• Title/Summary/Keyword: SUN: UV

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Quercetin과 (+)-Catechin의 카드뮴(II)에 대한 착물반응 (Complexation Studies for Cadmium (II) with Quercetin and (+)-Catechin)

  • 이정호;신선우;백승화
    • 약학회지
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    • 제53권6호
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    • pp.342-350
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    • 2009
  • The interaction of cadmium (II) ion with quercetin and (+)-catechin was investigated in aqueous solution at various pH. The flavonoid/cadmium stochiometries for cadmium (II) binding to quercetin and (+)-catechin have been determined by UV-vis spectroscopy. 1 : 1 Cd (II)-Flavonoid complex had a maximum absorbance and showed the bathochromic shift of the long-wavelength band of the UV-vis spectra in the alkaline pH, that occurs upon complexation, due to a ligandto-metal charge transfer. These results suggest that Cd (II)-flavonoid complex has the optimal condition of chelation in 0.2 M $NH_3$ - 0.2 M $NH_4Cl$ (pH 8.0) solution.

광 가교성 폴리이미드의 광배향 특성 (The Characteristics of Photo-alignment with Photo-crosslinkable Polyimide)

  • 신동명;조선주;손병청;최정우;이미혜;최길영
    • 한국응용과학기술학회지
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    • 제16권1호
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    • pp.15-20
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    • 1999
  • Photo-crosslinkable polyimide(PI) which contains CF3 moiety was synthesized. Polarized UV light transformed ketone group of PI to hydroxyl group, which was confirmed by IR and UV-visible spectroscopy. We investigated the dichroic UV-absorption before and after photo-reaction with linearly polarized light. In particular we have attempted to clarify the relationship between the anisotropy of surface region and surface azimuthal anchoring energy and knew that the anchoring energy of photo-alignment PI is comparable with that of mechanical rubbing.

ZnO를 사용한 MOS 커패시터의 제작 조건에 따른 특성 변화 (Property Variations of ZnO-based MOS Capacitor with Preparation Conditions)

  • 남형진
    • 반도체디스플레이기술학회지
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    • 제9권3호
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    • pp.75-78
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    • 2010
  • In this study we investigated the electrical properties of ZnO-based MOS capacitor with $HfO_2$ as the gate dielectric. MIM capacitor, which uses either $HfO_2$ or $Al_2O_3$ as the dielectric layer, is also studied to understand the dependency of the dielectrics on the preparation conditions. It was found that thinner $HfO_2$ films yield better electrical properties, namely lower leakage current and higher breakdown electric field. These properties were observed to deteriorate when subsequently annealed. Capacitance in the depletion region of MOS capacitor was found to increase with UV ozone treatment time up to 60min. However, when the treatment time was extended to 120min, the trend is reversed. The 'threshold voltage' was also observed to positively shift with UV ozone treatment time up to 60min. The shift apparently saturated for longer treatment.

DPSS UV Laser와 습식 식각을 이용한 금형강 미세 가공 (Micromachining for plastic mold steel using DPSS UV laser and wet etching)

  • 민경익;김재구;조성학;최두선;황경현
    • 한국레이저가공학회지
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    • 제12권3호
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    • pp.1-6
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    • 2009
  • This paper describes the method for the fabrication of micro dot array on a plastic mold steel using DPSS (diode pumped solid-states) UV laser and wet etching process. We suggest the process of the ablation of a photoresist (PR) coated on plastic mold steel and wet etching process using solutions of various concentrations of $FeCl_3$, $HNO_3$ in water as etchant. This method makes it possible to fabricate metallic roller mold because the microstructures are directly fabricated on the metal surface. In the range of operating conditions studied, $17\;{\mu}J$ laser pulse energy and 50 ms laser exposure time, an etchant containing 40wt% $FeCl_3$, 5wt% $HNO_3$ and etch time for 45 s gave the $10\;{\mu}m$ of micro dot pattern on plastic mold steel.

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Quantitative Analyses for the Quality Evaluation of Salviae Miltiorrhizae Radix by HPLC

  • Fang, Zhe;Moon, Dong-Cheul;Son, Kun-Ho;Son, Jong-Keun;Min, Byung-Sun;Woo, Mi-Hee
    • Natural Product Sciences
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    • 제16권4호
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    • pp.251-258
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    • 2010
  • In this study, quantitative analysis for the quality evaluation of Salviae Miltiorrhizae Radix using HPLC/UV was developed. For quantitative analysis, six major bioactive compounds were determined. The separation conditions employed for HPLC/UV were optimized using ODS $C_{18}$ column ($250{\times}4.6\;mm$, $5\;{\mu}m$) with gradient condition of A (1% formic acid in $H_2O$) and B (acetonitrile : methanol : formic acid = 100 : 75 : 1) as the mobile phase at a flow rate of 1.0 mL/min and a detection wavelength of 280 nm. These methods were fully validated with respect to the linearity, accuracy, precision and recovery. The HPLC/UV method was applied successfully to the quantification of six major compounds in the Salviae Miltiorrhizae Radix. The results indicate that the established HPLC/UV method is suitable for the quantitative analysis.

UV법에 의한 안정화 이산화염소 원액 성분 특성에 관한 연구 (A study on the characteristics of the components of stabilized chlorine dioxide by UV method)

  • 김호순;안창진;윤제용;이상덕
    • 상하수도학회지
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    • 제11권2호
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    • pp.105-111
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    • 1997
  • Chlorine dioxide is being used to control THMs formation or taste & odor in water treatment plant. Recently, some operators or academic circles doubted the effectiveness of stabilized chlorine dioxide which is presumed as a liquid form of chlorine dioxide. In this study, we investigated components which consist of stabilized chlorine dioxide in terms of chlorine dioxide and chlorite. Two analytical methods used in this study are UV method and Iodometric method. Iodometric method is recommended by Korean EPA to check the purity of stabilized chlorine dioxide. The samples of stabilized chlorine dioxide from four water treatments were investigated and compared with that produced from chlorine dioxide generator on-site. This study demonstrated that the component of stabilized chlorine dioxide was overwhelmingly chlorite (${ClO_2}^-$) not chlorine dioxide ($ClO_2$) by UV method. It was also proved that Iodometric method (2nd method) recommended by Korean EPA could not differentiate between $ClO_2$ and ${ClO_2}^-$. Iodometric method (2nd method) recommended by Korean EPA should be revised accordingly to measure chlorine dioxide properly.

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살충제 Carbofuran의 수중광분해 (Aqueous Photolysis of the Organophosphorus Insecticide Carbofuran)

  • 김균;김용화
    • 한국환경농학회지
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    • 제21권3호
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    • pp.172-177
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    • 2002
  • 살충제 carbofuran의 수중 광분해 실험을 미국 EPA 및 OECD 방법으로 수행하였다. Carbofuran은 자연광을 흡수하지 않는 화합물이지만, 야외에서 증류수로 수행한 광분해시험 결과 반감기가 9.7일, SUNTEST에서 3.4일, SUNTEST의 UV하에서 1시간으로 신속한 광분해가 일어남을 확인하였다. 특히 논물에서는 SUNTEST에서의 반감기가 14시간으로 증류수 보다 약 6배 가속화되었으며, 살균한 논물보다는 비살균 논물에서의 광분해가 다소 빠르게 일어났다. 이와 같은 결과로 볼 때 carbofuran의 경우 수도작 상황에서 sensitizer 등에 의한 간접 광분해의 가능성이 있음을 확인하였다.

가시광선, 자외선과 적외선에 대한 학생들의 개념 (Korean Secondary Students' Conceptions about Visible light, Ultra Violet and Infrared Ray)

  • 한신;박태윤
    • 대한지구과학교육학회지
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    • 제8권1호
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    • pp.35-44
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    • 2015
  • The purpose of this paper is to identify the conceptions of middle school and high school students about visible light, Ultra violet(UV) and Infrared ray(IR). We administered questionnaire 40 people of middle school 3rd students and 43 people of high school 2nd students in Gyeonggi-do. Misconceptions about visible light, UV and Ir were observed in many students. The results of study are as follows: Firstly, Many students think that it is possible to see objects without visible light. The explanations given by students for the visiblity of objects in darkness indicates a heavy reliance on personal experiences. Secondly, we have confirmed that high school students well understand the fact that the object reflects the light. However, a significant number of students exhibited an eye-centered perspective of vision. Thirdly, students had a variety of ideas about the meaning of the term UV and IR. Analysis of questionnaire data indicates that many students believe that it is possible to see objects in the presence of UV light alone.

자외선 경화형 폴리우레탄 아크릴레이트 수지의 반응성 희석제 함량에 따른 물성 연구 (Study on the Properties of UV-curable Polyurethane acrylate with reactive diluents content)

  • 심재학;서은선;이원영;김구니
    • 접착 및 계면
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    • 제18권4호
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    • pp.159-165
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    • 2017
  • 본 연구에서는 반응성 희석제로 사용되는 BA의 함량에 따른 자외선 경화형 폴리우레탄 아크릴레이트 수지를 제조하여 수지의 열적 기계적 성질, 접착강도, 굴곡성을 확인하였다. BA의 함량이 40% 이상으로 증가할수록 Polyol의 Tg와 아크릴 수지의 Tg가 분리되어 나타난 것을 DSC로 통해 확인하였다. 또한 BA의 함량이 증가할수록 아크릴 수지의 낮은 기계적인 물성이 주도적으로 발현되어 인장강도와 신장률, 접착강도가 감소하는 것으로 나타났다. 굴곡성을 평가한 결과 BA의 함량이 40%인 경우 경도가 낮으면서 다른 수지에 비해 Tm이 낮아 굴곡성이 우수한 것으로 나타났다.

Quantitative and Pattern Recognition Analyses for the Quality Evaluation of Cimicifugae Rhizoma by HPLC

  • Fang, Zhe;Moon, Dong-Cheul;Son, Kun-Ho;Son, Jong-Keun;Min, Byung-Sun;Woo, Mi-Hee
    • Bulletin of the Korean Chemical Society
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    • 제32권1호
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    • pp.239-246
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    • 2011
  • In this study, quantitative and pattern recognition analysis for the quality evaluation of Cimicifugae Rhizoma using HPLC/UV was developed. For quantitative analysis, three major bioactive phenolic compounds were determined. The separation conditions employed for HPLC/UV were optimized using ODS $C_{18}$ column ($250{\times}4.6mm$, $5{\mu}M$) with isocratic elution of acetonitrile and water with 0.1% phosphoric acid as the mobile phase at a flow rate of 1.0 mL/min and a detection wavelength of 323 nm. These methods were fully validated with respect to the linearity, accuracy, precision, recovery, and robustness. The HPLC/UV method was applied successfully to the quantification of three major compounds in the extract of Cimicifugae Rhizoma. The HPLC analytical method for pattern recognition analysis was validated by repeated analysis of twelve reference samples corresponding to five different species of Cimicifugae Rhizoma and seventeen samples purchased from markets. The results indicate that the established HPLC/UV method is suitable for the quantitative analysis and quality control of multi-components in Cimicifugae Rhizoma.