• 한국연소학회:학술대회논문집
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• 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
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• pp.257-262
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• 2003

Engine-out HC emissions were investigated during engine start. The tests were conducted on a 1.5L, 4-cylinder, 16 valve, multipoint-port-fuel-injection gasoline engine at different coolant temperatures and fuel injection-skip methods; no skip, 1 cycle-skip and 3 cycle-skip. To understand the characteristics of engine-out HC emissions, HC concentration was measured at a exhaust port using a Fast Response Flame Ionization Detector (FRFID). The result show that HC emissions were emitted at the cold coolant temperature much higher than those of the hot coolant. In additions, the fuel injection skip highly reduced engine-out HC emissions. It is convinced that optimized fuel injection skips according to coolant temperatures could be applied to reduce HC emissions during SI engine start.

• 한국경영과학회:학술대회논문집
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• 대한산업공학회/한국경영과학회 1996년도 춘계공동학술대회논문집; 공군사관학교, 청주; 26-27 Apr. 1996
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• pp.225-229
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• 1996

In order to accomplish large-size information systems successfully, one of the most improtant factor is the system integration(SI) of individual software projects which consist of the systems. A developer of each project should consider aspects of SI through the development cycle, and a manager of the entire system should manage, control, and evaluate each from a SI point of view. In this research, management models for the system managers, development models for the developers of unit projects, and standardized output documents for the management and evaluation purpose are presented based on the SI concepts.

• 한국응용과학기술학회지
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• 제32권4호
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• pp.718-723
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• 2015

For the fabrication of the Si negative electrode in Li-ion batteries (LIBs) containing the cross-linking polymer binder, in this work, the urethane acrylate (UA) oligomer was synthesized via a simple synthetic process. The cross-linked poly(urethane acrylate) (CPUA)/carbone black (CB)/Si composite (CPUA/CB/Si composite) was fabricated through reactions between their reactive vinyl segments in the UA oligomer. Interestingly, the CPUA/CB/Si composite showed better cycle performance than the poly(vinylidene fluoride) (PVdF)/CB/Si composite (PVdF/CB/Si composite) and the polyurethane (PU)/CB/Si composite (PU/CB/Si composite). The CPUA/CB/Si composite had the best lithiation of about $2586mAh\;g^{-1}$. The UA oligomer showed a good compatibility with the electrode materials and current collector after and before a curing process.

• 마이크로전자및패키징학회지
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• 제10권3호
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• pp.1-7
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• 2003

잉크젯 헤드의 발열체에 적용하기 위해 $poly-Si/SiO_2/Si$ 다층기판 위에 결정화된 안정한 코발트실리사이드$(CoSi_2)$ 박막을 형성하여 오메가 형태의 발열체를 제작하고 발열체의 구조적 형상과 온도저항계수 등 전기적 특성을 조사, 연구하였다 $(CoSi_2)$ 박막의 형성은 금속 Co 박막을 급속 열처리장치를 이용하여 $800^{\circ}C$에서 20초 동안 질소 분위기에서 열처리하여 실리사이드 박막을 형성하였다. 발열체의 온도 저항계수 값은 약 $0.0014/^{\circ}C$ 값을 얻을 수 있었다. 인가전압 10 V, 주파수 10KHz 및 펄스간격 $1{\mu}s$ 인가시 발열체의 순간전력은 최대 2W를 나타내었다. 반복된 전압인가에 따른 발열체의 피로특성을 조사한 결과 15 V 이하의 전압인가시 $10^8$ 펄스 cycle 까지 저항변화가 거의 없었으나 17 V 인가전압에서는 $10^6$ cycle에서 발열체의 저항이 급격히 증가하였다.

• Korean Chemical Engineering Research
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• 제56권1호
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• pp.139-142
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• 2018

Silicon (Si) is a promising anode material for next-generation lithium ion batteries (LIBs) because of its high capacity of 4,200 mAh/g ($Li_{4.4}Si$ phase). However, the large volume expansion of Si during lithiation leads to electrical failure of electrode and rapid capacity decrease. Generally, a binder is homogeneously mixed with active materials to maintain electrical contact, so that Si needs a particular binding system due to its large volume expansion. Polyvinyl alcohol (PVA) is known to form a hydrogen bond with partially hydrolyzed silicon oxide layer on Si nanoparticles. However, the decrease of its cohesiveness followed by the repeated volume change of Si still remains unsolved. To overcome this problem, we have introduced the electrospinning method to weave active materials in a stable nanofibrous PVA structure, where stresses from the large volume change of Si can be contained. We have confirmed that the capacity retention of Si-based LIBs using electrospun PVA matrix is higher compared to the conservative method (only dissolving in the slurry); the $25^{th}$ cycle capacity retention ratio based on the $2^{nd}$ cycle was 37% for the electrode with electrospun PVA matrix, compared to 27% and 8% for the electrodes with PVdF and PVA binders.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1994년도 추계학술대회 논문집
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• pp.59-64
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• 1994

The Si-SiO$_2$interface trpas of the degraded short-channel SONOSFET memory devices were investigated using the charge pumping techniques. The degradation of devices with write/erase cycle appeared as the increase of the Si-SiO$_2$interface trap density. In order to determine the capture cross-section of the interface trap. I$\_$CP/-V$\_$GL/ characteristic curves were measured at different temperatures. Also, the spatial distributions of Si-SiO$_2$interface trap were examined by the variable-reverse bias boltage method.

• 한국자동차공학회논문집
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• 제4권3호
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• pp.122-129
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• 1996

The spark timing is one of major parameters to the engine performance and emissions. The ECU controls the spark timing based on preset values, which are functions of load and speed, in most of today's automotive SI engine. In this system, the preset spark timing can be different from optimum value due to the deviations from mass production, aging effects and so on. In the present study, a control logic is investigated for real time adaptation of spark timing to optimal value. It has been found that crank angle of miximum cylinder pressure is one of the appropriate parameters to estimate the optimum spark timing throught experiment. It has also been observed for spark timing convergence by variation of engineering model factors. The simulation program including engineering model for cycle by cycle variation of combustion is developed for surveying spark timing control logic. It is also shown that simulation results reflect experiment outputs and reasonableness of spark timing control logic for crank angle of maximum cylinder pressure.

• Korean Chemical Engineering Research
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• 제62권1호
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• pp.19-26
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• 2024

본 연구에서는 리튬이온배터리용 고용량 음극활물질인 실리콘의 부피팽창을 완화하고 사이클 안정성을 향상시키기 위해 SiOx@C 복합소재를 제조하였다. Stӧber 법을 통해 입자 크기가 각각 100, 200, 500 nm인 SiO₂를 합성하였고, 마그네슘 열환원을 통해 SiOx (0≤x≤2)를 제조하였다. 그 후 SiOx에 PVC를 탄화시켜 SiOx와 C의 비율에 따라 SiOx@C 음극활물질을 합성하였다. 제조된 SiOx와 SiOx@C 음극활물질의 물리적 특성은 XRD, SEM, TGA, 라만분광법, XPS, BET를 사용해 분석하였다. 그리고 사이클 테스트, 율속특성, CV, EIS 테스트를 통해 전기화학적 특성을 조사하였다. 입자 크기가 가장 작은 100 nm SiOx에 SiOx:C=70:30으로 탄소를 코팅하여 제조된 SiOx@C-7030은 100 사이클에서 1055 mAh/g의 방전용량과 81.9%의 용량을 유지하여 가장 우수한 전기화학적 특성을 보여주었다. 이는 SiOx 음극활물질 입자의 크기를 줄이고, 탄소를 코팅하여 사이클 안정성을 향상시킬 수 있다는 것을 의미한다.

• 한국세라믹학회지
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• 제47권4호
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• pp.319-324
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• 2010

Screen printable $MoSi_2$ paste and its ceramic sheet heater were investigated. $MoSi_2$ powder without $Mo_5Si_3$ second phase, which causes so-called pest phenomena, was synthesized by SHS technique. Over glaze was also developed for preventing pest phenomenon. The maximum temperature of $MoSi_2$ ceramic heater was over $500^{\circ}C$. After several heat up and cooling cycle, the $MoSi_2$ heater reveals pest phenomenon. Conductive $MoSi_2$ paste could be used in electronic ceramics, i.e., MLCC, LTCC, HTCC, and etc.

• 전기화학회지
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• 제26권3호
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• pp.35-41
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• 2023

리튬이온 이차전지용 음극 활물질인 탄소가 코팅된 실리콘 일산화물(carbon-coated silicon monoxide, c-SiO_x)은 용량이 높지만, 충방전 중의 부피변화로 인해 사이클 수명이 제한된다. 특히, 활물질의 큰 부피 변화는 전극의 구조를 변형시켜 전자의 전달경로가 쉽게 손상될 수 있다. 전극에서 전자전달 경로를 형성하는 도전재인 카본블랙 중 일부를 선형의 형태를 지니는 탄소나노튜브(carbon nanotube, CNT)로 대체하여 활물질의 부피변화로 인한 전극의 손상을 완화하여 성능을 개선하고자 한다. 전극 내의 전체 도전재의 함량을 10 중량%로 고정하고, 탄소나노튜브의 상대적인 함량을 0, 2, 5, 10, 25 중량%로 카본블랙의 일부를 대체하여 전극을 제조하고 전기화학적 성능을 평가하였다. 전극 내의 탄소나노튜브의 함량이 증가함에 따라 사이클 수명과 속도특성이 모두 향상된다. 부피 변화가 큰 c-SiO_x 음극에 소량의 CNT를 도전재로 적용하는 것으로 전지의 전기화학적 성능을 크게 향상시킬 수 있다. 또한 CNT를 잘 분산시키게 되면 더 적은 양을 사용하면서도 동등한 성능을 구현할 수 있다.