• 한국대기환경학회지
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• 제11권4호
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• pp.307-313
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• 1995

An automatic method is developed for the determination of SOx in atmosphere. The method involves SOx sampling in diffusion scrubber followed by ion chromatographic analysis. Filtered air is withdrawn at 1.8.ell./min through a diffusion scrubber of which inner tube is made of PTFE(Gore-tex) membrane tubing. 1mM $H_{2}$ $O_{2}$ is used as absorbing solution so that SOx is oxidized to S $O_{4}$$^{2-}$. The scrubbered solution is automatically injected into ion chromatograhpy eith conductivity detection for sulphate determination. Replacement of commonly used polyproplene membrane with PTFE gives several merits such as easy preparation of diffusion scrubber, better collection efficiency. No measurable memory effect is experienced, and this isin contrast to previous work for ammonia. Detection limit of this method defined by three times standard deviation is 0.56ppbv. The precision is 0.4% RSD at SOx concentration of 7.3ppbv Results for Seoulatmosphere ate presented.

• 해양환경안전학회지
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• 제26권3호
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• pp.262-268
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• 2020

The IMO (International Maritime Organization) has mandated the restriction of SOx emissions to 0.5 % for all international sailing vessels since January 2020. And, a number of countries have designated emission control areas for stricter environmental regulations. Three representative methods have been suggested to cope with these regulations; using low-sulphur oil, installing a scrubber, or using LNG (Liquefied Natural Gas) as fuel. In this paper, economic analysis was performed by comparing the method of installing a scrubber with the method of using low-sulphur oil without installing additional equipment. We suggested plausible layouts and compared the pros and cons of dif erent scrubber types for retrofitting. We selected an international sailing ship as the target vessel and estimated payback time and benefits based on navigation route, fuel consumption, and installation and operation costs. Two case of oil prices were analyzed considering the uncertainty of fuel oil price fluctuation. We found that the expected payback time of investment varies from 1 year to 3.5 years depending on the operation ratio of emission control areas and the fuel oil price change.

• Journal of Advanced Marine Engineering and Technology
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• 제30권1호
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• pp.81-87
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• 2006

In marine air pollution control, SCR (Selective Catalytic Reduction) is reconized as the most effect method to control NOx, but on the other hand. seawater scrubber applying the basic characteristic that is naturally alkaline (pH typically around 8.1) is viewed as an economical SOx removal system at present. Especially, seawater scrubber would not be necessary to follow any of the various land based flue gas desulfurization methods. i.e. wet, dry or alkali scrubbing. However, these methods are not readily adaptable to marine conditions due to the quantifies of consumables required i.e. lime or limestone, the means of operation and the commercial availability. This research is undertaken to develop a new method as the main target of eliminating all exhaust emissions, particularly vessel, because of easy access to seawater and apt to apply a wet scrubber system. First, using the acidic seawater by seawater electrolysis, nitric monoxide(NO) is adequately oxidized to nitric dioxide $(NO_2)$by ClOx-in the acidic seawater, the electrolyzed alkaline seawater by electrolysis which contains mainly NaOH together with alkali metal ions $(i.e\;Na^{+}\;K^{+},\;Mg_{2}\;^{+},\;Ca_{2}\;^{+})$, is used as the absorption medium of NOx, the SOx are absorbed by relatively high solubility compared to other components of exhaust pollutants. The results found that the NOx and SOx removals could be achieved nearly Perfect.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 2015년도 추계학술대회
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• pp.64-65
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• 2015

본 연구는 PM과 SOx를 효과적으로 저감 시킬 수 있는 Water- Scrubber와 오염물과 세정수의 분리가 가능한 Purifier를 이용한 새로운 순환식 배기가스 세정시스템의 개발하여 PM, PAH 제거효율을 산정한 결과, PM과 PAH모두 유입 수 대비 99%이상 처리되는 것을 확인하였으며, 수질인자도 재사용이 가능한 유입수의 수준으로 분석되었다.

• 한국응용과학기술학회지
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• 제34권2호
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• pp.289-295
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• 2017

현 국제해사기구(IMO)에서의 선박엔진에서 발생되는 NOx와 SOx 등의 연소 가스 배출에 대한 규제 강화에 따라, 발트 해 연안을 지나는 모든 선박들은 배출되는 연소가스 저감장치를 장착해야 된다. 국내에서도 IMO의 규제에 따른 NOx와 SOx를 저감장치를 개발하고 있으며, 그중에 대표적인 장치인 Scrubber는 세정액으로 암모니아수와 요소수를 사용하게 되고 사용된 폐 세정액에는 NOx와 SOx와 반응한 질산암모늄과 황산암모늄이 포함되어 있다. 본 연구에서는 폐 세정액이 포함하고 있는 유용한 부산물을 유기용매를 사용하는 염석법을 적용하여 회수하였다. 질산암모늄과 황산암모늄의 회수방법과 질안석회를 추출 후 회수된 부산물의 정성분석을 위하여, FT-IR 분석을 통하여 물질의 정성적 특성과 화학적 조성을 평가해 보았다. 한편 응집제를 투입하여 질안석회를 침전시켜 비료상의 물질로 회수하였다. $FeSO_4$ 응집제와 $CaCl_2$를 응집보조제로 사용하고 입자의 크기를 키우기 위해 $CaCO_3$를 사용하였다.

• Journal of Advanced Marine Engineering and Technology
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• 제33권3호
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• pp.373-377
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• 2009

It is well known that SOx and NOx concentration has a considerable influence on the $N_2O$ emission of the greenhouse gas properties. The quantity of SOx generated during combustion, on fuel specific basis, is directly related to the sulfur content of the fuel oil. However, restricting the fuel oil sulfur content is only a partial response to limiting the overall quantity of SOx emissions, as there remains no over control on the fuel oil consumption other than the commercial pressure which have always directed the attention. This study was carried out as a new basic experiment method of emission control, manly targeted to the vessel. In the experiment, where the scrubbing was achieved through spray tower with high alkaline water made from the electrolysis of seawater, the combined action was to neutralize the exhaust gases (SOx, PM, CO etc.), dilute it, and wash it out. The results showed that SOx reduction of around 95 percent or over could be achieved when using in the high alkaline water, and also leaded to a reduction in the stability of the each pollutant components including the PM (Particulate Matter). The results suggest that the seawater electrolysis method has a very effective reduction of emissions without heavy cost, or catalysts particularly on board.

• 대한조선학회지
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• 제55권1호
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• pp.45-49
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• 2018

• 대한조선학회지
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• 제56권1호
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• pp.34-38
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• 2019

• 한국기계가공학회지
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• 제21권2호
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• pp.1-10
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• 2022

Exhaust gases emitted from internal combustion engines contain nitrogen oxides (NOx) and sulfur oxides (SOx), which are major air pollutants causing acid rain, respiratory diseases, and photochemical smog. As a countermeasure, scrubber systems are being studied extensively. In this study, the pressure drop characteristics were analyzed by changing the exhaust gas inflow velocity using a scrubber for a 700 kW engine as a model. In addition, the fluid flow inside the scrubber and the behavioral characteristics of the droplets were studied using CFD, and the design compatibility of the cleaning device was verified. Flow analysis was performed using inertial and viscous resistances by applying porous media to the complex shape of the scrubber. The speed of the exhaust passing through the outlet nozzle from the inlet was determined through the droplet behavior analysis by spraying, and the flow characteristics for the pressure drop were studied. In addition, it was confirmed through computational analysis whether there was a stagnation section in the exhaust gas flow in the scrubber or the sprayed droplets were in good contact with the exhaust gas.

• 유기물자원화
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• 제31권3호
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• pp.93-102
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• 2023

본 연구는 NOx, SOx를 동시 제거하는 방법에 추가로 대기 중에 존재하는 중금속 오염물질에 대해 처리가능한지를 스크러버에 산화제와 환원제를 마이크로버블 장치에 투입하여 2차 오염물질이 발생 되지 않는 친환경적인 처리방식을 연구하고자 하였다. 마이크로버블로 처리하고자 하는 대기 중 중금속 물질은 납화합물(Pb)을 선정하여 제거효율을 확인하였다. 마이크로버블을 스크러버에 연결하여 처리함으로써 NOx, SOx 뿐만 아니라 대기 중 중금속 물질 저감효과 및 비용 절감과 2차 환경오염물질이 발생 되지 않는 것을 확인하였다. 본 연구를 통하여 기존에 SCR과 같이 고비용의 처리방식이 아닌 친환경적인 방법을 적용하여 저비용으로 NOx, SOx, 중금속을 동시 제거가 가능하였으며, 산화제와 환원제 및 마이크로버블을 적절히 사용하면 경제적이고 효율적인 대기오염물질 처리가 가능하였으므로 환경방지시설의 기술 발전에 도움이 될 것으로 기대된다.