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Morphology-Controlled Fabrication of ZnS Nanostructures with Enhanced UV Emission

  • Kim, Yeon-Ho;Jang, Du-Jeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.587-587
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    • 2013
  • ZnS is well-known direct band gap II-VI semiconductor, and it attracts intense interest due to its excellent properties of luminescence which enable ZnS to have promising materials for optical, photonic and electronic devices. Especially, the emission wavelength of ZnS falls in the UV absorption band of most organic compoundsand biomolecules, thus it is envisaged that ZnS based devices may find applications in increasingly important fluorescence sensing. We have developed a facile and effective one-step process for the fabrication of single-crystalline and pure-wurtzite ZnS nanostructures possessing sharp band-edge emission at room-temperature having diverse length-to-width ratios. Each of nanostructures was composed of chemically pure, structurally uniform, single-crystalline, and defect-free ZnS. These features not only suppress trap or surface states emission centered at 420 nm, but also enhance UV band-edge emission centered at 327 nm, which give as-synthesized our ZnS nanostructures possible sharp UV emission at room temperature. The reaction medium consisting of mixed solvents such as hydrazine, ethylenediamine, and water as well as proper reaction time and temperature have played an important role in the crystallinity and optical properties of ZnS nanostructures. As-synthesized our ZnS nanostructures possessing sharp UV emission guarantee high potential for both fundamental research and technological applications.

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Mcl-PHAs Produced by Pseudomonas sp. Gl01 Using Fed-Batch Cultivation with Waste Rapeseed Oil as Carbon Source

  • Mozejko, Justyna;Wilke, Andreas;Przybylek, Grzegorz;Ciesielski, Slawomir
    • Journal of Microbiology and Biotechnology
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    • v.22 no.3
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    • pp.371-377
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    • 2012
  • The present study describes medium-chain-length polyhydroxyalkanoates (mcl-PHAs) production by the Pseudomonas Gl01 strain isolated from mixed microbial communities utilized for PHAs synthesis. A two-step fed-batch fermentation was conducted with glucose and waste rapeseed oil as the main carbon source for obtaining cell growth and mcl-PHAs accumulation, respectively. The results show that the Pseudomonas Gl01 strain is capable of growing and accumulating mcl-PHAs using a waste oily carbon source. The biomass value reached 3.0 g/l of CDW with 20% of PHAs content within 48 h of cultivation. The polymer was purified from lyophilized cells and analyzed by gas chromatography (GC). The results revealed that the monomeric composition of the obtained polyesters depended on the available substrate. When glucose was used in the growth phase, 3-hydroxyundecanoate and 3-hydroxydodecanoate were found in the polymer composition, whereas in the PHAs-accumulating stage, the Pseudomonas Gl01 strain synthesized mcl-PHAs consisting mainly of 3-hydroxyoctanoate and 3-hydroxydecanoate. The transcriptional analysis using reverse-transcription real-time PCR reaction revealed that the phaC1 gene could be transcribed simultaneously to the phaZ gene.

Harmonic Identification Algorithms Based on DCT for Power Quality Applications

  • Yepes, Alejandro G.;Freijedo, Francisco D.;Doval-Gandoy, Jesus;Sanchez, Oscar Lopez;Fernandez-Comesana, Pablo;Alvarez, Jano Malvar
    • ETRI Journal
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    • v.32 no.1
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    • pp.33-43
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    • 2010
  • The increasing demand for non-sinusoidal currents affects the quality of distribution networks. Harmonic detection is a crucial step in the cancellation of those components by active power filters. In this paper, the discrete cosine transform (DCT) is compared with different implementations based on Fourier transforms, demonstrating their equivalences and the advantages provided by the former. We demonstrate that the phase error in the presence of grid frequency deviations and the transient length are reduced by half in comparison to the discrete Fourier transform. A novel algorithm is developed to provide frequency adaptation to the DCT, taking advantage of its good features. The window width is adjusted in real time according to the actual value of the grid fundamental frequency by means of a phase-locked loop. A technique based on dithering is employed to overcome the limitation caused by the truncation of the window number of samples, so the frequency resolution is enhanced. The theoretical approach is verified by simulated and experimental results.

Energy-Efficient Reference Walking Trajectory Generation Using Allowable ZMP (Zero Moment Point) Region for Biped Robots (2족 보행 로봇을 위한 허용 ZMP (Zero Moment Point) 영역의 활용을 통한 에너지 효율적인 기준 보행 궤적 생성)

  • Shin, Hyeok-Ki;Kim, Byung-Kook
    • Journal of Institute of Control, Robotics and Systems
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    • v.17 no.10
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    • pp.1029-1036
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    • 2011
  • An energy-efficient reference walking trajectory generation algorithm is suggested utilizing allowable ZMP (Zero-Moment-Point) region, which maxmizes the energy efficiency for cyclic gaits, based on three-dimensional LIPM (Linear Inverted Pendulum Model) for biped robots. As observed in natural human walking, variable ZMP manipulation is suggested, in which ZMP moves within the allowable region to reduce the joint stress (i.e., rapid acceleration and deceleration of body), and hence to reduce the consumed energy. In addition, opimization of footstep planning is conducted to decide the optimal step-length and body height for a given forward mean velocity to minimize a suitable energy performance - amount of energy required to carry a unit weight a unit distance. In this planning, in order to ensure physically realizable walking trajectory, we also considered geometrical constraints, ZMP stability condition, friction constraint, and yawing moment constraint. Simulations are performed with a 12-DOF 3D biped robot model to verify the effectiveness of the proposed method.

Development of an Integer Algorithm for Computation of the Matching Probability in the Hidden Markov Model (I) (은닉마르코브 모델의 부합확률연산의 정수화 알고리즘 개발 (I))

  • 김진헌;김민기;박귀태
    • Journal of the Korean Institute of Telematics and Electronics B
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    • v.31B no.8
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    • pp.11-19
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    • 1994
  • The matching probability P(ο/$\lambda$), of the signal sequence(ο) observed for a finite time interval with a HMM (Hidden Markov Model $\lambda$) indicates the probability that signal comes from the given model. By utilizing the fact that the probability represents matching score of the observed signal with the model we can recognize an unknown signal pattern by comparing the magnitudes of the matching probabilities with respect to the known models. Because the algorithm however uses floating point variables during the computing process hardware implementation of the algorithm requires floating point units. This paper proposes an integer algorithm which uses positive integer numbers rather than float point ones to compute the matching probability so that we can economically realize the algorithm into hardware. The algorithm makes the model parameters integer numbers by multiplying positive constants and prevents from divergence of data through the normalization of variables at each step. The final equation of matching probability is composed of constant terms and a variable term which contains logarithm operations. A scheme to make the log conversion table smaller is also presented. To analyze the qualitive characteristics of the proposed algorithm we attatch simulation result performed on two groups of 10 hypothetic models respectively and inspect the statistical properties with repect to the model order the magnitude of scaling constants and the effect of the observation length.

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Liquid Phase Adsorption Properties of Organo Surfur Compounds on Cation Exchanged Natural Zeolites (陽이온 交換한 天然 제올라이트에 依한 有機黃化合物의 液相吸着 特性)

  • Kim, Jong-Taik;Heo, Nam-Ho
    • Journal of the Korean Chemical Society
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    • v.28 no.3
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    • pp.194-202
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    • 1984
  • The adsorption properties of organo sulfur compounds on cation exchanged natural zeolites from n-heptane were investigated. The equilibrium adsorbed amounts were dependent upon the exchanged cation and the nature of organo sulfur compounds such as length, volume, electronical structure. The increasing orders of equilibrium adsorbed amounts were thiophene derivatives, disulfide, sulfide mercaptane and thiophene, benzothiaphene, dibenzothiophene. And $Co^{+2}$-zeolite was the most prominent adsorbant. Rate determining step of the adsorption at initial stage was intraparticle diffusion into the transitional pores of zeolite. These adsorption rates were dependent upon the bulkiness of adsorbate. Finally, preadsorbed water didn't affect these adsorption until the cation exchanged natural zeolite contained 2.26${\times}10^{-3}$ mol/g of water. It indicated that water preferentially occupied the micro pores of the cation exchanged natural zeolites.

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Characterization of a Membrane Interface for Analysis of Air Samples Using Time-of-flight Mass Spectrometry

  • Jang, Yu-Mi;Oh, Jun-Sik;Park, Chang-Joon;Yang, Sang-Sik;Jung, Kwang-Woo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2791-2796
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    • 2010
  • In the present study, we constructed a membrane inlet assembly for selective permeation of volatile airborne organic compounds for subsequent analysis by time-of-flight mass spectrometry. The time-dependent diffusion of analytes through a $75\;{\mu}m$ thick polydimethylsiloxane membrane was measured by monitoring the ion signal after a step change in the sample concentration. The results fit well to a non-steady-state permeation equation. The diffusion coefficient, response time, and sensitivity were determined experimentally for a range of polar (halogenated) and nonpolar (aromatic) compounds. We found that the response times for several volatile organic compounds were greatly influenced by the alkyl chain length as well as the size of the substituted halogen atoms. The detection limits for benzene, ethylbenzene, and 2-propanol were 0.2 ppm, 0.1 ppm, and 3.0 ppm by volume, respectively, with a linear dynamic range greater than three orders of magnitude. These results indicate that the membrane inlet/time-of-flight mass spectrometry technique will be useful for a wide range of applications, particularly for in situ environmental monitoring.

The Analysis of Water Tree Degradations in Underground Distribution Cables Using Image Measurement (가교폴리에틸렌 지중케이블에서 화상계측을 이용한 수트리 열화현상 분석)

  • Kim, Duck-keun;Lim, Jang-Seob;Lee, Jin;Lee, Joon-Ung;Kim, Tae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.19-23
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    • 1998
  • Water tree degradations have been considered as one of the most important causes of failure in underground distribution cables with polymeric insulation. Water tree growth is a preliminary step in the sequence of electrical tree initiation and electrical breakdown of the insulation. In this paper, needle electrode is made use of the etching methods and the pellet type specimen is made to observe the water tree in succession. In previous methods are able to observe the tree degradations without cutting and dyeing. The water tree image is recorded on VTR with CCD camera. The tree length of X, Y axis direction and aging area(treeing area) are calculated with image measurement. As a result of this study, water tree is observed by non-destructive method. Electrical tree is initiated from needle electrode tip only but water tree is initiated from total area of water electrode. Electrical tree owing to water treeing is initiated at low electric field and grown with discontinuously. Namely, water tree is shown up a different characteristics of tree growth.

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Development of Corona Cage Measurement System for Simulation on Electrical Environmental Characteristics of HVDC Overhead Transmission Line (HVDC 가공 송전선로 전기환경특성 모의시험용 코로나 케이지 계측시스템 개발)

  • Kil, Gyung-Suk;Yang, Kwang-Ho;Lee, Sung-Doo;Ju, Mun-No
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.5
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    • pp.245-249
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    • 2006
  • Corona characteristics of conductors are dependent on the electric field conditions in the immediate vicinity of the conductors. In case of DC transmission line, particularly, the space charge plays an important role in the electric field distribution. Therefore, DC corona cage simulation is necessary for long-term test in the same conditions. This paper presents the results of designing and constructing hardwares such as DC power supply, measurement system and DAS to carry out the simulation. The corona cage longitudinally is divided into five equal length sections and three inner sections of those are isolated from the ground of outer cage. The measurement items are radio noise, corona current, television noise, audible noise and meteorological conditions. In the next step, various simulations about the type and configuration of two or three candidate conductors will be conducted. And then finally an environmentally-friendly conductor for HVDC overhead transmission line will be decided.

Design and Fabrication of Movable Micro-Fersnel Lens on XY-stage (XY-Stage에 의해 정적인 변위를 갖는 미세 프레넬 렌즈(Micro-Fresnel Lens)의 설계 및 제작)

  • Kim, Che-Heung;Ahn, Si-Hong;Lim, Hyung-Taek;Kim, Yong-Kweon
    • Proceedings of the KIEE Conference
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    • 1998.07g
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    • pp.2515-2517
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    • 1998
  • The micro fresnel lens(MFL) was modeled and fabricated on a XY-stage electrostatically driven by comb actuator. The modeled MFL was approximated as a step shape with 4-phase and 4-zone plate. The focal length and diameter of the MFL is 20mm and 912${\mu}m$, respectively. The XY-stage suspending the MFL is designed to generate a large static displacement up to about 20${\mu}m$. On SOI substrates, we first fabricated MFL using the RIE(reactive Ion etching) technology and then patterned and etched bulk silicon to make XY-stage. After the fabrication of all structures on top side of the SOI substrates. $Si_3N_4$ was deposited for passivation of all structures using PECVD(plasma enhanced chemical vapor deposition). All the MFL systems width comb drive actuator were released by KOH etching from the bottom side of the SOI wafer using double-sided alignment technique. In fabrication of MFL, a dry etching conditions is established in order to improve surface roughness and to control the etched depth.

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