• Bulletin of the Korean Chemical Society
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• v.18 no.8
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• pp.868-873
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• 1997

Nucleophilic substitution reactions of 1-phenylethyl chlorides (1-PEC; YC6H4CH(CH3)Cl) with phenoxides (XC6H4O-) and thiophenoxides (XC6H4S-) are investigated theoretically using the PM3 method. The Bronsted α and β values are greater for the phenoxides indicating a more advanced reaction in the transition state (TS) than for the thiophenoxides. This is supported by a greater magnitude of ρX (- 6.4 ∼ - 7.4) and ρXY (- 0.76) for the phenoxides than for the thiophenoxides (ρX = - 3.6 ∼ - 4.4 and ρXY = - 0.60). The percentage bond order changes, %Δn≠, suggest that the extents of bond making and breaking are similar for the phenoxides and hence the TS is symmetrical, but bond making is somewhat greater than bond cleavage for the thiophenoxides indicating an unsymmetrical TS. The reactions in the gas phase for both nucleophile series proceed by a SN2 mechanism with a tight TS and negative charge development on the reaction center carbon, Cα. The reactions in water investigated with model systems of benzyl and 1-phenylethyl chlorides using the Cramer-Truhlar solvation model (PM3-SM3) indicate that the reactions of 1-PEC are far more complex due to enhanced stabilization of the carbocation by the methyl substitution for a benzylic hydrogen.

• Proceedings of the KIPE Conference
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• 2019.07a
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• pp.195-197
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• 2019

자동차용 배터리는 초기 용량의 80% 이하가 되면 교체하게 되며, 근간 폐배터리의 수가 폭발적으로 증가할 것으로 예측되고 있다. 폐배터리의 폐기로 인한 환경 파괴를 방지하고 자원을 재활용하기 위해서 자동차에서 나오는 폐배터리를 에너지저장장치(ESS)로 재사용 하는 것에 대한 관심이 높아지고 있다. 폐배터리를 ESS로 재구성하기 위해서는 폐배터리 모듈의 그레이딩을 통해 비슷한 성능의 모듈끼리 모아서 구성하는 것이 매우 중요하다. 배터리 모듈 간의 불균형은 전체 시스템의 성능을 저하시키며, 따라서 비슷한 성능과 잔존 수명을 가진 모듈을 골라내는 일은 폐배터리의 재사용에 있어서 첫 번째 선결 과제가 된다. 본 연구에서는 폐배터리의 상태 및 잔존수명평가를 위해 배터리 모듈의 임피던스 스펙트럼을 측정할 수 있는 장비를 개발하였다. 폐배터리 모듈에 AC 섭동을 인가하고 이를 측정하여 임피던스 스펙트럼을 계산할 수 있는 하드웨어와 소프트웨어를 개발하였다. 개발 장비는 60V이하의 폐배터리 모듈의 임피던스 스펙트럼을 0.1Hz에서 1kHz까지 측정 가능하며, 측정 결과를 바탕으로 커브 피팅을 통해 등가회로의 파라미터도 계산할 수 있다. SM3에서 얻어진 폐배터리 모듈을 이용하여 측정한 임피던스 스펙트럼을 상용장비인 BIM2로 측정한 결과를 비교하였고, Reduced Chi-Square를 이용한 분석결과 두 데이터가 거의 일치함을 알 수 있었다.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.20 no.2
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• pp.23-31
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• 2021

Surface texturing is a promising route to reduce the friction forces between two surfaces in sliding contact. To this end, the fabrication of micro dimples is one of the most widely used surface texturing methods. According to published results, textured surfaces with elliptical micro dimples offer the best friction performance. Therefore, we fabricated elliptical micro dimples on carbon steel (SM45C) by using dual frequency vibration assisted machining. High and low frequencies of 16.3 kHz and 230 Hz were applied to the 3D resonant elliptical vibrator. The 3D resonant elliptical vibrator with a triangular cubic boron nitride insert was assembled on a computer numerically controlled turning lathe. Oval micro dimples of various profiles were manufactured on carbon steel. In terms of the profile of the elliptical micro dimples, the experimental results indicated that the average micro dimple width and depth were 112 ㎛ and 7.7 ㎛. These dimensions are closely related to the cutting conditions and can be easily controlled.

• International Journal of Korean Welding Society
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• v.2 no.1
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• pp.15-20
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• 2002

This paper describes the weldability and mechanical behavior of JIS S45C medium carbon steel (corresponding to KS SM45C and SAE 1045) for machine structures in CW Nd:YAG laser welding. In general, medium carbon steels have a limited application to the industrial fields in spite of good mechanical characteristics. This is due to welding difficulty because of the high carbon contents and impurities in this material. Therefore, in this study the laser weldability of medium carbon steel with adjusted contents of S and P has been investigated in order to extend the application to medium carbon steels. Several experiments and numerical simulations have been conducted to determine the characteristics of mechanical behavior in CW Nd:YAC laser welds. The results of the simulations concur with the experiment results. From the result of this study, the application possibility of CW Nd:YAG laser welding to medium carbon steel has been confirmed. Also, the appropriateness of mechanical behavior simulation has been verified to analyze and predict the welding phenomena.

• Annual Conference of KIPS
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• 2008.05a
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• pp.913-916
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• 2008

TPS(Triple Play Service)를 통한 IP-TV,인터넷, 전화 등이 통합되는 추세에서, IPv6 상용네트워크가 수 년 안에 구축될 필연성을 공감하고 있다. 그러나 [1] 현재 IP-TV 서비스에서 Delay, Jitter,전송장애등 QoS에 대한 사용자 불만이 계속 발생하고 있다. 또한 현재 서비스중지 (DoS : Denial of Service)를 유발하는 [2] 인터넷 침해 사고가 월 평균 2157건 이상 발생하는 등, Security Issue의 증가 문제가 지속 되고 있다. IPv4/IPv6 듀얼 스택 멀티 캐스트 네트워크를 구현하여, 라우팅, 멀티캐스트(PIM-SM), QoS, Security 이슈에 대한, 최적의 방안을 도출하여, 라우팅 구현시 IPv6 라우팅 프로토클 간에 재분배(Redistribution) 장애 해결책, IPv6 특성에 따른 멀티캐스트 그룹주소 지정시의 장애대책을 제시하였고, QoS 에서는 기존의 QoS 정책의 문제점과 IPv6의 고유한 패킷 구조의 장점을 활용한 Adaptive QoS 방법을 제시하고, IPv6 멀티캐스트 서비스 중지 공격 유형을 정의하여, 최적화된 IPv6 멀티캐스트 구성 모델을 제시 하였다. 결론적으로 구현된 시스템에서 IPv6 패킷 분석을 통해서 최적화된 경로 통신 및 차별화된 IPv6 패킷의 QoS 방안을 제시하였으며, 서비스 중지공격을 대응하는 Security 보장성을 갖고 있음을 검증하여, 향후 상용화된 IPv4/IPv6 네트워크 구현을 위한 최적화 방안을 제시 하였다.

• Korean Journal of Veterinary Service
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• v.47 no.1
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• pp.9-17
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• 2024

Porcine epidemic diarrhea (PED) is a highly contagious enteric viral disease of pigs with watery diarrhea in piglets, which ultimately results in huge economic losses in the swine industry. The spike (S) protein plays an important role in viral pathogenicity, tissue tropism, infection, dissemination and the trypsin-dependent proliferation of the PED virus (PEDV). In the present study, we determined the full-length spike (S) gene sequences of twenty PEDV field strains detected in Jeonbuk province in 2022. Phylogenetic analysis showed that the twenty PEDV field strains were classified into G2b group and shared 98.6~100% of nucleotide homology and 97.4~100% of amino acid homology with each other. Mutations of amino acid sequences on the neutralizing epitope of S protein were observed in the twenty field strains compared to the previous vaccine strain SM-98-1 (G1a group). Therefore, these amino acid mutations in the PEDV S protein may result in a new genotype of the virus and highly pathogenic virus, so continuous monitoring is required.

• Nuclear Engineering and Technology
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• v.56 no.7
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• pp.2625-2632
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• 2024

In this study, we investigated the possibility of employing accident tolerant fuel (ATF) in VVER-1200/V491 assembly without gadolinium-containing fuel rods using the Monte Carlo code Serpent 1.1.7 with ENDF/B-VII cross-section library. The analysis involves assembly design with reflective boundary conditions. To compare the neutronic performances, U-5Mo, U-7.5Mo, U-10Mo, and U-15Mo fuels were chosen in addition to ordinary UO₂ fuel. The concentration of ¹³⁵Xe, ¹⁴⁹Sm, fissile and fertile isotopes with burnup, reactivity feedback with fuel temperature variation, and β eff values were calculated. The results indicate that the fuel cycle length increases by 54.27% for U-5Mo, 32.6% for U-7.5Mo, and 13.8% for U-10Mo, while it decreases by 16.4% for U-15Mo fuel. Additionally, the effect of ⁹⁵Mo content in natural Mo was investigated by reducing the ⁹⁵Mo concentration. According to the results, each proposed fuel's fuel cycle length extended when the depletion ratio of ⁹⁵Mo increased. Additionally, the calculations for reactivity feedback guarantee safe operating conditions for all U-xMo fuels.

• Restorative Dentistry and Endodontics
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• v.33 no.2
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• pp.148-161
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• 2008

The purpose of this study was to evaluate the effect of chlorhexidine (CHX) on microtensile bond strength (${\mu}TBS$) of dentin bonding systems. Dentin collagenolytic and gelatinolytic activities can be suppressed by protease inhibitors, indicating that MMPs (Matrix metalloproteinases) inhibition could be beneficial in the preservation of hybrid layers. Chlorhexidine (CHX) is known as an inhibitor of MMPs activity in vitro. The experiment was proceeded as follows: At first, flat occlusal surfaces were prepared on mid-coronal dentin of extracted third molars. GI (Glass Ionomer) group was treated with dentin conditioner, and then, applied with 2 % CHX. Both SM (Scotchbond Multipurpose) and SB (Single Bond) group were applied with CHX after acid-etched with 37% phosphoric acid. TS (Clearfil Tri-S) group was applied with CHX, and then, with adhesives. Hybrid composite Z-250 and resin-modified glass ionomer Fuji-II LC was built up on experimental dentin surfaces. Half of them were subjected to 10,000 thermocycle, while the others were tested immediately. With the resulting data, statistically two-way ANOVA was performed to assess the ${\mu}TBS$ before and after thermo cycling and the effect of CHX. All statistical tests were carried out at the 95 % level of confidence. The failure mode of the testing samples was observed under a scanning electron microscopy (SEM). Within limited results, the results of this study were as follows; 1. In all experimental groups applied with 2 % chlorhexidine, the microtensile bond strength increased, and thermo cycling decreased the micro tensile bond strength (P > 0.05). 2. Compared to the thermocycling groups without chlorhexidine, those with both thermocycling and chlorhexidine showed higher microtensile bond strength, and there was significant difference especially in GI and TS groups. 3. SEM analysis of failure mode distribution revealed the adhesive failure at hybrid layer in most of the specimen. and the shift of the failure site from bottom to top of the hybrid layer with chlorhexidine groups. 2 % chlorhexidine application after acid-etching proved to preserve the durability of the hybrid layer and microtensile bond strength of dentin bonding systems.

• The Journal of Society for e-Business Studies
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• v.16 no.1
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• pp.1-15
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• 2011

The new environment of music service has brought changes in digital music industry. Today, various forms of music contents are presented in ubiquitous environments. Thus, securing various contents becomes very important in monopolistic competition of music market. Under the circumstance, web 2.0 provides a networking environment to form diverse relations. Social Network Service (SNS) is a service to emphasize people relation and is different from information-centered Internet service. And mobile SNS becomes popular as Smartphone rapidly increases. NeowizBugs merged with NeowizInternet managing Sayclub of a music-specified SNS site. And the firm confirms comprehensive contents by making ties with SM entertainment. Thus, the integration corporation secures and manages a new business model by linking digital contents with SNS. Generally, music-specified SNS has advertisement business model and uses a recommend system utilizing the database of users. By introducing the case of NeowizBugs, this study tries to identify the success strategy of music distributors fitting ubiquitous environment including web 2.0, mobile SNS, Smartphone, etc.

• Proceedings of the Korea Water Resources Association Conference
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• 2009.05a
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• pp.415-420
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• 2009

공학 분야에 있어서 수치 해석적 연구가 많은 주목을 받고 있다. 경제적 측면을 비롯한 다양한 측면에 있어서 모의의 간편성으로 인해 하천에서의 수리학적 거동모의에 수치해석 모의 분석법이 쓰이고 있는데 모의결과의 비교 및 검증을 위해서는 현장 실험 혹은 모형실험이 선행되어야만 한다. 본 연구에서는 강재로 제작된 S자 형태의 만곡부를 두 개 갖고 있는 사행수로 실험 장치를 제작하여 두 가지 유량조건 (30, 60 ${\ell}$/sec.)과 두 가지 하류단 수위조건 (30, 40 cm)에 대하여 수평 2차원 유속분포 자료를 이용하였다. 유속장의 자료는 Sontek사에의 3차원 micro-ADV(Acoustic Doppler Velocimeter)를 이용하여 측정하였다. 주 흐름은 직선구간에서는 중앙에서 최대 유속을 나타내며, 좌우대칭적인 유속분포의 모습을 보이고, 만곡부에서는 수로안쪽을 따라 최대유속이 발생하였다. 이는 만곡부의 정점부분에서의 이차류 발생 및 소멸에 의한 연직방향 유속분포를 통해 발생되는 현상이라 사료된다. 또한 본 연구에서는 2차원 하천해석 상용프로그램인 RAMS (베타버젼)와 SMS를 이용하여 흐름해석을 수행하였다. 실험 자료와의 비교를 통하여 두 가지 상용프로그램의 경우 모두 다소 과대 산정되는 것을 알 수 있었고, 만곡부와 직선부의 유속분포에 대한 모의결과는 RAMS (RAM2)의 결과가 보다 실험결과와 잘 일치하는 것으로 분석되었다. 위와 같은 유속분포의 분석을 통하여 각각의 상용소프트웨어의 적용성을 비교해 보았으며 향후 오염물질 거동해석 모형을 실험수로에 적용하여 그 결과를 비교할 수 있을 것으로 예상한다.