• Korean Journal of Soil Science and Fertilizer
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• v.48 no.1
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• pp.64-71
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• 2015

Soil contamination with arsenic and heavy metals is a worldwide problem. Main objective of this research was to evaluated effects of reducing heavy metal leaching under reduced soil condition amended with industrial by-products. The contaminated soil was amended with 3% (w/w) of limestone (Ls), steel slag (SS) and acid mine drainage sludge (AMDS). Synthetic acid rain ($H_2SO_4:HNO_3=6:4$, pH 5.5 fixed) was used for feeding solution with flow rate of $0.78{\sim}0.88mL\;min^{-1}$. Results showed that similar pH and EC of leachate was observed in all treatments regardless of applied industrial by-products. However, arsenic concentration of leachate increased when industrial by-products were mixed. Meanwhile, concentration of heavy metal in the leachate decreased from 11.3 to 4.59 mg for Cd, from 92.3 to 7.93 mg for Pb, and from 11,716 to 1,788 mg for Zn via immobilization in soil with AMDS amended, respectively. Overall, application of industrial by-products can be an environmentally-friendly way to remediate soil and(or) leachate contaminated with metal(loid)s in metal mine site.

• Magazine of the Korean Society of Agricultural Engineers
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• v.40 no.2
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• pp.112-122
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• 1998

Measurement of electrical resistivity in soils has been used for many years with purpose of estimating in situ porosity or density. Recently electrical resistivity has also been used as an indicator of soil contaimination. This paper presents the result of laboratory experiment to investigate the resistivity variation in contaminated sandy soils. The results can be used with the Cone Penetrometer Test (CPT) result to analyse ground condition. In the experiment, the water content and leachate concentration of soils were controlled by groundwater and leachate, and then the resistivity measurement was made with 'STING-R1' by Advanced Geosciences Inc. In the case of using groundwater, the resistivity was in the range of over 1000${\omega}{\cdot}m$, but in the case of using polluted water by leachate, the resistivity decreased significantly down to 10~ 100${\omega}{\cdot}m$ for the same moisture content. Also the resistivity varied according to the degree of saturatrion. Therefore, if soil is contaminated by leachate, the CPT with electrical resistivity sensor might be used to investigate the contamination status and plume migration. But exact component of leachate and the pollutant concentration are still hard to identify.

• Proceedings of the Korean Geotechical Society Conference
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• 2001.11a
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• pp.42-71
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• 2001

Leakage detection system can possibly locate leak point without laboratory analysis. Several different types of sensors provide these benefits. But the use of these technologies is not widespread, mainly because of cost. Each of the leakage detection systems available has different advantages and disadvantages. The ideal system would be affordable, durable enough to last through the life of the landfill, automated, and applicable to all types of landfills. The laboratory tests were performed to investigate the relationship between electrical resistivity and the unsaturated subsurface condition and to evaluate the contamination due to leachate based on measuring electrical resistivity. The results of experiment show that the electrical resistivity of soil decreases as moisture density increases. The electrical resistivity of soil decreases as the concentration of leachate in pore fluid increases. These facts indicate that electrical resistivity method can be a promising tool in detecting of leachate. Also, the field model tests were conducted to verify that detection of leachate leak point on detection system using electrical characteristics is accurate. Field model test results of leakage detection system imply that the leakage detection system using electrical characteristics have the great potential of detecting exactly the leak point of leachate.

• Journal of Environmental Impact Assessment
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• v.12 no.3
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• pp.161-170
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• 2003

To investigate the characteristics of 17 solid waste landfills in the upper drainage basin of Lake Daechong, the landfill sites were surveyed, the leachate of these landfills were analyzed, and the analysis results were assessed from standpoint of water contamination. Sanitary landfills which are now being operated are relatively well equipped with facilities such as leachate collection, daily soil cover and landfill gas treatment devices. But a few of open-dumping landfills were leaking leachate apparently and were supervised improperly and neglectfully by local governments. Some of sanitary landfills exceeded the COD permission criteria of leachate effluent, and some of open-dumping landfills exceeded SS, T-P, Pb, As, Fe, Mn permission criteria of leachate effluent. To improve the water quality of Lake Daechong which is utilized for supplying drinking water, agricultural water, and industrial water to the great part of Chungchong area, the adequate and prompt measures for preventing Daechong Lake water contamination from landfills leachate is necessary.

• Journal of Environmental Science International
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• v.7 no.3
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• pp.383-392
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• 1998

Pollution characteristics of leachate and underground soul of the two landfill states were Investigated Domestic wastes were dumped In the two adjacent landfill states. Only small portion of S landifill site was filled with domestic wastes at the first stage of dumping, and most portion of the site was filled with construction wastes. However Y landfill strate was filed with mostly domestic wastes. Higher concentrations of organic pollutants including VOCs were measured In Y landfill site leachate than In S tendon site. Underground souls of the two linam states were analyzed by the two kinds of leaching methods, KEP (Korean Extraction Processl and Acid Digestion. Underground souls of the both landfill states were not polluted by leachates. Underground soils of the two were composed of firie salty material. Thus It Is fecund that fine silty soul layer of the sea shore may be used as a landfillsite.

• Proceedings of the Korean Geotechical Society Conference
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• 2002.03a
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• pp.343-346
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• 2002

The chemical compatibility of leachate with the two natural materials was analyzed by performing the hydraulic conductivity test. The selected liner materials were natural marine clay and weathered soil sampled from Kimpo wastefill and Daehwa Dong, Kyonggi Do, respectively. PARAFIX, which is mainly composed of paraffin, cement, stearic acid, PVA etc., was used as solidifying agent. The chemical solutions used in the test were 10% acetic acid, 10% methanol, and real leachate from Kimpo wastefill and the results of tests were compared with that of distilled water. The results of tests show that hydraulic conductivity of solidified clay was increased slightly with permeation of acetic acid, methanol and the increase of hydraulic conductivity was not shown with permeation of leachate, distilled water and in case of weathered soil. Based on the tests, it is ascertained that the tested liner materials can be stable with the solution of low concentration.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 1998.10a
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• pp.388-394
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• 1998

In this study, the influence of soil contaminant on the cement solidification treatment was considered. Unconfined compression strength(UCS) test was carried out for solidificated specimen, Setting time was measured for cement slurry that was mixed with leachate and wastewater. It was appeared that treatment effect were affected by the the kind of soil, organic content, component of pore water and its concentration. And UCS of samples which were cured in the leachate were decrease about l/5. Especially for the marine clay, UCS of samples which were cured in leachate during 180 days were smaller than 90 days cured samples in the case of cement mixing ratio 5%, 10%.

• Journal of Soil and Groundwater Environment
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• v.16 no.4
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• pp.53-61
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• 2011

This study examined evaluation on stabilization of major and trace elements in tailings by various surface water-preventing materials. Six columns were filled with tailings of the Sinlim mine, then covered with tailings only, compacted soils, clay, soil-bentonite mixture, pozzolan and bentonite mat. After injection of artificial rain water, the leachate was sampled with times (3, 6, 9 and 12 pore volume) and analysed for major (Ca, Na, Mg, K) and trace elements (As, Cd, Cu, Pb, Zn) by ICP-AES. With exception to pozzolan type, the pH values of leachate from the other types became stabilized from 5.5 to 7.5, and EC (electric conductivity) of leachate from them decreased with times. For the pozzolan type, however, the pH and EC of leachate increased with time due to its alkalinity producing system. Concentrations of most major and trace elements in leachate decreased and stabilized with time. Consequently, soil-bentonite mixed cover shows the best ability of water-preventing and reducing mobility of elements in tailings site.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.04a
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• pp.98-103
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• 2001

In order to understand the characteristics of leachate at the Seokdae municipal waste landfill in the Pusan city, the correlation between leachate pollution loading and volume of gas production. concentration of gas and subsidence of ground, the characteristical methos, geochemical analyses and laboratory column tests using samples of gases, leachate and surface soil of Seokdae waste landfill area. Through the analysis of water balance, leachate flow rate and pollution loading were estimated. Geistatistical analysis of four gas components ( $O_2$, C $H_4$, $H_2$S and CO) shows the possibility of ground subsidence around the group of a site with high concentration of gas. From geochemical analyses of leachate, EC and Total-Alkalinity of ground subsidence around the group of a site with high concentration of gas. From geochemical analysis of leachate, Ec and Total-Alkalinity were increased, and Cl, Cr, Mn, Cu, Zn, Cd and Pb were decreassed comparing to the part, and the type of water quality was Na-HC $O_3$ in trilinear diagram. It shows that biodecomposition of municipal wastes continues actively. From the analysis of water balance, the total leachate flow rate is about 465.11㎥/day and pure pollution loading of Cl, Mn and Fe are estimated to 223.8kg/day, 0.2kg/day, 0.3kg/day, respectively. The laboratory column test of residual soil and landfill soil shows 0.206cm and 0.019cm for linear velocity(equation omitted), 0.234 $\textrm{cm}^2$/min and 0.018$\textrm{cm}^2$/min for diffusion coefficient ( $D_{ι}$), and 1.136cm and 0.095cm longitudinal dispersion index ($\alpha$$_{ι}$), respective]y. It demonstrates that the delay time of contamination for residual soil is shorter than that of landfill soil.

• Journal of Soil and Groundwater Environment
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• v.6 no.2
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• pp.31-38
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• 2001

An illegal landfill In Korea was evaluated in a view of environmental quality to figure out reusing the area. The sampling spots were selected at a point in the landfill and three points in it's around area(two points in a paddy soils and one in a farm field). The eleven pollutants regulated in the Korean Soil Environmental Preservation Act (KSEPA) were analysed from the soil sample with the method of the KSEPA. As the results of the analysis the level of concentration with most samples indicated the requirement of the KSEPA. The concentration of soil samples met the standard: however, some pollutants in the ground water and leachate showed higher concentration than that of the requirement. Therefore, we must consider the treatments of the pollutants in the ground water and leachate when designing this landfill area for reusing.