolyte (SPE) composed of poly (vinyl alcohol) (PVA) and lithium trifluoromethanesulfonate ($LiCF_{3}SO_{3}$) was prepared by means of the solution cast technique to observe that Li ion can move by ion hopping decoupled from polymer segmental motion inside of the 'fast cationic transport process'. The highest ion conductivity of the SPEs obtained from ac impedance measurements was $1.42{\times}10^{-3}S/cm$ at room temperature for SPE with 80wt% of salt concentration. Using LSV, we found that the SPEs had good electrochemical stabilities and using FT-IR and AFM, we found the formation of network-like structure.

  • PDF