• Title/Summary/Keyword: SOx and NOx

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An Experimental Study of N2O Concentration Profiles in Planner Premixed Flame (평면예혼합화염중의 N2O 농도변화에 관한 실험연구)

  • An, Suk-Heon
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.2
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    • pp.267-271
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    • 2009
  • The Marine Environment Protection Committee(MEPC) which is the IMO's specialized committee on marine pollution related matters deals with GHG related issues to discuss and compile possible approaches on technical, operational and market based measures to address GHG emissions from ships. The nitrous oxide($N_2O$) which remains generally in the atmosphere for around 114 years is one of the green house gases. The global warming potential of $N_2O$ is 310 times than $CO_2$ in the given period 100 years. It seems that the $N_2O$ formation is influenced by the nitrogen compound contained in the fuel which is named as "Fuel N" during the combustion process or the NOx, SOx and $H_2O$ through the emission gases before exhausted into the atmosphere. This paper has carried out an experimental study of the $N_2O$ concentration profiles by the change of $NH_3$ flows in the planner premixed combustion with using $C_3H_8$ and air.

A Study on Estimation of Air Pollutants Emission from Traditional Fireplace in Korea (아궁이 사용에 의한 대기오염물질 배출량 산정에 관한 연구)

  • Kim, Dong Young;Choi, Min-Ae;Han, Yong-Hee;Park, Sung-Kyu
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.6
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    • pp.538-544
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    • 2014
  • A traditional fireplace has been used, but not much, for heating and cooking in rural area, Korea. Traditional fireplace as one type of biomass burnings is also emitting various air pollutants. Air pollutants emission from traditional fireplace was estimated in this study. There are two types of traditional fireplace, one for combined heating and cooking, the other one for cooking only. Types of fuels mostly used in traditional fireplace were wood, agricultural residue, solid waste. Activity levels such as fuel types, amount of fuel loading, and temporal variation were investigated by field survey over Korea. Estimated annual emissions from traditional fireplace were CO 6,335.0, NOx 555.0, SOx 9.6, VOC 1,771.7, TSP 181.4, $PM_{10}$ 119.9, $PM_{2.5}$ 96.2, $NH_3$ 1.4 ton/yr respectively. When emissions compared with the national emission inventory (CAPSS: Clean Air Policy Support System) of 2010 year, CO and $PM_{10}$ occupy 0.8% and 0.1% of total national emission, respectively.

Performance of a Pilot-scale Rice Husk Incinerator

  • Park, Seung J.;Kim, Myoung H.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1996.06c
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    • pp.906-917
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    • 1996
  • This study was conducted to find possible application areas of the by-products generated from the incineration of rice husk. To this end, a pilot-scale rice husk incinerator system was constructed and its performed test was carried. Major findings are summarized as follows. 1. The rice husk incinerator system developed in this study performed satisfactory in terms of thermal efficiencies. At the optimum operating conditions, thermal conversion efficiency and heat exchanger efficiency was 97% ad 60%, respectively, while overall thermal efficiency of the system was 58%. Under all conditions tested, temperatures in the combustion chamber were quite uniform and crystallization of SiO$_2$ in the ash was negligible. 2. NOx and SOx content in the flue gas was well below the legal limit but the CO concentration was around the legal limit. 3. Thermal energy from combustion was successfully recovered by a heat exchanger to provide hot water, ash was found a good supplementary cementing m terial, and the flue gas also was an acceptable $CO_2$ supplier to greenhouses.

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A Study on the Characteristics of Pollutants in CFBC Boiler with Ammonium Sulfate Injection (황산암모늄 주입시 CFBC 보일러의 오염물질 특성 연구)

  • Lee, Chang-Yeol;Jeong, Bok-Hoa;Chung, Jin-Do
    • Journal of Korea Society of Waste Management
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    • v.35 no.8
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    • pp.754-761
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    • 2018
  • There is growing concern over the effects of global warning. In response, the power generation sector must consider a wider range of systems and fuels to generate power. One of the classes of solid fuels that is being increasingly developed is biomass. However, one of the most serious problems that biomass plants face is severe corrosion. To mitigate the problem, various approaches have been proposed in terms of additive utilization. This study is based on the results obtained during the co-combustion of wood chip and waste wood in a circulating fluidized bed boiler (CFBC boiler). The KCl concentration was reduced from 59.9 ppm to 3.9 ppm during the injection of ammonium sulfate, and NOx was reduced by 25.5 ppm from 30.6 ppm to 5.1 ppm. However, SOx increased by 110.2 ppm from 33.2 ppm to 143.4 ppm, and HCl increased by 71.5 ppm from 340.5 ppm to 412.0 ppm. Thus, we confirmed that the attitude of the superheater tube was reduced by 87 ~ 93%, and the injection of ammonium sulfate was effective in preventing high-temperature corrosion.

Performance evaluation of nitrate removal in high TDS wet scrubber wastewater by ion exchange resin with dissolved air flotation (DAF) process

  • Kim, Bongchul;Yeo, Inseol;Park, Chan-gyu
    • Membrane and Water Treatment
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    • v.13 no.1
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    • pp.1-6
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    • 2022
  • The regulations of the International Maritime Organization (IMO) have been steadily strengthened in ship emissions. Accordingly, there is a growing need for development of related technologies for the removal of contaminants that may occur during the treatment of SOx and NOx using a wet scrubber. However, this system also leads to wastewater production when the exhaust gas is scrubbed. In this research, we evaluated the performance of an ion selective resin process in accordance with scrubber wastewater discharge regulations, specifically nitrate discharge, by the IMO. Accelerated real and synthetic wastewater of wet scrubbers, contained high amounts of TDS with high nitrate, is used as feed water in lab scale systems. Furthermore, a pilot scale dissolved air flotation (DAF) using microbubble generator with ion exchange resin process was combined and developed in order to apply for the treatment of wet scrubber wastewater. The results of the present study revealed that operating conditions, such as resin property, bed volume (BV), and inlet wastewater flow rate, significantly affect the removal performance. Finally, through a pilot test, DAF with ion exchange resin process showed a noticeable improvement of the nitrate removal rate compared to the single DAF process.

A Study on Operating Characteristics of the CO2 Laser with Inductively Pulsed Power System (유도형(誘導型) Pulsed Power 전원을 이용한 CO2 레이저 동작 특성에 관한 연구)

  • Kim, Geun-Yong;Min, Byoung-Dae;Kim, Yong-Cheol;Lee, Yu-Soo;Chung, Hyun-Ju;Kim, Hee-Je
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1710-1713
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    • 2002
  • Recently, the pulsed power system has been used to many applications. Such as remediation of environmental hazards, food sterilization, air pollution control E/P (Electrostatic Precipitator), DeNOx/DeSOx power system, ozone generator, high energy physics, and other power source applications. A pulse energy efficiency for load depends on the rising time, peak value. Pulse duration and impedance matching etc. The pulsed power system generally required for short pulse duration and high peak value was forced to consider its volume and economy. In this paper, we investigated operating characteristics of the CO2 laser using an inductively pulsed power system.

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The Four Power Plants Field Demonstration Research on Combustion Characteristic of the Bio Oil for Fuel Switching (국내 4개 중유발전소 실증실험을 통한 발전연료 대체용 바이오중유의 연소특성 연구)

  • Baek, Sehyun;Kim, Hyunhee;Park, Hoyoung;Kim, Young Joo;Kim, Tae Hyung;Ko, Sung Ho
    • Journal of the Korean Society of Combustion
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    • v.20 no.1
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    • pp.15-23
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    • 2015
  • This paper presents the results of field demonstration for fuel switching to bio-fuel oil in 4 commercial heavy oil fired power plants. The 100% fuel switching field demonstration was successfully carried out in two tangential-firing boilers at a capacity of 75 and 100 MWe respectively without major equipment retrofit, and also 25% bio-fuel oil blending for two opposite firing boilers at a capacity of 350 and 400 MWe respectively. Despite the low density and heating value, the bio fuel was successfully replaced heavy fuel oil at the full load by only adjusting operational parameters. Incase of bio fuel oil combustion, heat absorption of radiative heat transfer section was reduced while convection section has opposite trend. In pollutants emission, a major reductionin SOx as well as 10-20% reduction in NOx were achieved by the fuels witching. On the other hand, boiler efficiency was slightly underestimated.

Effect of Temperature on Electrochemical Characteristics of Stainless Steel in Green Death Solution Using Cyclic Potentiodynamic Polarization Test (순환동전위 분극실험을 이용한 스테인리스강의 그린데스용액에서 전기화학적 특성에 미치는 온도의 영향)

  • Hwang, Hyun-Kyu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.5
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    • pp.266-280
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    • 2021
  • Since 2020, the International Maritime Organization (IMO) has updated regulations on the sulfur content to be less than 0.5% in exhaust gas emitted from ships. Accordingly, the exhaust gas post-treatment device for ships, which is SOx/NOx reduction technology, was introduced. However, the exhaust gas post-treatment device is suffering corrosion because of the harsh corrosive environment formed by sulfate and chlorine oxide through the desulfurization process. In this investigation, cyclic potentiodynamic polarization (CPDP) experiment for UNS S31603 and UNS N08367 was performed in a green death solution that simulates the environment of a desulfurization device. The corrosion rate of UNS S31603 at the highest temperature was about 3 times higher than that of UNS N83067. Also, electron microscope scan revealed corrosion type UNS N83067 presents intergranular corrosion tendency. On the other hand, UNS S31603 was observed as general corrosion. The α values of UNS N08367 at 30 ℃ and 60 ℃ were higher than those of UNS S31603, thus UNS N08367 is considered to have a higher local damage tendency. Whereas, since the α value of UNS S31603 at 90 ℃ is larger than that of UNS N08367, UNS S31603 is considered to have a higher local damage trend.

A Study on Toxicity Evaluation of Combustion Gases Released from the Residental Container Fire - Efficiency Test for the Fire Gas Mask Filters (주거용 컨테이너 화재시 발생되는 연소가스의 독성 평가에 관한 연구 - 화재용 방독면 filter의 성능평가를 중심으로)

  • Lee Jung Yun;Kim Jeong Hun;Kim Youn-Hi;Jung Ki Chang
    • Journal of the Korean Society of Safety
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    • v.19 no.4 s.68
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    • pp.48-54
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    • 2004
  • The recent Ire incident in an elementary school of Chonan city causes the media focus on the fire safety of residential container buildings. In this study, real fire tests were conducted in this kind of buildings. Combustion products including $O_2,\; CO_2,\;CO,\;NOx,\;SOx,\;HCI,\;HCN$ were measured, and blood samples of lab rats were analyzed in terms of Co-Hb, Glucose, AST(GOT), ALT(GPT), in order to investigate the hazard-reduction effects of employing gas mask protected with filter during the fire emergency of residential container buildings. According to the test results, whether or not employing the filter showed a sheer difference in the toxicity of the fire-induced gases, and then the importance of wearing a gas mask was evidently demonstrated.

Synthesis and Characterization of Oxygen Evolution Nanofiber electrocatalyst for Water Electrolysis (수전해 산소발생을 위한 나노섬유 전기화학 촉매 합성 및 특성분석)

  • Won, Mi-So;Jang, Myeong-Je;Lee, Gyu-Hwan;Choe, Seung-Mok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.186-186
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    • 2016
  • 수소는 연료전지 등의 에너지원으로 사용될 경우 NOx, SOx, $CO_2$ 등의 한경오염물질, 온실가스를 발생시키지 않기 때문에 친환경 에너지원으로 각광을 받고 있다. 수전해는 수소를 생산하는 가장 간단하고 효율적인 방법 중의 하나로서, 잉여전력 또는 신재생에너지에 의한 전기에너지를 통해 환경오염물질 발생 없이 고순도의 수소를 얻을 수 있으며 분산/대량 생산이 용이하다. 수전해에서 환원전극에서는 수소발생반응이 일어나고, 산화전극에서는 산소발생반응이 일어난다. 이때 주로 산소발생전극 촉매로는 과전압이 작게 걸리고 활성이 우수한 귀금속 계열의 $IrO_2$$RuO_2$ 등의 촉매가 현재 사용되고 있다. 본 연구에서는 고분자 용액을 만들어 전기방사를 이용하여 공정변수에 따른 직경과 morphology를 확인하였고, 고가의 귀금속 산화물 대신 저렴한 전이금속산화물인 Cu와 Co를 이용하여 1D 나노섬유를 산소발생 촉매로 합성하였다. 합성된 나노섬유의 구조적, 물리화학적 특성을 분석하고 산소발생반응(OER)에 대한 전기화학적 활성 및 내구성을 평가하였다.

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