• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.222-222
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• 2011

Plastic product is increasing by the growth of its demand and most of refused plastics are incinerated or reclaimed. However, the refused plastic is not easily decomposed and has the environmental problem with its various toxic gas in case of incineration. Therefore, many countries such as USA, Japan, Germany and other developed industrial countries as well as Korea are interested in studying the recyclable resource of refused plastic. The macromolecular waste pyrolysis has the advantage of collecting of raw materials in high price and can at least get fuel gas or oil with high heat capacity. It also discharges low waste gas and low toxic gas including SOx, NOx and HCl heavy metals. However, pyrolyzed oil includes enough excess unsaturated hydrocarbons to form tar, which can cause the nozzle of engines to plug when pyrolyzed oil is used as fuel. Activated carbon was proven to have prominent adsorption capability among the other adsorbents that were mainly composed of carbon. This study examined the possibility of application in activated charcoal of its solid formation by analysing the feature of pyrolysis which is one of the chemical recycling methods and getting chemical analysis of the product and activated energy. Analyze the element of the oil produced by pyrolysis using GC-MS. The experiment of tar adsorption using fly-ash showed that fly-ash improved the optical intensity of pyrolyzed oil and decreased oxygen compounds in the pyrolyzed oil.

• 한국해양공학회지
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• 제32권5호
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• pp.380-385
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• 2018

With the tightening of environmental regulations (i.e., IMO Tier III), natural gas (NG) has been spotlighted as an eco-friendly fuel with few air pollutants other than nitrogen oxides (NOx) and sulfur oxides (SOx). For reasons of economic efficiency, it is mainly stored and transported in a liquid state at $-163^{\circ}C$, which is a cryogenic temperature, using a liquefied gas storage tank. Accordingly, it is necessary to reduce the boil-off gas (BOG) occurrence due to the heat flow according to the temperature difference between the inside and outside of the storage tank. Therefore, in this study, a BOG measurement test on an independent-type storage tank made up of SUS304L was carried out. The test results showed the tendency for BOG occurrence according to the temperature under different filling ratios.

• Journal of Advanced Marine Engineering and Technology
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• 제36권6호
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• pp.788-793
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• 2012

본 연구는 해군함정에 탑재되어 있는 주 추진 디젤엔진에서 배출되는 입자상 물질, 황산화물, 이산화탄소 및 질소산화물의 배출량 예측에 초점을 두었다. 국제사회 및 각국의 정부는 인간의 건강 및 환경을 보호하기 위해 선박의 배기가스 규제를 엄격히 적용하고 있으며 선박 제작사들은 이러한 법규에 대응하기 위해 다양한 기술을 선박에 적용시키고 있다. 엄격히 적용되는 배기가스 법규는 선박의 크기에 따라 차이를 보이고 있지만 함정은 규제대상에서 제외된다. 다양한 연구결과에 의해 선박의 배기가스 배출량 계수(emission factor)는 지속적으로 최신화되고 있으나 함정의 배출량 계수는 그 특성의 차이 때문에 설정이 어려운 실정이다. 본 논문은 함정 엔진의 연료소모량과 함정에서 사용하고 있는 연료의 황성분 함량을 분석하여 항해 시 선박에 적용되고 있는 오염물질 기여도 조사(emission inventory) 방법론을 해군함정에 적용시켜 정속항해 조건에서 배기가스 총 배출량을 예측하는 것이다.

• 한국기후변화학회지
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• 제7권4호
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• pp.477-484
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• 2016

In general, $CH_4$ concentrations generated in combustion facilities are known to be ppm units. In most cases, $CH_4$ samples are collected in Tedlar bags and transported to laboratories for analysis. Considering this fact, in the present study, an attempt was made to find out how long samples can be stored in cases where they are kept in bags and transported as a preliminary study for sampling. According to the results of the experiment using simulated gases (1 ppm, 5 ppm, 10 ppm) in Tedlar bag, $CH_4$ was safe up to 240 hr which is the full time. In the case of simulated gases are containing 4 kind gases ($N_2$, $CO_2$, $CH_4$, and $N_2O$). Field samples (samples of obtained by collecting combustion facilities' exhaust gases) are known to contain highly reactive substances (for example NOx, SOx, and VOCs) and may affect each other. In the present study, one site sample was secured from each of a bituminous coal combustion facility and an LNG combustion facility and whether the concentrations of $CH_4$ gas would change over time (24 hr, 96 hr, 144 hr, 192 hr) was checked. Since site samples could not be analyzed on the day of collection, an experiment was started 24 hr after the time point of sampling to analyze the samples. As with the results of analysis of the simulated gas (240 hr), the results of analysis using the site sample indicated that it could be stored for the full study period 192 hr. Therefore, it was judged that if 192 hr would be taken after sampling before the sample would be analyzed, the concentration value should be reliable.

• 농업과학연구
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• 제47권4호
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• pp.1049-1056
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• 2020

Ultrafine dust causes asthma and respiratory and cardiovascular diseases when inhaled. Ammonia (NH3) plays a big role in ultrafine dust formation in the atmosphere by reacting with nitrogen oxides (NOx) and sulfur oxides (SOx) emitted from various sources. The agricultural sector is the single largest contributor of NH3, with the vast majority of emissions ensuing from fertilizers and livestock sector. Interest in using biochar to attenuate these NH3 emissions has grown. This experiment was conducted to study the effects of using rice hull biochar pyrolyzed at three different temperatures of 250℃ (BP 4.6, biochar pH 4.6), 350℃ (BP 6.8), and 450℃ (BP 10.3) on the emission of ammonia from soil fertilized with urea. The emissions of NH3 initially increased as the experiment progressed but decreased after peaking at the 84th hour. The amount of emitted NH3 was lower in soil with biochar amendments than in that without biochar. Emissions amongst biochar-amended soils were lowest for the BP 6.8 treatment, followed in an ascending order by BP 10.3 and BP 4.6. Since BP 6.8 biochar with neutral pH resulted in the lowest amount of NH3 emitted, it can be concluded that biochar's pH has an effect on the emissions of NH3. The results of this study, therefore, indicate that biochar can abate NH3 emissions and that a neutral pH biochar is more effective at reducing gaseous emissions than either alkaline or acidic biochar.

• 해양환경안전학회지
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• 제28권3호
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• pp.451-458
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• 2022

In Korea, five major ports have been designated as sulfur oxide emission control areas to reduce air pollutant emissions, in accordance with Article 10 of the "Special Act on Port Air Quality" and Article 32 of the "Ship Pollution Prevention Regulations". As regulations against vessel-originated air pollutants (such as PM, CO2, NOx, and SOx) have been strengthened, the Ministry of Oceans and Fisheries(MOF) enacted rules that newly built public ships should adopt eco-friendly propulsion systems. However, particularly in diesel-electric hybrid propulsion systems,the demand for precise control schemes continues to grow as the fuel saving rate significantly varies depending on the control strategy applied. The conventional Power Take In-Power Take Off(PTI - PTO) mode control adopts a rule-based strategy, but this strategy is applied only in the low-load range and PTI mode; thus, an additional method is required to determine the optimal fuel consumption point. The proposed control method is designed to optimize fuel consumption by applying the equivalent consumption minimization strategy(ECMS) to the PTI - PTO mode by considering the characteristics of the specific fuel oil consumption(SFOC) of the engine in a diesel-electric hybrid propulsion system. To apply this method, a specific fishing vessel model operating on the Korean coast was selected to simulate the load operation environment of the ship. In this study, a 10.2% reduction was achieved in the MATLAB/SimDrive and SimElectric simulation by comparing the fuel consumption and CO2 emissions of the ship to which the conventional rule-based strategy was applied and that to which the ECMS was applied.

• 환경위생공학
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• 제15권2호
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• pp.95-101
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• 2000

산업의 고도화에 따른 경제성장으로 인류의 삶의 질은 많이 좋아졌지만 경제활동으로 인한 각종 환경 오염물질은 상대적으로 많이 배축된 것이 사실이다. 특히 대기오염물질의 주 요인이 되고있는 질소산화물과 아황산가스 등 많은 오염물질이 있지만 최근 더욱더 문제가 되고있는 것이 휘발성 유기화합물질로써 대기중의 탄화수소 화합물의 총칭으로 광 화학 옥시던터와 오존 등으로 인한 대기오염으로 인체에 미치는 영향이 아주 심각하며, 발생장소도 대규모 석유화학 장치산업의 원유를 정제하는 정제공정에서부터 저유소 및 중간 제품공정, 그리고 소비자가 직접 접하는 전국각지에 산재되어 있는 주유소 등에서 많은 량의 휘발성 유기화합물질이 발생되고 있다. 이에 대한 대책으로 정부차원에서 우선 대규모 석유화학단지를 휘발성 유기화합물질 배출저감을 위한 종합대책지역으로, 전남 여천지역은 1996. 9. 20일, 울산지역은 1997. 7. 1일에 지정고시 하였다. 울산지역의 경우 당초 대상물질이 47개 항목에서 시행초기에 보완적인 차원에서 크실렌 및 초산 등 일부물질이 수정된 31개 항목으로 변경고시 되었으며, 이에 대해 사업장에서는 해당물질에 따른 처리시설을 설치 가동 중에 있다. 그러나 휘발성 유기화합물질의 발생조건과 발생량, 각 물질의 혼합시 안전성문제 등이 공정조건상 일정하지 않아 방지시설 선정설치에 많은 에로사항이 있었다. 기존의 시설에 방지시설을 추가한다는 것은 화학공장 특성상 여러 가지 조건이 있으며, 그 동안 많은 시행착오를 하면서 설치하였다. 그러나 일부시설은 아직도 완벽한 방지효과를 얻기에는 부족하므로 향후 계속적인 기술 및 설비투자와 관리대책이 보완되어야 할 것으로 사료된다.

• 품질경영학회지
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• 제43권3호
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• pp.359-372
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• 2015

Purpose: Through studying the expert's and non-experts panel responses to the questions regarding the attributes of chemical-biological protection cloth quality in terms of the levels of customer demand and technical factors has been studied. We are applied to a QFD matrix with find out the relationship between the selective removal efficiency of chemical-biological cloth and the guidelines of technical approach. Methods: We fabricated several composite of ion-exchange resins with selectively permeable performance designed to facilities water vapor transport and selective adsorption of the harmful gases. With these materials, we characterized on the selectively permeable performance to identify ion-exchange resin with chemical-biological protective cloth. Results: Results showed that ion exchange materials possessed performance with selectively efficiencies as NH3, SOx, NOx and HCl gas. The selective adsorption amount of ammonia and hydrogen gases were $90-80{\mu}g/g$ with TRILITE SCR-BH sulfonated ion exchange resin. The PP non-woven/ion exchange resin adsorbent materials possessed performance with water vapor permeability were 1,100-1,350 g/m2/day, it's was two times high value compare with activated carbon. With these materials, we characterized selectively removal efficiency to identify new ion-exchange material with chemical-biological protective capability. Conclusion: This study shows that a QFD aids in deciding with of the adsorption parameters to optimized with chemical-biological protection cloth manufacturing.

• 한국응용과학기술학회지
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• 제32권1호
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• pp.48-55
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• 2015

전 세계적으로 증가하고 있는 선박 배출가스 규제를 위해 국제해사기구(IMO)는 배출되고 있는 가스의 부정적 환경영향에 대한 부각과 함께 법적인 규제를 강화하고 있다. 국제해사기구(IMO) 규제에 따라, 발트 해 연안을 지나는 모든 배들은 배출가스 제거창치를 장착해야 한다. 다양한 최신 탈황/탈질 장치가 소개되고 있는 가운데, 선박의 제한 된 공간을 활용한 폐 세정액 회수 공정 또한 중요한 기술로 발전 가능하다. 탈황/탈질 장치 후단에서 발생되는 폐 세정액은 질산암모늄, 황산암모늄과 같은 유용부산물을 포함하고 있다. 본 연구는 선택적 유기용매 염석 법, 저온 결정화 추출, 열 감압농축을 이용하여 유용부산물로서 질산암모늄을 추출하였다. 열 감압농축으로 얻어진 부산물을 반복적 유기용매 추출방법으로 정제했을 시 가장 높은 순도의 질산암모늄이 추출 되었다. 분석 장비를 통해 추출 된 유용 부산물의 성분 및 특성을 평가하였다.

• 환경위생공학
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• 제23권3호
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• pp.9-22
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• 2008

This study was conducted to develop a system that processes harmful gases and dust, which being generated in the production of micro-inorganic fabric. This can be obtained by melt spinning raw materials such as agalmatolite, fluorspar, limestone, silica under high temperature at $1500-1600^{\circ}C$ in a glass recuperator using a dry method by Cyclone Reactor or Envelope Type (ET) type Bag Filter. If the number of the members of Korea Glass Industry Association reaches up to 45, the damage of the harmful gas being generated in recuperator should not be small. In addition, research of existing facilities showed the most of harmful gas treatment facilities which adopt wet treatment or semi-dry treatment process. This was caused the problems for wastewater and the second pollutive materials. Moreover, in the dust collecting facility behind recuperator, it is also problematic that electric dust collector requires enormous initial investment. We have researched various methods to show both economic and efficient new processes for the preventive facilities of recuperator. As the result of the experiments, the removal efficiencies of HF and SOx were 99% and 87%, respectively. Although it was insignificant reaction, a pretty much interesting result that NOx showed an absorption reaction with $Ca(OH)_2$(removal efficiency was more than 25%) was obtained.