• Applied Biological Chemistry
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• v.20 no.1
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• pp.109-116
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• 1977

Much attention has been paid to the fact that quite a few herbicides such as phenylcarbamates, phenylureas, and acylanilides form azo compounds known as carcinogens by virtue of the microoranisms in soil. In consequence, many investigators synthesized. TCAB, an azo compound, starting from 3,4-dichloronitrobenzene for the related studies. However, the authors were under the necessity of synthesizing $^{14}C-ring-labeled$ TCAB from $^{14}C-ring-labeled$ 3,4-DCA available, in addition to making up for the disadvantage of dechlorination in the reduction of 3,4-dichloronitrobenzene. The new method is as follows:TCAB, $^{14}C-ring-labeled$ and non-labeled, was produced by aerial oxidation of 3,4-DCA catalyzed by CuCl with pyridine as solvent at $60^{\circ}C$ for 5-12 hrs, giving 80.2% yield. The procedure forpurification was described in detail. The identities of TCAB isomers were confirmed by means of autoradiography, TLC, GLC, IR, and MS.

• Korean Journal of Medicinal Crop Science
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• v.7 no.1
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• pp.58-62
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• 1999

This study was to determine aromatic constituents and essential oil content in the root of Codonopsis lanceolata grown at different altitudes; Andong(150m), Mt. Hagka(550m) and Mt. Irwol(750m). Soil pH in Mt. Hagka and Mt. Irwol was 5.6 and 6.1, respectively, which was lower than in Andong(150m), but organic matter content was higher than that of Andong with 6.7 to 8.8%. Fresh root yield also increased as cultural region was located at higher altitude. In particular, yield in Mt. Irwol was 281kg/10a. Essential oil content was highest of 0.006% in the Mt. Irwo1. Forty-eight volatile aromatic compounds in the root of Codonopsis lanceolata were identified by GC/MS. Major aromatic compounds were 1-hexanol, cis-3-hexano1. and Trans-2-hexanol. In partucular, Trans-2-hexanol, was highest in Mt. Irwol attaining the 47.22% area. As a result, it was considered that cultural region above 700m in altitude was the most effective for the improvement of essential oil and aromatic constituents in the roots of Condonopsis lanceolata Trautv.

• Journal of Korean Society of Forest Science
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• v.35 no.1
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• pp.9-14
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• 1977

The productive structure and the productivity of ${\times}$Populus albaglandulosa plantations, where are middle parts of the Korean peninsula, were studied by means of stratifying clip technique and of allometry. The densities of stands in the sample areas were 693 trees/ha in 6 year-old plantation and 527 or 625 trees/ha in 9 year-old one. The photosynthetic part of the productive structure was not shown normal conical form but layering. So this was efficient to transmit solar radiation into the stand floor. The standing crop of the terrestrial parts of 6 year-old plantation was 18.11 ton/ha and that of 9 year-old one 38.8 to 47.3 ton/ha. The wood volume to trunk to 6 year-old was $31.3m^3/ha$ and that of 9 year-old was 68.8 to $83.9m^3/ha$. The annual net production of 6 year-old plantation was 4.8 ton/ha/year and that of 9 year-old one was 10.0 to 11.7 ton/ha/year and its wood volume of trunks was 17.9 to $21.1m^3/ha/year$. In the 9 year-old plantation the standing crop or the annual net production was different between two sample areas. This seemed that the cause was not due to chemical character but to physical character of soil.

• Geotechnical Engineering
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• v.8 no.2
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• pp.5-20
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• 1992

The physical-based and lumped-parameter hydrologic groundwater flow model for predicting the rainfall-triggered rise of groundwater levels in hillside slopes is developed in this paper to assess the risk of landslides. The developed model consists of a vertical infiltration model for unsaturated zone linked to a linear storage reservoir model(LSRM) for saturated zone. The groundwater flow model has uncertain constants like soil depttL slope angle, saturated permeability, and potential evapotranspiration and four free model parameters like a, b, c, and K. The free model parameters could be estimated from known input-output records. The BARD algorithm is uses as the parameter estimation technique which is based on a linearization of the proposed model by Gauss -Newton method and Taylor series expansion. The application to examine the capacity of prediction shows that the developed model has a potential of use in forecast systems of predicting landslides and that the optimal estimate of potential 'a' in infiltration model is the most important in the global optimum analysis because small variation of it results in the large change of the objective function, the sum of squares of deviations of the observed and computed groundwater levels. 본 논문에서는 가파른 산사면에서 산사태의 발생을 예측하기 위한 수문학적 인 지하수 흐름 모델을 개발하였다. 이 모델은 물리적인 개념에 기본하였으며, Lumped-parameter를 이용하였다. 개발된 지하수 흐름 모델은 두 모델을 조합하여 구성되어 있으며, 비포화대 흐름을 위해서는 수정된 abcd 모델을, 포화대 흐름에 대해서는 시간 지체 효과를 고려할 수 있는 선형 저수지 모델을 이용하였다. 지하수 흐름 모델은 토층의 두께, 산사면의 경사각, 포화투수계수, 잠재 증발산 량과 같은 불확실한 상수들과 a, b, c, 그리고 K와 같은 자유모델변수들을 가진다. 자유모델변수들은 유입-유출 자료들로부터 평가할 수 있으며, 이를 위해서 본 논문에서는 Gauss-Newton 방법을 이용한 Bard 알고리즘을 사용하였다. 서울 구로구 시흥동 산사태 발생 지역의 산사면에 대하여 개발된 모델을 적용하여 예제 해석을 수행함으로써, 지하수 흐름 모델이 산사태 발생 예측을 위하여 이용할 수 있음을 입증하였다. 또한, 매개변수분석 연구를 통하여, 변수 a값은 작은 변화에 대하여 목적함수값에 큰 변화를 일으키므로 a의 값에 대한 최적값을 구하는 것이 가장 중요한 요소라는 결론을 얻었다.

• Journal of the Korean Geotechnical Society
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• v.28 no.6
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• pp.19-29
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• 2012

Pack micropiles were recently developed to improve pile capacity of general micropiles. Pack micropiles were made by warping thread bar or steel pipe of general micropile by geotexlile pack and grouting inside the pack with pressure. According to the pressure, the boring hole could be enlarged. A series of pile uplift tests were performed on three micropiles. Two out of the three piles were the pack micropiles and the other was the general micropile, in which a thread bar was used in the boring hole. According to the pressure applied to the pack micropiles, the diameter of boring hole was enlarged from 152 mm to 220 mm. Unit skin friction mobilized on side surfaces of micropiles increased with displacement of pile head and reached on a constant value, which represents that the relative displacement between piles (or thread bar) and soils was reached on critical state. And the uplift resistance of pack micropile was higher than that of general micropile. Two reasons can be considered: One is that the frictional surface increases due to enlarging diameter of boring holes and the other is that the unit skin friction could increase due to compressing effect of surrounding soils by soil displacement as much as the enlarging volume of boring hole. The compression effect appeared at deeper layer rather than surface layer. The unit skin friction mobilized on micropiles with small diameter was higher than the ones on large bored piles.

• Journal of the Korean Geotechnical Society
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• v.30 no.3
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• pp.59-72
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• 2014

For circular rigid footings with a rough base on sand, combined vertical - moment loading capacity was studied by three-dimensional numerical modelling. Mohr-Coulomb plasticity model with the associated flow-rule was used for the soil. After comparing the results of the swipe loading method, which can construct the interaction diagram with smaller number of analyses, and those of the probe loading method, which can simulate the load-paths in the conventional load tests, it was found that both loading methods give similar results. Conventional methods based on the effective width or area concept and the results by eccentricity factor ($e_{\gamma}$) were reviewed. The results by numerical modelling of this study were compared with those of previous studies. The combined loading capacity for vertical (V) - moment (M) loading was barely affected by the internal friction angle. It was found that the effective width concept expressed in the form of eccentricity factor can be applied to circular footings. The numerical results of this study were smaller than the previous experimental results and the differences between them increased with the eccentricity and moment load. Discussions are made on the reason of the disparities between the numerical and experimental results, and the areas for further researches are mentioned.

• Journal of the Korean Geotechnical Society
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• v.32 no.11
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• pp.83-96
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• 2016

The surface settlement of the back ground of a braced wall due to the ground excavation has the great influence on the safety of the surrounding area. But it is not easy to predict the settlement of the surrounding area due to proud excavation. Estimation of the settlement of the surface ground induced by the deformation of the braced wall is performed by FEM and empirical method (Peck, Clough etc). In this research, surface settlement of the back ground braced wall depending on the joint dips in rocks during excavating the composit ground was measured at the large scale model test (standard: $0.3m{\times}0.3m{\times}0.5m$). The scale of model test was 1/14.5 and the ground was excavated in ten steps. Earth pressure on the braced wall and ground surface settlement on the back ground of a braced wall were investigated. The surface settlement during the excavation depended on the joint dips in rocks on of the ratio of rock layer. Maximum earth pressure and maximum surface settlement were masured at the same excavation step. In accordance with the increase of the rock layer dips and rock layer ratio, the ground surface settlement increased. The maximum ground surface settlement was 17 times larger at 60 degree joint dips in rocks than that of the horizontal ground conditions. And the position of the maximum surface settlement by empirical method was calculated at the point, which was 17%~33% of excavation depth. In accordance with the increase of the rock layer dips and rock layer ratio, the ground maximum surface settlement increased. The ground surface settlement of composite ground is smaller than that of the empirical.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.33 no.2
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• pp.529-536
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• 2013

The semi-distributed rainfall runoff model of SWAT is applied to the Seom-river experimental watershed. The simulations of various antecedent periods before the targeted simulation periods of 2002 to 2009 are not necessary despite of the slight appearance of corresponding changes in simulated total runoff. The simulated results of total runoff by using various numbers of soil layer maps have little differentiated nevertheless the slight changes in simulated results have been appeared. The 7 parameters of CANMX, $CN_2$, ESCO, GW_REVAP, SOL_ALB, SOL_AWC, and SOL_K greatly govern the rainfall runoff are confirmed and their sensitivity analyses have been carried out. The optimal parameters used in SWAT are derived by SUFI-2 of SWAT-CUP. The NS and $R^2$ are 0.99 and 0.98, respectively which is shown the good agreement between the observed and the simulated results. The uncertainty factors of P-factor and R-factor are 0.85 and 0.06, respectively which is also shown the high efficiency of the model. The high applicability is also shown with improving the RMSE in SWAT model simulation using the parameters estimated by SUFI-2 of SWAT-CUP.

• Journal of Korean Tunnelling and Underground Space Association
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• v.15 no.5
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• pp.455-468
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• 2013

In recent, various types of steel pipe-roof methods, which is reinforced by mortar after propulsion of steel pipe into the ground, have been used for the construction of trenchless underpass. Integrated steel pipe-roof has flexural stiffness and can resist against overburden load and reduce the stress acting on the concrete underpass structures. Due to arching effect, vertical and horizontal stress distribution around the steel pipe-roof is changing. In this study, therefore, the characteristic of stress distribution around the underpass induced by the construction of integrated steel pipe-roof is investigated by using numerical method. To examine the soil-structure interaction, interface element is introduced. Results show that vertical stress acting on the concrete structure placing inside the steel pipe-roof is significantly reduced due to arching effect and flexural stiffness of integrated steel pipe-roof. Design load can be reduced and effective design of underpass will be available if the earth pressure reduction due to arching effect is considered in the design stage.

• The Journal of Natural Sciences
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• v.5 no.1
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• pp.67-75
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• 1992

In the our country, especially in Yeongil and Wolsung area, abundant authigenic zeolites are found from the tuffaceous sediments and volcanic rocks of Miocene age showing wide variation in their mineralogy and abundance from horizon to horizon. The principal zeolite species identified are clinopti-lolite. mordenite. heulandite. ferrierite, and erionite. etc. Zeolite minerals are widely used in many countries in the following applications; (a) in air separation adsorption processes; (b)as desiccants; (c)in inorganic building materials; (d)in papermaking; (e)in fertilizers; (f)as soilconditioners-this application is based upon the ability of the zeolite to ion exchange with soil nutrients; (g)in the treatment of radioactive wastes; and (h)as adsorbents for toxic gases, etc. In the present paper, using natural zeolite mordenite treated with IN hydrochloric acid or IN sodium chloride solution as column packings, separation characteristics of argon, nitrogen, carbon monoxide, and methane gases have been studied by gas chromatography. By the use of mordenite treated with hydrochloric acid solution, the tailing peak of methane showed from untreated mordenite was satisfactorily reduced, although it was difficult to separate it from carbon monoxide with a column activated at $300^{\circ}C$. Using a column activated at $350^{\circ}C$, methane could be separated from carbon monoxide easily but only carbon monoxide eluted as a bad defined peak. Mordenite treated with sodium chloride solution was generally similar to chromatograms obtained by using the untreated mordenite. Both the above chemical treatments of mordenite had little effect on the separations of argon and nitrogen. The separations and the HETP values obtained from natural zeolite mordenite treated with continuously hydrochloric acid and sodium chloride solutions were almost identical with those obtained with synthetic molecular sieve 5A zeolite. On the other hand, the efficiency of column was good in the range 20~3Oml/min of the carrier helium gas rate.