• Title/Summary/Keyword: SMA-based materials

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Synthesis and Characterization of Water Repellent Materials Containing 2-(Perfluorooctyl) Ethyl Acrylate and m-Isopropenyl-α, α-Dimethylbenzyl Isocyanate (2-(Perfluorooctyl) Ethyl Acrylate (PFOEA) 및 m-Isopropenyl-α, α-Dimethylbenzyl Isocyanate (TMI)가 함유된 발수체 합성 및 특성연구)

  • Kang, Young Taec;Kwak, Eun Mi;Chung, Ildoo
    • Journal of Adhesion and Interface
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    • v.15 no.4
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    • pp.151-160
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    • 2014
  • A series of terpolymers based on stearyl methacrylate (SMA), n-methyol acrylamide (n-MAM), and 2-(perfluorooctyl) ethyl acrylate (PFOEA) were synthesized by changing PFOEA contents up to 8 wt% in order to obtain optimal water-repellent properties. In addition, various contents of m-isopropenyl-${\alpha}$,${\alpha}^{\prime}$-dimethylbenzyl isocyanate (TMI) from 1 to 4 wt% were added to the above terpolymers with 4 wt% of PFOEA content. The emulsion polymerization was carried out using tridecyl alcohol (EO)7 (TDA-7) as a nonionic surfactant, alkyl dimethyl amine derivatives (ADAD) as a cationic surfactant, and 2,2'-azobis(2-amidinopropane dihydrochoride) (AAPDL) as an initiator. The synthesized copolymers were characterized by FT-IR spectroscopies, contact angle, surface energy, and water-repellency. Surface and thermal properties were analyzed by SEM, TGA, and DSC. It was found that water repellency increased with increasing the contents of PFOEA and TMI.

Seismic behavior of steel column-base-connection equipped by NiTi shape memory alloy

  • Jamalpour, Reza;Nekooei, Masoud;Moghadam, Abdolreza Sarvghad
    • Structural Engineering and Mechanics
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    • v.64 no.1
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    • pp.109-120
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    • 2017
  • The behavior of moment resistant steel structures depends on both the beam-column connections and columns foundations connections. Obviously, if the connections can meet the adequate ductility and resistance against lateral loads, the seismic capacity of these structures will be linked practically to the performance of these connections. The shape memory alloys (SMAs) have been most recently used as a means of energy dissipation in buildings. The main approach adopted by researchers in the use of such alloys is firstly bracing, and secondly connecting the beams to columns. Additionally, the behavior of these alloys is modeled in software applications rarely involving equivalent torsional springs and column-foundation connections. This paper attempts to introduce the shape memory alloys and their applications in steel structural connections, proposing a new steel column-foundation connection, not merely a theoretical model but practically a realistic and applicable model in structures. Moreover, it entails the same functionality as macro modeling software based on real behavior, which can use different materials to establish a connection between the columns and foundations. In this paper, the suggested steel column-foundation connection was introduced. Moreover, exploring the seismic dynamic behavior under cyclic loading protocols and the famous earthquake records with different materials such as steel and interconnection equipment by superelastic shape memory alloys have been investigated. Then, the results were compared to demonstrate that such connections are ideal against the seismic behavior and energy dissipation.

Nonlinear earthquake capacity of slender old masonry structures prestressed with steel, FRP and NiTi SMA tendons

  • Preciado, Adolfo;Ramirez-Gaytan, Alejandro;Gutierrez, Nayar;Vargas, David;Falcon, Jose Manuel;Ochoa, Gil
    • Steel and Composite Structures
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    • v.26 no.2
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    • pp.213-226
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    • 2018
  • This paper focuses on the seismic protection of slender old masonry structures by the implementation of prestressing devices at key locations. The devices are vertically and externally located inside the towers in order to be reversible and calibrated. An extensive parametric study on a selected slender tower is carried out based on more than 100 nonlinear static simulations aimed at investigating the impact of different parameters on the seismic performance: (i) different prestressing levels; (ii) shape memory alloy superelasticity and (iii) changes in prestressing-forces in all the stages of the analysis until failure and masonry toe crushing. The tendon materials under analysis are conventional prestressing steel, fiber-reinforced polymers of different fibers and shape memory alloys. The parametric study serves to select the most suitable prestressing device and optimal prestressing level able to dissipate more earthquake energy. The seismic energy dissipation is evaluated by comparing the structural capacity curves in original state and retrofitted.

Influence of Heat Treatment on Transformation Characteristics and Shape Recovery in Fe-X%/Mn-5Cr-5Co-4Si Alloy Ribbons (Fe-X%Mn-5Cr-5Co-4Si 합금 리본의 변태특성 및 형상기억능에 미치는 열처리 영향)

  • Kang, H.W.;Jee, K.K.;Jang, W.Y.;Kang, J.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.3
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    • pp.160-166
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    • 2001
  • The change of ribbon geometry, microstructure and shape recovery with Mn contents, wheel speed and various annealing temperature have been studied in Fe-X%Mn-5Cr-5Co-4Si (X%=15, 20, 24) shape memory alloy (SMA) ribbons rapidly solidfied by single roll chill-block melt-spinning process. The thickness and width of melt-spun ribbons are reduced, results in refining and uniformalizing grains with increasing wheel speed. In the ribbons melt-spun at a wheel speed of 15m/sec, both ${\varepsilon}$ and ${\alpha}^{\prime}$martensites are formed in ribbon 1 (15.5wt%Mn), while only ${\varepsilon}$ martensite is revealed in ribbon 2 (20.2wt%Mn) and ribbon 3 (23.5wt%Mn). The volume fraction of ${\varepsilon}$ martensite is decreased with increasing Mn contents, and those of ${\varepsilon}$ as well ${\alpha}^{\prime}$martensites are increased due to thermal stress relief and grain growth with increasing annealing temperature. Ms temperatures of the ribbons 1, 2 and 3 are fallen with increasing Mn contents. $M_s$ temperatures of the ribbons 1, 2 and 3 annealed at $300^{\circ}C$ for 3 min are risen abruptly, but are nearly constant even at higher annealing temperature, i.e., 400, 500 and $600^{\circ}C$ for 3 min. Shape recovery of the ribbons 1, 2 and 3 increased 30%, 52% and 69% with Mn contents, respectively. Shape recovery of ribbon 1 (15.5wt%Mn) formed ${\varepsilon}$ and ${\alpha}^{\prime}$martensites decreased because of the presence of ${\alpha}^{\prime}$martensite but those of ribbon 2 (20.2wt%Mn) and ribbon 3 (23.5wt%Mn) formed ${\varepsilon}$ martensite increased with increasing annealing temperature.

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Evaluation of Dynamic Modulus based on Aged Asphalt Binder (아스팔트 바인더의 노화특성을 고려한 동탄성계수 평가)

  • Lee, Kwan-Ho;Cho, Kyung-Rae;Lee, Byung-Sik;Song, Yong-Seon
    • Journal of the Korean Society of Hazard Mitigation
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    • v.8 no.3
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    • pp.51-58
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    • 2008
  • Development of a new design guide which is based on empirical-mechanistic concept for pavement design is in action. It is called AASHTO 2002 Design Guide in USA and the KPRP(Korean Pavement Research Project) in Korea. The material characteristic of hot mix asphalt is a key role in the design guide. Therefore it is urgent to get a proper materials database, especially the dynamic modulus of hot mix asphalt. In this research, dynamic modulus test, which is based on aged asphalt binder, has been carried out and proposed the predicted equation of dynamic modulus. Nine different hot mix asphalt with three different asphalt binder have been used for the dynamic modulus test. Short-term aging, which is covers the time for the production of asphalt plant, transportation, lay-down, and compaction, can be simulated at $135^{\circ}C$ with 2 hour curing. Long-term aging has been carried out for a performance period of asphalt pavement. The dynamic modulus of asphalt pavement increases with aging time. As the nominal aggregate size increases, the change of dynamic modulus is not big.