• Title/Summary/Keyword: SR-B1

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Removal of Cesium and Separation of Strontium for the Analysis of the Leachate of Spent Fuel (사용후핵연료 침출액 분석을 위한 세슘의 제거 및 스트론튬의 분리)

  • Kim, Seung Soo;Chun, Kwan Sik;Kang, Chul Hyung
    • Analytical Science and Technology
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    • v.15 no.1
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    • pp.1-6
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    • 2002
  • The selective removal of cesium by ammonium molybdophosphate (AMP) was studied in order to reduce an interference by high radioactivity of cesium on the determination of low radioactive elements in leachate of spent fuel. The removal of Cs, U, Ce, La, Co Ca, Na Sr and K was investigated for the leachate and the bentonite in contact with a spent fuel. More than 90% of cesium was removed by AMP and Ca, Na, Co and Sr was remained in 0.1 M $HNO_3$. However, three valence elements such as La and Ce were also removed by AMP. Though a little of potassium of the bentonite components was adsorbed on AMP, the potassium in the bentonite solution diluted to its concentration in a real sample would not affect the capacity of AMP greatly. From another experiment for the separation of strontium as a leaching indicator of spent fuel, the recovery of strontium in 8.0 M $HNO_3$ solution by using Sr-resin (Eichrom, P/N SR-B50-A) was more than 95% by eluting with 0.05 M $HNO_3$.

Characteristics of the Lidar Ratio Determined from Lidar and Sky Radiometer Measurements in Seoul (라이다와 스카이 라디오미터 관측 자료를 이용한 서울지역 라이다 비의 특성 분석)

  • Kim, M.H.;Kim, S.W.;Yoon, S.C.;Sugimoto, Nobuo;Sohn, B.J.
    • Atmosphere
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    • v.21 no.1
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    • pp.57-67
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    • 2011
  • Aerosol lidar ratio (extinction-to-backscatter ratio) at 532 nm was determined using 4-year measurements of elastic-backscatter lidar and sky radiometer at Seoul National University of Seoul, Korea. The mean lidar ratio (with standard deviation) based on 4 years of measurements is found to be $61.7{\pm}16.5$ sr, and weak seasonal variations are noted with a maximum in JJA ($68.1{\pm}16.8$ sr) and a minimum in DJF ($57.2{\pm}17.9$ sr). The lidar ratios for clean, dust, and polluted conditions are estimated to be $45.0{\pm}9.5$ sr, $51.7{\pm}13.7$ sr, and $62.2{\pm}13.2$ sr, respectively. While the lidar ratio for the polluted condition is appears to be consistent with previous studies, clean and dust conditions tend to have larger ratios, compared to previous estimates. This discrepancy is thought to be mainly due to the anthropogenic aerosols existing throughout the year around Seoul, which may cause increased lidar ratios even for clean and dust conditions.

Synthesis and Photoluminescence of the Sr1-xBaxAl2O4:Eu2+, Dy3+ Long Phosphorescence Phosphor (Sr1-xBaxAl2O4:Eu2+, Dy3+계 축광성 형광체의 합성과 그의 발광특성)

  • Park, Jin-Woo;Kim, Jung-Sik
    • Journal of the Korean Ceramic Society
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    • v.43 no.6 s.289
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    • pp.333-337
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    • 2006
  • In this study, the $Sr_{1-x}Ba_{x}Al_{2}O_{4}:Eu^{2+},Dy^{3+}$ phosphor were prepared by the solid-state reaction method and its photoluminescence properties were investigated. Starting powders of $SrCO_3,\;BaCO_3,\;and\;Al_{2}O_3$ were mixed with $Eu_{2}O_3$ as activator, $Dy_{2}O_3$ as co-activator and $B_{2}O_3$ as flux. Then, the mixed powders were heated at the temperature of $1100{\sim}1400^{\circ}C$ for 3 h under the reducing ambient atmosphere of $95%Ar+5%H_2$. The effect of Ba addition from 0.0 to 1.0 mol on photoluminescence was investigated. As the amount of Ba increased, the intensity of emission increased and the optimum long phosphorescence occurred at the amount of 0.1 mol Ba. The optimum sintering condition for long phosphorescent phosphor of $Sr_{1-x}Ba_{x}Al_{2}O_{4}:Eu^{2+},Dy^{3+}$($x=0{\sim}1.0mol$) was found at $1400^{\circ}C$. The excitation spectra showed a broad band of $250{\sim}450nm$ with maximum peak at 360 nm. The maximum peak intensity of emission spectra occurred at the range of $480{\sim}520nm$, depending on Ba content.

Effect of Scutellaria Radix extract drug on immune cells and cytokines in BALF of OVA-induced asthmatic mice (황금이 천식모델 생쥐의 면역세포 및 사이토카인에 미치는 영향)

  • Cho, Cheol-Jun;Lim, Do-Hee;Hwang, Ji-Ho;Yang, Soo-Young;Park, Yang-Chun
    • The Journal of Internal Korean Medicine
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    • v.27 no.1
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    • pp.114-125
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    • 2006
  • objective : The purpose of this research is to examine the effects of Scutellaria Radix(SR) extract on immune cells and cytokines in ovalbumin(OVA)-induced asthmatic mice. Methods : In vivo, C57BL/6 mice were sensitized and handicapped by OVA for 9 weeks. In this experiment, one group was not treated, and the other group was treated with SR extract for six weeks(five times per week) and analyzed by ELISA and flow cytometer. Results : In vivo, there were significant decreases in eosinophils, IL-4, IL-13 in BALF (bronchoalveolar lavage fluid) compared with that of control group. However,$IFN{\gamma}$ in the SR group increased significantly compared with that of control group. Additionally, the population of $CD3e^-/CCR3^+,\;CD69^+/CD3e^+,\;IgE^+/B220^+,\;CD11b^+/Gr-1^+$ cells in the SR group decreased compared with that of control group. conclusion : The results of this study support a role for SR as an effective treatment for asthma in its experimental success in significantly decreasing inflammation and asthma reactions, and in increasing $IFN{\gamma}$, Which helps prevent such reactions.

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Ferroelectric Properties $\textrm{SrBi}_{2}\textrm{Ta}_{2}\textrm{O}_{9}$ Thin Films Deposited by RF Magnetron Sputtering Technique (RF magnetron sputtering법에 의해 제조된 $\textrm{SrBi}_{2}\textrm{Ta}_{2}\textrm{O}_{9}$박막의 강유전 특성에 관한 연구)

  • Park, Sang-Sik;Yang, Cheol-Hun;Yun, Sun-Gil
    • Korean Journal of Materials Research
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    • v.7 no.6
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    • pp.505-509
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    • 1997
  • FRAM(Ferroelectric Random Access memory)에의 응용을 위해 rf magnetron sputtering법을 이용하여 SrB $i_{2}$T $a_{2}$ $O_{9}$(SBT)박막을 증착하였다. 사용된 기판은 Pt/Ti/Si $o_{2}$Si이었으며 50$0^{\circ}C$에서 증착한 후 80$0^{\circ}C$의 산소 분위기 하에서 1시간 동안 열처리하였다. 증착시 증착 압력을 변화시켜 가면서 이에 따른 특성의 변화를 고찰하였다. 박막내의 Bi와 Sr의 부족을 보상하기 위해 20mole%의 Bi $O_{2}$와 30mole%의 SrC $O_{3}$를 과잉으로 넣어 타겟을 제조후 사용하였고 박막들의 두께는 300nm의 두께를 가지며 증착압력에 따라 다른 미세 구조르 보였다. 10mtorr에서 증착한 박막의 조성은 S $r_{0.6}$B $i_{3.8}$Ta/ sub 2.0/ $O_{9.0}$이었다. 이 SBT 박막의 잔류 분극(2 $P_{r}$)과 보전계(2 $E_{c}$)값은 각각 인가 전압 5V에서 18.5 $\mu%C/$\textrm{cm}^2$과 150kV/cm이었고, signal/noise비는 3V에서 4.6을 나타내었다. 5V의 bipolar pulse하에서 $10^{10}$cycle까지 피로 현상이 나타나지 않았으며, 누설 전류 밀도는 133kV/cm에서 약 1x$10^{-7A}$$\textrm{cm}^2$의 값을 보였다.을 보였다.

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Dielectric properties and microstructures of (CaxSr1-x)ZrO3 ceramics

  • Li, Yu-De;Chen, Jian-Ming;Lee, Ying-Chieh
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.461-466
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    • 2018
  • The effects of Ca/Sr ratio and the sintering temperature on the properties of $(Ca_xSr_{(1-x)})ZrO_3$ (CSZ) ceramics were investigated in this study. CSZ ceramics were prepared using solid-state reaction process, which were sintered in air at temperatures ranging from $1350^{\circ}C$ to $1450^{\circ}C$. Their structures were characterized by X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Transmission Electron Microscopy (TEM). The change in Ca/Sr ratio significantly affected the crystalline phase and the dielectric properties of the $(Ca_xSr_{(1-x)})ZrO_3$ ceramics. The secondary phase, $Ca_{0.15}Zr_{0.85}O_{1.85}$, was observed and increased correspondingly with the rising of sintering temperatures. In order to understand the effects of secondary phase on the dielectric properties of CSZ ceramics, the $Ca_{0.15}Zr_{0.85}O_{1.85}$ phase was prepared individually using solidstate method. The $Ca_{0.15}Zr_{0.85}O_{1.85}$ ceramics sintered at $1500^{\circ}C$ for 2 hours possessed a dielectric constant (${\varepsilon}_r$) of 21.7, a dielectric loss ($tan{\delta}$) of $49.510^{-4}$ and an Insulation Resistance (IR) of $2.1{\times}10^{10}{\Omega}$. The ($Ca_{0.7}Sr_{0.3})ZrO_3$ ceramics exhibited the best dielectric properties, with a permittivity of 29, a dielectric loss ($tan{\delta}$) of $2.7{\times}10^{-4}$, and an Insulation Resistance (IR) of $2.6{\times}10^{12}{\Omega}$.

Effect of Na Substitution for the Ca Site in the Bi$_2$Sr$_2$Ca$_{1-x}$Na$_x$Cu$_2$O$_{8+y}$ Superconductors (Bi$_2$Sr$_2$Ca$_{1-x}$Na$_x$Cu$_2$O$_{8+y}$ 산화물 고온초전도체의 Ca 위치에 Na 치환 효과)

  • 이민수;송승용;이종용;송기영;최봉수
    • Journal of the Korean Ceramic Society
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    • v.35 no.10
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    • pp.1007-1013
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    • 1998
  • The samples of Bi2Sr2Ca1-xNaxCu2O8+y with various carrier concentration were synthesized by substituting Na for Ca ion. The superconducting properties hall coefficients and X-ray powder diffraction were measur-ed the sampled. Single phase samples were obtained for 0$\leq$x<0.3 of Bi2Sr2Ca1-xNaxCu2O8+y In the single phase the critical temperature. {{{{ { T}_{c } }} and carrier concentration increase with the increase of Na concentration pass through a maximum and then decreases. In the range of x$\geq$0.7 to the Na doped samples however we observed the metal-semiconductor transition. The c-axis seemed to decrease and a and b-axes increase with increasing Na concentration in the single phase. Decreasing of c-axis while increasing x is due to the smaller size of {{{{ {Na}^{+1 } }} ions to the {{{{ { Ca}^{+2 } }} ions. In the range of x>0.3 however the trend becomes ambiguous due to the inclusion of the 10K phase and impurity phase.

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The Characteristics of (Ba,Sr)$TiO_3$ Thin Films Etched With The high Density $BCl_3/Cl_2$/Ar Plasma ($BCl_3/Cl_2$/Ar 고밀도 플라즈마에서 (Ba,Sr)$TiO_3$ 박막의 식각 특성에 관한 연구)

  • Kim, Seung-Bum;Kim, Chang-Il
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.863-866
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    • 1999
  • (Ba,Sr)$TiO_3$ thin films have attracted groat interest as new dielectric materials of capacitors for ultra-large-scale integrated dynamic random access memories (ULSI-DRAMs) such as 1 Gbit or 4 Gbit. In this study, inductively coupled $BCl_3/Cl_2$/Ar plasmas was used to etch (Ba,Sr)$TiO_3$ thin films. RF power/dc bias voltage = 600 W/-250 V and chamber pressure was 10 mTorr. The $Cl_2/(Cl_2+Ar)$ was fixed at 0.2, the (Ba,Sr)$TiO_3$ thin films were etched adding $BCl_3$. The highest (Ba,Sr)$TiO_3$ etch rate is 480$\AA/min$ at 10 % $BCl_3$ adding to $Cl_2$/Ar. The characteristics of the plasmas were estimated using optical emission spectroscopy (OES). The change of Cl, B radical density measured by OES as a function of $BCl_3$ percentage in $Cl_2$/Ar. The highest Cl radical density was shown at the addition of 10% $BCl_3$ to $Cl_2$/Ar. To study on the surface reaction of (Ba,Sr)$TiO_3$ thin films was investigated by XPS analysis. Ion enhancement etching is necessary to break Ba-O bond and to remove $BaCl_2$. There is a little chemical reaction between Sr and Cl, but Sr is removed by physical sputtering. There is a chemical reaction between Ti and Cl, and Tic14 is removed with ease. The cross-sectional of (Ba,Sr)$TiO_3$ thin film was investigated by scanning electron microscopy (SEM), the etch slope is about $65\;{\sim}\;70$.

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Sintering Period Dependence of Composition and Superconducting Properties of (BiPb)SrCaCuOx System ((BiPb)SrCaCuOx계에서 소결시간에 따른 조성과 초전도 성질의 변화)

  • Prak, S.;Im, H. B.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.10a
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    • pp.98-101
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    • 1988
  • The material system (Bi$\sub$0.7/Pb$\sub$0.3/)Sr$_1$Ca$_1$Cu$\sub$1.8/Ox forms, at 845$^{\circ}C$, two major phases having a high Tc(100K) and a low Tc(∼70K) both of which consists of platelets and a non-superconducting minor phase which has rod-like shape and isolated by the major phases. As the sintering period increases, the amount of high Tc phase increases accompanying the decrease in low Tc phase while the amount of the non-superconducting phase is sintering period independent, resulting in a superconductor with Tc of 100K. Changes in compositions of each phase also occur during sintering due to evaporation of bismuth and lead.

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Sintering Behavior and Electrical Properties of Strontium Titanate-Based Ceramic Interconnect Materials for Solid Oxide Fuel Cells (고체산화물 연료전지용 Strontium Titanate 세라믹 접속자 소재의 소결 거동 및 전기적 특성)

  • Park, Beom-Kyeong;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.80.1-80.1
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    • 2010
  • A strontium titanate ($SrTiO_3$)-based material with a perovskite structure is considered to be one of the promising alternatives to $LaCrO_3$-based materials since $SrTiO_3$ perovskite shows a high chemical stability under both oxidizing and reducing atmospheres at high temperatures. $SrTiO_3$ materials exhibit an n-type semiconducting behavior when it is donor-doped and/or exposed to a reducing atmosphere. In this work, $Sr_{1-x}La_xTi_{1-y}M_yO_3$ materials doped with $La^{3+}$ in A-sites and aliovalent transition metal ions ($M^{n+}$) in B-sites were synthesized by the modified Pechini method. The X-ray diffraction analysis indicated that the materials synthesized by the Pechini process exhibited a single curbic perovskite-type structure without any impurity phases, and are tolerant, to some extent, to cation doping. The sintering behaviors of $Sr_{1-x}La_xTi_{1-y}M_yO_3$ in $H_2/N_2$ and air were characterized by dilatometry and microstructural observations. The electrical conduction mechanism and the dopant effect are discussed based on the defect structures and the electrical conductivities measured at various oxygen partial pressures and temperatures.

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