• 제목/요약/키워드: SO

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$SO_{2}$에 의한 dopachrome 형성 억제 패턴 (Inhibition Patterns of Dopachrome Formation as Influenced by Sulfur Dioxide)

  • 조윤옥;이미순
    • Journal of Nutrition and Health
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    • 제17권1호
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    • pp.60-67
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    • 1984
  • 감자의 마쇄된 조직에서 추출한 효소액과 감자박편을 이용하여 효소적 변색에 대한 $SO_{2}$의 억제 기작을 조사하였다. $SO_{2}$는 경쟁적인 방식으로 dopachrome형성을 억제하는 것으로 나타났다. 불충분한 $SO_{2}$의 농도에서는 시간이 경과함에 따라 dopachrome의 형성이 재개시되었다. 본 실험의 결과는 $SO_{2}$가 효소적 갈변중의 중간산물과 addition compounds를 형성하여 효소적 변색을 지연시킬 수도 있다는 것을 시사하였다. 감자박편에서 dopachrome생성을 억제하기 위하여 는 마쇄된 조직에서보다 더 많은 $SO_{2}$가 요구되었다.

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Calciumsilicate의 생성반응에 미치는 $SO_3$ 영향(III) (Effect of $SO_3$ on Calciumsilicate Formation(III))

  • 임은극;박병철
    • 한국세라믹학회지
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    • 제21권3호
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    • pp.221-230
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    • 1984
  • In this study an investigation was made to determine optimum ratio between $SO_3$, MgO and $K_2O$ that maximizes $C_2S$ formation in Clinkering reaction Using response surface analysis method. It was proved that 1) Residual $K_2O$ int he clinker should be converted to $K_2SO_4$ because $K_2SO_4$ has less effect on the burnability than $K_2O$, 2) Optimum ratio if $SO_3$/K2O is 1.5, 3) Optimun balance between $CaSO_4$ and MgO is to be adjusted to such a level that w/o SO3=0.7(w/o MgO-2).4) In case of lack of $K_2O$ free CaO was minimized when $K_2SO_4$=2.3w/o and MgO=1.5w/o but if remaining $K_2O$ was 2w/o free CaI was minimized in the level that $K_2SO_4$=2.3w/o and MgO =1.5 w/o but if remaining $K_2O$ was 2 w/o free CaO was minimized in the level that $K_2SO_4$=4.5w/o and MgO =3.0 w/o.

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『의림촬요(醫林撮要)-삼소문(三消門)』의 의학적 성취

  • 조선영;차웅석;김남일;유원준
    • 한국의사학회지
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    • 제19권1호
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    • pp.149-166
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    • 2006
  • Following former study(A Study of the Perception of SoGal in the early through mid Chosun Dynasty-Focusing on "UiBangYuChi(醫方類聚)" and "DongUiBoGam(東醫寶鑑)", there were medical attainments in this study on SoGal(消渴) of "UiRimChualYo(醫林撮要) SamSoMun(三消門)". 1. SoGal(消渴) theory of "UiRimChualYo(醫林撮要) SamSoMun(三消門)" presented the lack of Bodily Liquids and Blood theory(津液 血不足論) overcoming the limits of the fire/heat theory(火熱論). 2. In the "UiRimChualYo(醫林撮要) SamSoMun(三消門)", the concept of SoGal was started to change simple symptoms into the diseases including ethology, pathology and prognosis etc. 3. In the "UiRimChualYo(醫林撮要) SamSoMun(三消門)", the prescriptions of JaEum(滋陰) were thought significantly. On the other hand the prescriptions of HuaYul(火熱) were excluded at all. 4. The use of warm herb like BuJa(附子) was showed through GaGamSinGiHwan(加 減腎氣丸) and succeeded in "DongUiBoGam" the kidney's fire(坎火衰少論) lack theory. The futuristic percetion of "UiRimChualYo(醫林撮要) SamSoMun(三消門)" influenced "DongUiBoGam(東醫寶鑑)" was able to have progress ideas about SoGal.

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Continuous ion-exchange membrane electrodialysis of mother liquid discharged from a salt-manufacturing plant and transport of Cl- ions and SO42- ions

  • Tanaka, Yoshinobu;Uchino, Hazime;Murakami, Masayoshi
    • Membrane and Water Treatment
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    • 제3권1호
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    • pp.63-76
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    • 2012
  • Mother liquid discharged from a salt-manufacturing plant was electrodialyzed at 25 and $40^{\circ}C$ in a continuous process integrated with $SO_4{^{2-}}$ ion low-permeable anion-exchange membranes to remove $Na_2SO_4$ and recover NaCl in the mother liquid. Performance of electrodialysis was evaluated by measuring ion concentration in a concentrated solution, permselectivity coefficient of $SO_4{^{2-}}$ ions against $Cl^-$ ions, current efficiency, cell voltage, energy consumption to obtain one ton of NaCl and membrane pair characteristics. The permselectivity coefficient of $SO_4{^{2-}}$ ions against $Cl^-$ ions was low enough particularly at $40^{\circ}C$ and $SO_4{^{2-}}$ transport across anion-exchange membranes was prevented successfully. Applying the overall mass transport equation, $Cl^-$ ion and $SO_4{^{2-}}$ ion transport across anion-exchange membranes is evaluated. $SO_4{^{2-}}$ ion transport number is decreased due to the decrease of electro-migration of $SO_4{^{2-}}$ ions across the anion-exchange membranes. $SO_4{^{2-}}$ ion concentration in desalting cells becomes higher than that in concentration cells and $SO_4{^{2-}}$ ion diffusion is accelerated across the anion-exchange membranes from desalting cells toward concentrating cells.

반건식 배연탈황법에 의한 연소 페가스 중 $SO_2$제거에 관한 연구 (A Study on $SO_2$Removal in Flue Gas by Semidry Flue Gas Desulfurization Method)

  • 송호철;이윤기;박진원
    • 한국대기환경학회지
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    • 제14권4호
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    • pp.273-280
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    • 1998
  • The investigation on the removal of 502 gas fro.In flue gas which causes serious air pollution was made by using a semi dry flue gas desulfurization method. Experiments were carried out as a function of process variables which would affect SO2 removal efficiency. Process variables inclilded SO2 inlet concentration, inlet temperature of simulated flue gas, sorbent weight fraction, and volume flow rate of sorbent slurry. In this study, used sorbent was Ca(OH), and simulated flue gas was prepared by mixing pure SO2 gas with air. Experimental conditions were varied at 140~18$0^{\circ}C$ of inlet temperature of the simulated flue gas, 500~2000ppm of inlet SO2 concentration, 0.4~1.0% of sorbent concentration, and 10~25 mL/min of flow rate of sorbent slurry. Among process variables, inlet concentration of SO2 was found to be the most significant factor to affect SO2 removal efficiency. The concentration of Ca(OH2) had a lower effect on SO2 removal than SO2 inlet concentration removal amount was 0.108, 0.141, 0.153 g SO2/g Ca(OH)2 respectively- As 200 mmol of HNO3 was added into slurry to improve removal efficiency, initial pH was maintained and solubility of slurry increased, so that removal efficiency elevated. Adding over 200 mmol of HNO3 into slurry caused removal efficiency lower. Therefore it could be concluded the optimum was 200 mmol of HNO3 input.

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톤버스트 응답 신호의 스펙트럼 추정에 의한 배터리의 SoC 측정에 관한 연구 (A Study on SoC Measurement of Battery by Spectrum Estimation of Tone Burst Response Signal)

  • 최경수;강대수
    • 한국인터넷방송통신학회논문지
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    • 제18권1호
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    • pp.217-222
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    • 2018
  • 배터리의 열화는 SoC 및 SoH의 변화에 따라 결정된다. 배터리의 열화를 판정하기 위해 전달 함수에 의한 배터리 SoC를 측정 하는 방법을 연구 하였다. 배터리의 SoC는 DC 저항이 검출되는 1Hz 대역에서 가장 크게 변화 한다. 하지만 관측하기 협소한 대역이기 때문에 톤버스트 신호를 입력신호로 사용하여 배터리의 주파수 응답대역을 대역을 1kHz로 이동 시켰다. 신호의 주파수 영역 특성을 관측을 위해 Welch스펙트럼 추정 방법을 사용하였다. 스펙트럼 추정 결과 배터리의 응답 신호는 SoC가 40%, 60%, 80% 일 때 각각 1dB의 차이를 갖는 것을 확인 하였으며, 이를 통해 새로운 배터리 SoC의 측정 방식을 제안 하였다.

소풍탕(疎風湯)이 고혈압과 동맥혈관에 미치는 영향 (Effects of SoPung-Tang extract on Hypertension and Common Carotid Artery)

  • 최석진;김희택;조학준;김호현
    • 동의생리병리학회지
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    • 제19권6호
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    • pp.1622-1628
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    • 2005
  • This study was undertaken to define the effect of SoPung-Tang extract on hypertension in spontaneous hypertensive rat and norepinephrine- induced arterial contraction in rabbit. In order to investigate the effect of SoPung-Tang extract on contracted rabbit carotid arterial strips, transverse strips with intact or damaged endothelium were used for the experiment using organ bath. To analyze the mechanism of SoPung-Tang extract-induced relaxation, SoPung-Tang extract infused into contracted arterial strips induced by norepinephrine after treatment of indomethacin, Nu-nitro-L-arginine, methylene blue or tetraethylammonium chloride. Blood pressure was significantly decreased five days after administration of SoPung-Tang extract. SoPung-Tang extract relax arterial strip with endothelium contracted by norepinephrine, but in the strips without endothelium, SoPung-Tang extract- induced relaxation was significantly inhibited. SoPung-Tang relax arterial strip contracted by norepinephrine, but in the strips contracted by high $K^+$, SoPung-Tang extract-induced relaxation was significantly inhibited. The endothelium-dependent relaxation induced by SoPung-Tang extract was decreased by the pre-treatment of $N{\omega}$-nitro-L-arginine or methylene blue, but it was not observed in the strips pre-treated with indomethacin or tetraethylammonium chloride. When $Ca^{2+}$ was applied, the strips which were contracted by norepinephrine in a $Ca^{2+}$-free solution, arterial contraction was increased. But pre-treatment of SoPung-Tang extract inhibited contractile response to $Ca^{2+}$. We suggest that SoPung-Tang could be applied effectively for hypertension and may suppress influx of extra-cellular $Ca^{2+}$ through the formation of nitric oxide in the vascular endothelial cells.

Electrochemical Performance of LiMn2O4 Cathodes in Zn-Containing Aqueous Electrolytes

  • Kamenskii, Mikhail A.;Eliseeva, Svetlana N.;Volkov, Alexey I.;Kondratiev, Veniamin V.
    • Journal of Electrochemical Science and Technology
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    • 제13권2호
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    • pp.177-185
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    • 2022
  • Electrochemical properties of LiMn2O4 cathode were investigated in three types of Zn-containing electrolytes: lithium-zinc sulfate electrolyte (1M ZnSO4 / 2M Li2SO4), zinc sulfate electrolyte (2MZnSO4) and lithium-zinc-manganese sulfate electrolyte (1MZnSO4 / 2MLi2SO4 / 0.1MMnSO4). Cyclic voltammetry measurements demonstrated that LiMn2O4 is electrochemically inactive in pure ZnSO4 electrolyte after initial oxidation. The effect of manganese (II) additive in the zinc-manganese sulfate electrolyte on the electrochemical performance was analyzed. The initial capacity of LiMn2O4 is higher in presence of MnSO4 (140 mAh g-1 in 1 M ZnSO4 / 2 M Li2SO4 / 0.1 M MnSO4 and 120 mAh g-1 in 1 M ZnSO4 / 2MLi2SO4). The capacity increase can be explained by the electrodeposition of MnOx layer on the electrode surface. Structural characterization of postmortem electrodes with use of XRD and EDX analysis confirmed that partially formed in pure ZnSO4 electrolyte Zn-containing phase leads to fast capacity fading which is probably related to blocked electroactive sites.

명반석의 열분해 (A Study on the Thermal Decomposition of Alunite)

  • 김형석;조동성
    • 자원리싸이클링
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    • 제7권5호
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    • pp.33-40
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    • 1998
  • 명반석[$K_2$$SO_4$.$Al_2$($SO_4$)$_3$.(OH)$4Al_3$]과 석회석(CaCo$_3$)의 혼합소성에서 무수석고(CaSO$_4$)의 생성은 주로 $SO_3$(g)와 CaO(s)가 발생되는 온도와 속도에 의존된다. 그러므로 본 연구에서는 먼저 명번석의 열분해로 생성되는 물질과 $SO_3$(g)가 이탈되는 온도와 속도를 조사하였다. 상압의 공기분위기에서 명반석은 $500~580^{\circ}C$에서 탈수되어 (SO$KAl_4$)$_2$$Al_2$$O_3$로 분해된다. 이때에 탈수되는 속도는 kt=${1-(1-{alpha}^{1/3})}^{2}}$에 일치하고, 탈수 활성화에너지는 약 73.01kcal/mol로 계산된다. $SO_3$(g)는 $580~700^{\circ}C$에서도 서서히 발생되지만 $700~780^{\circ}C$에서는 급격히 발생된다. KAl($SO_4$)$_2$가 분해되는 속도는 kt=$1-{(1-{alpha})}^{1/3}$에 일치하며, 분해활성화에너지는 약 66.84kcal/mol로 계산된다. 명반석광석에 함유된 $SiO_2$와 kaolinite는 $SO_3$(g)의 발생온도 및 속도에는 거의 영향을 끼치지 않는다.

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담지 코발트 촉매를 이용한 SO2의 원소황으로의 환원반응 특성 (The Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur over Supported Cobalt Catalysts)

  • 박준효;한종대
    • 공업화학
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    • 제10권8호
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    • pp.1129-1135
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    • 1999
  • ${\gamma}-Al_2O_3$, $TiO_2$$SiO_2$에 코발트를 함침시켜 촉매를 제조하고, 고정층 미분반응기에서 CO에 의한 $SO_2$환원반응 특성을 조사하였다. 이때 온도는 $350{\sim}550^{\circ}C$ 영역에서, $SO_2$농도를 1000~10000 ppm, $CO/SO_2$몰비를 1.0~3.0, 공간속도를 $5000{\sim}15000h^{-1}$의 영역에서 사용하였으며 대기압하에서 실행하였다. ${\gamma}-Al_2O_3$$TiO_2$는 코발트 담체로 우수한 특성을 보였으며, 5 wt % 코발트를 ${\gamma}-Al_2O_3$에 함침시켜 얻은 촉매로 $400^{\circ}C$ 이상의 온도에서 90% 이상의 높은 $SO_2$전환율과 6% 이하의 낮은 COS수율을 얻을 수 있었다. $CO/SO_2$의 최적몰비는 양론비인 2.0으로 나타났으며, 몰비가 3.0으로 증가하면 $SO_2$전환율은 증가하였으나 대부분의 반응생성물이 COS로 나타났다. 실험영역의 $SO_2$농도와 공간속도의 변화는 $SO_2$ 전환율과 반응선택성에 큰 영향을 미치지 않았다. 코발트는 활성화된 이후에 $CoS_2$ 상태로 존재하였으며 반응후에도 상변화는 관찰되지 않았다.

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