• Title/Summary/Keyword: SO2 gas

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Photodecomposition Properties of Formaldehyde Using PS Nanofiber and Photocatalyst (극세섬유와 광촉매를 이용한 포름알데히드의 광분해 특성)

  • An H.H.
    • Journal of the Korean Institute of Gas
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    • v.10 no.2 s.31
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    • pp.1-6
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    • 2006
  • In this study we proposed on effect of the photodecomcomposition of coated nanofiber by $Pd/TiO_2$ for the removal of formaldehyde gas as indoor air pollutant. The photocatalytic reactor was setup in the inside of rectangular box (volume 2 l), UV lamp and the coating nanofiber with $Pd/TiO_2$. This study investigated the reaction rate and the adsorption constant of Langmuir-Heinshelwood, conversion of formaldehyde gas on temperature ($40^{\circ}C{\sim}80^{\circ}C$), effect of conversion (%) under different concentration, and effect of conversion (%) with humidity level on added $SO_2$ gas. As results, the rate constant (k) and adsorption constant (ft) were 114.94ppmv/min, $0.0036ppmv^{-1}$, respectively. and the conversion (%) of formaldehyde gas on temperature ($40^{\circ}C{\sim}80^{\circ}C$) was decreased to about 24%, compare with the first conversion (%). In conversion effect of increasing humidity levels, the presence of sulfur dioxide further decreased than without sulfur dioxide. the decreasing reason of conversion with presence sulfur dioxide judged as a cause of interference factor on the decrease of contact chance with photocatalysts.

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Fabrication and Sensing Properties of NASICON Thick Film SO2 Gas Sensor Using Screen-print Method (스크린 인쇄법을 이용한 NASICON 후막 SO2가스 센서의 제조 및 특성)

  • Bae, J.C.;Lee, S.T.;Jun, H.K.;Bang, Y.I.;Lee, D.D.;Huh, J.S.
    • Korean Journal of Materials Research
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    • v.13 no.2
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    • pp.115-119
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    • 2003
  • The thick film type sensor having Pt/Na Super Ionic Conductor(NASICON) solid electrolyte/Pt/$Na_2$$SO_4$/Pt catalyst system for $SO_2$gas was fabricated by screen-print method. The phase of Na Super Ionic Conductor solid electrolyte sintered at different temperature of 1050, 1150,$ 1250^{\circ}C$ and for different time of 1.5, 2.5, 3.5 hr were investigated by XRD. The Electromotive Force variation of the sensor with $SO_2$concentrations and operating temperatures were investigated. The major phase of Na Super Ionic Conductor film sintered at 115$0^{\circ}C$ for 3.5 hr was sodium zirconium silicon phosphate($Na_3$Zr$_2$$Si_2$PO$_{12}$). The Nernst's slope of Na Super Ionic Conductor sensor for $SO_2$gas with the variation of concentration from 10 to 100 ppm was 167.14 ㎷/decade at the operating temperature of $500 ^{\circ}C$. The increase of oxygen partial pressure was not affected to the variation of Nernst's slope.e.

Simultaneous removal of $SO_X$ and $NO_X$ by wet scrubber at small and medium craft (중소형 선박의 $SO_X/NO_X$ 동시제거를 위한 습식세정시스템)

  • Cha, Yu-Joung;Lee, Ju-Yeol;Ha, Tae-Young;Park, Byung-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.159-166
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    • 2014
  • In recent years, researchers have put a considerable effort to decrease the emission of harmful gaseous pollutants to the atmosphere. In order to remove simultaneously $SO_2$ and $NO_X$ from the flue gas of small and medium-sized ship, we designed minimal wet scrubber inside a compact multistage modular system. In this study we proceed experiment of elemental technology at each stage of the scrubber. The each stage is oxidation of NO which is the main component of $NO_X$, and removal of $SO_2$, respectively. $NaClO_2$ was used to oxidize NO gas, and NaOH was used to remove $SO_2$ gas. The maximum NO conversion efficiency and the $SO_2$ removal efficiency are both indicate 100%.

A Study on the Change of Condensable Particulate Matter by the SO2 Concentration among Combustion Gases (연소 배출가스 중 SO2 농도에 따른 응축성먼지 변화에 관한 연구)

  • Yu, JeongHun;Lim, SeulGi;Song, Jihan;Lee, DoYoung;Yu, MyeongSang;Kim, JongHo
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.5
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    • pp.651-658
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    • 2018
  • Particulate matter (PM) emitted from fossil fuel-combustion facilities can be classified as either filterable or condensable PM. The U.S. Environmental Protection Agency (EPA) defined condensable PM as material that is in the phase of vapor at the stack temperature of the sampling location which condenses, reacts upon cooling and dilution in the ambient air to form solid or liquid in a few second after the discharge from the stack. Condensable PM passed through the filter media and it is typically ignored. But condensable PM was defined as a component of primary PM. This study investigates the change of condensable PM according to the variation in the sulfur dioxide of combustion gas. Domestic oil boilers were used as the source of emission ($SO_2$) and the level of $SO_2$ concentration (0, 50, 80, and 120 ppm) was adjusted by diluting general light oil and marine gas oil (MGO) that contains sulfur less than 0.5%. Condensable PM was measured as 2.72, 6.10, 8.38, and $13.34mg/m^3$ when $SO_2$ concentration in combustion gas were 0, 50, 80, and 120 ppm respectively. The condensable PM tended to increase as the concentration of $SO_2$ increased. Some of the gaseous air pollutants emitted from the stack should be considered precursors of condensable PM. The gas phase pollutants which converted into condensable PM should reduced for condensable PM control.

Effect of Sulfur Dioxide Gas and Abscisic Acid Pretreatment on Physiological Susceptibility and Growth Damages of Coniferous Seedlings (아황산(亞黃酸)가스 및 ABA 전처리(前處理)가 침엽수(針葉樹) 유묘(幼苗)의 생장피해(生長被害)와 생리적(生理的) 감수성(感受性)에 미치는 영향(影響))

  • Lee, Im Kyun;Kim, Young Chai
    • Journal of Korean Society of Forest Science
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    • v.83 no.3
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    • pp.331-343
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    • 1994
  • This study was conducted to find out the effect of $SO_2$ gas on growth of tree species and the effect of pretreatment of ABA to Pinus koraiensis. Abies holophylla and Taeus cuspidata on the susceptibility for $SO_2$ gas damage. The survey was carried out on the water contents of leaf and shoot, and the acidities of bark and leaf, and the chlorophyll and water soluble sulfur contents, and the changes of transpiration rates on selected seedlings exposed to $SO_2$ gas at seven levels : 0ppm, 0.5ppm, 1ppm, 2ppm, 4ppm, 26.4ppm ABA, 56.8ppm ABA. The results obtained from this research are as follows : 1. The water contents of leaf and shoot of the three tree species decreased with increasing concentrations of $SO_2$ gas and the relative susceptibility of Abies holophylla was larger than those of Taxus cuspidata and Pinus koraiensis because moisture diminution rates were higher in leaves and shoots of Abies holophylla than those of other species. 2. The acidities of bark and leaf of the three tree species increased with increasing concentrations of $SO_2$ gas. The relative susceptibility of Pinus koraiensis in bark acidity was larger than those of Abies holopfaylla and Toxus cuspidata. Abies holophylla was more susceptive than Pinus koraiensis and Taxus cuspidata. 3. Water soluble sulfur contents of the three tree species increased with increasing concentration of $SO_2$ gas. The relative susceptibility of Taxus cuspidata in water soluble sulfur contents was lager than those of Pinus koraiensis and Abies holophylla. 4. Leaf chlorophyll contents of the three tree species decreased with increasing concentrations of $SO_2$ gas. The order of the relative susceptibility in leaf chlorophyll contents was Taxus cuspidata, Abies holophylla and Pinus koraiensis. 5. Correlation coefficients among the measurement were highly significant for $SO_2$ treatment in all three tree species. 6. The transpiration rates of Abies holophylla and Taxus cuspidata did not change until up to 220 minutes after initiation of $SO_2$ gas fumigation, and changed a little during the time between 220 minutes and 270 minutes. On the other hand, Pinus koraiensis continued to change in transpiration rates little by little from the start of $SO_2$ gas treatment up to 270 minutes, meaning that Pinus koraiensis is less sensitive to ABA. 7. When 2ppm of $SO_2$ was treated. ABA pretreatment effect was detected on the six measurement parameters. ABA affected the resistance of plants by inducing stomata closure. 8. The order of relative susceptibility of the three tree species to $SO_2$ gas fumigation was Abies holophylla, Taxus cuspidata and Pinus koraiensis. Pinus koraiensis was more resistant to $SO_2$ gas than Abies holophylla and Taxus cuspidata.

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The effect of H2O, NH3 and applied voltage to the particle conversion in the desulfurization system using a nano-pulse plasma (나노펄스 플라즈마를 이용한 탈황 시스템의 H2O 및 NH3, 펄스 인가전압에 따른 입자변환 분석)

  • Kim, Younghun;Shin, Dongho;Lee, Gunhee;Hong, Keejung;Kim, Hak-Joon;Kim, Yong-Jin;Han, Bangwoo;Hwang, Jungho
    • Particle and aerosol research
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    • v.16 no.1
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    • pp.1-8
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    • 2020
  • Nano-pulse plasma technology has great potential as the process simplicity, high efficiency and low energy consumption for SO2 removal. The research on the gas-to-particle conversion is required to achieve higher efficiency of SO2 gas removal. Thus, we studied the effect of the relative humidity, NH3 concentration and applied voltage of the nano-pulse plasma system in the gas to particle conversion of SO2. The particles from the conversions were increased from 10 to 100 nm in diameter as relative humidity, NH3 concentration, applied voltage increases. With these results, nano-pulse plasma system can be used to more efficient removal of SO2 gas by controlling above parameters.

$SO_2$ and CO Removal Characteristics in Various Applied Voltage of Nonthermal Discharge Plasma in a Crossed DC Magnetic Field (전.자계상의 전원장치변화에 따른 비열방전 플라즈마의 $SO_2$와 CO가스 제거특성)

  • Lee, Geun-Taek;Geum, Sang-Taek;Mun, Jae-Duk
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.3
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    • pp.215-220
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    • 1999
  • $SO_2$and CO gas removal characteristics of a wire-to-cylinder type nonthermal discharge plasma reactor in various applied voltage (-dc, ac, fast rising pulse and high frequency pulse) and a crossed dc magnetic field have been investigated. The experiment has been emphasized on the oxidizing characteristics of $SO_2$ and CO gas by $O_3$ and the applying of a crossed magnetic field, which would induce the cyclotronic and drift motions of electrons making the residual time longer in the removal airgap space. And it also would enhance the energy of electrons and the electrophysicochemical actions to remove the pollutant gases effectively. It is found thatthe corona onset voltage and the breakdown voltage were decreased with increasing the crossed magnetic field and decrease initial fed $SO_2$and CO concentration. As a result, a higher ozone generation and $SO_2$ and CO gas removal rate of 20[%] can be obtained with -dc, ac and fast rising pulse corona discharges in the crossed dc current-induced magnetic field. But high frequency pulse didn't show effect in applying of a crossed magnetic field.

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Study on Wet Scrubber for SOX/NOX Treatment in Ship Flue Gas (선박 배가스내 SOX/NOX 처리용 습식 스크러버에 대한 연구)

  • Choi, Jin-Sik;Kim, Jae-Gang;Park, Byung Hyun;Lee, Ju-Yeol
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.183-188
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    • 2017
  • This study deals with $de-SO_X$ and $de-NO_X$ process of a wet scrubber for small size ship engines. The experiment was conducted according to the E3 mode of the $NO_X$ technical code. In order to discharge the sulfur containing flue gas, ditertiarybutyldusulfide was added to the diesel fuel to increase the sulfur content. NO gas, which occupies most of the nitrogen oxides in the exhaust gas, was oxidized into $NO_2$ and absorbed by a wet scrubber. The developed equipment of this work achieved 100% of removal efficiency for highly soluble $SO_2$ gas in an aqueous solution.

High Temperature SO2-gas Corrosion of Fe-18%Cr-10%Ni Steels for Coal-fired Power Plant (화력발전소용 Fe-18%Cr-10%Ni 강의 고온 SO2 가스 부식)

  • Lee, Dong-Bok
    • Journal of the Korean institute of surface engineering
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    • v.40 no.5
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    • pp.219-224
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    • 2007
  • The corrosion characteristics of Fe-18Cr-10Ni steels were studied between $600^{\circ}C$ and $1000^{\circ}C$ in Ar+(0.2, 1)%$SG_2$ gas for up to 300 hr in order to employ Fe-18Cr-10Ni steels in the coal-fired power plants. The corrosion resistance of Fe-18Cr-10Ni steels was good due mainly to the high amount of Cr, which formed $Cr_2O_3$ from the initial corrosion stage. Fe in the steels corroded to mainly $Fe_2O_3$ and $Fe_3O_4$. Ni was not susceptible to corrosion under the current corrosion condition. Relatively thin, single-layered scales formed.

The Analysis of Insulation Properties with Electron Collision Processes on SF6 Mixture Gases (전자충돌과정을 통한 SF6 혼합기체의 절연특성 분석)

  • So, Soon-Youl
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.59 no.2
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    • pp.197-201
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    • 2010
  • $SF_6$ gas would be used in power transformer, GIS (Gas insulated switchgear) and so on because of its electrically superior insulation and chemically stable structure. Recently, the reduction of $SF_6$ is required to avoid global warming and the researches on the dilution of $SF_6$ with other gases have been carried out. $SF_6$ mixture gases with $N_2$ and $C_xF_y$ have drawn attention to the synergy effect. However, in order to understand the mechanism of the synergy effect, it is important to analyze and evaluate properties of mixture gases quantitatively. In this paper, we investigated the mechanism of synergy effect from electron collision processes and electron energy distribution by solving Boltzmann equation with propagator method. Three kinds of gases for dilution of $SF_6$ ($SF_6/N_2$, $SF_6/CF$4 and $SF_6/C_4F_8$) are considered in this simulation. On the properties of $SF_6/N_2$ mixture gas, the variation of reduced electric field was shown highly within 0%~40% mixtures of $SF_6$. And the more low-level electron energy has been distributed, the higher insulation capability has appeared.